Abstract: The present invention is directed to an improvement in a wire or cable system comprising a wire or cable portion, an insulation composition surrounding the wire or cable portion, a filler material surrounding the insulation composition and a jacket composition surrounding the filler material wherein either the insulation composition, the jacket composition, or both comprise at least one antioxidant, wherein the improvement comprises the inclusion in the filler material of a stabilizing mixture comprising at least two antioxidants, selected from at least two members of the group consisting of:(a) metal dithiocarbamate salts,(b) amine antioxidants, and(c) sterically hindered phenolic antioxidants,wherein the stabilizing mixture is present in the filler material in an amount that is effective for the reduction of the oxidation of the cable filling material, thereby reducing deterioration of the jacket and/or insulation.
Type:
Grant
Filed:
March 25, 1998
Date of Patent:
June 27, 2000
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
Christopher John Fagouri, Robert Scott Archibald
Abstract: A liquid phase polymerization process is provided for producing a polyolefin elastomer, e.g., one derived from ethylene, another .alpha.-olefin such as propylene and, optionally, a diene, employing a metallocene catalyst. The process comprises contacting monomer under liquid phase polymerization conditions with a catalyst composition obtained by combining (a) a metallocene procatalyst, preferably one containing a bridging group possessing at least two bulky groups, and (b) a cocatalyst such as aluminoxane, preferably a cation-generating cocatalyst, in partial on total replacement of aluminoxane.
Abstract: Polyurethane prepolymers are disclosed prepared with mononuclear aromatic diisocyanate such as toluene diisocyanate and an aliphatic diisocyanate such as H12MDI. These prepolymers can be cured with 4,4'-methylene-bis-(3-chloro-2,6-diethylaniline) to form a cured urethane elastomer with reduced propensity to crack during the curing process, extended pour life (a slower rate of viscosity buildup after curative and prepolymer are mixed), low hysteresis, and a low level of free toluene diisocyanates and/or other toxic or volatile substances to increase worker safety during processing. It has also been found that prepolymers made from toluene diisocyanate and cured with a blend of two aromatic diamine curatives yields urethane elastomers with the same reduced propensity to crack during the curing process.
Type:
Grant
Filed:
November 27, 1996
Date of Patent:
April 4, 2000
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
Ronald Owen Rosenberg, Ajaib Singh, Ronald Walter Fuest
Abstract: Insecticidal dihydrooxadiazine compounds having the formula: ##STR1## wherein X is O or S; R is a substituted or unsubstituted phenyl or heterocyclic group; R.sup.1 is halogen, haloalkyl or haloalkoxy; R.sup.2, R.sup.3 , and R.sup.4 are, independently, hydrogen, alkyl or alkoxy; R.sup.5 is nitro, cyano, alkoxy, alkyl, haloalkoxy, dialkylamino, alkylthio, phenoxy, phenylthio, or alkoxycarbonyl; R.sup.6 is hydrogen, alkyl, alkylthio, alkoxyalkyl, alkoxycarbonyl, acyl, or benzyl, wherein R.sup.3 and R.sup.5 together can form a ring.
Type:
Grant
Filed:
February 12, 1998
Date of Patent:
January 4, 2000
Assignees:
Uniroyal Chemical Company, Inc., Uniroyal Chemical Co./CIE.
Inventors:
Anupama Mishra, Mark Achiel Dekeyser, Paul Thomas McDonald
Abstract: A method for preparing substituted triazines includes reacting a phenylazoaniline with a cyanuric halide to produce a (phenylazo) phenylamino-1,3,5-triazine, which is then reduced to form an aminoanilino-1,3,5-triazine. The aminoanilino-1,3,5-triazine can be alkylated under reducing conditions to produce an N-alkyl-phenylenediamino-1,3,5-triazine such as 2,4,5-tris-[N-alkyl-p-phenylenediamino]-1,3,5-triazine, which is useful as an antiozonant in rubber and other polymer formulations.
Abstract: A polyurethane elastomer possessing high resilience and high clarity is obtained by subjecting to polyurethane elastomer-forming conditions a polyurethane elastomer-forming reaction mixture comprising:a) an isocyanate selected from the group consisting of diphenyl methane diisocyanate, isocyanate obtained from the reaction of polyol with MDI and mixtures thereof;b) at least one polyol; and,c) at least one diol chain extender of the general formula:HO--(CH.sub.2).sub.x --OHwherein x is an integer from 5 to about 16.
Abstract: An EPDM rubber composition useful for producing a tack-free crosslinked EPDM rubber product which composition consists of:i) at least one EPDM terpolymer;ii) at least one silicone-modified EPDM elastomer;iii) an organic peroxide; andiv) optionally, at least one tack-neutral additive.
Abstract: The invention concerns a silicone-modified EPDM modified with a freeze release additive of a fatty acid amide and/or optionally, graphite having at least 85% carbon, and compounded and co-extruded onto the surface of elastomeric sponge automotive weatherstripping thereby forming a permanent skin surface on the sponge material. The resulting material has improved and desirable freeze-release and coefficient of friction properties. These improved properties eliminate the need for currently used spray coatings, resulting in manufacturing cost savings and more durable surface.
Type:
Grant
Filed:
November 14, 1997
Date of Patent:
October 19, 1999
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
Angela Ellen Bova, Donald William Tredinnick
Abstract: A process for the preparation of a substituted 2-benzo[b]thiophenecarboxylic acid compound or an alkali metal salt thereof, which comprises reacting a halobenzoyl derivative with mercaptoacetic acid in the presence of an alkali metal hydroxide and water. Substituted 2-benzo[b]thiophenecarboxylic acid compounds and alkali metal salts thereof are useful as intermediates for pharmaceuticals, agricultural chemicals, material preservatives, and the like.
Type:
Grant
Filed:
March 16, 1998
Date of Patent:
October 12, 1999
Assignees:
Uniroyal Chemical Company, Inc., Uniroyal Chemical Co./CIE.
Abstract: The invention relates to a process for the production of plastic parts, particularly pipes and sleeves, by the extrusion of a mixture of polyethylene homopolymer, copolymer or block polymer (PE) and a polymeric plasticizer reactive therewith, as well as small amounts of conventional additives, in which the moulded or extruded plastic part optionally subsequently undergoes cross-linking and stretching, or cross-linking only, in which a mixture of PE and EPDM with an average molecular weight of 1,000 to 20,000 in a weight ratio of 90 to 97% PE and 3 to 10% by weight EPDM is moulded or extruded.
Abstract: Compounds of of the formula ##STR1## wherein R is a C.sub.6 -C.sub.10 aryl group, optionally substituted with one or more halogen atoms, phenoxy, or, linear or branched, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 haloalkoxy, or C.sub.1 -C.sub.6 haloalkyl; R.sup.1 is C.sub.3 -C.sub.6 cycloalkyl or, linear or branched, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.2 -C.sub.8 alkoxyalkyl or C.sub.1 -C.sub.6 haloalkyl; n is 1, 2 or 3; and R.sup.2 is CN, C(O)NH.sub.2 or C(S)NH.sub.2, or the physiologically acceptable salts thereof with organic and inorganic acids. These compounds are useful as fungicides.
Type:
Grant
Filed:
September 26, 1997
Date of Patent:
August 31, 1999
Assignees:
Uniroyal Chemical Company, Inc., Uniroyal Chemical Co./Cie.
Inventors:
Hoi Kiong Lai, Douglas Irving Relyea, Robert Allan Davis
Abstract: A method for encapsulating segments of signal transmission devices such as splices, pressure blocks and end blocks with a room-temperature curable composition comprising:(1) a hydroxy-functional compound having a molecular weight of greater than 500 and a hydroxy functionality of 2 or more;(2) an epoxy-functional compound having an epoxy functionality of 2 or more; and(3) a curative catalyst, in an amount effective to crosslink the epoxy and hydroxy components of the respective epoxy-functional and hydroxy-functional compounds.
Type:
Grant
Filed:
August 8, 1997
Date of Patent:
August 17, 1999
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
William Davis Sigworth, Thomas Harald Peter
Abstract: Disclosed herein is a composition comprising:(A) a lubricant, and(B) at least one cyclic thiourea selected from the group consisting of: ##STR1## wherein R.sub.1 and R.sub.2 are independently selected from the group consisting of alkyl, functionalized alkyl, and hydrogen.
Abstract: A method for producing aromatic amines such as N-phenyl-p-phenylenediamine is disclosed wherein an amine substituted aromatic such as aniline is oxidized with oxygen or hydrogen peroxide in the presence of a preferred trisodium pentacyano ferrate(II) complex containing various water soluble ligands, such as ammonia, mono alkyl amine, dialkyl amines, and trialkyl amines. The complex is subsequently catalytically reduced by hydrogenation using certain heterogeneous metal catalysts to yield the desired aromatic amine.
Type:
Grant
Filed:
March 13, 1997
Date of Patent:
July 20, 1999
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
Edward L. Wheeler, Russell E. Malz, Jr., Mark W. Simon
Abstract: Phenolic amides, useful as stabilizers for organic materials such as polyols and polyurethanes, possess the general formula ##STR1## wherein n is 0 to 3, R.sub.1, is alkyl of from 1 to about 6 carbon atoms, R.sub.2 is hydrogen or alkyl of from 1 to about 6 carbon atoms, R.sub.3 is hydrogen or hydrocarbyl of up to about 20 carbon atoms, optionally containing one or more heterocyclic groups, R.sub.4 is hydrocarbyl of up to about 20 carbon atoms, optionally containing one or more heterocyclic groups, or R.sub.3 and R.sub.4 together with the nitrogen atom to which they are bonded are joined together to form a heterocyclic group, optionally containing one or more additional heterocyclic atoms.
Abstract: Compounds of the formula ##STR1## wherein Q is a hydrazone derivative;R.sup.1 is hydrogen, halogen, alkyl or alkoxy;R.sup.2 is hydrogen, halogen, alkyl, alkoxy, alkenoxy, alkynyloxy, halomethyl, trifluoromethoxy, alkylthio, nitro or cyano; andR.sup.6 is a substituted carboxamide, carbothioamide, phosphonosoamide, or phosphonothioamide,useful as anti-HIV agents.
Type:
Grant
Filed:
December 12, 1997
Date of Patent:
June 22, 1999
Assignees:
Uniroyal Chemical Company, Inc., Uniroyal Chemical Co./CIE.
Inventors:
Walter Gerhard Brouwer, Ewa Maria Osika
Abstract: Disclosed is an aromatic diisocyanate prepolymer combined with a dibasic ester, preferably a mixed dialkyl ester of adipic, glutaric and succinic acids, which when used with amine or polyol curatives to make solid, non-foamed elastomeric polyurethane and/or polyurethane/urea products reduces viscosity and improves wettability of the castable polyurethane prepolymer without loss of cured physical properties. This improved wettability of the liquid prepolymer is useful for impregnation of fabrics, preferably polyesters, during the manufacture of a polyurethane coated fabric type belting.
Abstract: A method for coating a cylindrical object which comprises applying to the cylindrical object an effective amount of a polyurethane composition comprising:a) an isocyanate-terminated polyurethane prepolymer; andb) a curative agent comprising i) a polyol; ii) an aromatic diamine; iii) a thixotropic aliphatic amine; and iv) a thixotropic colloidal additive.
Abstract: A polyurethane composition comprising:a) an isocyanate-terminated polyurethane prepolymer; andb) a curative agent comprising i) a polyol; ii) an aromatic diamine; iii) a thixotropic aliphatic amine; and iv) a thixotropic colloidal additive. This composition is useful for coating cylindrical objects.
Abstract: Compounds having the structural formula: ##STR1## wherein: R is C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkyl, C.sub.7 -C.sub.9 aralkyl, or nitroso; R' is C.sub.1 -C.sub.4 alkyl; and R" is C.sub.1 -C.sub.4 alkyl. These compounds exhibit insecticidal and miticidal activity.
Type:
Grant
Filed:
October 24, 1996
Date of Patent:
February 23, 1999
Assignees:
Uniroyal Chemical Company, Inc., Uniroyal Chemical Co./CIE.
Inventors:
Mark Achiel Dekeyser, Paul Thomas McDonald