Patents Assigned to Toray Battery Separator Film Co., Ltd.
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Publication number: 20170005309Abstract: Disclosed is an organic/inorganic composite porous film comprising: (a) inorganic particles; and (b) a binder polymer coating layer formed partially or totally on surfaces of the inorganic particles, wherein the inorganic particles are interconnected among themselves and are fixed by the binder polymer, and interstitial volumes among the inorganic particles form a micropore structure. A method for manufacturing the same film and an electrochemical device including the same film are also disclosed. An electrochemical device comprising the organic/inorganic composite porous film shows improved safety and quality.Type: ApplicationFiled: September 15, 2016Publication date: January 5, 2017Applicants: LG Chem, Ltd., TORAY BATTERY SEPARATOR FILM CO., LTD.Inventors: Hyun Hang YONG, Sang Young LEE, Seok Koo KIM, Soon Ho AHN, Jung Don SUK
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Patent number: 9502705Abstract: A microporous membrane includes a low melting polypropylene, the low melting polypropylene being a polypropylene homopolymer or copolymer having an MFR?2.0×102, a Tm of 85.0° C. to 130.0° C., and a Te-Tm?10° C.Type: GrantFiled: December 20, 2011Date of Patent: November 22, 2016Assignee: Toray Battery Separator Film Co., Ltd.Inventors: Patrick Brant, Takeshi Ishihara, Satoshi Miyaoka, Donna J. Crowther, Koichi Kono
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Publication number: 20160336569Abstract: A battery separator is disclosed. The battery separator includes a polyolefin porous membrane which has a plurality of protrusions including a polyolefin. The protrusions are interspersed randomly on at least one surface of the polyolefin porous membrane at a density of not less than 3 protrusions/cm2 and not greater than 200 protrusions/cm2. The protrusions have a size W, where 5 ?m?W?50 ?m, and the protrusions have a height H, where 0.5 ?m?H. The battery separator also includes a modified porous layer, including a fluorine-based resin, and a plurality of inorganic particles laminated on the at least one surface of the polyolefin porous membrane. A concentration of the inorganic particles is not less than 40 wt. % and is less than 80 wt. %.Type: ApplicationFiled: December 16, 2014Publication date: November 17, 2016Applicant: TORAY BATTERY SEPARATOR FILM CO., LTD.Inventors: Naoki MIZUNO, Koichi MATANO
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Patent number: 9492965Abstract: A multi-layer, microporous polyolefin membrane comprising a polypropylene layer and a polyethylene resin layer and having well-balanced permeability, mechanical strength, heat shrinkage resistance, shutdown properties and meltdown properties can be obtained by (1) forming a sheet comprising a gel-like polypropylene layer containing a membrane-forming solvent or a polypropylene layer containing no membrane-forming solvent and a gel-like polyethylene resin layer containing a membrane-forming solvent, stretching the sheet at two-stage temperatures, and then removing the membrane-forming solvent, or (2) forming a gel-like polypropylene sheet containing a membrane-forming solvent or a polypropylene sheet containing no membrane-forming solvent, and a gel-like polyethylene resin sheet containing a membrane-forming solvent, stretching them at two-stage temperatures, removing the membrane-forming solvent, and then laminating the resultant microporous polypropylene membrane and the resultant microporous polyethylene meType: GrantFiled: October 19, 2006Date of Patent: November 15, 2016Assignee: TORAY BATTERY SEPARATOR FILM CO., LTDInventors: Kotaro Takita, Shintaro Kikuchi
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Publication number: 20160329609Abstract: A multi-layer, microporous polyolefin membrane having at least three layers, which comprises first microporous layers made of a polyethylene resin for constituting at least both surface layers, and at least one second microporous layer comprising a polyethylene resin and polypropylene and disposed between both surface layers, the heat of fusion (?Hm) of the polypropylene measured by differential scanning calorimetry being 90 J/g or more, and the polypropylene content in the second microporous layer being 50% or less by mass based on 100% by mass of the total of the polyethylene resin and the polypropylene.Type: ApplicationFiled: July 21, 2016Publication date: November 10, 2016Applicant: TORAY BATTERY SEPARATOR FILM CO., LTDInventors: Shintaro KIKUCHI, Kotaro TAKITA, Koichi KONO
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Patent number: 9490463Abstract: Disclosed is an organic/inorganic composite porous film comprising: (a) inorganic particles; and (b) a binder polymer coating layer formed partially or totally on surfaces of the inorganic particles, wherein the inorganic particles are interconnected among themselves and are fixed by the binder polymer, and interstitial volumes among the inorganic particles form a micropore structure. A method for manufacturing the same film and an electrochemical device including the same film are also disclosed. An electrochemical device comprising the organic/inorganic composite porous film shows improved safety and quality.Type: GrantFiled: March 5, 2013Date of Patent: November 8, 2016Assignees: LG CHEM, LTD., TORAY BATTERY SEPARATOR FILM CO., LTDInventors: Hyun Hang Yong, Sang Young Lee, Seok Koo Kim, Soon Ho Ahn, Jung Don Suk
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Patent number: 9431642Abstract: A multi-layer, microporous polyolefin membrane having at least three layers, which comprises first microporous layers made of a polyethylene resin for constituting at least both surface layers, and at least one second microporous layer comprising a polyethylene resin and polypropylene and disposed between both surface layers, the heat of fusion (?Hm) of the polypropylene measured by differential scanning calorimetry being 90 J/g or more, and the polypropylene content in the second microporous layer being 50% or less by mass based on 100% by mass of the total of the polyethylene resin and the polypropylene.Type: GrantFiled: July 14, 2006Date of Patent: August 30, 2016Assignee: TORAY BATTERY SEPARATOR FILM CO., LTD.Inventors: Shintaro Kikuchi, Kotaro Takita, Koichi Kono
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Publication number: 20160240830Abstract: Considering that the battery separator of embodiments of the present invention will have thinner materials and lower costs, provided are a polyolefin porous membrane with exceptionally high peel strength between the polyolefin porous membrane and a modified porous layer, suitable for high-speed processing during slit processing and the battery assembly process, and suitable for laminating on a modified porous layer, and a battery separator obtained by laminating a modified porous layer on the polyolefin porous membrane. A polyolefin porous membrane comprising protrusions of polyolefin having a size (W) within a range of 5??m?W?50 ?m and a height (H) within a range of 0.5 ?m?H and irregularly disposed on both sides of the polyolefin porous membrane in a density not less than 3/cm2 and not more than 200/cm2 per side, and the polyolefin porous membrane having a thickness of not more than 25 ?m.Type: ApplicationFiled: September 29, 2014Publication date: August 18, 2016Applicant: TORAY BATTERY SEPARATOR FILM CO., LTD.Inventors: Naoki MIZUNO, Koichi MATANO
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Patent number: 9419265Abstract: The present disclosure provides a method for manufacturing an electrospun microfiber non-woven web with high strength for a lithium secondary battery, a non-woven web manufactured therefrom, and a separator comprising the non-woven web. More specifically, the present disclosure provides a microfiber non-woven web manufactured by bringing a solution of engineering plastic resin with high heat-resistance into electrospinning, the manufacture thereof, and a separator comprising the web. According to the present disclosure, the engineering plastic resin with high heat-resistance is used in the manufacture of the microfiber non-woven web to provide improved physical properties including tensile strength and good heat-resistance and chemical-resistance, as compared with conventional polyethylene-based separators.Type: GrantFiled: October 31, 2014Date of Patent: August 16, 2016Assignees: LG CHEM, LTD., TORAY BATTERY SEPARATOR FILM CO., LTD.Inventors: Won-Pill Hwang, Byeong-Gyu Cho, Young-Deok Kim
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Publication number: 20160226051Abstract: A preparation method of a separator according to the present disclosure includes preparing an aqueous slurry including inorganic particles, a binder polymer, and an aqueous medium, and coating the aqueous slurry on at least one surface of a porous polymer substrate to form an organic-inorganic composite porous coating layer, wherein capillary number of the aqueous slurry has a range between 0.3 and 65.Type: ApplicationFiled: April 1, 2015Publication date: August 4, 2016Applicants: LG CHEM, LTD., TORAY BATTERY SEPARATOR FILM CO., LTD.Inventors: Joo-Sung LEE, Sun-Mi JIN
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Patent number: 9337461Abstract: A composite porous membrane is a composite porous membrane, wherein a porous membrane B including a heat-resistant resin is laminated on the surface of a polypropylene resin of an outermost layer of a porous membrane A composed of at least one layer, wherein at least one of the outermost layers comprises the polypropylene resin. The composite porous membrane satisfies a particular range of peeling strength at the interface between the porous membrane A and the porous membrane B and a particular range of difference between air resistance of the whole composite porous membrane and air resistance of the porous membrane A, provided that the porous membrane A satisfies a particular range of average pore size and porosity.Type: GrantFiled: August 29, 2011Date of Patent: May 10, 2016Assignee: Toray Battery Separator Film Co., Ltd.Inventors: Naoki Mizuno, Michihiko Irie, Yoshitaka Ayuzawa, Masanori Nakamura
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Publication number: 20160118639Abstract: Provided is a microporous polyolefin membrane which has excellent oxidation resistance and electrolyte injection performance and further has excellent permeability and strength balance. The multilayer, microporous polyolefin membrane has a first microporous layer containing polypropylene. The electrolyte injection performance is 20 seconds or less, at least one surface layer is the first microporous layer, and the PP distribution in the first microporous layer is uniform in the in-plane direction.Type: ApplicationFiled: May 29, 2014Publication date: April 28, 2016Applicant: TORAY BATTERY SEPARATOR FILM CO., LTD.Inventor: Takeshi ISHIHARA
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Patent number: 9295950Abstract: The invention relates to microporous membranes comprising polymer and having well-balanced permeability, shutdown temperature, and pin puncture strength. The invention also relates to methods for making such membranes, and the use of such membranes as battery separator film in, e.g., lithium ion secondary batteries.Type: GrantFiled: March 5, 2010Date of Patent: March 29, 2016Assignee: Toray Battery Separator Film Co., Ltd.Inventors: Takeshi Ishihara, Satoshi Miyaoka, Koichi Kono, Donna J. Crowther, Patrick Brant
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Patent number: 9289728Abstract: The invention relates to microporous membranes comprising polymer and having well-balanced permeability, shutdown temperature, and pin puncture strength. The invention also relates to methods for making such membranes, and the use of such membranes as battery separator film in, e.g., lithium ion secondary batteries. The membrane has a shutdown temperature <130.5° C.Type: GrantFiled: March 5, 2010Date of Patent: March 22, 2016Assignee: Toray Battery Separator Film Co., Ltd.Inventors: Takeshi Ishihara, Satoshi Miyaoka, Koichi Kono, Donna J. Crowther, Patrick Brant
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Patent number: 9293754Abstract: A battery separator includes a porous membrane A including a polyethylene resin, and a porous membrane B laminated thereon including a heat resistant resin and inorganic particles or cross-linked polymer particles, wherein the porous membrane A satisfies expressions (a) to (c), and the entire battery separator satisfies expressions (d) to (f).Type: GrantFiled: February 7, 2013Date of Patent: March 22, 2016Assignee: Toray Battery Separator Film Co., Ltd.Inventors: Naoki Mizuno, Michihiko Irie, Masanori Nakamura, Ken Shimizu
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Patent number: 9287545Abstract: The separator of the present invention comprises a porous composite having a porous substrate and a first porous coating layer formed on at least one surface of the porous substrate and comprising a mixture of inorganic particles and a first binder polymer; and a second porous coating layer formed on a first surface of the porous composite and comprising a mixture of cathode active material particles, a second binder polymer and a first conductive material, a third porous coating layer formed on a second surface of the porous composite and comprising a mixture of anode active material particles, a third binder polymer and a second conductive material, or both of the second porous coating layer and the third porous coating layer. Also, the separator of present invention may further comprise a fourth porous coating layer formed on at least one outermost surface thereof and comprising a fourth binder polymer.Type: GrantFiled: March 27, 2013Date of Patent: March 15, 2016Assignees: LG Chem, Ltd., Toray Battery Separator Film Co., Ltd.Inventors: Joo-Sung Lee, Jong-Hun Kim, Jin-Woo Kim
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Patent number: 9287542Abstract: A multi-layer, microporous polyolefin membrane comprising first microporous layers constituting at least both surface layers, and at least one second microporous layer disposed between both surface layers, the first microporous layer comprising a first polyethylene resin containing 8% or more by mass of ultra-high-molecular-weight polyethylene having a weight-average molecular weight of 1×106 or more, the second microporous layer comprising a second polyethylene resin containing 7% or less by mass of the ultra-high-molecular-weight polyethylene, and having a structure in which a pore diameter distribution curve obtained by mercury intrusion porosimetry has at least two peaks, and the total thickness of the first microporous layers being 15-60% per 100% of the total thickness of the first and second microporous layers.Type: GrantFiled: July 12, 2012Date of Patent: March 15, 2016Assignee: TORAY BATTERY SEPARATOR FILM CO., LTDInventors: Kotaro Takita, Junko Takita, Shintaro Kikuchi
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Patent number: 9276247Abstract: A separator including a porous substrate, and a porous coating layer formed on at least one surface of the porous substrate and including a mixture of inorganic particles and a binder polymer. A continuous or discontinuous patterned layer is formed on the surface of the porous coating layer to allow an electrolyte solution to permeate therethrough. The continuous or discontinuous patterned layer may be formed with continuous grooves to allow an electrolyte solution to permeate therethrough. Due to this structure, the wettability of the separator with an electrolyte solution is improved, shortening the time needed to impregnate the electrolyte solution into the separator.Type: GrantFiled: November 29, 2012Date of Patent: March 1, 2016Assignees: LG CHEM, LTD., TORAY BATTERY SEPARATOR FILM CO., LTD.Inventors: Joo-Sung Lee, Jeong-Min Ha, Sun-Mi Jin, Bo-Kyung Ryu, Jong-Hun Kim
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Publication number: 20160013461Abstract: A polyolefin porous membrane disclosed. The membrane includes a plurality of protrusions of polyolefin having a size (W) of 5 ?m?W?50 ?m and a height (H) of 0.5 ?m?H. The protrusions are disposed on one side of the polyolefin porous membrane with a density of at least 3/cm2 and at most 200/cm2, and the polyolefin porous membrane has a thickness of at most 20 ?m. A battery separator including the membrane is also disclosed.Type: ApplicationFiled: February 12, 2014Publication date: January 14, 2016Applicant: Toray Battery Separator Film Co., Ltd.Inventors: Naoki MIZUNO, Koichi MATANO
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Patent number: 9203071Abstract: The invention relates to microporous membranes having at least two layers, a first layer comprising polymethylpentene and a second layer which comprises a polymer and has a composition that is not substantially the same as that of the first layer. The invention also relates to methods for making such membranes and the use of such membranes as battery separator film in, e.g., lithium ion batteries.Type: GrantFiled: June 8, 2010Date of Patent: December 1, 2015Assignee: Toray Battery Separator Film Co., Ltd.Inventors: Takeshi Ishihara, Satoshi Miyaoka