Abstract: A fuel cell reactor, preferably a solid oxide fuel cell (SOFC) reactor, for performing direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product is confined by walls, where reactants are flown in the anode compartments and air is introduced to the cathode compartments, and where oxygen is transferred from one side of the walls to the other side to promote or inhibit a chemical reaction. The process for direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product takes place in the anode compartment of the reactor, in which produced hydrogen, limiting the conversion to the equilibrium, is reacted in situ with oxygen ions transferred from the cathode compartment to produce steam, thereby removing the equilibrium-limiting hydrogen from the reaction.
Abstract: A method and reactor for performing exothermic reactions with parallel operated catalyst modules arranged in stacked order within a pressure shell and adapted to axial flow of process gas through one or more catalyst layers and at least one catalyst layer cooled by an intrabed heat exchanger.
Type:
Application
Filed:
December 19, 2018
Publication date:
November 26, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Christian Henrik Speth, Tommy Lykke Wind, Uffe Bach Thomsen, Anders Helbo Hansen
Abstract: A process for the removal of nitrous oxide (N2O) contained in a process off-gas in an axial flow reactor. The process includes the steps of (a) adding an amount of reducing agent into the process off-gas; (b) in a first stage passing in axial flow direction the process off-gas admixed with the reducing agent through a first monolithic shaped catalyst active in decomposing nitrous oxide by reaction with the reducing agent to provide a gas with a reduced amount of nitrous oxide and residual amounts of reducing agent; and (c) in a second stage passing the gas with a reduced amount of nitrous oxide and residual amounts of the reducing agent in axial flow direction through a second monolithic shaped catalyst active in oxidation of the residual amounts of the reducing agent.
Type:
Application
Filed:
May 12, 2020
Publication date:
November 26, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Janus Emil Münster-Swendsen, Niklas Bengt Jakobsson
Abstract: A process for the cleaning of a lean gas stream contaminated with volatile organic compounds (VOCs) and/or sulfur-containing compounds comprises the steps of adding ozone to the contaminated lean gas stream, subjecting the ozone-containing lean gas stream to ultraviolet irradiation, thereby transforming VOCs to particles, maintaining the irradiated gas stream in a stay zone for a sufficient time to allow aerosol particle growth, and passing the gas stream through a catalytic bag filter at a temperature down to room temperature to remove the formed particles and eliminate any remaining ozone. The bag filter has been made catalytic by impregnation with one or more metal oxides in which the metals are selected from V, W, Pd and Pt, supported on TiO2.
Type:
Grant
Filed:
September 11, 2017
Date of Patent:
November 17, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Janus Emil Münster-Swendsen, Niklas Bengt Jakobsson
Abstract: A catalytic reactor comprises a filter unit which extracts and collects particles from the fluid flow stream above the reactor internals, the filter unit comprises elements which are safely, easily and quickly handled without the need for tools.
Abstract: In a novel method for start-up heating of a converting re-actor in an ammonia synthesis plant, the conventional use of a gas fired heater is replaced by inductive heating. The inductive heating is obtained using an alternating high frequency current, which is passed through an inductive coil located inside the reactor, especially mounted inside a pressure shell. The method makes it possible to run reactions at high temperatures and high pressures in a very efficient way.
Abstract: The invention provides a method for the production of a supported nickel catalyst, in which an aqueous mixture comprising an alkali metal salt plus other metal salts is sintered to form a support material. A supported nickel catalyst comprising potassium ?-alumina is also provided.
Type:
Grant
Filed:
September 14, 2017
Date of Patent:
September 22, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Joachim Harteg Jacobsen, Charlotte Vinding Ovesen, Christian Daugaard
Abstract: A u-tube heat exchanger has inlet tubes arranged in a pressure neutral inlet tube plate, a heating medium flows via the inlet tubes into u-tubes arranged in a tube sheet where the medium splits in two and flows from both ends of the u-tubes into a heating medium outlet chamber and exits the heat exchanger via an outlet nozzle.
Abstract: A process for producing UREA, said process comprising the steps of:—purification of a hydrocarbon feed gas removing Sulphur and/or chloride components if present, —reforming the hydrocarbon feed gas in a reforming step where the steam/carbon ratio is less than 2.6 thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —optionally adding H2O to the synthesis gas from the reforming step maintaining an overall steam/carbon less than 2.
Type:
Application
Filed:
March 7, 2018
Publication date:
July 23, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Christian Henrik Speth, Per Juul Dahl, Annette E. Kroll Jensen, Niels Christian Schjødt, Marcus Symreng
Abstract: Method for the preparation of a monolithic catalyst for the reduction of nitrogen oxides VOC and carbon monoxide in an off-gas, the catalyst comprises at least one platinum group metal, vanadium, titania and optionally tungsten oxide.
Type:
Grant
Filed:
June 19, 2017
Date of Patent:
July 21, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Kim Hougaard Pedersen, Viggo Lucassen Hansen, Francesco Castellino
Abstract: The invention relates to a catalyst material comprising a support, a first metal and a second metal on said support. The first and second metals are in the form of a chemical compound. The first metal is Fe, Co or Ni, and the second metal is selected from the group consisting of Sn, Zn and In. The invention also relates to a process for the preparation of hydrogen cyanide (HCN) from methane (CH4) and ammonia (NH3), wherein the methane and ammonia are contacted with a catalyst according to the invention.
Type:
Grant
Filed:
November 30, 2018
Date of Patent:
July 14, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Burcin Temel McKenna, Poul Erik Højlund Nielsen
Abstract: A process for co-production of methanol and ammonia in parallel based on autothermal reforming with oxygen enriched air from electrolysis of water and separation of air and preparation of ammonia with hydrogen from the electrolysis of water and nitrogen from the separation of air.
Abstract: A fuel cell stack comprises a thin process-gas-connection-endplate with a temperature expansion coefficient which is substantially the same as the temperature expansion coefficient of the plurality of fuel cells and interconnects forming the fuel cell stack, the length and width of the thin process-gas-connection-endplate is matching the length and width of the fuel cells and interconnects and the process-gas-connection-endplate is sealed to the stack of cells and interconnects so the process-gas-connection-endplate, cells and interconnects form one integrated unit, wherein process gas distribution tubes are fixed connected, e.g. welded or brazed to the process-gas-connection-endplate.
Abstract: The present application relates to a process for treating the off gas from a carbon black process, said process comprising the steps of: providing an off gas from a carbon black process, reacting said off gas in a first reaction step forming water and S, and condensing the S at a temperature Tcon where S is in a liquid phase and the water is in gas form thereby achieving a gaseous stream comprising water and a liquid stream comprising S, and wherein the first reaction step is carried out over a monolith catalyst.
Type:
Application
Filed:
January 25, 2018
Publication date:
June 18, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Niklas Bengt Jakobsson, Peter Bo Olsen, Janus Emil Münster-Swendsen
Abstract: A process for combined removal of siloxanes and sulfur-containing compounds from biogas streams, such as streams from landfills or anaerobic digesters, comprises heating the biogas stream and optionally mixing it with air, feeding the gas to a first filter unit with high temperature resistance, injecting a dry sorbent into the first filter unit to capture siloxanes present in the gas, recycling part of the exit gas from the first filter unit to the inlet thereof for the sulfur-containing compounds to be captured by the dry sorbent or optionally to a second filter unit inlet for the sulfur-containing compounds to be captured by a sulfur-specific sorbent and recovering clean gas from the first or optionally from the second filter unit.
Type:
Grant
Filed:
June 13, 2017
Date of Patent:
June 16, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Niklas Bengt Jakobsson, Janus Emil Münster-Swendsen
Abstract: A catalyst-containing ceramic dust filter for off-gas or exhaust gas cleaning is prepared by a method comprising the steps of making a water-based impregnation slurry, which comprises a catalytically effective amount of at least one catalytically active metal and an oxide support, to form a catalytically active metal oxide support, impregnating the filter substrate with the impregnation slurry, spraying from the inside to control the amount of liquor while leaving the outer few millimeters of the filter wall dry, and drying the impregnated filter. The impregnated filter is preferably dried by using microwave energy.
Abstract: Oxygen is removed from a gas feed such as a landfill gas, a digester gas or an industrial CO2 off-gas by removing sulfur-containing compounds and siloxanes from the feed gas, heating the feed gas, injecting one or more reactants for oxygen conversion into the heated feed gas, carrying out a selective catalytic oxygen conversion in at least onesuitable reactor and cleaning the resulting oxygen-depleted gas. The reactants to be injected comprise one or more of H2, CO, ammonia, urea, methanol, ethanol and dimethylether (DME).
Abstract: A process including (a) directing a hydrocarbon mixture to contact a material catalytically active in hydrocracking under hydrocracking conditions, (b) providing a first hydrocracked product, (c) directing an amount of the first hydrocracked product and an amount of a converted hydrocracked product to a product separation step separating it into one or more products and a recycle oil having a higher boiling point than the products, (d) directing the recycle oil to contact a second material catalytically active in hydrocracking under hydrocracking conditions providing a second hydrocracked product, (e) directing at least an amount of the second hydrocracked product as feed to a second separation step, separating the second hydrocracked product in at least two fractions, a converted hydrocracked product and an unconverted oil an unconverted oil having a higher average boiling point than the recycle oil, (f) withdrawing at least an amount of the unconverted oil as purge.