Abstract: The vinyl aromatic-1,3-diene copolymers stabilized with protection colloids are used in the form of aqueous polymer dispersions or water-redispersible polymer powders for modifying materials that contain plaster or calcium carbonate. The polymer dispersions or polymer powders are obtained by the emulsion-polymerization of a mixture containing at least one vinyl aromatic and at least one 1,3-diene in the presence of at least one protection colloid and without any emulsifier, and by optionally drying the aqueous polymer dispersions thus obtained.
Type:
Grant
Filed:
March 23, 2001
Date of Patent:
May 20, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Theo Mayer, Peter Fritze, Reinold Härzschel, Hans-Peter Weitzel
Abstract: The invention relates to a process for the chlorination of methylsilanes, which comprises reacting methylsilanes with chlorine in the presence of at least 0.1% by weight of hydrogen chloride, based on the weight of methylsilane of the formula (II), under the action of electromagnetic radiation which induces chlorination, chlorine being used in a substoichiometric amount based on the methylsilane of the formula (II), and the reaction being carried out at temperatures below the boiling point of the methylsilane of the formula (II). The invention further relates to an apparatus suitable for carrying out the chlorination of an industrial scale.
Type:
Application
Filed:
October 18, 2002
Publication date:
May 8, 2003
Applicant:
Wacker-Chemie GmbH
Inventors:
Helmut Hollfelder, Siegfried Pflaum, Franz Riener
Abstract: A water-soluble, crosslinkable protective colloid is provided having a molecular weight of least than 500,000 comprising:
a) 20 to 959 by weight of monomer units containing sulphonic acid or sulphonate groups,
b) 4 to 800 by weight of monomer units containing N-methylol or N-alkoxymethyl groups, and
c) 0.1 to 20% by weight of hydrophobic monomer units such as water insoluble ethylenically unsaturated compounds and the hydrophobic end groups of initiator radicals or regulator molecules. Optionally, up to 50% by weight of the monomer units containing sulphonic acid or sulphonate groups can be replaced by monomer units containing carboxyl groups or monomer units containing amide groups.
Type:
Grant
Filed:
August 27, 2001
Date of Patent:
May 6, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Klaus Kohlhammer, Gerhard Koegler, Monika Rockinger, Walter Dobler
Abstract: The invention relates to organopolysiloxane resins which have a glass transition temperature of more than 60° C. and OH contents of from 1 percent to 8 percent by weight.
Abstract: The invention relates to the utilization of aqueous polymer dispersions or of polymer powders which can be redispersed in water and which are based on protective colloid-stabilized aromatic vinyl-1,3-diene-copolymers in adhesive formulations used in the building industry, whereby the polymer dispersion and the polymer powders are produced by emulsion polymerization of a mixture containing at least one aromatic vinyl and at least one 1,3-diene in the presence of one or more protective colloids, without using an emulsifier, and by optionally drying of the aqueous polymer dispersion obtained thereby.
Type:
Grant
Filed:
May 11, 2001
Date of Patent:
April 22, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Reinhard Härzschel, Theo Mayer, Hans-Peter Weitzel
Abstract: Organic fibers are treated with aqueous preparations comprising amino-functional organosilicon compounds of the general formula
H2N—R1—SiR2O(SiR2O)iSiR2—R1—NH2
where
i is an integer from 1 to 1000,
R is an identical or different monovalent hydrocarbon radical having 1 to 18 carbon atoms per radical, and
R1 is a divalent hydrocarbon radical having 2 to 10 carbon atoms. The treated organic fibers, particularly in the form of textiles, exhibit a soft hand and good rewettability.
Type:
Grant
Filed:
March 26, 2002
Date of Patent:
April 15, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Michael Messner, Wolfgang Schattenmann, Renate Minigshofer, Evelyn Richter
Abstract: A device for simultaneously separating a multiplicity of wafers from a hard brittle workpiece having a longitudinal axis, with a wire web made from saw wire and with an advancing device which brings about a translational relative movement, which is perpendicular to the longitudinal axis of the workpiece, between the workpiece and the wire web of the wire saw, in the course of which movement the workpiece is passed through the wire web, wherein the wire web is formed from a multiplicity of individual wires, and wherein there is a device for holding and rotating the workpiece about the longitudinal axis.
Type:
Grant
Filed:
December 5, 2000
Date of Patent:
April 8, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Bernhard Holzmuller, Ulrich Wiese, Jochen Greim
Abstract: There is provided an aromatic polycarbonate resin composition which exhibits high flame retardancy without sacrificing melt-molding stability or melt fluidity when molding the resin composition. The flame retardant aromatic polycarbonate resin composition comprises a resin component (a) comprising an aromatic polycarbonate and optionally a styrene polymer, the resin composition having an aromatic polycarbonate content of 20% by weight or more; and 0.1 to 50 parts by weight of an organopolysiloxane (b) comprising a linear organopolysiloxane (b)i and a cyclic organopolysiloxane (b)ii, component (b)ii present in an amount of from 5 to 95% by weight based on the total weight of components (b)i and (b)ii.
Abstract: A process for preparing silanes of the formula 1:
RaSiHbCl4-a-b (1)
where
R is methyl or ethyl,
a is 0, 1, 2 or 3 and
b is 0 or 1,
from hydrogen chloride gas and reactants selected from among
a) silicon metal,
b) disilanes and oligosilanes whose radicals are selected from among H, R and Cl,
and mixtures thereof, wherein the hydrogen chloride gas is prepared from H2 and Cl2 in a concerted process.
Type:
Grant
Filed:
May 3, 2002
Date of Patent:
April 1, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Willi Streckel, Wilfried Kalchauer, Herbert Straussberger
Abstract: A composition comprising peroxidically crosslinking condensation-crosslinking, or addition-crosslinking silicone rubber; metal compounds selected from metal oxides such as magnesium oxide, aluminum oxide, tin oxide, calcium oxide and barium oxide and precursors thereof which produce oxides on heating, boric acid, and zinc borate; platinum complexes having at least one unsaturated group; and hollow beads. The compositions form a coherent ceramic insulation upon heating which still enables the conductors to carry high voltage electrical signals.
Type:
Application
Filed:
September 10, 2002
Publication date:
March 20, 2003
Applicant:
WACKER-CHEMIE GmbH
Inventors:
Dietrich Wolfer, Wilhelm Marsch, Werner Brennenstuhl
Abstract: Crosslinkable polymer compositions are provided which can be in the form of a polymer powder which is redispersible in water or as an aqueous dispersion. The polymer composition is composed of A) a copolymer of one or more comonomers of vinyl esters of straight-chain or branched alkanecarboxylic acids having 1 to 18 C atoms, acrylates or methacrylates of branched or straight-chain alcohols having 1 to 15 C atoms, dienes, olefins, vinylaromatics and vinyl halides, and of from 0.1 to 10% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated comonomers containing epoxide groups, and B) one or more non-copolymerizable compounds having at least two epoxide groups. The invention furthermore relates to a process for the preparation of the crosslinkable polymer compositions and their use in chemical products for the construction industry.
Type:
Grant
Filed:
January 25, 2001
Date of Patent:
March 18, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Klaus Kohlhammer, Klaus Adler, Herbert Eck, Hermann Lutz
Abstract: The invention relates to a polycrystalline SiC shaped body, which consists of 96% by weight to 99.5% by weight of hard-material grains having a core/shell structure, 0 to 0.1% by weight free carbon, remainder a partially crystalline binder phase; having the following properties: density at least 99.5% of the theoretical density, dark green coloring of ground sections or polished surfaces through characteristic light absorption in the orange spectral region at 1.8 to 2.2 eV, resistivity of at least 107 ohm·cm, and fracture toughness of at least 4.0 MPa.m½, measured using the bridge method.
Type:
Grant
Filed:
July 8, 2000
Date of Patent:
March 11, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Karl-Alexander Schwetz, Lorenz Sigl, Thomas Kempf, Georg Victor
Abstract: The invention relates to a method for producing organopolysiloxane terminated with alkoxy groups, wherein A) organopolysiloxane terminated with HO is reacted with B) alkoxysilane having at least three alkoxy groups and/or whose partial hydrolysate is made to react in the presence of C) acid phosphoric acid ester of general formula (I): (HO)aOP(—O—[(CR12)b—O]c[(CR22)d]e—L—M)(3−a), wherein a=1 or 2; R1 and R2=a hydrogen, methyl or hydroxyl radical; b and d=2 or 3; c=integral values from 2 to 15; e=0 or 1; L=a radical from the group —O—, —COO—, —OOC—, —CONR3—, —NR4CO— and —CO—; R3 and R4=a hydrogen or a C1-C10-alkyl radical and M=a monovalent, optionally a hydroxyl, fluorine, chlorine, bromine, C1-C10-alkoxylalkyl or cyano group substituted C1- to C20-hydrocarbon radical, provided that the radicals R1 and R2 can only be at one give
Type:
Grant
Filed:
July 18, 2000
Date of Patent:
March 11, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Norman Dorsch, Rudolf Heinrich, Oswin Sommer, Stefan Oberneder, Wolfgang Hechtl
Abstract: The invention relates to a fast-drying rendering and coating composition comprising a binder in the form of an aqueous polymer dispersion or of a water-redispersible polymer powder, and also an organic precipitant, if desired in combination with an inorganic precipitant.
Type:
Grant
Filed:
March 6, 2000
Date of Patent:
March 11, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Hans-Peter Weitzel, Harald Zeh, Peter Ball, Klaus Marquardt
Abstract: In a process for extracting cellulose from fibrous materials such as wood, the fibrous materials are reacted with a chemical disintegration solution in the presence of organosilicic compounds.
Type:
Grant
Filed:
June 27, 1997
Date of Patent:
February 18, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Willibald Burger, Outi Neubig, Kimmo Lappalainen, Hannu Wahlberg
Abstract: A polyorganosiloxane containing the units (HR2Si—O1/2) HM units, (Si—O4/2) Q units, (R1Si—O3/2) T units and (R2Si—O2/2) D units in a ratio of from 2:1:0:0 to 6:4:2:2, or (HR2Si—O1/2) HM units, (R1Si—O3/2) T units, (R2Si—O2/2) D units and (R2(R1O)Si—O1/2) in a ratio HM:T:D:alkoxyM of from 1:2:0:0 to 3:4:2:2 is described, where R are identical or different, non-halogenated or halogenated hydrocarbon radicals having from 1 to 18 carbon atoms per radical, or are OR1, where R1 is a monovalent, unsubstituted or substituted hydrocarbon radical having from 1 to 8 carbon atoms, and in each molecule there are at least 3 Si-bonded hydrogen atoms. The polyorganosiloxanes are particularly useful as crosslinking agents in addition curable elastomer formulations.
Type:
Grant
Filed:
May 4, 2000
Date of Patent:
February 11, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Peter Fink, Peter Jerschow, Hedwig Schreiter, Richard Birneder, Alois Riedl
Abstract: Disclosed is a fiber binding powder composition for consolidating fiber materials, comprising
a) a polymer powder based on a polyvinyl alcohol stabilized polymer of one or more monomers selected from the group consisting of the vinyl esters of branched or unbranched carboxylic acids having 1 to 12 carbon atoms, the esters of acrylic acid and methacrylic acid with branched or unbranched alcohols having 1 to 12 carbon atoms, aromatic vinyl compounds, vinyl halides, olefins and dienes, and
b) an inorganic compound which is solid at room temperature and which enters a chemical bond with the OH groups of the polyvinyl alcohol on introduction of said powder into water.
Type:
Grant
Filed:
June 18, 1999
Date of Patent:
January 28, 2003
Assignee:
Wacker-Chemie GmbH
Inventors:
Klaus Kohlhammer, Gerhard Koegler, Susanne Seidl, Sabine Gruber, Herbert Proebstl
Abstract: The invention relates to a composition, to a process for its preparation and to a method of coating shaped articles or elastomeric materials, where the composition can be prepared using
(1) polymer components selected from the group consisting of
(A1) polyorganosiloxanes comprising units (T units) of the formula (R1Si—O3/2) and optionally, units (M units) of the formula (R3Si—O1/2)
(A2) polyorganosiloxanes comprising units (Q units) of the formula (Si—O4/2) and, optionally, units (M units) of the formula (R3Si—O1/2)
in which
R is identical or different and represents unhalogenated or halogenated hydrocarbon radicals having 1 to 18 carbon atom(s) per radical or OR1, where
R1 is identical or different and represents hydrogen or a monovalent, unsubstituted or substituted hydrocarbon radical having 1 to 8 carbon atom(s),
with the proviso that there are from 0.01% to 3.0% by weight, preferably from 0.
Abstract: The invention relates to a composition which comprises at least one polyorganosiloxane in aqueous solution or dispersion, in the absence of additional dispersants.