Abstract: A composite quantum-dot photodetector comprising a substrate with a colloidally deposited thin film structure forming a photosensitive region, the thin film containing at least one type of a nanocrystal quantum-dot, whereby the nanocrystal quantum dots are spaced by ligands to form a lattice, and the lattice of the quantum dots has an infill material that forms an inorganic matrix that isolates the nanocrystal quantum dots from atmospheric exposure.

Abstract: An optical-dispersion corrected optical-element with a first and a second surface for imaging equal angle quadrilateral focal plane array (FPA). The optical-dispersion element comprises a first nanocomposite-ink with a first nanofiller dispersed in a cured organic-matrix and a second nanocomposite-ink with a second nanofiller dispersed in the cured organic-matrix. Optical-dispersion of the second nanocomposite-ink is different than optical-dispersion of the first nanocomposite-ink. The distribution of the first nanocomposite-ink and second nanocomposite-ink corrects chromatic aberration and creates a refractive gradient that is non-radially symmetric to correct for an image plane array.

Abstract: Optical inks suitable for 3D printing fabrication of gradient refractive index (GRIN) optical components are composed a monomer matrix material doped with ligand-functionalized nanoparticles, wherein the monomer has a viscosity less than 20 cPoise and is UV curable to form a solid polymer. The matrix material doped with the ligand-functionalized nanoparticles has a transmittance of at least 90% in a predetermined optical wavelength range, wherein the ligand functionalized nanoparticles have a size less than 100 nm, are loaded in the monomer matrix material at a volume percent of at least 2%, and alter an index of refraction of the monomer matrix by at least 0.02. The ligand-functionalized nanoparticles have a plurality of ligands attached to a nanoparticle core surface with an anchor functional group and terminated with a buoy functional group that are reactive, non-reactive, or combinations thereof. In some embodiments the ligands have a length less than 1.

Abstract: Methods of manufacturing a volumetric continuous gradient complex dielectric element with drop-on-demand techniques, such as inkjet printing, by calculating spatial placement of nanocomposite-ink droplets are disclosed. The methods comprise determining or having a multi-dimensional gradient profile representing a volumetric gradient complex dielectric element. Providing or having a plurality of nanocomposite-inks, at least one of the nanocomposite-inks having a curable organic-matrix and a concentration of nanoparticles dispersed within to print the volumetric continuous gradient complex dielectric device. A print mask is determined in one-, two-, or three-dimensions that reconstructs the multi-dimensional gradient profile as a discretized pattern based on the material properties of the plurality of nanocomposite-inks and properties of a printing apparatus with a plurality of printheads.

Abstract: An apparatus for manufacturing nanocomposite-ink, the apparatus comprising, a nanoparticle reservoir, an organic-matrix reservoir, a homogenizer, and a dispenser. The homogenizer combines the nanoparticles and the organic-matrix, dispersing the nanoparticles within the organic-matrix, thereby producing a nanocomposite-ink for dispensement by the dispenser.

Abstract: A method of manufacturing a 3-dimensional variable refractive-index optical-element with surface figure, the method comprising: depositing a plurality of nanocomposite-inks comprising an organic-matrix with a nanoparticle filler dispersed within, and at least partially curing a portion of the nanocomposite-ink to form a nanocomposite slab that is at least semi-solid; transferring the nanocomposite slab to a press, the press having a die mold with at least a first surface figure; and actuating the press to compress the nanocomposite slab and impart the die mold's first surface figure onto the nanocomposite slab to form a nanocomposite optical-element.

Abstract: A method of inkjet printing a gradient dielectric element in a deposition and photo-polymerization process. The method comprises: providing a plurality of complex-dielectric-inks that are inkjet printable including a nanocomposite-ink with an organic-matrix and a nanoparticle filler dispersed within. The plurality of complex-dielectric-inks have a first complex-dielectric-ink having a first photoinitiator and a second complex-dielectric-ink with a second photoinitiator. The first and second complex-dielectric-ink have different wavelength selective photo-polymerization absorption bands such that spectrally discrete exposure results in different degrees of polymerization of the first and second complex-dielectric-ink.

Abstract: Optical inks suitable for 3D printing fabrication of gradient refractive index (GRIN) optical components are composed a monomer matrix material doped with ligand-functionalized nanoparticles, wherein the monomer has a viscosity less than 20 cPoise and is UV curable to form a solid polymer. The matrix material doped with the ligand-functionalized nanoparticles has a transmittance of at least 90% in a predetermined optical wavelength range, wherein the ligand functionalized nanoparticles have a size less than 100 nm, are loaded in the monomer matrix material at a volume percent of at least 2%, and alter an index of refraction of the monomer matrix by at least 0.02. The ligand-functionalized nanoparticles have a plurality of ligands attached to a nanoparticle core surface with an anchor functional group and terminated with a buoy functional group that are reactive, non-reactive, or combinations thereof. In some embodiments the ligands have a length less than 1.

Abstract: Methods of manufacturing a volumetric continuous gradient complex dielectric element with drop-on-demand techniques, such as inkjet printing, by calculating spatial placement of nanocomposite-ink droplets are disclosed. The methods comprise determining or having a multi-dimensional gradient profile representing a volumetric gradient complex dielectric element. Providing or having a plurality of nanocomposite-inks, at least one of the nanocomposite-inks having a curable organic-matrix and a concentration of nanoparticles dispersed within to print the volumetric continuous gradient complex dielectric device. A print mask is determined in one-, two-, or three-dimensions that reconstructs the multi-dimensional gradient profile as a discretized pattern based on the material properties of the plurality of nanocomposite-inks and properties of a printing apparatus with a plurality of printheads.

Abstract: A nanocomposite-ink refractive gradient optic with variable focus optic comprising a first optical-element, a second optical-element, each the optical-elements comprised of a cured nanocomposite-ink wherein the first and second optical-element have a cubic volumetric gradient complex optical index such that when arranged in tandem along an optical axis the optical power varies based on linear translation with respect to another.

Abstract: An optical-dispersion corrected optical-element, the optical-element comprising a first nanocomposite-ink, the first nanocomposite-ink comprising nanofillers dispersed in a cured organic-matrix, a second nanocomposite-ink, the second nanocomposite-ink comprising the nanofillers dispersed in a the cured organic-matrix, optical-dispersion of the second nanocomposite-ink different than optical-dispersion of the first nanocomposite-ink, wherein the distribution of the first nanocomposite-ink and the second nanocomposite-ink result in optical-dispersion refractive-gradients, where the refractive-gradients correct chromatic aberration.

Abstract: A method of manufacturing a multi-material functional article, the method comprising the steps of providing a design module from a database, the design module encoded with physical characteristics, material needs, additive manufacturing equipment required, and performance outputs required for modeling a multi-material functional article, allowing a user access to the design module to integrate the design module into a functional article design, having the design module interface with available additive manufacturing equipment and allowing the user to print the multi-material functional article.

Abstract: A method to manufacture optics and optical subsystems. In one aspect, a method to manufacture an optical-element in accordance with the present disclosure comprise the steps of: Printing at least a part of a mold with an additive manufacturing printer. Optically figuring the mold to the specifications of the desired optical-element. Printing a nanocomposite-ink into the mold. Selectively, curing the nanocomposite-ink. Repeating at least the steps of deposition of the nanocomposite-ink and selective curing, until the mold is sufficiently filled and cured. Optionally, releasing the optical-element from the mold.

Abstract: Optical inks suitable for 3D printing fabrication of gradient refractive index (GRIN) optical components are composed a monomer matrix material doped with ligand-functionalized nanoparticles, wherein the monomer has a viscosity less than 20 cPoise and is UV curable to form a solid polymer. The matrix material doped with the ligand-functionalized nanoparticles has a transmittance of at least 90% in a predetermined optical wavelength range, wherein the ligand functionalized nanoparticles have a size less than 100 nm, are loaded in the monomer matrix material at a volume percent of at least 2%, and alter an index of refraction of the monomer matrix by at least 0.02. The ligand-functionalized nanoparticles have a plurality of ligands attached to a nanoparticle core surface with an anchor functional group and terminated with a buoy functional group that are reactive, non-reactive, or combinations thereof. In some embodiments the ligands have a length less than 1.

Abstract: Methods of manufacturing a volumetric continuous gradient complex dielectric element with drop-on-demand techniques, such as inkjet printing, by calculating spatial placement of nanocomposite-ink droplets are disclosed. The methods comprise determining or having a multi-dimensional gradient profile representing a volumetric gradient complex dielectric element. Providing or having a plurality of nanocomposite-inks, at least one of the nanocomposite-inks having a curable organic-matrix and a concentration of nanoparticles dispersed within to print the volumetric continuous gradient complex dielectric device. A print mask is determined in one-, two-, or three-dimensions that reconstructs the multi-dimensional gradient profile as a discretized pattern based on the material properties of the plurality of nanocomposite-inks and properties of a printing apparatus.

Abstract: A composite quantum-dot photodetector comprising a substrate with a colloidally deposited thin film structure forming a photosensitive region, the thin film containing at least one type of a nanocrystal quantum-dot, whereby the nanocrystal quantum dots are spaced by ligands to form a lattice, and the lattice of the quantum dots has an infill material that forms an inorganic matrix that isolates the nanocrystal quantum dots from atmospheric exposure.

Abstract: An apparatus for depositing nanocomposite material comprising a nanocomposite-ink factory and inkjet printer. The nanocomposite-ink factory producing nanocomposite-ink and the inkjet printer receiving the nanocomposite-ink. The inkjet printer having a printhead and a positioning mechanism. The printhead having one or more nozzles to dispense nanocomposite-ink droplets.

Abstract: A nonlinear nanocomposite optical-element comprising a nanocomposite comprising one or more optically nonlinear (NLO) nanofillers dispersed in a cured organic-matrix. The NLO nanofillers have a high ?(3) susceptibility relative to a linear nanofiller. The distribution of the NLO nanofiller has a nanofiller gradient that changes based on optical radiation intensity.

Abstract: An aerial fluid delivery system comprises a dispenser, a loiter-line, and an aircraft. The dispenser capable of releasing controlled amounts of a fluid. The loiter-line connected to the dispenser and connected to an aircraft, wherein the aircraft can maneuver the dispenser via the loiter-line such that the dispenser is positioned for accurate fluid delivery to a target. The dispenser fluid can be an aerosol, a dispersion, optical taggants, or powder based.

Abstract: A nanocomposite optical modulator device comprising an optically transparent electro-optic region. The electro-optic region exhibiting second-order optical nonlinearity properties. The nanocomposite optical modulator further comprises one or more dielectric layers, with at least one of the dielectric in contact with the electro-optic region, one or more electrodes in proximity to the electro-optic region. Wherein at least one of the aforementioned elements is nanocomposite material with nanoparticle loading from about 0.25% to about 70% volume.