Patents Assigned to Umicore Shokubai Japan Co., Ltd.
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Publication number: 20240011420Abstract: A fine particle filter for removing a particulate matter from exhaust gas of an internal combustion engine includes a wall-flow type filter that has a porous wall, and a ceramic layer that is made of ceramic particles and that is applied in a flow channel of the wall-flow type filter, wherein the ceramic layer has a porosity of 20% or more and 41% or less. The ceramic particles may be formed of one selected from the group consisting of alumina, silica, zirconia, ceria, titania, and zeolite.Type: ApplicationFiled: December 1, 2021Publication date: January 11, 2024Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Shota KAWASHIMA, Yuki SANO, Takuya ENOSAKA
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Publication number: 20240001349Abstract: An Al—P composite oxide containing aluminum oxide and phosphorus oxide, wherein with respect to the total mass of the Al—P composite oxide, the aluminum oxide content is 79 mass % or more and 97 mass % or less in terms of Al2O3, the zirconium oxide content is 0 mass % or more than 0 mass % and 7 mass % or less in terms of ZrO2, and the phosphorus oxide content is 3 mass % or more and 14 mass % or less in terms of PO4.Type: ApplicationFiled: December 7, 2021Publication date: January 4, 2024Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Tatsuya KUMON, Yosuke GOTO, Yusaku MAEJIMA
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Patent number: 11813590Abstract: A gasoline engine exhaust gas purification catalyst for purifying exhaust gas emitted from a gasoline engine includes a precious metal, alumina, and a ceria/zirconia composite oxide supported on a three-dimensional structure, and has pores having a peak 1 at a pore size of not less than 0.001 ?m and not greater than 0.05 ?m, pores having a peak 2 at a pore size of not less than 2.5 ?m and not greater than 5.0 ?m, and pores having a peak 3 at a different pore size than the above pore sizes in a pore size distribution measured by mercury intrusion method, wherein the pore volume of the pores having the peak 3 is greater than 1.4% of the total pore volume. A production method for the catalyst, and an exhaust gas purification method using the catalyst are also described.Type: GrantFiled: November 11, 2019Date of Patent: November 14, 2023Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yuji Ogino, Masanori Ikeda, Hideki Goto
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Publication number: 20230271164Abstract: A Ce—Zr composite oxide contains cerium and zirconium, wherein an uneven distribution ratio of cerium atoms is 1.80 or less. A method for producing a Ce—Zr composite oxide includes an acid treatment step of bringing at least one selected from the group consisting of sulfuric acid, nitric acid, and hydrochloric acid, in an amount of 4 to 28 parts by mass with respect to 100 parts by mass of the raw material composite oxide, into contact with the surface of a raw material composite oxide containing cerium and zirconium, and a calcination step of calcining the treated composite oxide obtained in the acid treatment step at 400 to 1200° C. for 5 to 300 minutes.Type: ApplicationFiled: April 19, 2021Publication date: August 31, 2023Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventor: Daishi FUJINO
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Patent number: 11691133Abstract: Described are a catalyst capable of effectively oxidizing an exhaust gas, a method for preparing the catalyst, and a method for oxidizing an exhaust gas using the catalyst. The exhaust gas oxidation catalyst includes at least two layers, a lower catalyst layer and an upper catalyst layer, laminated on a three-dimensional structure, wherein the lower catalyst layer and the upper catalyst layer independently contain precious metal and alumina and/or zeolite, and at least a part of the upper catalyst layer contains pores derived from a pore connecting agent with a combustion decomposition temperature of 300° C. or more to less than 450° C.Type: GrantFiled: November 11, 2019Date of Patent: July 4, 2023Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Tatsuya Kumon, Yosuke Goto, Franz Dornhaus
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Publication number: 20230058556Abstract: An object of the present invention is to provide means for releasing oxygen at a temperature lower than conventional means in an exhaust gas purification catalyst. A Ce—Zr composite oxide is provided, which has a crystallite diameter of 6.5 nm or less and a BET specific surface area of 90 m2/g or more.Type: ApplicationFiled: April 5, 2021Publication date: February 23, 2023Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yuji OGINO, Yusuke HANEDA, Koji NAKAGAWA, Shinji IWAMOTO
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Publication number: 20220341356Abstract: In an exhaust gas purification catalyst, a catalytic component (100) containing a first oxide (21), a second oxide (22), and a precious metal (30) is supported on a three-dimensional structure (10); the ratio of the amount of precious metal (30) supported on the first oxide (21) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22), or the ratio of the amount of precious metal (30) supported on the second oxide (22) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22) is 70% or more to 100% or less, as measured by an electron probe microanalyzer (EPMA); and the amount of carbon monoxide that the precious metal (30) can adsorb per unit mass is 15 mL/g or more to 100 mL/g or less.Type: ApplicationFiled: October 6, 2020Publication date: October 27, 2022Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yasuyuki TAKEDA, Shigekazu MINAMI
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Patent number: 11446638Abstract: An object of the present invention is to provide means for improving the hydrogen generation properties of a hydrogen-producing catalyst. A hydrogen-producing catalyst according to one aspect of the present invention comprises Rh and a composite containing Al, Ce, and Zr. When a ratio of the number of Al atoms to the number of Ce atoms (Al/Ce) in the composite measured by X-ray fluorescence (XRF) analysis is R1 and a ratio of the number of Al atoms to the number of Ce atoms (Al/Ce) in the composite measured by an X-ray photoelectron spectroscopy (XPS) method is R2, a value of R2/R1 is greater than 2.25 and less than 5.92.Type: GrantFiled: December 13, 2018Date of Patent: September 20, 2022Assignee: UMICORE SHOKUBAI JAPAN CO., LTDInventors: Kenji Ashikari, Yuji Ogino, Yusuke Haneda
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Patent number: 11446639Abstract: An exhaust gas cleaning catalyst is provided with a fire-resistant three-dimensional structural body, a first catalyst layer provide on a first surface side of the fire-resistant three-dimensional structural body, and a second catalyst layer provided on a side of the first catalyst layer opposite to the fire-resistant three-dimensional structural body. The first catalyst layer contains: a complex oxide including cerium and zirconium; and elemental rhodium. The second catalyst layer contains: a complex oxide including cerium and zirconium; and elemental palladium. The amount of cerium included in the second catalyst layer, in terms of cerium dioxide, is 10-25 g per liter of the fire-resistant three-dimensional structural body.Type: GrantFiled: September 24, 2019Date of Patent: September 20, 2022Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yuji Ogino, Yusuke Haneda
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Publication number: 20220280921Abstract: A three-dimensional structure (10); and a catalytic component (100) that contains a precious metal complex (22) containing platinum and palladium and a porous material (21), which is supported on the three-dimensional structure (10); where the surface accumulation C (Pt) of the platinum is 0.00070 or more to 0.01000 or less, the surface accumulation C (Pd) of the palladium is 0.00800 or more to 0.10000 or less, the surface accumulation C (Pt) is expressed by C (Pt)=PXPS (Pt)/(d2×PTEM (Pt)×0.01), and the surface accumulation C (Pd) is expressed by C (Pd)=PXPS (Pd)/(d2×PTEM (Pd)×0.01).Type: ApplicationFiled: October 6, 2020Publication date: September 8, 2022Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yusuke KOITO, Franz DORNHAUS
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Patent number: 11344864Abstract: It is an object to provide a catalyst that can effectively purify exhaust gas, in particular, carbon monoxide (CO) in exhaust gas, emitted from a diesel engine, a production method therefor, and an exhaust gas purification method using the same. A diesel engine exhaust gas purification catalyst for purifying exhaust gas emitted from a diesel engine of the present invention comprises a precious metal and alumina and/or zeolite supported on a three-dimensional structure, and has peaks for not less than three different pore sizes in a pore size distribution measured by the mercury intrusion method, wherein one of the peaks is a peak 2 at a pore size of not less than 0.3 ?m and less than 1.0 ?m, and the pore volume of the peak 2 being greater than 3.1% of the total pore volume.Type: GrantFiled: November 11, 2019Date of Patent: May 31, 2022Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yosuke Goto, Tatsuya Kumon, Franz Dornhaus
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Publication number: 20220062869Abstract: An exhaust gas purification catalyst including at least two layers, a lower catalyst layer and upper catalyst layer, on a refractory three-dimensional structure, wherein the lower catalyst layer and upper catalyst layer independently include a precious metal, alumina, and cerium-zirconium composite oxide, and at least a portion of the upper catalyst layer is formed using a manufacturing method including: applying a slurry for forming the upper catalyst layer onto the lower catalyst layer, the slurry containing a pore connecting agent with a combustion decomposition temperature of 150° C. or more to 400° C. or less, a precious metal precursor, alumina, and cerium-zirconium composite oxide, the content ratio of the pore connecting agent being less than 20 mass % of the total solid content when heated to 1000° C.; and holding the workpiece in an oxygen containing gas at a temperature above ?150° C. and +50° C. or lower, relative to the combustion decomposition temperature.Type: ApplicationFiled: November 11, 2019Publication date: March 3, 2022Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Hirotaka KUNO, Masashi NAKASHIMA, Yuji OGINO
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Publication number: 20220023847Abstract: Described are a catalyst capable of effectively oxidizing an exhaust gas, a method for preparing the catalyst, and a method for oxidizing an exhaust gas using the catalyst. The exhaust gas oxidation catalyst includes at least two layers, a lower catalyst layer and an upper catalyst layer, laminated on a three-dimensional structure, wherein the lower catalyst layer and the upper catalyst layer independently contain precious metal and alumina and/or zeolite, and at least a part of the upper catalyst layer contains pores derived from a pore connecting agent with a combustion decomposition temperature of 300° C. or more to less than 450° C.Type: ApplicationFiled: November 11, 2019Publication date: January 27, 2022Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Tatsuya KUMON, Yosuke GOTO, Franz DORNHAUS
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Publication number: 20220016614Abstract: An exhaust gas purification catalyst (C), including a three-dimensional structure (10) and a catalyst component layer (20) supported on the three-dimensional structure (10), where the average thickness of the catalyst component layer (20) is 15 ?m or more to 200 ?m or less, the average particle size of the catalyst component is 2 ?m or more to 10 ?m or less, and the catalyst component particle size variation coefficient is 10 or more and less than 50. The particle distribution of the catalyst component can be 90% or more to 99.9% or less.Type: ApplicationFiled: December 26, 2019Publication date: January 20, 2022Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Ayana AKAMATSU, Jianjun LIN
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Publication number: 20210379566Abstract: It is an object to provide a catalyst that can effectively purify exhaust gas, in particular, carbon monoxide (CO) in exhaust gas, emitted from a diesel engine, a production method therefor, and an exhaust gas purification method using the same. A diesel engine exhaust gas purification catalyst for purifying exhaust gas emitted from a diesel engine of the present invention comprises a precious metal and alumina and/or zeolite supported on a three-dimensional structure, and has peaks for not less than three different pore sizes in a pore size distribution measured by the mercury intrusion method, wherein one of the peaks is a peak 2 at a pore size of not less than 0.3 ?m and less than 1.0 ?m, and the pore volume of the peak 2 being greater than 3.1% of the total pore volume.Type: ApplicationFiled: November 11, 2019Publication date: December 9, 2021Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yosuke GOTO, Tatsuya KUMON, Franz DORNHAUS
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Publication number: 20210354110Abstract: A gasoline engine exhaust gas purification catalyst for purifying exhaust gas emitted from a gasoline engine includes a precious metal, alumina, and a ceria/zirconia composite oxide supported on a three-dimensional structure, and has pores having a peak 1 at a pore size of not less than 0.001 ?m and not greater than 0.05 ?m, pores having a peak 2 at a pore size of not less than 2.5 ?m and not greater than 5.0 ?m, and pores having a peak 3 at a different pore size than the above pore sizes in a pore size distribution measured by mercury intrusion method, wherein the pore volume of the pores having the peak 3 is greater than 1.4% of the total pore volume. A production method for the catalyst, and an exhaust gas purification method using the catalyst are also described.Type: ApplicationFiled: November 11, 2019Publication date: November 18, 2021Applicant: Umicore Shokubai Japan Co., Ltd.Inventors: Yuji OGINO, Masanori IKEDA, Hideki GOTO
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Patent number: 11149603Abstract: In order to provide an exhaust gas purification catalyst capable of purifying hydrocarbons, carbon monoxide, and nitrogen oxides in exhaust gas at low temperatures, the exhaust gas purification catalyst according to the present invention includes: a region (2) containing palladium and yttrium on a three-dimensional structure (1), and a first region (3) and a second region (4) provided on the region (2) in order from an inflow side of exhaust gas to an outflow side of exhaust gas. The concentration of yttrium contained in the first region (3) and/or the second region (4) is higher than the concentration of yttrium contained in the region (2).Type: GrantFiled: April 26, 2018Date of Patent: October 19, 2021Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Hirotaka Kuno, Masashi Nakashima, Takahiro Ikegami, Kosuke Mikita, Masanori Ikeda, Shigekazu Minami
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Patent number: 11141713Abstract: In order to provide an exhaust gas purification catalyst capable of purifying hydrocarbons, carbon monoxide, and nitrogen oxides in exhaust gas at low temperatures, the exhaust gas purification catalyst according to the present invention includes: a region (2) containing palladium on a three-dimensional structure (1), and a first region (3) and a second region (4) provided on the region (2) in order from an inflow side of exhaust gas to an outflow side of exhaust gas. The concentration of rhodium contained in the first region (3) is higher than the concentration of rhodium contained in the second region (4).Type: GrantFiled: April 26, 2018Date of Patent: October 12, 2021Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Hirotaka Kuno, Takahiro Ikegami, Kosuke Mikita, Masashi Nakashima, Shigekazu Minami, Masanori Ikeda
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Patent number: 11143072Abstract: In order to provide an exhaust gas purification catalyst capable of purifying hydrocarbons, carbon monoxide, and nitrogen oxides in exhaust gas at low temperatures, the exhaust gas purification catalyst according to the present invention includes: a region (2) containing palladium on a three-dimensional structure (1), and a first region (3) and a second region (4) provided on the region (2) in order from an inflow side of exhaust gas to an outflow side of exhaust gas. The concentration of neodymium contained in the first region (3) is higher than the concentration of neodymium contained in the second region (4).Type: GrantFiled: April 26, 2018Date of Patent: October 12, 2021Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Hirotaka Kuno, Masashi Nakashima, Kenji Ashikari, Yuji Ogino, Kazuyoshi Komata, Shigekazu Minami
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Publication number: 20210299638Abstract: An exhaust gas cleaning catalyst is provided with a fire-resistant three-dimensional structural body, a first catalyst layer provide on a first surface side of the fire-resistant three-dimensional structural body, and a second catalyst layer provided on a side of the first catalyst layer opposite to the fire-resistant three-dimensional structural body. The first catalyst layer contains: a complex oxide including cerium and zirconium; and elemental rhodium. The second catalyst layer contains: a complex oxide including cerium and zirconium; and elemental palladium. The amount of cerium included in the second catalyst layer, in terms of cerium dioxide, is 10-25 g per liter of the fire-resistant three-dimensional structural body.Type: ApplicationFiled: September 24, 2019Publication date: September 30, 2021Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yuji OGINO, Yusuke HANEDA