Abstract: A lubricating composition suited to use in lubricating an internal combustion engine includes an oil of lubricating viscosity and a compound comprising a polyolefin-substituted bridged hydroxyaromatic compound or metal salt thereof, wherein the polyolefin is derived from a isobutylene having a number average molecular weight of 150 to 800.
Type:
Application
Filed:
May 21, 2021
Publication date:
September 2, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Edward P. Sampler, Gary M. Walker, Stephen J. Cook, Samuel M. Kilsby
Abstract: Lubricating compositions containing a phosphorus-containing salt of an acylated ethylene-?-olefin polymer substituted with an aliphatic polyamine having at least one primary or secondary amine, the lubricating composition having a total phosphorus content in an amount of 200 ppm to 600 ppm by weight of the lubricating composition. The phosphorus-containing salt additive described herein can be used as an anti-wear agent in lubricating composition for diesel engines.
Type:
Application
Filed:
June 19, 2019
Publication date:
September 2, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Daniel J. Knapton, Allison M. Williamson, Thomas Derevjanik
Abstract: A polyisobutylene-substituted hydroxyaromatic compound and derivatives thereof which are suitable for use as additives in lubricating compositions. The polyisobutylene-substituted hydroxyaromatic compound may include the reaction product of a hydroxyaromatic compound with a polyisobutylene having a number average molecular weight of 150 to 800.
Type:
Application
Filed:
May 18, 2021
Publication date:
September 2, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Edward P. Sampler, Gary M. Walker, Stephen J. Cook, Samuel M. Kilsby
Abstract: The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.
Abstract: The invention provides a lubricant composition comprising an oil of lubricating viscosity and a protic acid salt of an N-hydrocarbyl-substituted gamma-(?-) or delta-amino(thio)ester. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.
Type:
Grant
Filed:
November 4, 2016
Date of Patent:
July 27, 2021
Assignee:
Lubrizol Corporation
Inventors:
Daniel J. Saccomando, William R. S. Barton, Ewan E. Delbridge, Patrick E. Mosier
Abstract: The disclosed technology relates to a lubricant composition for automotive gears, axles and bearings, the lubricant composition containing an oil of lubricating viscosity and a metal thiophosphate compound, such as zinc dialkyldithiophosphate, as well as a method of obtaining extreme pressure performance in automotive gears, axles and bearings at lower sulfur content than is typical, by lubricating such automotive gears, axles and bearings with a lubricant composition containing a metal thiophosphate compound, such as zinc dialkyldithiophosphate.
Type:
Application
Filed:
August 1, 2019
Publication date:
July 22, 2021
Applicant:
The Lubrizol Corporation
Inventors:
William R.S. Barton, Brian B. Filippini
Abstract: Thioether-substituted phenols that are the reaction product of a thioether-substituted alcohol or thioether-substituted amine and a phenol with at least one pendant acyl group and have a ratio of sulfur groups to phenol groups of at least 1:1 and uses for thioether-substituted phenols. Methods of lubricating an internal combustion engine by contacting the internal combustion engine with a lubricating composition comprising a thioether-substituted phenol. Methods of reducing deposit formation and/or corrosion in an engine using a lubricating composition comprising a thioether-substituted phenol.
Abstract: The invention provides lubricating composition comprising: an oil of lubricating viscosity, and an oxyalkylated hydrocarbyl phenol, wherein the oxyalkylated hydrocarbyl phenol is substituted with at least one aliphatic hydrocarbyl group of 40 to 96 carbon atoms, and wherein the oxyalkylated hydrocarbyl phenol is substantially free of aromatic hydrocarbyl groups. The invention further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The invention further relates to the use of the oxyalkylated hydrocarbyl phenol in the lubricating composition to a passenger car internal combustion engine at least one of (i) control of fuel economy, (ii) control of corrosion, (iii) cleanliness, and (iv) control of bore wear.
Type:
Application
Filed:
March 9, 2021
Publication date:
June 24, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Yanshi Zhang, Gary M. Walker, Ewan E. Delbridge, Edward P. Sampler, Neil L. Simpson
Abstract: The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and an ashless antioxidant. The ashless antioxidant may be selected from phenolic compounds, aryl amine compounds, and sulfurized olefins, especially 2,6-hindered phenols and diarylamine compounds.
Type:
Grant
Filed:
September 19, 2014
Date of Patent:
June 15, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Patrick E. Mosier, Jeffry G. Dietz, Alexander Sammut
Abstract: A hydraulic lubricating oil composition is provided which contains a synergistic mixture of three phosphorous antiwear components in order to provide good thermal stability and good demulsibility to the lubricating oil composition.
Abstract: The invention provides a lubricating composition comprising a low viscosity base oil and a synergistic mixture of a functionalized ethylene-?-olefin copolymer, a poly(meth)acrylate polymer, and a metal-free anti-wear agent. The invention also provides a method of lubricating an internal combustion engine using such a lubricating composition.
Type:
Application
Filed:
June 26, 2018
Publication date:
May 20, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Paul R. Vincent, Timothy R. Smith, Eugene Pashkovski, Reid A. Patterson
Abstract: The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.
Abstract: The invention provides lubricating composition comprising: an oil of lubricating viscosity, and an oxyalkylated hydrocarbyl phenol, wherein the oxyalkylated hydrocarbyl phenol is substituted with at least one aliphatic hydrocarbyl group of 40 to 96 carbon atoms, and wherein the oxyalkylated hydrocarbyl phenol is substantially free of aromatic hydrocarbyl groups. The invention further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The invention further relates to the use of the oxyalkylated hydrocarbyl phenol in the lubricating composition to a passenger car internal combustion engine at least one of (i) control of fuel economy, (ii) control of corrosion, (iii) cleanliness, and (iv) control of bore wear.
Type:
Grant
Filed:
June 26, 2019
Date of Patent:
April 27, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Yanshi Zhang, Gary M. Walker, Ewan E. Delbridge, Edward P. Sampler, Neil L. Simpson
Abstract: A lubricating composition includes a sulfurized oxy-substituted aromatic polyol compound and an oil of lubricating viscosity. The sulfurized oxy-substituted aromatic polyol compound includes at least one of a sulfurized oxy-substituted aromatic polyol and a salt of a sulfurized oxy-substituted aromatic polyol. The compound is suitable as a replacement for detergents that contain Cn alkyl phenols derived from oligomers of propylene.
Type:
Grant
Filed:
December 7, 2016
Date of Patent:
April 13, 2021
Assignee:
THE LUBRIZOL CORPORATION
Inventors:
Kamalakumari K. Salem, Gary M. Walker, Ewan E. Delbridge, David J. Moreton, Adam Cox, W. Preston Barnes, James P. Roski, Mohamed G. Fahmy
Abstract: Lubricating compositions comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The lubricating composition also comprises an antiwear agent. Methods of lubricating an internal combustion engine comprise contacting the internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. Methods of reducing lubricant oxidation and/or corrosion in an internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The use of a comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative to reduce lubricant oxidation and/or corrosion in an internal combustion engine.
Abstract: The disclosed technology provides a method of lubricating a compression-ignition internal combustion engine with a maximum laden mass over 2,700 kg comprising supplying to the engine a lubricating composition comprising: an oil of lubricating viscosity, a 300 TBN or higher alkaline earth metal sulfonate detergent having a metal ratio of 10 to 40, an alkaline earth metal sulfonate detergent having a metal ratio of 3 to 9, and a TBN of 81 to 180 mg KOH/g, wherein the sulfonate detergents provide a total amount of sulfonate substrate of 1 wt % to 3 wt % of the lubricating composition, 0.1 to 1.2 wt % of antioxidant, wherein at least 20 wt % of the antioxidant is a phenolic antioxidant, a borated compound present in an amount to deliver 25 ppm to 300 ppm of boron, the lubricating composition has a sulfated ash content of 0.5 wt % to not more than 1.5 wt %, and the lubricating composition has a TBN of 6.5 to 15 mg KOH/g.
Abstract: The present invention relates to a lubricating composition containing: an oil of lubricating viscosity, a non-borated dispersant, a detergent, and an antiwear package comprising (a) a derivative of a hydroxycarboxylic acid, (b) an amine salt of a phosphoric acid ester, and (c) a phosphite having at least one hydrocarbyl group with 4 or more carbon atoms. The invention further provides for a method of lubricating a driveline device application by employing a lubricating composition containing the antiwear package.
Abstract: A composition obtained by reacting an O,O?-dialkyldithiophosphoric acid with a hydroxyalkyl acrylate or a hydroxyalkyl methacrylate, and reacting the product thereof with a dialkylphosphite provides good antiwear protection.
Type:
Application
Filed:
October 22, 2020
Publication date:
February 11, 2021
Applicant:
The Lubrizol Corporation
Inventors:
William D. Abraham, Mahmud M. Hussain, Kurt F. Wollenberg
Abstract: The present invention relates to a lubricating composition containing (a) an oil of lubricating viscosity; and (b) a compound selected from the group consisting of: (i) an ester-containing heterocycle; (ii) an amide-containing heterocycle; and (iii) a pyrimidine, wherein the ester-containing heterocycle and the amide-containing heterocycle have a hydrocarbyl group containing 6 to 40 carbon atoms. The invention further provides for a method of supplying an internal combustion engine with the lubricating composition.
Type:
Grant
Filed:
December 20, 2019
Date of Patent:
February 9, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Patrick E. Mosier, Jason R. Brown, Matthew D. Gieselman, Calvin W. Schroeck, Seth L. Crawley, William R. S. Barton, William C. Ward, Jr.
Abstract: The invention relates to quaternary ammonium amide and/or ester salts and their use as additives, including their use in fuels, such as diesel fuel. The invention particularly relates to the use of quaternary ammonium amide and/or ester salts as detergents in diesel fuels.
Type:
Grant
Filed:
October 14, 2019
Date of Patent:
February 9, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Paul R. Stevenson, James C. Ray, David J. Moreton, James H. Bush