Abstract: An externally heated cast iron vessel, intended for containing a reactive molten metal, such as aluminum, is made resistant to attack by the molten metal, thereby increasing its useful service life and minimizing contamination of the melt, by lining the inside of the cast iron shell with a plurality of inert self-supporting, refractory plates, of for example, graphite, in such manner that the plates are free to move along their joints as well as relative to the shell upon thermal expansion, and permitting the molten metal to penetrate behind the lining through the joints and crevices therein opened by thermal expansion, thereby producing a refractory layer, in situ in the space between said lining and the inside surface of said cast iron shell, comprising a solid (FeAl.sub.3) reaction product of iron and said molten metal.
Abstract: A system is provided for the production of sterile, non-pyrogenic isotonic solutions of sodium pertechnetate. The system is comprised of a portable apparatus having contained in one unit a shielded column containing molybdenum-99 from which the technetium 99m is eluted, a reservoir of sterile isotonic saline solution, conduit means for transferring the solution to and from the column and dispensing the eluted radioisotope into a shielded vial from which the physician can extract the required amount.
Type:
Grant
Filed:
June 16, 1975
Date of Patent:
April 26, 1977
Assignee:
Union Carbide Corporation
Inventors:
Wayne Joseph Gemmill, Sr., Frank Ernest Cerone, Jr.
Abstract: Zeolitic molecular sieves having high SiO.sub.2 /Al.sub.2 O.sub.3 molar ratios and containing Cu.sup.+ cations are found to exhibit a high degree of selectivity and affinity for CO molecules and are capable of separating CO from gas streams even when water vapor is present.
Type:
Grant
Filed:
September 26, 1975
Date of Patent:
April 26, 1977
Assignee:
Union Carbide Corporation
Inventors:
Jule Anthony Rabo, James Nelson Francis, Charles Leslie Angell
Abstract: This invention relates to enchancing the bonding of polysulfide sealants to a variety of inorganic substrates, most particularly, to metal, ceramic, concrete, and glass substrates. This improved bonding of sealant is achieved by the use of a silane adhesion promoter which is characterized by the following formula:R -- SiX.sub.3wherein R is a norbornenyl, bicyclopentenyl, or a mercaptonorbornyl containing radical, and "X" is a hydrolyzable group.
Abstract: A galvanic cell, and a method for making it, having a resealable vent closure consisting of a resilient elastomeric sponge gasket disposed and compressed between the cover of the cell and the upper wall of the cell's container and designed such that gas buildup within the cell in the range of about 5 to 75 psi will vent along the cover-gasket interface and/or container-gasket interface.
Abstract: Zeolitic molecular sieves having high SiO.sub.2 /Al.sub.2 O.sub.3 molar ratios and containing Ag.sup.+ cations are found to exhibit a high degree of selectivity and affinity for CO molecules and are capable of separating CO from gas streams even when water vapor is present.
Type:
Grant
Filed:
August 10, 1976
Date of Patent:
April 26, 1977
Assignee:
Union Carbide Corporation
Inventors:
Jule Anthony Rabo, James Nelson Francis, Charles Leslie Angell
Abstract: Articles for conditioning hair have been fabricated by blending water soluble polymers with water insoluble polymers to form interpenetrating networks so that the water soluble polymer can be extracted from the article when wet or when brought in contact with wet hair.
Abstract: Sulfur dioxide can be adsorbed from gas mixtures using cross-linked, water-insoluble polymers of N-glycidylpiperazine or N-glycidyl polyalkylpiperazines as the adsorbents.
Type:
Grant
Filed:
February 4, 1976
Date of Patent:
April 19, 1977
Assignee:
Union Carbide Corporation
Inventors:
Robert James Cotter, Michael John Keogh, William Donald Heitz
Abstract: Vulcanizable ethylene polymer based compositions which are susceptible to scorching when processed at elevated temperatures, prior to vulcanization, in the presence of certain organic peroxide compounds, are protected against such scorching by the incorporation therein of certain organic hydroperoxide compounds and organic compounds containing at least three allyl groups.
Abstract: Organosilicone compositions are provided which comprise polysiloxane-polyoxyalkylene copolymers containing monofunctional siloxy units (M.sub.o) and difunctional siloxy units (D.sub.o), an average of between about 2 and about 100 silicon-bonded morpholino-bearing groups (Q) for every two moles of M.sub.o and an average of between 2 and about 30 silicon-bonded, organic-capped polyoxyalkylene blocks (E) for every two moles of M.sub.o, the monofunctional units encompassed by M.sub.o having at least two alkyls bonded to the respective silicon atoms thereof and the difunctional units encompassed by D.sub.o having at least one alkyl bonded to the respective silicon atoms thereof, the remaining organic group bonded to silicon of said monofunctional and difunctional siloxy units being alkyl, Q or E. The polymers of the invention find particular application in the manufacture of cellular urethane products including flame-retarded urethane foam.
Abstract: In an apparatus for stuffing flowable product into a shirred tubing disposed on a stuffing horn to produce stuffed tubular articles of predesired length on a continuous basis, a sensing member is employed for detecting movement of the trailing end portion of the shirred tubing on the stuffing horn which activates control for interrupting the stuffing operation of the apparatus so as to terminate the flow of product from the stuffing horn before the shirred tubing is completely expended.
Abstract: This invention relates to improving the known process for disposing of refuse while simultaneously producing a useful gaseous product and an inert solid residue in a shaft furnace in which refuse is fed into the top portion of said furnace, an oxygen containing gas is fed into the base, and in which the organic portion of the refuse is pyrolized to char, oils and gas containing a high concentration of CO and H.sub.2, and the inorganic portion of the refuse is fluidized and tapped from the base of the furnace.The improvement in the above-described process comprises removing a portion of the char from the furnace while retaining a sufficient amount of combustible materials in the furnace to satisfy the energy requirements of the process. The improvement permits a reduction in the oxygen requirements of the process and has a beneficial effect on the specific heating value of the fuel gas produced.
Abstract: An improved process for producing pitch which is transformed, in part, to a liquid crystal or so-called "mesophase" state. According to the process, the mesophase content of the pitch is formed while agitating the pitch so as to produce a homogeneous emulsion of the immiscible mesophase and non-mesophase portions of the pitch. Mesophase pitches prepared in this manner have been found to possess a lesser amount of high molecular weight molecules in the mesophase portion of the pitch and a lesser amount of low molecular weight molecules in the non-mesophase portion of the pitch, and thus a smaller differential between the average molecular weights of the mesophase and non-mesophase portions of the pitch, than mesophase pitches having the same mesophase content which have been prepared in the absence of such agitation.
Type:
Grant
Filed:
October 31, 1974
Date of Patent:
April 12, 1977
Assignee:
Union Carbide Corporation
Inventors:
Irwin Charles Lewis, Edgar Ronald McHenry, Leonard Sidney Singer
Abstract: Addition of strontium to silicon or ferrosilicon using a mixture containing carbon and at least one material selected from the group of strontium oxide, and strontium carbonate and strontium sulfate.
Type:
Grant
Filed:
December 31, 1975
Date of Patent:
April 12, 1977
Assignee:
Union Carbide Corporation
Inventors:
James Herbert Downing, James Enoch Wells, III
Abstract: A plastic film packaging bag is fabricated with directionally tear-prone wicket mounting holes having a hole edge reinforcing bead of plastic selectively thinner in the desired tearing direction formed by a hot gas stream directed through shaped templates holding the bag.
Abstract: Organosilicone polymers are provided which comprise polysiloxane-polyoxyalkylene block copolymers wherein the polysiloxane blocks are trialkylsiloxyendblocked and contain reoccurring difunctional dialkylsiloxy monomeric units in combination with reoccurring difunctional cyanoalkyl-alkylsiloxy or cyanoalkoxyalkylsiloxy monomeric units, the mol ratio of the dialkylsiloxy units to the cyano-substituted siloxy units being about 10-200:3-100, and wherein the polysiloxane and polyoxyalkylene blocks are joined through an Si--C or an Si--O--C linkage, and from about 20 to about 65 weight per cent of the oxyalkylene units of the polyoxyalkylene blocks are constituted of oxyethylene units. The block copolymers of the invention are effective stabilizers of flexible polyether polyolbased polyurethane foams and offer particular advantage in the formation of flame-retarded foams.
Abstract: Corona induced chemical reactions are conducted in a corona discharge zone in which narrow high voltage pulses are applied along with a relatively low voltage bias potential. It is found that for many corona discharge reactions, such as the conversion of oxygen to ozone, the present method increases the electrical efficiency of the reaction.
Abstract: Compositions of amine derivatives of acrylated epoxidized soybean oil, which are the reaction products of an organic amine with the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, and an acrylyl compound which are useful as coatings and inks are cured by radiation. The compositions can also contain photosensitizers and/or pigments.
Type:
Grant
Filed:
March 28, 1975
Date of Patent:
April 5, 1977
Assignee:
Union Carbide Corporation
Inventors:
David John Trecker, George Wayne Borden, Oliver Wendell Smith
Abstract: A particular class of morpholino-bearing polyalkylsiloxanes are provided which consist essentially of: (1) monofunctional siloxy units (M.degree.) the respective silicon atoms of which have two alkyls bonded thereto, the third silicon-bonded organic group being alkyl or Q where Q is morpholinoalkyl- or morpholinoalkoxyalkyl; (2) an average of from about 0.5 to about 8 moles of difunctional dialkylsiloxy units for every two moles of M.degree.; from zero up to an average of about 8 moles, for every two moles of M.degree., of difunctional monoalkylsiloxy units in which the second organic group bonded to silicon is Q, provided an average of at least about 0.5 and no more than about 8 moles of said silicon-bonded Q groups are present in the siloxanes for every two moles of M.degree..