Patents Assigned to The Kansai Electric Power Co., Inc.
  • Patent number: 8623286
    Abstract: A system for collecting carbon dioxide in flue gas includes a stack that discharges flue gas discharged from an industrial facility to outside, a blower that is installed at the downstream side of the stack and draws the flue gas therein, a carbon-dioxide collecting device that collects carbon dioxide in the flue gas drawn in by the blower, and a gas flow sensor arranged near an exit side within the stack. A drawing amount of the flue gas by the blower to the carbon-dioxide collecting device is increased until an flow rate of the flue gas from the stack becomes zero in the gas flow sensor, and when the discharged amount of flue gas from the stack becomes zero, drawing in any more than that amount is stopped, and the carbon dioxide in the flue gas is collected while the flue gas is drawn in by a substantially constant amount.
    Type: Grant
    Filed: February 10, 2009
    Date of Patent: January 7, 2014
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Takashi Kamijo, Yasuyuki Yagi, Kouki Ogura
  • Publication number: 20130340623
    Abstract: A CO2 recovery device includes a cooling tower including a cooling unit for bringing the flue gas, which contains CO2, into contact with water so as to cool flue gas; a CO2-absorbing unit for bringing the flue gas into contact with a CO2 absorbent (lean solution) so as to remove CO2 from flue gas; and a regenerator including an absorbent regenerating unit for releasing CO2 from a rich solution so as to regenerate the CO2 absorbent. The CO2-absorbing unit includes: a cocurrent flow CO2-absorbing unit provided in a cocurrent flow CO2 absorber, for bringing the flue gas into contact with the CO2 absorbent in a cocurrent flow so as to remove CO2 from flue gas and a countercurrent CO2-absorbing unit provided in a CO2 absorber, for bringing the flue gas into contact with the CO2 absorbent in a countercurrent flow so as to remove CO2 from flue gas.
    Type: Application
    Filed: April 11, 2012
    Publication date: December 26, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Tatsuya Tsujiuchi, Hiroshi Tanaka, Hiromitsu Nagayasu, Takuya Hirata, Tsuyoshi Oishi, Masahiko Tatsumi, Koji Kadono
  • Patent number: 8597418
    Abstract: An absorbent according to the present invention absorbs CO2 or H2S contained in flue gas emitted from a power generating plant such as a thermal plant, and contains three or more amine compounds selected from linear or cyclic amine compounds having a primary amino group, and linear or cyclic amine compounds having a secondary amino group. By way of a synergetic effect of the mixture of these compounds, the absorption speed of CO2 or H2S absorption is improved. A small amount of CO2 contained in a large amount of boiler flue gas can be absorbed efficiently.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: December 3, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Yukihiko Inoue, Ryuji Yoshiyama, Tsuyoshi Oishi, Masaki Iijima, Masazumi Tanoura, Tomio Mimura, Yasuyuki Yagi
  • Publication number: 20130291717
    Abstract: A CO2 recovery system includes an absorber 2 and a regenerator 3. The absorber 2 includes a CO2 absorbing section 21 and at least one water-washing section 22. The CO2 absorbing section 21 allows flue gas 101 to come into contact with a basic amine compound absorbent 103 so that the basic amine compound absorbent 103 absorbs CO2 in the flue gas 101. The at least one water-washing section 22 allows the decarbonated flue gas 101A in which the amount of CO2 has been reduced in the CO2 absorbing section 21 to come into contact with wash water 104A and 104B to reduce the amounts of the basic amine compounds entrained in the decarbonated flue gas 101A. The regenerator 3 releases the CO2 from the basic amine compound absorbent 103 containing CO2 absorbed therein.
    Type: Application
    Filed: July 10, 2013
    Publication date: November 7, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Hiromitsu Nagayasu, Takashi Kamijo, Takahito Yonekawa, Hiroshi Tanaka, Shinya Kishimoto, Takuya Hirata, Tatsuya Tsujiuchi, Masaru Chiyomaru, Koji Nakayama, Masahiko Tatsumi, Yasuyuki Yagi, Kazuhiko Kaibara
  • Patent number: 8535427
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A regeneration heater heats lean solution that accumulates near a bottom portion of the regeneration tower with saturated steam thereby producing steam condensate from the saturated steam. A steam-condensate heat exchanger heats the rich solution conveyed from the absorption tower to the regeneration tower with the steam condensate.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: September 17, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Takashi Kamijo, Takahito Yonekawa, Tomio Mimura, Yasuyuki Yagi
  • Patent number: 8529678
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A regeneration heater heats lean solution that accumulates near a bottom portion of the regeneration tower with saturated steam thereby producing steam condensate from the saturated steam. A steam-condensate heat exchanger heats the rich solution conveyed from the absorption tower to the regeneration tower with the steam condensate.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: September 10, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Takashi Kamijo, Takahito Yonekawa, Tomio Mimura, Yasuyuki Yagi
  • Publication number: 20130206010
    Abstract: A CO2 recovery system according to the present invention includes: a CO2 absorber that brings a cooled CO2-containing exhaust gas into contact with a CO2-absorbent that absorbs CO2, thereby removing the CO2 from the exhaust gas; an absorbent regenerator that releases CO2 from a CO2-absorbent that has absorbed CO2 (rich solution), thereby regenerating the absorbent; and a lean solution temperature-reduction unit that recovers heat from a lean solution discharged from the absorbent regenerator.
    Type: Application
    Filed: July 27, 2011
    Publication date: August 15, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Masaki Iijima, Yasuyuki Yagi, Kazuhiko Kaibara
  • Publication number: 20130206000
    Abstract: A reclaiming apparatus 106 includes: a sealed container 106a that is an absorbent reservoir for storing therein a part of an absorbent that has absorbed CO2 in flue gas, and a heater that heats the absorbent stored in the sealed container 106a. The reclaiming apparatus 106 distributes a part of the absorbent stored in the sealed container 106a, and brings the distributed absorbent into counter-current contact with steam. Because a part of the absorbent stored in the absorbent reservoir is brought into counter-current contact with the steam, absorbent component contained therein becomes volatilized, and is separated from depleted materials. In this manner, the absorbent component can be extracted from the depleted materials, and a loss of the absorbent can be reduced.
    Type: Application
    Filed: March 15, 2013
    Publication date: August 15, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
  • Patent number: 8506683
    Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: August 13, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8506693
    Abstract: A CO2 recovery system includes an absorber 2 and a regenerator 3. The absorber 2 includes a CO2 absorbing section 21 and at least one water-washing section 22. The CO2 absorbing section 21 allows flue gas 101 to come into contact with a basic amine compound absorbent 103 so that the basic amine compound absorbent 103 absorbs CO2 in the flue gas 101. The at least one water-washing section 22 allows the decarbonated flue gas 101A in which the amount of CO2 has been reduced in the CO2 absorbing section 21 to come into contact with wash water 104A and 104B to reduce the amounts of the basic amine compounds entrained in the decarbonated flue gas 101A. The regenerator 3 releases the CO2 from the basic amine compound absorbent 103 containing CO2 absorbed therein.
    Type: Grant
    Filed: October 7, 2010
    Date of Patent: August 13, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd, The Kansai Electric Power Co., Inc.
    Inventors: Hiromitsu Nagayasu, Takashi Kamijo, Takahito Yonekawa, Hiroshi Tanaka, Shinya Kishimoto, Takuya Hirata, Tatsuya Tsujiuchi, Masaru Chiyomaru, Koji Nakayama, Masahiko Tatsumi, Yasuyuki Yagi, Kazuhiko Kaibara
  • Publication number: 20130192470
    Abstract: A CO2 recovery system according to the present invention includes: a cooling tower that uses cooling water to cool a CO2-containing exhaust gas discharged from industrial equipment such as a boiler or a gas turbine; a CO2 absorber that brings the cooled CO2-containing exhaust gas into contact with a CO2-absorbent that absorbs CO2, thereby removing the CO2 from the exhaust gas; and a first absorbent regenerator and a second absorbent regenerator that release CO2 from a CO2-absorbent that has absorbed CO2 (rich solution), thereby regenerating the CO2-absorbent. A second lean solution at the outlet of the second absorbent regenerator is subjected to vacuum flash vaporization, and the resulting vapor is inputted to the first absorbent regenerator.
    Type: Application
    Filed: July 27, 2011
    Publication date: August 1, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Masaki Iijima, Masahiko Tatsumi, Yasuyuki Yagi
  • Publication number: 20130189174
    Abstract: Provided are a CO2 absorber that reduces CO2 contained in flue gas; a regenerator that reduces CO2 contained in rich solvent absorbing CO2 to regenerate the rich solvent, so that lean solvent having the CO2 reduced in the regenerator is reused in the CO2 absorber; a heat exchanger that allows the rich solvent to exchange heat with the lean solvent; and a controller that controls to extract rich solvent portion that is part of the rich solvent, to allow the rich solvent portion to bypass the heat exchanger, and to be supplied into the top of the regenerator without exchanging heat so as to minimize a sum of an enthalpy that is taken out of the regenerator as CO2 gas accompanying steam and an enthalpy of the lean solvent after heat exchange with the rich solvent in the heat exchanger.
    Type: Application
    Filed: March 11, 2013
    Publication date: July 25, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: MITSUBISHI HEAVY INDUSTRIES, LTD., THE KANSAI ELECTRIC POWER CO., INC.
  • Publication number: 20130164203
    Abstract: A CO2 recovery system includes an absorber 2 and a regenerator 3. The absorber 2 includes a CO2 absorbing section 21 and a water-washing section 22. The CO2 absorbing section 21 allows flue gas 101 to come into contact with a basic amine compound absorbent 103 so that the basic amine compound absorbent 103 absorbs CO2 in the flue gas 101. The water-washing section 22 allows the decarbonated flue gas 101A in which the amount of CO2 has been reduced in the CO2 absorbing section 21 to come into contact with circulating wash water 104 and to be washed with the wash water 104 so that the amounts of the basic amine compounds entrained in the decarbonated flue gas 101A are reduced. The regenerator 3 releases CO2 from the basic amine compound absorbent 103 the CO2 absorbed therein.
    Type: Application
    Filed: February 13, 2013
    Publication date: June 27, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: MITSUBISHI HEAVY INDUSTRIES, LTD., THE KANSAI ELECTRIC POWER CO., INC.
  • Patent number: 8425849
    Abstract: A reclaiming apparatus 106 includes: a sealed container 106a that is an absorbent reservoir for storing therein a part of an absorbent that has absorbed CO2 in flue gas, and a heater that heats the absorbent stored in the sealed container 106a. The reclaiming apparatus 106 distributes a part of the absorbent stored in the sealed container 106a, and brings the distributed absorbent into counter-current contact with steam. Because a part of the absorbent stored in the absorbent reservoir is brought into counter-current contact with the steam, absorbent component contained therein becomes volatilized, and is separated from depleted materials. In this manner, the absorbent component can be extracted from the depleted materials, and a loss of the absorbent can be reduced.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: April 23, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Masahiko Tatsumi, Yasuyuki Yagi, Kouki Ogura
  • Publication number: 20130087041
    Abstract: In a reclaiming apparatus (106) that includes an airtight container (106a) as an absorbent storing unit that stores a part of an absorbent that absorbs CO2 included in an exhaust gas and a heating unit that heats the absorbent stored in the airtight container (106a), a part of the absorbent stored in the airtight container (106a) is distributed, and a gaseous body is brought into counterflow contact with the absorbent that is distributed. As a result, since the gaseous body is brought into counterflow contact with a part of the absorbent stored in the absorbent storing unit, an absorbent component volatilizes and is separated from a degraded material, and the absorbent component can be extracted from the degraded material, whereby a loss of the absorbent can be reduced.
    Type: Application
    Filed: July 26, 2011
    Publication date: April 11, 2013
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Masaki Iijima, Masahiko Tatsumi, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8415502
    Abstract: A reaction column (12) to which a raw material mixture (11) containing a mono-lower-alkylamine (AA: raw material I) and an alkylene oxide (AO: raw material II) is supplied, an unreacted raw material distillation column (14) that separates an unreacted raw material (15) from a reaction product (13a) (containing the unreacted raw material (15), a target reaction product (monomer) (17), and a by-product (dimer) (18)), and a flash drum (16) to which a reaction product (13b) (containing the target reaction product (monomer) (17) and the by-product (dimer) (18)) is supplied, the flash drum (16) separating a mono-lower-alkyl monoalkanolamine (monomer, the target reaction product 17) in a gas state, are provided.
    Type: Grant
    Filed: October 24, 2008
    Date of Patent: April 9, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc., Nippon Nyukazai Co., Ltd.
    Inventors: Tatsuya Tsujiuchi, Shinya Tachibana, Tsuyoshi Oishi, Tomio Mimura, Yasuyuki Yagi, Hidehisa Mita, Ryosuke Araki, Kenji Saito
  • Patent number: 8414694
    Abstract: Provided are a CO2 absorber that reduces CO2 contained in flue gas; a regenerator that reduces CO2 contained in rich solvent absorbing CO2 to regenerate the rich solvent, so that lean solvent having the CO2 reduced in the regenerator is reused in the CO2 absorber; a heat exchanger that allows the rich solvent to exchange heat with the lean solvent; and a controller that controls to extract rich solvent portion that is part of the rich solvent, to allow the rich solvent portion to by pass the heat exchanger, and to be supplied into the top of the regenerator without exchanging heat so as to minimize a sum of an enthalpy that is taken out of the regenerator as CO2 gas accompanying steam and an enthalpy of the lean solvent after heat exchange with the rich solvent in the heat exchanger.
    Type: Grant
    Filed: December 23, 2009
    Date of Patent: April 9, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Kouki Ogura, Masahiko Tatsumi, Yasuyuki Yagi
  • Patent number: 8409339
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A regeneration heater heats lean solution that accumulates near a bottom portion of the regeneration tower with saturated steam thereby producing steam condensate from the saturated steam. A steam-condensate heat exchanger heats the rich solution conveyed from the absorption tower to the regeneration tower with the steam condensate.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: April 2, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Takashi Kamijo, Takahito Yonekawa, Tomio Mimura, Yasuyuki Yagi
  • Patent number: 8398758
    Abstract: A CO2 recovery system includes an absorber 2 and a regenerator 3. The absorber 2 includes a CO2 absorbing section 21 and a water-washing section 22. The CO2 absorbing section 21 allows flue gas i01 to come into contact with a basic amine compound absorbent 103 so that the basic amine compound absorbent 103 absorbs CO2 in the flue gas 101. The water-washing section 22 allows the decarbonated flue gas 101A in which the amount of CO2 has been reduced in the CO2 absorbing section 21 to come into contact with circulating wash water 104 and to be washed with the wash water 104 so that the amounts of the basic amine compounds entrained in the decarbonated flue gas 101A are reduced. The regenerator 3 releases CO2 from the basic amine compound absorbent 103 the CO2 absorbed therein.
    Type: Grant
    Filed: October 8, 2010
    Date of Patent: March 19, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Hiromitsu Nagayasu, Takashi Kamijo, Takahito Yonekawa, Hiroshi Tanaka, Shinya Kishimoto, Takuya Hirata, Tatsuya Tsujiuchi, Masaru Chiyomaru, Koji Nakayama, Masahiko Tatsumi, Yasuyuki Yagi, Kazuhiko Kaibara
  • Patent number: 8398757
    Abstract: A CO2 recovering apparatus includes a CO2 absorber that brings flue gas containing CO2 and O2 into contact with CO2 absorbing liquid to reduce CO2 in the flue gas; and a regenerator that reduces CO2 in CO2 absorbing liquid (rich solvent) that absorbed CO2 in the CO2 absorber to regenerate the CO2 absorbing liquid, so that the regenerated CO2 absorbing liquid (lean solvent) having CO2 reduced in the regenerator is reused in the CO2 absorber. A lower liquid reservoir is located at the bottom of the CO2 absorber, and an air-bubble gathering member is arranged therein to gather air bubbles included in the absorbing liquid.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: March 19, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Masahiko Tatsumi, Yasuyuki Yagi, Kouki Ogura