Abstract: A nonlimiting example method of forming polyamide polymer particles having pigments therein may comprising: mixing a mixture comprising a polyamide having a pigment pendent from a backbone of the polyamide (PP-polyamide), a carrier fluid that is immiscible with the PP-polyamide, and optionally an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the PP-polyamide and at a shear rate sufficiently high to disperse the PP-polyamide in the carrier fluid; and cooling the mixture to below the melting point or softening temperature of the PP-polyamide to form solidified particles comprising the PP-polyamide and, when present, the emulsion stabilizer associated with an outer surface of the solidified particles. Said solidified particles may be used in additive manufacturing to make a variety of objects like containers, toys, furniture parts and decorative home goods, plastic gears, automotive parts, medical items, and the like.

Abstract: A method for producing highly spherical polymer particles comprising a polyamide having an optical absorber pendent from a backbone of the polyamide (OAMB-polyamide) may comprise: mixing a mixture comprising the OAMB-polyamide, a carrier fluid that is immiscible with the OAMB-polyamide, and optionally an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the OAMB-polyamide and at a shear rate sufficiently high to disperse the OAMB-polyamide in the carrier fluid; and cooling the mixture to below the melting point or softening temperature of the OAMB-polyamide to form particles comprising the OAMB-polyamide and the emulsion stabilizer, when present, associated with an outer surface of the particles.

Abstract: Nozzles for an additive manufacturing device and methods for improving wettability of the nozzles are disclosed. The method may include subjecting the nozzle to a surface treatment. The surface treatment may include contacting a surface of the nozzle with one or more surface modifying agents. The surface modifying agents may include one or more of an oxidizing agent, an acid, a base, or combinations thereof. The one or more surface modifying agents may increase an oxygen content of the surface of the nozzle. An inner surface of the nozzle may have a water contact angle of greater than 1° and less than about 90°. The inner surface of the nozzle may be free or substantially free of a coating.

Abstract: Nozzles for additive manufacturing and methods for improving wettability of the nozzles are disclosed. The nozzle may include a body having an inner surface and an outer surface. The inner surface may define an inner volume of the nozzle, and may have a water contact angle of greater than 1° and less than about 90°. The method may include subjecting the nozzle to a surface treatment. The surface treatment may include plasma treating a surface of the nozzle such that free radicals, polar functional groups, or a combination thereof are formed at the surface of the nozzle.

Abstract: Additive manufacturing processes, such as powder bed fusion of thermoplastic particulates, may be employed to form printed objects in a range of shapes. It is sometimes desirable to form conductive traces upon the surface of printed objects. Conductive traces and similar features may be introduced during additive manufacturing processes by incorporating a metal precursor in a thermoplastic printing composition, converting a portion of the metal precursor to discontinuous metal islands using laser irradiation, and performing electroless plating. Suitable printing compositions may comprise a plurality of thermoplastic particulates comprising a thermoplastic polymer, a metal precursor admixed with the thermoplastic polymer, and optionally a plurality of nanoparticles disposed upon an outer surface of each of the thermoplastic particulates, wherein the metal precursor is activatable to form metal islands upon exposure to laser irradiation. Melt emulsification may be used to form the thermoplastic particulates.

Abstract: A method of making thermoplastic polymer particles may include mixing in an extruder a mixture comprising a thermoplastic polymer and a carrier fluid that is immiscible with the thermoplastic polymer at a temperature greater than a melting point or softening temperature of the thermoplastic polymer and at a shear rate sufficiently high to disperse the thermoplastic polymer in the carrier fluid; cooling the mixture to below the melting point or softening temperature of the thermoplastic polymer to form solidified particles comprising thermoplastic polymer particles having a circularity of 0.90 or greater and that comprise the thermoplastic polymer; and separating the solidified particles from the carrier fluid.

Abstract: Melt emulsification may be employed to form elastomeric particulates in a narrow size range when nanoparticles are included as an emulsion stabilizer. Such processes may comprise combining a polyurethane polymer and nanoparticles with a carrier fluid at a heating temperature at or above a melting point or a softening temperature of the polyurethane polymer, applying sufficient shear to disperse the polyurethane polymer as liquefied droplets in the presence of the nanoparticles in the carrier fluid at the heating temperature, cooling the carrier fluid at least until elastomeric particulates in a solidified state form, and separating the elastomeric particulates from the carrier fluid. In the elastomeric particulates, the polyurethane polymer defines a core and an outer surface of the elastomeric particulates and the nanoparticles are associated with the outer surface. The elastomeric particulates may have a D50 of about 1 ?m to about 1,000 ?m.

Abstract: Methods for producing a polyamide having an optical absorber pendent from the polyamide's backbone (OAMB-polyamide) may comprise: esterifying a hydroxyl-pendent optical absorber with a halogen-terminal aliphatic acid to yield a halogen-terminal alkyl-optical absorber; and N-alkylating a polyamide with the halogen-terminal alkyl-optical absorber to yield the OAMB-polyamide. Other methods for producing an OAMB-polyamide may comprise: esterifying a carboxyl-pendent optical absorber with a halogen-terminal aliphatic alcohol to yield a halogen-terminal alkyl-optical absorber; and N-alkylating a polyamide with the modified optical absorber to yield a polyamide having the OAMB-polyamide.

Abstract: Optical absorber-containing thermoplastic polymer particles (OACTP particles) may be produced by methods that comprise: mixing a mixture comprising a thermoplastic polymer, a carrier fluid that is immiscible with the thermoplastic polymer, and optionally an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the thermoplastic polymer and at a shear rate sufficiently high to disperse the thermoplastic polymer in the carrier fluid; cooling the mixture to below the melting point or softening temperature of the thermoplastic polymer to form solidified particles comprising the thermoplastic polymer; separating the solidified particles from the carrier fluid; and exposing the solidified particles to an optical absorber to produce the OACTP particles.

Abstract: A method for producing highly spherical polymer particles comprising a polyamide having an optical absorber in a backbone of the polyamide (IBOA-polyamide) may comprise: mixing a mixture comprising the IBOA-polyamide, a carrier fluid that is immiscible with the IBOA-polyamide, and optionally an emulsion stabilizer at a temperature greater than a melting point or softening temperature of the IBOA-polyamide and at a shear rate sufficiently high to disperse the IBOA-polyamide in the carrier fluid; and cooling the mixture to below the melting point or softening temperature of the IBOA-polyamide to form particles comprising the IBOA-polyamide and the emulsion stabilizer, when present, associated with an outer surface of the particles.

Abstract: A method for producing polyamide particles may include: mixing a mixture comprising a polyamide, a carrier fluid that is immiscible with the polyamide, and nanoparticles at a temperature greater than a melting point or softening temperature of the polyamide and at a shear rate sufficiently high to disperse the polyamide in the carrier fluid; cooling the mixture to below the melting point or softening temperature of the polyamide to form solidified particles comprising polyamide particles having a circularity of 0.90 or greater and that comprise the polyamide and the nanoparticles associated with an outer surface of the polyamide particles; and separating the solidified particles from the carrier fluid.

Abstract: Methods for synthesizing a polyamide having the optical absorber in the backbone of the polyamide may comprise: polymerizing polyamide monomers in the presence of an optical absorber selected from the group consisting of a polyamine optical absorber, a polyacid optical absorber, an amino acid optical absorber, and any combination thereof to yield the polyamide having the optical absorber in the backbone of the polyamide. Said polyamides having the optical absorber in the backbone of the polyamide may be useful in producing objects by methods that include melt extrusion, injection molding, compression molding, melt spinning, melt emulsification, spray drying, cryogenic milling, freeze drying polymer dispersions, and precipitation of polymer dispersions.

Abstract: A method of producing thermoplastic particles may comprise: mixing a melt emulsion comprising (a) a continuous phase that comprises a carrier fluid having a polarity Hansen solubility parameter (dP) of about 7 MPa0.5 or less, (b) a dispersed phase that comprises a dispersing fluid having a dP of about 8 MPa0.5 or more, and (c) an inner phase that comprises a thermoplastic polyester at a temperature greater than a melting point or softening temperature of the thermoplastic polyester and at a shear rate sufficiently high to disperse the thermoplastic polyester in the dispersed phase; and cooling the melt emulsion to below the melting point or softening temperature of the thermoplastic polyester to form solidified particles comprising the thermoplastic polyester.

Abstract: A method of assembling a plurality of linear arrays from a silicon wafer having a first surface and a second surface opposite the first surface, the first surface having at least a first linear array of sensor/emitter elements and a second linear array of sensor/emitter elements, each arranged parallel relative to a first direction, and a sacrificial portion positioned between the first linear array of sensor/emitter elements and the second linear array of sensor/emitter elements.

Abstract: A printable media including a carrier layer, a fabric layer and a first adhesive. The carrier layer includes a first surface having a first area, a second surface opposite the first surface, and a first rigidity. The fabric layer includes a third surface, a fourth surface opposite the third surface and including a second area, and a second rigidity less than the first rigidity. The fabric layer is secured to the carrier layer by the first adhesive bonding a first portion of the fourth surface to the first surface.

Abstract: A color shift security feature is provided. In at least one form, a clear colorant is used to add content to a document to provide a visual indication if the document is printed on a printer with self-limiting behavior. In this manner, in at least one form, it can be determined if a document is authentic, secure and/or authorized.

Abstract: An inkjet printer adjusts operation of a vacuum system coupled to a printhead to compensate for pressure changes in the manifold of the printhead caused by vertical displacement of the printhead within the printer. The inkjet printer includes a controller that determines either a difference between an optimal pressure in the manifold and a current pressure to operate a vacuum coupled to the manifold for pressure adjustment or it correlates a current printhead vertical position to a previously observed vertical position and uses a vacuum value associated with the previously observed vertical position to operate the vacuum.

Abstract: Disclosed is a diagnostic method and system including the processing of historical event logs generated by one or more devices. According to an exemplary embodiment, a diagnostic system includes an event log acquisition module, an event classification module classifying event logs acquired, and a diagnostic module generating a labeled version of the historical event log including labels provided by the classification module. The event classification module is trained using supervised machine learning techniques.

Abstract: A method of operating a printer repetitively merges a purge sheet into a media stream of a job stream in the printer so the controller of the printer can operate inactive inkjets and eject ink onto the purge sheet to maintain the operational status of the inactive inkjets. The purge sheet has a width that is at least the maximum width of a print zone in the printer in the cross-process direction and a length that is less than a length of any media sheet in the job stream in the process direction. The purge sheet is diverted through a duplex path in the printer to repetitively merge the purge sheet into the media stream of the job stream to maintain the operational status of the inactive inkjets.

Abstract: Described herein is a metallic toner. The metallic toner includes flake shape toner particles having a binder resin, zinc stearate, silica having a particle size of from 7 nm to less than 12 nm in an amount of about 0.1 weight percent to 1.0 about weight percent of the flake shape toner particle and tabular shape metallic pigments. The flake shape toner particles have an average major axis length of from 6 ?m to 20 ?m, an average thickness of from 1 ?m to 4 ?m and an average circularity of from 0.5 to 0.97. The tabular shape metallic pigments have an average major axis length of from 1 ?m to 14 ?m an average thickness of from 0.01 ?m to 0.5 ?m.