Patents Assigned to Toda Kogyo Corporation
  • Publication number: 20010009728
    Abstract: High-density acicular hematite particles comprise acicular hematite particles and a coat comprising an oxide of tin or oxides of tin and antimony, formed on at least a part of surfaces of said acicular hematite particles; and have an average major axial diameter of not more than 0.3 &mgr;m, a pH value of not less than 8, a soluble sodium salt content of not more than 300 ppm, calculated as Na, and a soluble sulfate content of not more than 150 ppm, calculated as SO4. Such high-density acicular hematite particles is suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium using magnetic particles containing iron as a main ingredient, have an excellent dispersibility in vehicle and a low volume resistivity.
    Type: Application
    Filed: January 12, 2001
    Publication date: July 26, 2001
    Applicant: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Yasuyuki Tanaka, Hiroko Morii
  • Patent number: 6251555
    Abstract: Black magnetic composite particles for black magnetic toner according to the present invention comprise: magnetite particle as core particle; fine particles which are adhered or exist on at least a part of the surface of each magnetite particle, and comprise oxides, oxide hydroxides or oxides and oxide hydroxides composed of at least one element selected from the group consisting of Si, Zr, Ti, Al and Ce; and a methyl hydrogen polysiloxane coating layer formed on said fine particles or said fine particles and the exposed surface of the magnetite particle, the average particle size of said black magnetic composite particles being 0.08 to 1.0 &mgr;m. Such black magnetic composite particles are suitable for a black magnetic toner which can exhibit not only an excellent flowability but also a high volume resistivity.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: June 26, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Seiji Ishitani, Yasuyuki Tanaka, Hiroko Morii
  • Patent number: 6248437
    Abstract: The present invention relates to acicular hematite particles containing aluminum of 0.05 to 50% by weight, calculated as Al, having an average major axial diameter of not more than 0.3 &mgr;m and a pH value of the particles of not less than 8, and containing soluble sodium salts of not more than 300 ppm soluble sodium, calculated as Na, and soluble sulfates of not more than 150 ppm soluble sulfate, calculated as SO4, which have an excellent dispersibility in a binder resin, and a magnetic recording medium which uses the hematite particles as non-magnetic particles for a non-magnetic undercoat layer, which has small light transmittance, smooth surface, high strength and high durability, and which is capable of suppressing the deterioration in the magnetic properties caused by a corrosion of the magnetic particles containing as a main ingredient in the magnetic recording layer.
    Type: Grant
    Filed: May 23, 2000
    Date of Patent: June 19, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Hiroko Morii, Yasuyuki Tanaka
  • Patent number: 6231661
    Abstract: A fine red iron oxide pigment of the present invention comprises hematite particles and having a geometrical standard deviation of major axial diameter of not more than 1.5, a geometrical standard deviation of minor axial diameter of not more than 1.3 and an average major axial diameter of 0.005 to 0.1 &mgr;m. Such fine red iron oxide pigment is uniform in both major axial diameter and minor axial diameter thereof and exhibits an excellent transparency.
    Type: Grant
    Filed: September 24, 1999
    Date of Patent: May 15, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Mineko Ohsugi, Hiroko Morii
  • Patent number: 6228924
    Abstract: Calcium-iron oxide composite particles of the present invention have a BET specific surface area of 0.1 to 100 m2/g and containing iron atom in an amount of 1 to 500 moles based on 100 moles of calcium atom, the iron atom of not less than 50% based on the total amount of iron atom contained in said calcium-iron oxide composite particles being bonded with calcium atom for forming a calcium-iron ferrite phase. A hydrogen chloride-scavenger comprising the calcium-iron oxide composite particles, is capable of effectively capturing harmful hydrogen chloride generated by thermal decomposition or combustion of chorine-containing resin molded products upon fire or incineration thereof, and fixing the hydrogen chloride as stable calcium chloride or the like.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: May 8, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Toshiki Matsui, Masaru Isoai, Yasuhiko Fujii, Satoshi Hatakeyama, Tomoko Okita, Tomoyuki Imai
  • Patent number: 6221519
    Abstract: A magnetic recording medium comprising: a plastic substrate; a nickel oxide underlayer formed on said substrate; and a cobalt-containing maghemite thin film formed on said nickel oxide underlayer, containing cobalt at a molar ratio of cobalt to iron of 0.01:1 to 0.1:1, and having either a spacing of a plane (311) of not more than 2.510 Å, a spacing of a plane (222) of not more than 2.415 Å or a spacing of a plane (220) of not more than 2.950 Å, a ratio value of an X-ray diffraction pattern peak intensity of either of the planes (311), (222) and (220) of said cobalt-containing maghemite thin film to an X-ray diffraction pattern peak intensity of the plane (400) thereof being more than 0.5. Such magnetic recording medium suitably applicable to existent magnetic recording systems using a ring-type magnetic head and capable of using a plastic substrate for providing a magnetic recording medium for high-density recording.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: April 24, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Takanori Doi, Kousaku Tamari, Yasuo Kakihara, Kenichi Nakata, Mitsuru Matsuura, Setsuo Yamamoto
  • Patent number: 6207279
    Abstract: High-density acicular hematite particles comprise acicular hematite particles and a coat comprising an oxide of tin or oxides of tin and antimony, formed on at least a part of surfaces of said acicular hematite particles; and have an average major axial diameter of not more than 0.3 &mgr;m a pH value of not less than 8, a soluble sodium salt content of not more than 300 ppm, calculated as Na, and a soluble sulfate content of not more than 150 ppm, calculated as SO4. Such high-density acicular hematite particles is suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium using magnetic particles containing iron as a main ingredient, have an excellent dispersibility in vehicle and a low volume resistivity.
    Type: Grant
    Filed: March 26, 1998
    Date of Patent: March 27, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Yasuyuki Tanaka, Hiroko Morii
  • Patent number: 6207253
    Abstract: Acicular hematite particles of the present invention comprise an average major axis diameter of 0.004 to 0.295 &mgr;m, a geometrical standard deviation of minor axis diameter of not more than 1.35 and a pH value of not less than 8, and containing not more than 300 ppm of soluble sodium salt, calculated as Na and not more than 150 ppm of soluble sulfate, calculated as SO4. Such acicular hematite particles are suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium which exhibits a low light transmittance, an excellent smooth surface and a high strength, and can be prevented from being deteriorated in magnetic properties due to the corrosion of magnetic acicular metal particles containing iron as a main component which are dispersed in a magnetic recording layer thereof.
    Type: Grant
    Filed: December 24, 1998
    Date of Patent: March 27, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Yasuyuki Tanaka, Keisuke Iwasaki, Hiroko Morii
  • Patent number: 6200376
    Abstract: Heat-resistant yellow pigment particles of the present invention comprise a composite metal oxide containing Fe, Ti and Li, and comprising a crystal phase having a pseudobrookite-type structure. Such the heat-resistant yellow pigment particles are free from contamination of harmful metals such as Pb, Cr, Cd, etc., show a clear yellow color, are excellent in heat resistance, chemical resistance and light resistance, and have a low specific gravity.
    Type: Grant
    Filed: April 7, 1999
    Date of Patent: March 13, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Tsutomu Katamoto, Mamoru Fujimoto
  • Patent number: 6197708
    Abstract: A dust-removing synthetic resin filter of the present invention comprises a filter material which comprises: synthetic resin fibers; and iron oxide particles having a catalytic activity to chlorine or hydrogen chloride gas. Such a dust-removing synthetic resin filter is capable of so-called clean combustion which is free from discharge of harmful substances upon incineration thereof and is advantageous from the standpoint of preventing environmental pollution.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: March 6, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Hideto Yoshida, Tomoyuki Imai, Yasuhiko Fujii, Masayuki Okamoto, Takahiro Imano
  • Patent number: 6187462
    Abstract: A magnetic recording medium of the present invention comprises: a plastic substrate; and a cobalt-containing maghemite thin film formed on said substrate, containing cobalt at a molar ratio of cobalt to iron of not more than 0.06:1, and having either a spacing of a plane (311) of not more than 2.510 Å, a spacing of a plane (222) of not more than 2.415 Å or a spacing of a plane (220) of not more than 2.950 Å; and has a coercive force of not less than 2,000 Oe. Such magnetic recording medium suitably applicable to existent magnetic recording systems using a ring-type magnetic head and capable of using a plastic substrate for providing a magnetic recording medium for high-density recording.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: February 13, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Takanori Doi, Kousaku Tamari, Yasuo Kakihara, Kenichi Nakata, Mitsuru Matsuura, Setsuo Yamamoto
  • Patent number: 6183868
    Abstract: The present invention relates to spindle-shaped goethite particles and spindle-shaped hematite particles, which have a narrow particle size distribution, include no dendrites, and have an appropriate particle shape and a large aspect ratio (major axial diameter/minor axial diameter); and spindle-shaped magnetic iron based alloy particles which are obtained from the spindle-shaped goethite particle or spindle-shaped hematite particles as a beginning material and which have a high coercive force and an excellent coercive force distribution. Such spindle-shaped goethite particles comprises: goethite seed containing 0.5 to 25 atm % of Co based on the total Fe in the spindle-shaped goethite particles, and goethite surface layer containing 0.5 to 15 atm % of Al based on the total Fe in the spindle-shaped goethite particles; and having an average major axial diameter of 0.05 to 1.0 &mgr;m.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: February 6, 2001
    Assignee: Toda Kogyo Corporation
    Inventors: Haruki Kurokawa, Kohji Mori
  • Patent number: 6165608
    Abstract: A magnetic recording medium of the present invention comprises:a substrate; anda cobalt-containing maghemite thin film formed on said substrate, containing cobalt at a molar ratio of cobalt to iron of not more than 0.06:1, having either a spacing of a (311) plane of not more than 2.510 .ANG., a spacing of a (222) plane of not more than 2.415 .ANG. or a spacing of a (220) plane of not more than 2.950 .ANG., and having a coercive force of not less than 1,800 Oe.Such a magnetic recording medium has as high a coercive force as possible, specifically not less than 1,800 Oe, and exhibits an excellent stability independent to change in passage of time and a large output in a high recording frequency region.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: December 26, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kousaku Tamari, Takanori Doi, Yasuo Kakihara, Kenichi Nakata
  • Patent number: 6159592
    Abstract: A magnetic recording medium comprising: a base film; a non-magnetic undercoat layer formed on said base film, comprising a binder resin and non-magnetic acicular particles containing iron as a main component, which particles comprise iron and zirconium of 0.05 to 30% by weight, calculated as Zr, based on the total weight of the particles, which is present within the particle; and a magnetic recording layer formed on said non-magnetic undercoat layer and comprising magnetic particles and a binder resin. Such a magnetic recording medium has a low light transmittance, an excellent smooth surface, a high mechanical strength and an excellent durability.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: December 12, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Hiroko Morii
  • Patent number: 6159594
    Abstract: A magnetic recording medium of the present invention comprises:a substrate;a nickel oxide underlayer formed on said substrate; anda cobalt-containing maghemite thin film formed on said nickel oxide underlayer, having either a spacing of a (311) plane of not more than 2.510 .ANG., a spacing of a (222) plane of not more than 2.415 .ANG. or a spacing of a (220) plane of not more than 2.950 .ANG., and having the ratio of either of X-ray diffraction spectrum peak intensities of the (311), (222) or (220) planes of said cobalt-containing maghemite thin film to an X-ray diffraction spectrum peak intensity of the (400) plane of more than 0.5:1.Such a magnetic recording medium has a higher coercive force, a higher saturation magnetization, less amount of noise generated, a large output in a high recording frequency region and less distortion of a reproduced waveform, and is suitable for use in current magnetic recording systems in which a ring-type magnetic write head is used.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: December 12, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kousaku Tamari, Takanori Doi, Yasuo Kakihara, Kenichi Nakata
  • Patent number: 6153296
    Abstract: Acicular hematite particles of the present invention contain zirconium of 0.05 to 30% by weight (calculated as Zr) based on the total weight of the particles, which is present within the particle, which have an average major axis diameter of not more than 0.3 .mu.m and a pH value of not less than 8, and contain not more than 300 ppm of soluble sodium salt, calculated as Na and not more than 150 ppm of soluble sulfate, calculated as SO.sub.4.Such acicular hematite particles are suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium which exhibits a low light transmittance, an excellent smooth surface, a high strength and an excellent durability, and can be prevented from being deteriorated in magnetic properties due to the corrosion of magnetic acicular metal particles containing iron as a main component which are dispersed in a magnetic recording layer thereof.
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: November 28, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Tosiharu Harada, Hiroko Morii
  • Patent number: 6139618
    Abstract: A fine yellow composite iron oxide hydroxide pigment of the present invention has an average major axial diameter of not less than 0.005 .mu.m and less than 0.1 .mu.m, which comprises:fine goethite particles as core particles, containing aluminum inside thereof in an amount of 0.05 to 50% by weight, calculated as Al, based on the weight of said core particles; anda composite oxide hydroxide of Fe and Al, coated on the surface of each core particle. Such fine yellow composite iron oxide hydroxide pigment are excellent in transparency and heat resistance.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: October 31, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Mineko Ohsugi, Hiroshi Sumita, Hiroko Morii
  • Patent number: 6130017
    Abstract: Black non-magnetic composite particles for black toner according to the present invention, comprise:black hematite particles or black iron oxide hydroxide particles as core particles;fine particles which are adhered or exist on at least a part of the surface of each magnetite particle, and comprise oxides, oxide hydroxides or oxides and oxide hydroxides composed of at least one element selected from the group consisting of Si, Zr, Ti, Al and Ce; anda methyl hydrogen polysiloxane coating layer formed on said fine particles or said fine particles and the exposed surface of the magnetite particle,the average particle size of said black non-magnetic composite particles being 0.08 to 1.0 .mu.m.Such black non-magnetic composite particles are suitable for a black toner which can exhibit not only an excellent flowability but also a high volume resistivity.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: October 10, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Seiji Ishitani, Yasuyuki Tanaka, Hiroko Morii
  • Patent number: 6124022
    Abstract: Acicular hematite particles of the present invention comprise a geometrical standard deviation of major axis diameter of not more than 1.50, a geometrical standard deviation of minor axis diameter of not more than 1.35, a BET specific surface area of 35.9 to 150 m.sup.2 /g and an average major axis diameter of 0.004 to 0.295 .mu.m. Such acicular hematite particles are suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium having a low light transmittance, an excellent smooth surface, a high mechanical strength and an excellent durability.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: September 26, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Yasuyuki Tanaka, Keisuke Iwasaki, Hiroko Morii
  • Patent number: 6120898
    Abstract: The present invention relates to acicular hematite particles containing aluminum of 0.05 to 50% by weight, calculated as Al, having an average major axial diameter of not more than 0.3 .mu.m and a pH value of the particles of not less than 8, and containing soluble sodium salts of not more than 300 ppm soluble sodium, calculated as Na, and soluble sulfates of not more than 150 ppm soluble sulfate, calculated as SO.sub.4, which have an excellent dispersibility in a binder resin, and a magnetic recording medium which uses the hematite particles as non-magnetic particles for a non-magnetic undercoat layer, which has small light transmittance, smooth surface, high strength and high durability, and which is capable of suppressing the deterioration in the magnetic properties caused by a corrosion of the magnetic particles containing as a main ingredient in the magnetic recording layer.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: September 19, 2000
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Keisuke Iwasaki, Hiroko Morii, Yasuyuki Tanaka