Patents Assigned to Total Raffinage Distribution S.A.
  • Patent number: 6136289
    Abstract: A process of preparing a ferrierite-type zeolite, with high crystallinity rate and having a anhydrous stage composition expressed by the formula M.sub.x (AlO.sub.2).sub.x (SiO.sub.2).sub.y, M being a cation of an alkaline metal such as Na or K, or a mix of both. The process contains a gel-producing step, by addition of boric acid to an aqueous aluminum-sulfate solution mixed with a aqueous solution containing oxides of Na and/or K and of Si, without the use of a structural agent. The invention also pertains to any zeolite obtained by this process, and its uses.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: October 24, 2000
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Georges Szabo, Paul Meriaudeau, Anh Tuan Vu, Sebastien Decker
  • Patent number: 6126813
    Abstract: The invention relates to a hydrocarbon catalytic cracking method in the presence of a catalyst in fluidized phase, within a tubular type reactor (1) containing an injection area.According to the invention, a substantial part of the load to be cracked is introduced into the injection area using at least one means of injection (3) of such load against the flow, in relation to the direction of flow of the catalyst grains, and a substantial part of the load to be cracked is simultaneously introduced in the same area using at least one means of injection (2) of such load in direction of the flow in relation to the direction of flow of the catalyst grains.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: October 3, 2000
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Marc Fersing, Mariano Del Pozo
  • Patent number: 6096104
    Abstract: Compositions including at least three metals (M1, M2, M3) are disclosed. The first metal (M1) is at least one metal selected from the iron group or the manganese group, and is preferably selected from iron, manganese, cobalt and nickel. The second metal (M2) is at least one metal selected from the rare earth group and is preferably selected from cerium, lanthanum, neodymium and praseodymiium. The third metal (M3) is selected from the group of alkaline or alkaline-earth metals, and is preferably selected from barium, strontium, calcium and lithium. The weight ratio (R) of metal (M3) to metal (M2) is greater than 0.15, and preferably greater than 1.5.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: August 1, 2000
    Assignees: Total Raffinage Distribution S.A., Gamlen Industries S.A.
    Inventors: Corinne Van den Neste, Jean Peyrot, Guy Brisset, Gerard Briard
  • Patent number: 5997726
    Abstract: A hydrocarbon catalytic cracking process in which, a substantial portion of the hydrocarbons is pulverized and placed in contact with a specific contact zone, which is composed of: a mixing chamber having a maximum section S.sub.2, the upper part of which is fed with a heated regenerated catalyst through an upper opening delimiting a catalyst-flow section S.sub.1, and a descending-flow reaction area, in which the solid-gas mixture emanating from the mixing chamber is poured through an intermediate opening having a section S.sub.3 located in the lower part of said chamber. The ratios S.sub.2 /S.sub.1 and S.sub.2 /S.sub.3 have values of between 1.5 and 8.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: December 7, 1999
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Marc Fersing, Mariano Del Pozo, Thierry Gauthier
  • Patent number: 5965784
    Abstract: An extraction process and an apparatus for separating aromatic compounds contained in a liquid hydrocarbon feedstock where the feedstock feed into the lower part of an extraction column is brought into intimate countercurrent contact therein with a third liquid and at least partially with at least one structured packing element (31) of the static mixer type contained in the upper part of the extraction column. Such third liquid (feed to the top of said column) is in the form of a solvent which is immiscible with the feedstock except for being capable of extracting the aromatic compounds. At least part of the extract phase rich in solvent and aromatic compounds is separated by liquid--liquid separation (26), preferably by gravity type decantation, into a phase rich in solvent and essentially depleted of raffinate, which is removed, and a phase rich in raffinate and impoverished in solvent, which is recycled to the extraction step. The extraction process is typically to be used to formulate lubricant oils.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: October 12, 1999
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Herve Bracou, Luc Gouzien
  • Patent number: 5954941
    Abstract: The invention concerns a jet engine fuel having the following characteristics:i) distilling range from 140 to 300.degree. C.;ii) cis-decalin/trans-decalin ratio greater than 0.2;iii) aromatics content less than 22% by volume;iv) sulfur content less than 100 ppm, andv) lower heating value per unit volume greater than 34.65 Mj/liter.Also process for making the same wherein for example a cut from catalytic cracking distilling between 140 and 300.degree.0 C. is subjected to a hydrotreatment step and then to a dearomatization step.
    Type: Grant
    Filed: April 28, 1997
    Date of Patent: September 21, 1999
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Sophie Mercier, Michel Laborde, Fran.cedilla.ois-Xavier Cormerais, Michel Thebault
  • Patent number: 5906229
    Abstract: Method and apparatus for the uniform dense pack filling of particles of a solid catalyst (6) in a tubular reactor, of the type comprising a plurality of vertical tubes (2) opening at their upper end at the surface of a tube plate, which connects them together and is substantially parallel to them, and having above the tube plate, a system for the uniform distribution in a falling rain of the particles of catalyst, the improvement including:an initial cylindrical wall adapted to rest around and above the tube plate, andcylindrical walls of successively smaller diameters (formed from the initial wall or separately) being also adapted to rest in succession on the tube plate in order to separate the tubes then currently completely filled with catalyst from the tubes not completely filled.
    Type: Grant
    Filed: April 28, 1997
    Date of Patent: May 25, 1999
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Yvon Haquet, Jean-Pierre Tref
  • Patent number: 5891821
    Abstract: A novel aqueous solution for the one step impregnation of catalytic supports, catalysts prepared from such solution, and the preparation and the use of catalysts prepared thereby. The catalysts prepared are used in the hydrotreatment of petroleum fractions and particularly in hydrodesulfurization and/or denitrogenization. The solution is a combination of at least one compound of a metal from group IVa (e.g. Zr), at least one compound of a metal from group VIa (e.g. Mo or W), at least one compound of a metal from group VIII (e.g. Co or Ni), and at least one water soluble amine (e.g. ethylenediamine or MEA).
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: April 6, 1999
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Olivier Poulet, Michel Bourgogne, Philippe Moldan
  • Patent number: 5853567
    Abstract: A method for reducing the viscosity of a liquid heavy hydrocarbon feedstock comprising the steps of bringing said feedstock to a temperature capable of cracking of at least a portion of the hydrocarbons present in said feedstock and introducing said feedstock into a bottom portion of a maturation device (i.e. a "soaker"), where the feedstock is displaced from the bottom upwards, to get evacuated from a top portion of the soaker towards a fractioning unit. The invention also relates to an apparatus comprising a soaker in which are located, transversely to the direction of displacement of the feedstock to be treated, a plurality of annular discs spaced apart from one another, each disc comprising a circular central passage substantially coaxial to the soaker, the treated feedstock circulating from the bottom portion upwards in the soaker through the central passages of the various annular discs.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: December 29, 1998
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Luc Gouzien, Elisabeth Mouchot, Pierre Lutran, Marc Persing
  • Patent number: 5810252
    Abstract: Methods and apparatus particularly useful for atomizing a heavy highly viscous liquid into fine droplets (such as petroleum distillate resid to droplets on the order of 100 thousandths of a millimeter), with the aid of at least one auxiliary gas. This employs in a nozzle head an array of a plurality of primary channels and at least two secondary channels associated with each said primary channel. The primary channels each have an inlet end connected to a high pressure source of liquid, and have an outlet end defining an atomization orifice. The secondary channels each have an inlet end being connected to at least one source of auxiliary gas and an outlet end. The outlets of the secondary channels each intersect with a commonly associated primary channel at the same or different locations upstream of the respective atomization orifice at angles of less than 90.degree., typically 45.degree. or less. Liquid is passed through a plurality of primary channels thereby forming a liquid core stream.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: September 22, 1998
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Yannick Pennamen, Didier Quevillon
  • Patent number: 5783068
    Abstract: The present invention relates to a process for dechlorinating a spent lubricating oil fraction, optionally mixed with another hydrocarbon stock. Upstream of the recycling operation in refining the spent oil, the latter is subjected to a dechlorination operation at least partially by passing it on a bed of particles (6) of a composition which neutralizes by absorption and containing, as active compound capable of fixing the chlorine, at least one metal oxide and/or at least one metal hydroxide.
    Type: Grant
    Filed: May 13, 1996
    Date of Patent: July 21, 1998
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Michel Laborde, Philippe Dolbecq
  • Patent number: 5782579
    Abstract: A pipe system for supplying liquid fuel to a underground tank from a supply station and for transfer of said fuel from said tank to at least one dispensing station, said system comprising an assembly of flexible inner piping through which the fuel flows and an assembly of flexible outer piping enveloping the inner piping. The assembly of outer piping is continuous and envelops the inner piping along its entire length without interruption between the supply station and the underground tank and/or between said tank and the dispensing station and advantageously with the inner piping centered within the outer piping by means of concentric spacers perforated to allow gasoline leaking thereinto to flow therepast along the thus formed annular spacing, and preferably also with a branch bypass pipe to interconnect the annular spacing of the outlet conduit with the annular spacing of the inlet conduit to allow collection of gasoline leaking into such spacings into a common gravity fed cup.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: July 21, 1998
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Jean-Claude Dupouy, Yannick Lallinec, Daniel Mahin
  • Patent number: 5763732
    Abstract: A method of isomerizing n-paraffins into isoparaffins in a cut of hydrocarbons with four carbon atoms or of hydrocarbons with five and/or six carbon atoms. The cut being processed enters at least one reactor containing a stationary catalyst bed. The charge travels over the bed. Either the rate of isomerization in the effluents or a parameter directly dependent thereon (such as the octane number) is preferably continuously measured. Some of the upstream catalyst, specifically between 1/3 and 2/3, is replaced with fresh catalyst once that rate has decreased 10 to 30% below a prescribed point. The charge is redirected through the reactor once the catalyst has been replaced.
    Type: Grant
    Filed: February 8, 1995
    Date of Patent: June 9, 1998
    Assignee: Total Raffinage Distribution , S.A.
    Inventors: Laurent Mariette, Marc Fersing, Michel Laborde, Jacques Couillard
  • Patent number: 5759250
    Abstract: The use of an asphalt having a penetrability at 25.degree. C. from 0 to 20 in the preparation of a road asphalt (i.e. a mixture of asphalt and mineral aggregate) intended in particular for building and strengthening roadbeds. Wherein, the asphalt content of the road asphalt is higher than 6 wt %. Also the road asphalt having such composition.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: June 2, 1998
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Michel Malot, Yannick Jolivet
  • Patent number: 5758699
    Abstract: A process for the uniform distribution of a comminuted solid in an enclosure into which the solid falls essentially vertically onto a mobile mechanism (particularly useful for charging catalyst particles to a reactor vessel) comprising deflector elements rotated around the same shaft and disposed on at least two vertically displaced levels. On each level is provided the same number of deflector elements of essentially identical shape, the deflector elements on the different levels being vertically disposed exactly above each other and, on each level, the deflector elements are rotated at the same speed so as to remain disposed vertically with respect to each other during the entire charging process.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: June 2, 1998
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Yvon Haquet, Thierry Patureaux
  • Patent number: 5716585
    Abstract: Process and apparatus for stripping fluidized solid particles countercurrently with a stripping fluid. This apparatus comprises at least one packing structure consisting of at least one element the flow cross-section of which is essentially transverse to the chamber axis, said element extending over the entire cross-section of the chamber in the circulation zone and consisting of cells or pathways through which pass the particles and the stripping fluid, said cells or pathways orienting the circulation of the fluid and of the particles to be stripped in approximately radial fashion.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: February 10, 1998
    Assignee: Total Raffinage Distribution, S.A.
    Inventors: Marie-Andree Senegas, Thierry Patureaux, Philippe Selem, Jean-Louis Mauleon
  • Patent number: 5703148
    Abstract: An asphalt-polymer composition containing:a) at least 25 to 97 wt % of an asphalt,b) at least 1 to 25 wt % of a polymer, andc) at least 2 to 50 wt % of aromatic compound(s),whereinthe aromatic compound(s) is present in an amount greater than 2 wt %,the at least one aromatic compound(s) and the polymer are present in amounts such that the ratio of amount present of aromatic compound to amount present of polymer is from 0.5 to 10, andthe composition has a FRAASS point of less than or equal to -13.degree. C. and a storage stability defined by a".DELTA. ring-and-ball" and a ".DELTA. penetrability" of less than or equal to 5. Also a process for preparing such asphalt-polymer composition including mixing the asphalt, the polymer and the aromatic compound at a temperature from 190.degree. to 300.degree. C. for a period of time preferably exceeding 30 minutes. The asphalt-polymer composition can be used as a road asphalt, emulsion or surface coating.
    Type: Grant
    Filed: March 16, 1995
    Date of Patent: December 30, 1997
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Yannick Jolivet, Michel Malot, Didier Jamois
  • Patent number: 5660716
    Abstract: A fluidized-bed process for catalytic cracking of a hydrocarbon feedstock where the hydrocarbon feedstock, particularly a feedstock with a high content of basic nitrogen compounds, and a catalyst circulate in the tubular zone co-currently from the top to the bottom, where the catalyst, which is under equilibrium conditions at 150.degree. C., and a pressure of 5 mbar, adsorbs less than 250 micromols, and preferably less than 50 micromols, of pyridine/g, and whose pyridine retention, after heating at 350.degree. C. under vacuum, does not exceed 20%, and preferably not 10%, of the amount adsorbed at 150.degree. C.
    Type: Grant
    Filed: January 18, 1995
    Date of Patent: August 26, 1997
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Michel Bourgogne, Thierry Patureaux, Nathalie Boisdron
  • Patent number: 5632884
    Abstract: A modified or bridged asphalt composition. The composition can be obtained by treating at least one asphalt base with an acid-derived compound having at least two functional groups capable, respectively, of being grafted onto one or more sites located on two or more different aromatic entities of the asphalt base, so as to link said entities by bridging.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: May 27, 1997
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Didier Jamois, Yannick Jolivet, Pierre Le Perchec, Bernard Fixari
  • Patent number: 5538625
    Abstract: The present invention relates to a steam cracking process and apparatus which permits the conversion of fractions of petroleum hydrocarbons. The claimed invention provides for the conversion of at least one light hydrocarbon fraction, as well as a heavier hydrocarbon feedstock. The inventive process takes place at a high temperature and in the presence of a dilute fluidized phase of heat-transfer particles. The process comprises contacting the light-hydrocarbon feedstock and then the heavier feedstock, in a sequential manner with catalytic or noncatalytic heat-transfer particles in a continuous flow reactor. The process further provides for separating and stripping, to separate at least 90 percent of the particles which are regenerated before recycling.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: July 23, 1996
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Jean-Bernard Sigaud, Jean-Louis Mauleon