Abstract: The disclosed technology relates to the production of graphene by exfoliation in the presence of a dispersant, and the composition of graphene produced thereby.
Type:
Application
Filed:
November 19, 2019
Publication date:
January 6, 2022
Applicant:
The Lubrizol Corporation
Inventors:
Thomas S. Corrigan, Paul E. Adams, John S. Manka, Eric Mock, Dean Thetford
Abstract: The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and an ashless dispersant. The ashless dispersant may be selected from succinimide compounds prepared from aliphatic or aromatic amines.
Type:
Grant
Filed:
September 3, 2020
Date of Patent:
January 4, 2022
Assignee:
The Lubrizol Corporation
Inventors:
Patrick E. Mosier, Jeffry G. Dietz, Alexander Sammut, Mary Galic Raguz, Matthew D. Gieselman
Abstract: Fuel compositions comprising at least 10 ppm by weight of a succinic ester acid amine salt or a succinamide acid amine salt (both “amine salt(s)”). The amine salt is the product of (a) and (b), wherein: (a) is an amine with (i) at least one tertiary nitrogen and (ii) at least one hydroxy alkyl functional group and/or at least one secondary amine functionality; and (b) is a hydrocarbyl-substituted succinic acid/or anhydride. The molar ratio of (a) to (b) may range from 3:1 to 1:3. The fuel composition may comprise gasoline, oxygenate, or mixtures thereof. Methods and uses for reducing carbonaceous deposits in an engine comprising operating the engine using the fuel composition having an amine salt therein.
Abstract: Compositions prepared from an adduct of mono-maleated polyunsaturated vegetable oil and an alcohol mixture comprising a hydrophobic alcohol having at least 9 carbon atoms and methoxypolyethylene glycol having a number average molecular weight (Mn) of at least 350. Metalworking fluids comprising less than 3 wt % of a composition that is an adduct of mono-maleated polyunsaturated vegetable oil and an alcohol mixture comprising an alcohol having at least 2 carbon atoms and methoxypolyethylene glycol having a number average molecular weight (Mn) of at least 350. Methods of improving the stability and/or lubricity of a metalworking fluid using a composition that is adduct of mono-maleated polyunsaturated vegetable oil and an alcohol mixture comprising an alcohol having at least 2 carbon atoms and methoxypolyethylene glycol having a number average molecular weight (Mn) of at least 350.
Abstract: A composition comprising an oil of lubricating viscosity and a compound represented by formula (I) wherein: R1 and R2 are each independently a hydrocarbyl group containing from about 4 to about 18 carbon atoms; p and q are each independently 0 or an integer from 1 to 3, and the sum of p and q is 1, 2, 3, 4, 5, or 6. The composition is effective at swelling seals.
Abstract: A lubricant composition is provided containing an oil of lubricating viscosity and a substantially sulfur-free alkyl phosphate amine salt, where at least 30 mole percent of the phosphorus atoms are in an alkyl pyrophosphate salt structure, along with either or both of a conventional phosphorous containing antiwear additive and a glycerol ester. In the phosphate amine salt, at least 80 mole percent of the alkyl groups are typically secondary alkyl groups of 3 to 12 carbon atoms. A method of improving wear over a wide temperature range in a mechanical device is also provided by employing the lubricant composition.
Type:
Grant
Filed:
April 25, 2018
Date of Patent:
November 23, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Brian B. Filippini, Suzanne Patterson, William R. S. Barton
Abstract: A lubricant composition of an oil of lubricating viscosity, a grafted copolymer viscosity modifier that is an ashless condensation reaction product of an olefin polymer, having a number average molecular weight of about 1000 to about 10,000, comprising carboxylic acid or equivalent functionality grafted onto the polymer backbone, with a monoamine or a polyamine often having a single primary amino group, which exhibits good dispersancy and viscometric performance in a driveline device.
Type:
Grant
Filed:
August 16, 2018
Date of Patent:
November 23, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Sona Sivakova, David M. Nickerson, Paul Simon O'Hora, William R. S. Barton
Abstract: The composition of the present invention related to a quaternary ammonium salt detergent and the use of such quaternary ammonium salt detergents in a fuel composition to reduce diesel injector deposits and remove or clean up existing deposits on the diesel injectors.
Type:
Grant
Filed:
April 27, 2020
Date of Patent:
November 16, 2021
Assignee:
The Lubrizol Corporation
Inventors:
James H. Bush, Robert H. Barbour, David J. Moreton, Hannah Greenfield, Paul R. Stevenson, David C. Arters
Abstract: A composition comprising an oil of lubricating viscosity and a compound represented by formula (I) wherein: x is 0 or 1; R1 is a hydrocarbyl group containing about 4 or about 18 carbon atoms; R2 is an aliphatic hydrocarbyl group containing about 1 to about 12 carbon atoms; and y is 0 or 1, which composition is effective at swelling seals.
Abstract: A lubricant composition comprising an oil of lubricating viscosity and about 0.01 to about 5 percent by weight of a (thio)phosphoric acid salt (“phos-amine salt”) of at least one hydrocarbyl amine. The hydrocarbyl amine may be a hindered hydrocarbyl amine, an aromatic hydrocarbyl amine, or a combination thereof.
Type:
Grant
Filed:
July 17, 2017
Date of Patent:
November 9, 2021
Assignee:
The Lubrizol Corporation
Inventors:
William R. S. Barton, Daniel J. Saccomando, Michael R. Sutton, Stephen J. Cook, Paul R. Vincent, Ewan E. Delbridge, Shawn Dickess, Yanshi Zhang
Abstract: A lubricating composition includes an oil of lubricating viscosity, an N-alkyl naphthylamine, and at least one ashless antioxidant selected from a diarylamine antioxidant, a phenolic antioxidant, and mixtures thereof. The lubricating composition has a phosphorus content of less than 0.15 weight percent. The combination of the N-alkyl naphthylamine and ashless antioxidant provides a beneficial effect on the basicity of the composition without negatively impacting seals performance.
Abstract: A composition obtained by reacting an O,O?-dialkyldithiophosphoric acid with a hydroxyalkyl acrylate or a hydroxyalkyl methacrylate, and reacting the product thereof with a dialkylphosphite provides good antiwear protection.
Type:
Grant
Filed:
October 22, 2020
Date of Patent:
October 26, 2021
Assignee:
The Lubrizol Corporation
Inventors:
William D. Abraham, Mahmud M. Hussain, Kurt F. Wollenberg
Abstract: A lubricating composition suited to use for lubricating a hydraulic system includes an oil of lubricating viscosity and a compound comprising a polyolefin-substituted bridged hydroxyaromatic compound or metal salt thereof, wherein the wherein the polyolefin is derived from a isobutylene having a number average molecular weight of 150 to 800.
Type:
Application
Filed:
June 2, 2021
Publication date:
October 7, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Edward P. Sampler, Gary M. Walker, Stephen J. Cook, Samuel M. Kilsby, Betsy J. Butke
Abstract: Lubricating compositions comprising an azole-acrylic adduct formed by contacting an azole compound with an acrylic. The adduct formed has at least one nitrogen-alkyl group comprising at least one acyl. The lubricating composition also comprises an antiwear agent and an antioxidant. Methods of lubricating an internal combustion engine comprising contacting the internal combustion engine with the lubricating composition comprising an azole-acrylic adduct formed by contacting an azole compound with an acrylic. Methods of reducing corrosion and/or seal deterioration in an internal combustion engine. The use of an azole-acrylic adduct in a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine.
Abstract: The invention relates to a seal swell agent which is a substituted sulfonyldibenzene compound, and lubricating compositions containing the seal swell agent. The substituents on the benzene rings may be hydrocarbyl groups of 4 to 20 carbon atoms or alkylene groups of 1-2 carbon atoms with further functional groups.
Type:
Grant
Filed:
April 15, 2020
Date of Patent:
October 5, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Mariam Shamszad, Paul E. Adams, Mahmud M. Hussain, Peter Miatt
Abstract: The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and an ashless antioxidant. The ashless antioxidant may be selected from phenolic compounds, aryl amine compounds, and sulfurized olefins, especially 2,6-hindered phenols and diarylamine compounds.
Type:
Application
Filed:
June 14, 2021
Publication date:
September 30, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Patrick E. Mosier, Jeffry G. Dietz, Alexander Sammut
Abstract: There is disclosed an antifoam component which includes at least one poly(acrylate) copolymer for use in a diesel fuel. Poly(acrylate) polymers prepared by polymerizing a (meth)acrylate monomer comprising C1 to C30 alkyl esters of (meth)acrylic acid (“multifunctional monomer”) are also disclosed. Other poly(acrylate) polymers prepared by polymerizing (i) a (meth)acrylate monomer comprising C1 to C4 alkyl esters of (meth)acrylic acid (“solubility monomer”); (ii) a (meth)acrylate monomer comprising C5 to C12 alkyl esters of (meth)acrylic acid (“surface tension monomer”); and (iii) optionally at least one additional monomer comprising a solubility monomer, a surface tension monomer, a monomer comprising C1 to C30 alkyl esters of (meth)acrylic acid (“multifunctional monomer”), or combinations thereof are also disclosed.
Type:
Grant
Filed:
September 21, 2017
Date of Patent:
September 21, 2021
Assignee:
The Lubrizol Corporation
Inventors:
James H. Bush, David M. Nickerson, Rochelle L. Kovach, Jayasooriya Sujith Perera, Elizabeth A. Schiferl, Kevin J. Hughes
Abstract: Additive compositions comprising (a) a hydroxycarboxylic acid; and (b) a compound derived from a hydrocarbyl-substituted succinic acid or anhydride wherein the ratio of (a) to (b) in the additive composition ranges from 1:9 to 9:1. The additive compositions may be added to a fuel. Methods of reducing wear in an engine comprising operating the engine using a fuel composition have the additive composition therein. The use of an additive composition in a fuel composition to reduce the fuel composition's coefficient of friction or to reduce wear in an engine.
Abstract: Lubricating compositions comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. The adduct formed has at least one sulfur-alkyl group comprising at least one acyl, or compounds having at least one nitrogen-alkyl group comprising at least one acyl, or mixtures thereof. The lubricating composition also comprises an antiwear agent and an antioxidant. Methods of lubricating an internal combustion engine comprising contacting the internal combustion engine with the lubricating composition comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. Methods of reducing corrosion and/or seal deterioration in an internal combustion engine. The use of a mercaptoazole-acrylic adduct in a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine.
Abstract: A lubricating composition suited to use in lubricating an internal combustion engine includes an oil of lubricating viscosity and a compound comprising a polyolefin-substituted bridged hydroxyaromatic compound or metal salt thereof, wherein the polyolefin is derived from a isobutylene having a number average molecular weight of 150 to 800.
Type:
Application
Filed:
May 21, 2021
Publication date:
September 2, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Edward P. Sampler, Gary M. Walker, Stephen J. Cook, Samuel M. Kilsby