Patents Assigned to Total Raffinage Distribution S.A.
  • Publication number: 20030006169
    Abstract: This invention relates to a method for drying the charge of a unit that treats petroleum cuts with a low water charge that consists in injecting a hydrolysable chemical compound into said charge.
    Type: Application
    Filed: July 3, 2002
    Publication date: January 9, 2003
    Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.
    Inventors: Pedro Nascimento, Jacques Couillard, Jean-Louis Mauleon, Alain Milan
  • Publication number: 20020139712
    Abstract: A method for the isomerization of a hydrocarbonic charge containing a substantial quantity of paraffin base hydrocarbons with 5 or 6 carbon atoms and a benzene content that is greater than or equal to 2% by weight, in which the charge to be treated passes, in the presence of hydrogen, at a total pressure greater than or equal to 10.105 Pa (10 bars) and at an average temperature ranging between 100 and 200° C., through at least one reactor (5) containing a catalyst. An adjunctive fluid is introduced in the upstream section of the reaction zone; a fluid that at 40° C. and under atmospheric pressure (1.0134.105 Pa), is in a gaseous phase and has a density that is less than or equal to that of the normal-pentane taken into account under the same conditions.
    Type: Application
    Filed: March 28, 2002
    Publication date: October 3, 2002
    Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.
    Inventors: Marc Fersing, Pedro Nascimento
  • Patent number: 6451615
    Abstract: Colored indicator for measuring the distribution of hydrocarbon families contained in a mixture, a procedure for obtaining it and its uses. In the colored indicator, the colorants that are able to be eluted with the family of aromatic hydrocarbons are free of organic compounds having an affinity with oxygenated compounds containing at least 6 carbon atoms.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: September 17, 2002
    Assignee: Total Raffinage Distribution S. A.
    Inventors: Francoise Borg, Luc Seyfried, Dominique Lefebvre
  • Patent number: 6448198
    Abstract: The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 135 m2/g, a pore volume greater than or equal to 0.16 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions. In a preferred embodiment of the method of the present invention, a hydrated zirconia gel is washed with a soluble polar organic solvent (other than water).
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: September 10, 2002
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Georges Szabo, Pedro Nascimento, Alain Milan, Sebastien Decker, Joeri Denayer, Jean-Pierre Dath
  • Patent number: 6441264
    Abstract: A method for separating at least a benzothiophene compound from a hydrocarbon mixture is disclosed. The method includes contacting the mixture of a fraction obtained therefrom with a reagent including an acceptor complexing agent &pgr;, to obtain a donor-acceptor complex between the acceptor complexing agent and the benzothiophene compound; and separating the complex from the mixture, or from the fraction, to obtain a fraction depleted or purified in the benzothiophene compound.
    Type: Grant
    Filed: April 17, 2000
    Date of Patent: August 27, 2002
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Marc Lemaire, Michéle Monnet, Michel Vrinat, Valérie Lamure, Emmanuelle Sanson, Alexandra Milenkovic
  • Publication number: 20020096452
    Abstract: This present invention concerns a procedure for cracking, in a fluidized bed, a hydrocarbon charge wherein the cooling particles, which may optionally also be catalytic particles, circulate in two successive reaction chambers (1; 16), in each of which they are brought into contact with at least one cut of hydrocarbons, and the reaction effluents from each of said chambers are directed towards one and the same fractionating unit.
    Type: Application
    Filed: July 3, 2001
    Publication date: July 25, 2002
    Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.
    Inventors: Marcellin Espeillac, Pierre Crespin
  • Patent number: 6416657
    Abstract: A method for the isomerization of a hydrocarbonic charge containing a substantial quantity of paraffin base hydrocarbons with 5 or 6 carbon atoms and a benzene content that is greater than or equal to 2% by weight, in which the charge to be treated passes, in the presence of hydrogen, at a total pressure greater than or equal to 10.105 Pa (10 bars) and at an average temperature ranging between 100 and 200° C., through at least one reactor (5) containing a catalyst. An adjunctive fluid is introduced in the upstream section of the reaction zone; a fluid that at 40° C. and under atmospheric pressure (1.0134.105 Pa), is in a gaseous phase and has a density that is less than or equal to that of the normal-pentane taken into account under the same conditions.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: July 9, 2002
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Marc Fersing, Pedro Nascimento
  • Publication number: 20020052431
    Abstract: An emulsion consists essentially of clear binders and possibly colored pigments, and contains at least one clear synthetic binder with a softening point or ball-ring temperature (TBA), measured according to the NFT 66-008 standard, that ranges between 30 and 100° C.
    Type: Application
    Filed: August 27, 2001
    Publication date: May 2, 2002
    Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.
    Inventors: Guy Lemoine, Jean-Philippe Gillet, Yannick Jolivet
  • Publication number: 20020052432
    Abstract: Bituminous compositions of the bitumen-polymer type, in homogenous phase, contain at least one bitumen base and are prepared from at least one polymer of the thermoplastic polyolefin type. These compositions have a thermoplastic polyolefin content of at least 1% by weight of which the crystallinity rate is greater than or equal to 30%, a melting temperature greater than or equal to 110° C. and a penetrability at 25° C. less than or equal to 300 tenths of a millimeter.
    Type: Application
    Filed: November 16, 2001
    Publication date: May 2, 2002
    Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.
    Inventors: Guy Lemoine, Jacques Nicaud, Jacques Jarrin
  • Patent number: 6375715
    Abstract: A receptacle (14) open in its upper part into which opens a conduit (13), is inserted between a device (11) for fast extraction and the stripping zone (18). The receptacle (14) consists at its base of at least one diffuser (15) fed in fluidization gas and to which the solid particles are put in a dense fluidized bed state (17), whose density ranges between 300 and 800 kg.m−3, then escape by overflow from the receptacle (14) toward the stripping zone (18) located below.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: April 23, 2002
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Jean-Louis Mauleon, Cyrille Mirgain
  • Patent number: 6350715
    Abstract: The invention pertains to a process for preparing an activated catalyst, to the activated catalyst composition and the use thereof in the conversion of hydrocarbon feedstocks, such as isomerisation. The catalyst composition comprising a Group VIII noble metal and a hydrocarbon-substituted aluminum compound on an alumina carrier is activated by contacting it with an inert gas in the absence of hydrogen at a temperature above 400° C., wherein at least when the hydrocarbon-substituted aluminum compound is a non-halide hydrocarbon-substituted aluminum compound, the catalyst composition is contacted with a halogen-containing gas either prior to the treatment with the inert gas or during the treatment with the inert gas, and subsequently cooling down the activated catalyst to ambient temperature in an inert gas optionally containing hydrogen or containing, at a temperature below 400° C.
    Type: Grant
    Filed: October 6, 1999
    Date of Patent: February 26, 2002
    Assignees: Total Raffinage Distribution S.A., Akzo Nobel N.V.
    Inventor: Gilbert Schuurhuis
  • Publication number: 20010001036
    Abstract: A process for hydrotreating a hydrocarbon feedstock (1) involving the use of at least one hydrotreatment, particularly hydrodesulfurization, reactor (2) and a fractionation unit (3), which latter contains two distinct injection zones (4,5) for the hydrocarbon feedstocks, a common zone (8) of vaporization of the light fractions and two distinct draw-off lines (6,7) for the liquid bottoms;
    Type: Application
    Filed: December 29, 2000
    Publication date: May 10, 2001
    Applicant: TOTAL RAFFINAGE DISTRIBUTION S.A.
    Inventors: Marcellin Espeillac, Pierre Crespin
  • Patent number: 6225517
    Abstract: An alkylation catalyst including a least one porous refractory metal oxide with at least one halogen on the surface thereof. The catalyst contains 0.005-1 wt % of at least one metal from groups IA and IIA of the periodic table of the elements and is particularly useful in an isobutane alkylation method using light olefins.
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: May 1, 2001
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Pedro Nascimento, Georges Szabo, Alain Milan
  • Patent number: 6217749
    Abstract: A process for hydrotreating a hydrocarbon feedstock (1) involving the use of at least one hydrotreatment, particularly hydrodesulfurization, reactor (2) and a fractionation unit (3), which latter contains two distinct injection zones (4, 5) for the hydrocarbon feedstocks, a common zone (8) of vaporization of the light fractions and two distinct draw-off lines (6, 7) for the liquid bottoms; the hydrocarbon feedstock (1) being subjected to a preliminary treatment either in a first hydrodesulfurization reactor (20) the operating conditions of which (P, T, LHSV) may be different from those of the hydrotreatment reactor (2), or in a sweetening apparatus or else in a sulfur trap, the hydrocarbon feedstock being then injected into the first injection zone (4) of the fractionation unit (3), the liquid bottoms being removed through the draw-off line (6) of the injection zone (4) and passed into a hydrotreatment reactor (2), the effluents from said reactor (2) being injected into a second injection zone (5) of the
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: April 17, 2001
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Marcellin Espeillac, Pierre Crespin
  • Patent number: 6194345
    Abstract: The invention relates to a process of activating a supported acid catalyst, and consists in the conversion of Lewis acid-type acid sites which are deposited on a solid substrate into activated acid sites in a non-oxydizing acid medium. The catalyst is exposed to a phase of activation in a medium containing a holohydric acid or a halohydric acid precursor, in the presence of at least one preferably parafinic hydrocarbon or hydrocarbon derivative, at a temperature greater than 20° and preferably between 100° C. and 250° C., and at a pressure of between 105 and 50,106 Pa, for a length of time sufficient to ensure conversion into activated acid sites.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: February 27, 2001
    Assignees: Total Raffinage Distribution S.A., Akzo Nobel N.V.
    Inventors: Peter Mangnus, Alain Milan, Georges Szabo
  • Patent number: 6180555
    Abstract: The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 150 m2/g, a pore volume greater than or equal to 0.20 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions.
    Type: Grant
    Filed: October 9, 1998
    Date of Patent: January 30, 2001
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Georges Szabo, Pedro Nascimento, Alain Milan, Sebsastien Decker
  • Patent number: 6159279
    Abstract: An asphalt-fines matrix contains a quantity of millings that ranges between 1 and 70% of the total weight of the incorporated mineral material, mixed with a heavy grade bituminous binder, and has a stiffness modulus E*, measured at 15.degree. C. and at 10 Hz, that ranges between 9.10.sup.3 and 15.10.sup.3 MPa.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: December 12, 2000
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Michel Malot, Yannick Jolivet
  • Patent number: 6158920
    Abstract: A roadway structure comprising from top to bottom:a top layer,at least one rigid foundation layer having a high modulus of rigidity and supporting the top layer,the ground, or an untreated material or a damaged roadway, andin addition particularly having an under layer beneath and adhered to the foundation layer, which under layer has a thickness such that it constitutes a support with a smooth and flat surface for the foundation layer laid thereon.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: December 12, 2000
    Assignee: Total Raffinage Distribution S.A.
    Inventor: Michel Malot
  • Patent number: 6156827
    Abstract: Bituminous compositions of the bitumen-polymer type, in homogenous phase, contain at least one bitumen base and are prepared from at least one polymer of the thermoplastic polyolefin type. These compositions have a thermoplastic polyolefin content of at least 1% by weight of which the crystallinity rate is greater than or equal to 30%, a melting temperature greater than or equal to 110.degree. C. and a penetrability at 25.degree. C. less than or equal to 300 tenths of a millimeter.
    Type: Grant
    Filed: February 17, 1999
    Date of Patent: December 5, 2000
    Assignees: Total Raffinage Distribution S.A., Institut Francais du Petrole
    Inventors: Guy Lemoine, Jacques Nicaud, Jacques Jarrin
  • Patent number: 6155101
    Abstract: A C.F.R. engine (26) is alternately supplied with a fuel being manufactured (22), sampled from the discharge line of the mixer and, through a line (24), with a reference product (25) of which the cetane number is known, by two separate supply circuits (22, 24) each having a high pressure fuel pump (33, 34), the C.F.R. engine (26) operating at a constant compression ratio.
    Type: Grant
    Filed: February 25, 1999
    Date of Patent: December 5, 2000
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Francois Renault, Daniel Lebreton, Jean-Pierre Drouault, Alain Picart