Abstract: The invention is a process for removing a chromium containing coating from an aluminum article. The chromium containing coating is removed from the aluminum article by contacting the aluminum article having the chromium containing coating with an alkaline treating bath to form an ultrasonically removable chromium containing coating and treating the aluminum article with the ultrasonically removable coating with ultrasonic vibrations to remove the chromium containing coating.
Abstract: An otherwise conventional Jernstedt salt dispersion for activating metal surfaces to improve the quality of subsequently deposited phosphate conversion coatings on the activated metal surface is stabilized against deterioration in storage for at least six months by utilizing in the dispersion a mixture of sodium and potassium salts, preferably condensed phosphate salts, in such amounts that the ratio of potassium to titanium is within the range from 8.0:1.0 to 40:1.0 and the ratio of potassium to sodium is within the range from 0.9:1.0 to about 2.5:1.0.
Abstract: A nickel and/or cobalt deposition process which can be run at a nearly neutral pH and which rapidly deposits nickel and/or cobalt in quantities large enough to improve the paint adhesion and post coating corrosion resistance, and which has a good solution stability, is achieved by treating zinc coated sheet steel with an aqueous solution that has a pH between 5 and 10 inclusive and comprises (A) a total of at least 0.01 g/L of metal ions selected from the group consisting of Ni.sup.2+ and Co.sup.2+ ions and (B) a sufficient amount to fully complex the metal ions recited in part (A) of complexing agents selected from the group consisting of ammonia and organic compounds having at least one amino group in the neutral region.
Abstract: This invention is directed to a method for treating fibers by applying thereto a compound having the general formula ##STR1## wherein R.sub.1 is an alkyl group from 1 to 23 carbon atoms, R.sub.2 is an alkyl group from 1 to 23 carbon atoms, n is a number from 3 to 15, m is a number from 1 to 6, Y is --O-- or --S--, and X is --C.sub.2 H.sub.4 O-- or --C.sub.3 H.sub.6 O--, or a mixture of --C.sub.2 H.sub.4 O-- and --C.sub.3 H.sub.6 O--.
Abstract: Concentrated hard surface cleaning compositions containing pine oil and/or terpenes and nonionic and a anionic surfactants can be obtained as clear liquids which remain clear when diluted with water.
Abstract: In the cold drawing of steel tubing, an excellent lubrication which permits drawing the tubing while retaining its original metallic luster can be achieved by first contacting the surfaces of the tubing, both exterior and interior, with a colloidal titanium containing aqueous composition, drying the tubing, and then applying to the surface of the tubing a liquid lubricating composition comprising (i) from 40 to 95% of a first component selected from the group consisting of olefin/oil or olefin/fat compounds which contain from 23 to 30% of sulfur and olefin/higher ester compounds which contain from 23 to 30% sulfur, including mixtures of two or more chemical species meeting this description; and (ii) from 5 to 50% of a second component selected from the group consisting of oil soluble polymer compounds, fats and oils, synthetic oils, mineral oils, higher fatty acids, and the amine salts of higher fatty acids.
Type:
Grant
Filed:
November 30, 1992
Date of Patent:
May 3, 1994
Assignee:
Henkel Corporation
Inventors:
Yoshio Nagae, Koji Kaburagi, Koji Hetsugi
Abstract: The invention is a process for reducing the fatty alcohol content of a mixture of fatty alcohol and fatty glycoside product by passing the mixture through a forced circulation evaporation zone to form a mixture of fatty alcohol and fatty glycoside product with a reduced fatty alcohol content and passing the mixture with the reduced fatty alcohol content to a wiped film evaporator to remove additional fatty alcohol.
Abstract: An improved process for preparing esters of an alcohol and a carboxylic acid employing sulfuric acid in an amount effective to both catalyze the reaction and to remove or immobilize the water of reaction whereby an ester is provided in increased yield and purity. Esters of long chain acids are useful for the preparation of diketones which find utility as metal extractants.
Abstract: An improved process for oximation of carbonyl compounds, such as ketones and aldehydes by oximation with hydroxylamine including oximation processes carried out in the presence of a catalytic amount of an acid phase transfer catalyst, such as 2-ethylhexanoic acid, and/or the presence of an alkali metal or alkaline earth metal catalyst. The resulting oximes are useful as metal extractants.
Abstract: An aqueous liquid composition containing polyethylene glycol with a molecular weight in the range of about 200 to about 8000, nonionic surfactant, and a corrosion inhibitor, and optionally, amphoteric surfactants and fluorinated surfactants is useful as a highlighting liquid for detection of surface irregularities on shaped metal surfaces and for preventing adhesion of weld splatter on surfaces coated with the composition. Preferably the corrosion inhibitor includes alkali metal salts of boric acid and of a mixture of branched chain carboxylic acids and amino acids.
Abstract: Pinhole and blister formation during autodeposition coating of galvanized steel and similar zinciferous surfaces can be greatly reduced by exposing the zinciferous surfaces to a pinhole inhibiting aqueous HF solution containing a suitable additive before using an autodeposition process itself. The most effective additives are boric acid, polyphosphonic acids, and polyethyleneimine.
Abstract: A composition for treatment and after treatment of surfaces, especially metals, with derivatives of polyphenol compounds is provided. The derivatives include substituted aminomethyl groups on at least some of the phenyl rings in the polyphenol polymers, with molecular weights within the range of about 700 to about 70,000 being preferred. The compositions are particularly useful for treating chromated aluminum surfaces prior to painting, to improve corrosion resistance, and when combined with surfactants, for treating plastic and painted surfaces to improve rinsability without water breaks.
Type:
Grant
Filed:
July 8, 1993
Date of Patent:
March 29, 1994
Assignee:
Henkel Corporation
Inventors:
Andreas Lindert, Gerald J. Cormier, John R. Pierce
Abstract: A full bridge switching power supply is coupled to an ozonator load via a series resonant circuit having a resonant frequency above the switching frequency. Power output is controlled by varying the duration of the times when diagonal switches are conducting, and the output voltage has a longer rise time than fall time due to there being intervals between the conduction periods of diagonal switches during which one of the switches is turned on to permit resonant current flow. The driving voltages for attaining this action are symmetrical rectangular waves of identical shape having different phases that are derived from out of phase pulses where width is varied by the timing of their trailing edges.
Abstract: Heating an aqueous mixture of a fluoroacid such as H.sub.2 TiF.sub.6 and an oxide, hydroxide, and/or carbonate such as silica produces a clear mixture with long term stability against settling of any solid phase, even when the oxide, hydroxide, or carbonate phase before heating was a dispersed solid with sufficiently large particles to scatter light and make the mixture before heating cloudy. The clear mixture produced by heating can either be mixed e with water soluble and/or water dispersible polymers that are polyhydroxyalkylamino- substituted polymers and/or copolymers of p-vinyl phenol, or with soluble hexavalent and/or trivalent chromium, to produce a composition that improves the corrosion resistance of metals treated with the composition, especially after subsequent painting.
Abstract: An ozonator power supply including a step-up transformer having one end of its primary winding connected to one side of an AC supply, its other end connected to the other side of the AC supply via a pair of switches connected in antiparallel, and a controller for providing switching pulses to said switches for making them conductive during variable portions of alternate half cycles of the AC voltage provided by said supply. An inductor is included in the circuit with the primary or secondary winding of the transformer that resonates with the capacitive impedance of an ozonator, for presenting a substantially non-reactive load to said AC supply.
Abstract: A test unit for a monitoring device includes reference and measuring electrodes coupled to a preamplifier and a temperature compensating resistor for the preamplifier. The test unit has components corresponding to those of the monitoring device as well as a power supply and a voltmeter coupled to the output of its preamplifier. Cables are provided for substituting either or both electrodes of the monitoring device for the electrodes of the test device, and a switch is provided for substituting a temperature compensation resistor of the monitoring device for the temperature compensation resistor of the test device. A cable is adapted for connection to either preamplifier for supplying it with operating potentials derived from the power supply and for coupling the output of either preamplifier to the voltmeter.
Abstract: Improved chromate conversion coating composition for forming non-cracking conversion coatings on aluminum or its alloys. Improvement is obtained by control of the total acid (TA) and free acid (FA) levels to a minimum of 6.0 and 3.5 respectively with a TA:FA ratio in the range of 1.5 to 2.5 by inclusion of aluminum nitrate in the composition.
Abstract: A metal treatment solution comprising an effective amount of a soluble or dispersible compound which is a derivative of a polyphenol. A composition for treatment and after treatment of metal with polyphenol compounds is provided. The present invention includes novel derivatives of polyphenol compounds which are useful in surface treatment solutions of dispersions. A method for using these solutions or dispersions is also provided. The molecular weight of the polyphenols used to form the derivatives of the present invention are in the range of from about 360 to 30,000 or greater. The resulting derivatives of the present invention typically have a molecular weight of up to about 2,000,000 with molecular weights within the range of about 700 to about 70,000 being preferred.
Type:
Grant
Filed:
March 18, 1992
Date of Patent:
November 30, 1993
Assignee:
Henkel Corporation
Inventors:
Andreas Lindert, John R. Pierce, David R. McCormick, William D. Zimmermann