Patents Assigned to Tokai Denka Kogyo Kabushiki Kaisha
  • Patent number: 5912385
    Abstract: This invention relates to a process for the production of an alkanesulfionic acid such as isethionic acid with a high purity in a high yield and at a low cost by oxidation of a (hydroxy)alkylmercaptan with hydrogen peroxide characterized in that a whole amount beyond a stoichiometric amount of a solution of hydrogen peroxide having a H.sub.2 O.sub.2 concentration of not less than 50% by weight is charged into a reaction vessel, said mercaptan is continuously fed at a temperature of 50.degree. C. or lower, aging is carried out, distillation with boiling is carried out and then the reaction mixture is contacted with an anion exchanger.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: June 15, 1999
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kazuyoshi Kushibe, Hiromitsu Kobayashi, Hirohisa Nitoh, Hirotsugu Kitamura
  • Patent number: 5340496
    Abstract: A stabilized sodium percarbonate is obtained by incorporating therein (A) at least one compound selected from the group consisting of mono- and dicarboxylic acids having not less than four carbon atoms and salts thereof; and (B) at least one compound selected from the group consisting of sulfates, nitrates and silicates of alkali metals and alkaline earth metals.
    Type: Grant
    Filed: March 12, 1993
    Date of Patent: August 23, 1994
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kanji Sato, Tomomasa Kondo
  • Patent number: 5223087
    Abstract: A chemical solubilizing agent for tin or a tin alloy used for electroconductive materials is provided. Said chemical solubilizing agent is an acidic solution containing hydrogen peroxide and an inorganic acid and 0.5-50 g liter of said acidic solution of at least one nitrogen-containing compound selected from the group consisting of heterocyclic compounds not having a double bond in the respective heterocyclic rings, cyclopentylamines and cyclohexylamines.
    Type: Grant
    Filed: April 5, 1990
    Date of Patent: June 29, 1993
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Katsutoshi Itani, Akira Hirai
  • Patent number: 5211927
    Abstract: An acidic aqueous hydrogen peroxide solution containing copper can be stabilized by adding an amino acid having the formula ##STR1## wherein Ar is an aromatic group.
    Type: Grant
    Filed: November 26, 1991
    Date of Patent: May 18, 1993
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Katsutoshi Itani, Yoko Miyashiro
  • Patent number: 5155241
    Abstract: Styrene oxide is prepared by reacting styrene and hydrogen peroxide in a heterogenous system in the presence of a bis(tri-n-alkyltinoxy) molybdic acid and an inorganic anion.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: October 13, 1992
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Keiichi Nishibe, Seiichi Rengakuji, Masami Inoue, Osami Ohura, Hirohisa Nitoh
  • Patent number: 5149871
    Abstract: A novel water-soluble produced by contacting thiourea dioxide with an aqueous solution comprising an amino acid having the general formula NH.sub.2 (CH.sub.2).sub.n COOH wherein n is an integer of 1 to 7 and a sodium, potassium or calcium salt of acetic acid.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: September 22, 1992
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Hirohisa Nitoh, Osami Ohura, Morio Suzuki
  • Patent number: 5122354
    Abstract: A crystallized, stable histidine-hydrogen peroxide adduct intermolecular-bonded at 1:1 ratio is provided.
    Type: Grant
    Filed: July 20, 1990
    Date of Patent: June 16, 1992
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kuniro Tsuji, Haruo Nukaya, Yasuhiro Kanaya
  • Patent number: 5055286
    Abstract: Metal ions contained in hydrogen peroxide can be removed efficiently, safely and inexpensively by contacting hydrogen peroxide to be purified with an anion exchange resin with a chelating agent adsorbed therein.
    Type: Grant
    Filed: June 15, 1988
    Date of Patent: October 8, 1991
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Satoru Watanabe, Osami Ohura
  • Patent number: 5041569
    Abstract: Styrene oxide is prepared by reacting styrene and hydrogen peroxide in a heterogeneous system in the presence of a bis(tri-n-alkyltinoxy)molybdic acid and an amine represented by the following general formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each independently represent H, CH.sub.3, C.sub.2 H.sub.5, C.sub.3 H.sub.7, C.sub.4 H.sub.9, or HOCH.sub.2 CH.sub.2.
    Type: Grant
    Filed: January 17, 1990
    Date of Patent: August 20, 1991
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Saburo Enomoto, Masami Inoue, Osami Ohura, Tutomu Kamiyama, Hirohisa Nitoh
  • Patent number: 5030373
    Abstract: An aqueous solution containing 0.1 g/l or more of piperidine or a derivative, 100-500 g/l of sulfuric acid, 10-50 g/l of hydrogen peroxide and 0.5 g/l or more of phosphoric acid is used for treating the surface of copper or copper alloy used in manufacturing of printed circuit.
    Type: Grant
    Filed: March 8, 1990
    Date of Patent: July 9, 1991
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Toshiya Kimura, Koichi Wakashima, Hidebumi Ohnuki, Shigeki Nakajima, Katsutoshi Itani, Akira Hirai
  • Patent number: 4943661
    Abstract: An amine-substituted thiourea dioxide is obtained by reacting thiourea dioxide and an aliphatic or aromatic primary amine in a neutral or acidic pH range.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: July 24, 1990
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Hirohisa Nitoh, Osami Ohura, Morio Suzuki
  • Patent number: 4610802
    Abstract: Activating thiourea dioxide is characterized by incorporating in the thiourea dioxide a substance which dissolves in water or an acidic aqueous solution and produces hydrogen.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: September 9, 1986
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Koichiro Fujiyasu, Shigeki Yoneyama, Haruhiko Ito
  • Patent number: 4382147
    Abstract: 4,4'-Dihydroxydiphenyl sulfone is isolated from a mixture of dihydroxydiphenyl sulfone isomers by heat dissolving the mixture in phenol and then cooling the resulting solution thereby allowing 4,4'-dihydroxydiphenyl sulfone to precipitate as an adduct with phenol.
    Type: Grant
    Filed: September 9, 1981
    Date of Patent: May 3, 1983
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Hirotsugu Kitamura, Yasumasa Shimizu, Osami Ohura
  • Patent number: 4244690
    Abstract: According to this invention, there is provided an improved method of dyeing fibrous products characterized in that, in the dyeing of fibrous products using an oxidation-reduction dyeing type dye and an aqueous alkali solution of thiourea dioxide as a reducing solution, the reduction of the dye with the said aqueous alkali solution of thiourea dioxide is carried out in the presence of one or more substances selected from the group consisting of saturated aliphatic ketones having 3 to 10 carbon atoms, saturated aliphatic ketocarboxylic acids having 3 to 10 carbon atoms and alicyclic ketones having 3 to 10 carbon atoms.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: January 13, 1981
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kanji Sato, Kazuyoshi Kushibe, Masaru Nishii, Yasuhiro Kanaya, Yasumasa Kawabe
  • Patent number: 4240791
    Abstract: According to this invention, there is provided a method of dyeing fibrous products characterized in that, in the dyeing of fibrous products using an oxidation-reduction dyeing type dye and an aqueous alkali solution of thiourea dioxide as a reducing solution, the reduction of the dye with the said aqueous alkali solution of thiourea dioxide is carried out in the presence of one or more dialdehyde compounds selected from dialdehyde compounds represented by the general formulaOHC--R--CHO (I)in which R is a saturated or unsaturated aliphatic or aromatic organic compound radical.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: December 23, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kanji Sato, Kazuyoshi Kushibe, Masaru Nishii, Yasuhiro Kanaya, Yasumasa Kawabe
  • Patent number: 4238411
    Abstract: According to this invention there is provided a method of recovering thiourea dioxide characterized in that in the production of thiourea dioxide by the reaction of thiourea and hydrogen peroxide in an aqueous solvent, the waste liquor after separation of the crystals of thiourea dioxide after reaction is treated with an ion-exchange resin to remove side reaction products and impurities contained therein, and is then concentrated with a reverse-osmotic membrane to crystallize the thiourea dioxide dissolved therein.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: December 9, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Osami Ohura, Osamu Fujimoto
  • Patent number: 4235812
    Abstract: According to this invention there is provided a process for preparing thiourea dioxide characterized in that in the production of thiourea dioxide by the reaction of thiourea and hydrogen peroxide in an aqueous solvent, ammonium bicarbonate is added to the reaction solution at a proper time.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: November 25, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Osamu Fujimoto, Jiro Watanabe, Kazuyoshi Kushibe
  • Patent number: 4233238
    Abstract: According to this invention there is provided a process for preparing thiourea dioxide characterized in that in the production of thiourea dioxide by the reaction of thiourea and hydrogen peroxide in an aqueous solvent, the filtrate after separation of the crystals of thiourea dioxide after reaction is treated with an ion-exchange resin to remove side reaction products and impurities contained therein and then is used again as a reaction solvent.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: November 11, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Osami Ohura, Osamu Fujimoto
  • Patent number: 4197256
    Abstract: According to this invention, there is provided a method of stabilizing an alkaline aqueous solution of thiourea dioxide characterized in that one or more substances selected from the group consisting of aliphatic ketones, alicyclic ketones and aliphatic dialdehydes are added to the said alkaline aqueous solution of thiourea dioxide.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: April 8, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kanji Sato, Kazuyoshi Kushibe, Masaru Nishii, Yasuhiro Kanaya, Yasumasa Kawabe
  • Patent number: 4097478
    Abstract: According to the present invention, there is provided a process for preparing pyrazines characterized in that a diol represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 are each a hydrogen atom or a hydrocarbon radical, and a diamine represented by the formula ##STR2## wherein R.sub.3 and R.sub.4 are each a hydrogen atom or a hydrocarbon radical, are subjected to a gas phase contact reaction in the presence of a zinc-containing catalyst.
    Type: Grant
    Filed: March 31, 1977
    Date of Patent: June 27, 1978
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventor: Kanji Sato