Abstract: A polyurethane resin-bonded pigment may exhibit excellent image density, dispersibility, storage stability, and resolubility, and may form an ink film that exhibits marker resistance and rubfastness. The polyurethane resin-bonded pigment is produced by bringing (I) a pigment having a surface acidic group into contact with (II) a basic compound having two or more amino groups selected from a primary amino group and a secondary amino group in its molecule in an aqueous medium to obtain a pigment having an unreacted surface amino group, and bringing the pigment having an unreacted surface amino group into contact with (III) a water-dispersible polyurethane resin having an isocyanate end group and (IV) a polyisocyanate compound to bond the pigment having an unreacted surface amino group and the water-dispersible polyurethane resin (III) having an isocyanate end group via a urea bond.
Abstract: A CVD-SiC formed body has low light transmittance and high resistivity, and may suitably be used as a member for an etcher that is used for a semiconductor production process, for example. The SiC formed body is formed using a CVD method, and includes 1 to 30 mass ppm of boron atoms, and more than 100 mass ppm and 1000 mass ppm or less of nitrogen atoms. The SiC formed body preferably has a resistivity of more than 10 ?·cm and 100,000 ?·cm or less, and a light transmittance at a wavelength of 950 nm of 0 to 1%.
Abstract: A pigment that exhibits excellent image density, dispersibility, storage stability, and resolubility, and forms an ink film that exhibits marker resistance and rubfastness is provided. A polyurethane resin-bonded pigment is produced by bringing (I) a pigment having a surface acidic group into contact with (II) a water-dispersible polyurethane resin having a tertiary amino group and an anionic polar group or a nonionic polar chain in an aqueous medium. The pigment (I) is preferably self-dispersible carbon black having a surface acidic group.
Abstract: A method for producing a pigment dispersion composition having excellent image density, dispersibility, and storage stability, has high resolubility, and forms an ink film having excellent marker resistance and scratch resistance. The method includes bringing a pigment (I) having a surface acidic group and a basic compound (II) having two or more ammo groups selected from a primary amino group and a secondary amino group in its molecule, into contact with each other in an aqueous medium to prepare a pigment having an unreacted surface amino group, bringing the pigment into contact with a polyisocyanate polyurethane resin (III) having two or more isocyanate end groups so that the pigment and the polyisocyanate polyurethane resin are bonded via a urea bond to prepare a dispersion of a polyurethane resin-bonded pigment (A), and heating the dispersion of the polyurethane resin-bonded pigment (A) at 40 to 100° C. for 1 to 30 days.
Abstract: A semiconductor substrate that includes a semiconductor layer that exhibits high crystallinity includes a graphite layer formed of a heterocyclic polymer obtained by condensing an aromatic tetracarboxylic acid and an aromatic tetramine, and a semiconductor layer that is grown on the surface of the graphite layer, or includes a substrate that includes a graphite layer formed of a heterocyclic polymer obtained by condensing an aromatic tetracarboxylic acid and an aromatic tetramine on its surface, a buffer layer that is grown on the surface of the graphite layer, and a semiconductor layer that is grown on the surface of the buffer layer.
Type:
Grant
Filed:
September 7, 2010
Date of Patent:
April 7, 2015
Assignees:
The University of Tokyo, Tokai Carbon Co., Ltd., National Institute of Advanced Industrial Science and Technology
Abstract: A method of producing a surface-treated carbon black powder dispersion includes subjecting carbon black fine particles having a volume average particle size of 100 nm to 20 ?m to wet granulation and drying by heating to obtain granulated carbon black having a hardness of 12 cN or less and a pH of less than 7, grinding the granulated carbon black to obtain a ground product having a volume average particle size of 20 nm to 20 ?m, and subjecting the ground product to wet oxidization in an aqueous medium. The resulting surface-treated carbon black powder dispersion exhibits excellent print density, print quality, discharge stability, and storage stability when used as an inkjet printer aqueous black ink.
Abstract: A method for producing a surface-treated carbon black particle aqueous dispersion that exhibits excellent blackness and dispersibility, exhibits excellent storage stability, suppresses feathering, exhibits an excellent discharge capability and rubfastness (quick-drying capability), and suppresses metal corrosion when used in an aqueous black pigment (colorant) ink, is disclosed. The method for producing a surface-treated carbon black particle aqueous dispersion includes providing an aqueous dispersion of oxidized carbon black particles obtained by forming acidic hydroxyl groups on a surface of carbon black particles having a DBP absorption of 120 cm3/100 g or more, neutralizing 5% or more and less than 50% of the acidic hydroxyl groups with a polyvalent cation, and neutralizing the remainder of the acidic hydroxyl groups with a monovalent cation.
Abstract: A method for producing a surface-treated carbon black particle aqueous dispersion that exhibits excellent blackness and dispersibility, exhibits excellent storage stability, suppresses feathering, exhibits an excellent discharge capability and rubfastness (quick-drying capability), and suppresses metal corrosion when used in an aqueous black pigment(colorant) ink, is disclosed. The method for producing a surface-treated carbon black particle aqueous dispersion includes providing an aqueous dispersion of oxidized carbon black particles obtained by forming acidic hydroxyl groups on a surface of carbon black particles having a DBP absorption of 120 cm3/100 g or more, neutralizing 5% or more and less than 50% of the acidic hydroxyl groups with a polyvalent cation, and neutralizing the remainder of the acidic hydroxyl groups with a monovalent cation.
Abstract: A method for producing a pigment dispersion composition having excellent image density, dispersibility, and storage stability, has high resolubility, and forms an ink film having excellent marker resistance and scratch resistance. The method includes bringing a pigment (I) having a surface acidic group and a basic compound (II) having two or more amino groups selected from a primary amino group and a secondary amino group in its molecule, into contact with each other in an aqueous medium to prepare a pigment having an unreacted surface amino group, bringing the pigment into contact with a polyisocyanate polyurethane resin (III) having two or more isocyanate end groups so that the pigment and the polyisocyanate polyurethane resin are bonded via a urea bond to prepare a dispersion of a polyurethane resin-bonded pigment (A), and heating the dispersion of the polyurethane resin-bonded pigment (A) at 40 to 100° C. for 1 to 30 days.
Abstract: A method of producing a fuel cell separator includes pressing a compact part-forming material that includes a carbonaceous powder and a thermosetting resin binder at a temperature equal to or higher than the softening temperature of the thermosetting resin binder and less than the curing temperature of the thermosetting resin binder to obtain a compact part-forming preformed sheet, preparing a porous part-forming powder that includes a carbonaceous powder and a thermosetting resin binder, placing the compact part-forming preformed sheet and the porous part-forming powder in a forming die that has a concave-convex forming surface corresponding to the shape of a gas passage so that the concave-convex forming surface faces the porous part-forming powder, and hot-pressing the compact part-forming preformed sheet and the porous part-forming powder using the forming die at a temperature equal to or higher than the curing temperature of the thermosetting resin binder included in the compact part-forming material or
Abstract: A polyurethane resin-bonded pigment may exhibit excellent image density, dispersibility, storage stability, and resolubility, and may form an ink film that exhibits marker resistance and rubfastness. The polyurethane resin-bonded pigment is produced by bringing (I) a pigment having a surface acidic group into contact with (II) a basic compound having two or more amino groups selected from a primary amino group and a secondary amino group in its molecule in an aqueous medium to obtain a pigment having an unreacted surface amino group, and bringing the pigment having an unreacted surface amino group into contact with (III) a water-dispersible polyurethane resin having an isocyanate end group and (IV) a polyisocyanate compound to bond the pigment having an unreacted surface amino group and the water-dispersible polyurethane resin (III) having an isocyanate end group via a urea bond.
Abstract: A method of producing a polyurethane resin-bonded pigment aqueous dispersion includes causing (I) a pigment having a surface acidic group to come in contact with (II) a basic compound having two or more amino groups selected from a primary amino group and a secondary amino group in its molecule in an aqueous medium so that the pigment has an unreacted surface amino group, and causing the pigment to come in contact and react with (III) a polyurethane resin having an isocyanate end group. A polyurethane resin-bonded pigment aqueous dispersion produced by the method exhibits excellent image density, dispersibility, and storage stability.
Abstract: A pigment that exhibits excellent image density, dispersibility, storage stability, and resolubility, and forms an ink film that exhibits marker resistance and rubfastness is provided. A polyurethane resin-bonded pigment is produced by bringing (I) a pigment having a surface acidic group into contact with (II) a water-dispersible polyurethane resin having a tertiary amino group and an anionic polar group or a nonionic polar chain in an aqueous medium. The pigment (I) is preferably self-dispersible carbon black having a surface acidic group.
Abstract: A negative electrode material for a nonaqueous secondary battery capable of realizing a nonaqueous secondary battery having a small charging/discharging irreversible capacity at an initial cycle and exhibiting an excellent high-rate charging/discharging characteristics and an excellent cycle performances is provided. The main component of the material is graphite particles. The median diameter is 5 ?m or more, and 40 ?m or less in the volume-basis particle size distribution based on the laser diffraction/scattering particle size distribution measurement. The tapping density is 0.7 g/cm3 or more. The specific surface area measured by a BET method is 0.2 m2/g or more, and 8 m2/g or less. The average circularity is 0.83 or more, and 1.00 or less. When an electrode is produced by a predetermined method for manufacturing an electrode and, the resulting electrode is subjected to X-ray diffraction, the graphite crystal orientation ratio I110/I004 on the electrode is 0.
Type:
Grant
Filed:
August 30, 2005
Date of Patent:
March 26, 2013
Assignees:
Mitsubishi Chemical Corporation, Tokai Carbon Co., Ltd.
Abstract: Carbon black includes primary particles having an average particle size of 15 to 40 nm, microprotrusions having an average length of 2 to 10 nm being formed on a surface of the primary particles. A method for producing carbon black includes introducing an oxygen-containing gas and fuel into a fuel combustion zone, mixing and combusting the oxygen-containing gas and the fuel to produce a high-temperature combusted gas stream, introducing a raw material hydrocarbon in a first stage of a raw material introduction zone and introducing the raw material hydrocarbon and an oxygen-containing gas in a second stage of the raw material introduction zone while introducing the high-temperature combusted gas stream into the raw material introduction zone to produce a carbon black-containing gas which is introduced into a reaction termination zone while spraying a coolant.
Abstract: A semiconductor substrate that includes a semiconductor layer that exhibits high crystallinity includes a graphite layer formed of a heterocyclic polymer obtained by condensing an aromatic tetracarboxylic acid and an aromatic tetramine, and a semiconductor layer that is grown on the surface of the graphite layer, or includes a substrate that includes a graphite layer formed of a heterocyclic polymer obtained by condensing an aromatic tetracarboxylic acid and an aromatic tetramine on its surface, a buffer layer that is grown on the surface of the graphite layer, and a semiconductor layer that is grown on the surface of the buffer layer.
Type:
Application
Filed:
September 7, 2010
Publication date:
July 26, 2012
Applicants:
TOKAI CARBON CO., LTD., THE UNIVERSITY OF TOKYO
Abstract: A method of producing a polyurethane resin-bonded pigment aqueous dispersion includes causing (I) a pigment having a surface acidic group to come in contact with (II) a basic compound having two or more amino groups selected from a primary amino group and a secondary amino group in its molecule in an aqueous medium so that the pigment has an unreacted surface amino group, and causing the pigment to come in contact and react with (III) a polyurethane resin having an isocyanate end group. A polyurethane resin-bonded pigment aqueous dispersion produced by the method exhibits excellent image density, dispersibility, and storage stability.
Abstract: A method of producing a surface-treated carbon black powder dispersion includes subjecting carbon black fine particles having a volume average particle size of 100 nm to 20 ?m to wet granulation and drying by heating to obtain granulated carbon black having a hardness of 12 cN or less and a pH of less than 7, grinding the granulated carbon black to obtain a ground product having a volume average particle size of 20 nm to 20 ?m, and subjecting the ground product to wet oxidization in an aqueous medium. The resulting surface-treated carbon black powder dispersion exhibits excellent print density, print quality, discharge stability, and storage stability when used as an inkjet printer aqueous black ink.
Abstract: A method of producing a fuel cell separator includes pressing a compact part-forming material that includes a carbonaceous powder and a thermosetting resin binder at a temperature equal to or higher than the softening temperature of the thermosetting resin binder and less than the curing temperature of the thermosetting resin binder to obtain a compact part-forming preformed sheet, preparing a porous part-forming powder that includes a carbonaceous powder and a thermosetting resin binder, placing the compact part-forming preformed sheet and the porous part-forming powder in a forming die that has a concave-convex forming surface corresponding to the shape of a gas passage so that the concave-convex forming surface faces the porous part-forming powder, and hot-pressing the compact part-forming preformed sheet and the porous part-forming powder using the forming die at a temperature equal to or higher than the curing temperature of the thermosetting resin binder included in the compact part-forming material or
Abstract: A negative electrode material for lithium ion secondary batteries includes core-shell composite particles prepared by covering the surface of a graphite powder with an amorphous carbon powder via a carbide of binder pitch, the graphite powder having an average particle diameter of 5 to 30 ?m and an average lattice spacing d(002) of less than 0.3360 nm, and the amorphous carbon powder having an average particle diameter of 0.05 to 2 ?m and an average lattice spacing d(002) of 0.3360 nm or more. A method to produce the negative electrode material includes mixing a graphite powder with pitch having a softening point of 70 to 250° C., adding an amorphous carbon powder to the resulting product, kneading the mixture while applying a mechanical impact to soften the pitch and carbonizing the pitch by heat treatment of the mixture at 750 to 2250° C. in a non-oxidizing atmosphere.