Patents Assigned to Zhejiang University of Technology
  • Patent number: 11767232
    Abstract: The present invention provides a process for continuous treatment of high-concentration organic wastewater and a device for continuous treatment of high-concentration organic wastewater. The process of the present application is that: high-concentration organic wastewater is continuously separated through the synergistic interaction of a multilayer evaporator and a heat pump, and the generated wastewater steam containing light components is continuously subjected to desulfurization and catalytic combustion after being mixed with air in a gaseous form, the treated wastewater can meet discharge standards, and heavy components of the generated wastewater can be recycled.
    Type: Grant
    Filed: July 6, 2021
    Date of Patent: September 26, 2023
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yong Nie, Shangzhi Yu, Xiaojiang Liang, Qinglong Xie, Zhenyu Wu, Jianfeng Bai
  • Patent number: 11761943
    Abstract: Disclosed is a confining pressure-adjustable test and observation system for soil deformation features during vacuum preloading. The system includes a soil vacuum consolidation system, a vacuum drive system, a confining pressure system and a monitoring system; where the soil vacuum consolidation system includes a model box filled with test soil, the confining pressure system is arranged in the model box, two sides of the model box are provided with slide plates, and the slide plates on two sides are provided with expansion control cavities at two side ends of the model box correspondingly, and a corrugated air bag is arranged in the expansion control cavity and is connected to an external air pump and an air bag air pressure control device through a pipeline; the test soil in the model box is covered with geotextile, and the geotextile is covered with a vacuum film.
    Type: Grant
    Filed: June 29, 2022
    Date of Patent: September 19, 2023
    Assignee: Zhejiang University of Technology
    Inventors: Honglei Sun, Zili He, Jingling Lu, Zhenqi Weng, Jian Wu, Shao Yang, Wanjie Wang
  • Patent number: 11692904
    Abstract: A boss structure sealing experiment device for an IV type hydrogen storage cylinder. The device includes a high-pressure chamber, a sealing leakage structure, a cylinder mouth valve, and a low-pressure chamber, where the high-pressure chamber, the sealing leakage structure, and the low-pressure chamber are tightly connected to one another through flange bolts, and the cylinder mouth valve is tightly connected to the high-pressure chamber through threads. Further disclosed is a sealing experiment system. The system includes a boss structure sealing experiment device, a high-pressure gas supply device, and a leaked gas detection device. The high-pressure gas supply device consists of a hydrogen source, a compressor, a buffer tank, a valve, and a pressure gauge; and the leaked gas detection device consists of a gas mixing chamber, a carrier gas, and a gas leakage detector. Further disclosed is a test method for a boss structure sealing experiment.
    Type: Grant
    Filed: October 14, 2022
    Date of Patent: July 4, 2023
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yuebing Li, Zhouxin Pan, Jiqi Zhu, Zengliang Gao, Weiya Jin, Xing He
  • Publication number: 20230159366
    Abstract: A novel geotextile tube type sludge dehydration device combined with vacuum preloading including a geotextile tube for filling sludge, a pump drainage mechanism, vacuum tubes and a vacuum pump, where the geotextile tube is divided into top cloth and bottom cloth, a slurry filling inlet is provided on the top cloth, and the top cloth and the bottom cloth are sewn by means of a portable rechargeable bag sewing machine; and the pump drainage mechanism is arranged in the geotextile tube, is connected to the vacuum pump by means of the vacuum tubes, and includes a drainage plate and a hand connector, the drainage plate being inserted into the hand connector, the hand connector is connected to the vacuum tubes, and is fixed by hoops, and the vacuum tubes pass through flange piece ports on the geotextile tube, to be connected to the vacuum pump.
    Type: Application
    Filed: October 17, 2022
    Publication date: May 25, 2023
    Applicant: Zhejiang University of Technology
    Inventors: Honglei Sun, Zhenqi Weng, Wanjie Wang
  • Patent number: 11640145
    Abstract: Aiming at insufficient drying seafood on-board caused by hull swings, the present invention involves the establishment of location correction system for processing seafood transportation displaced by wind waves and anti-accumulation drying processing method. This invention employs CFD-DEM method to simulate the state and distribution of the material particles modulated by the deflector angle and wind speed. Finally, the optimized rotation angle of deflector and wind speed are obtained where material particles are equally distributed. Meanwhile, the uniform and fast drying of the marine products in the swinging hull are achieved. This invention shows the great advantages of high efficiency, automation and continuity.
    Type: Grant
    Filed: September 10, 2020
    Date of Patent: May 2, 2023
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yuting Ding, Xuxia Zhou, Shichen Zhu, Zhigang Ke, Long Lin, Yucong Zhang, FangRui Yu, Zhaoyong Lin, Ning Lin, Xia Xu
  • Patent number: 11617374
    Abstract: A method for preserving aquatic products at sea includes the following steps: an on-board refrigeration system is used to refrigerate the antifreeze solution, and the antifreeze solution is used as a main cold source, and temperatures at centers of fish bodies drop rapidly to achieve rapid cooling and reduce activity of endogenous enzymes and inhibit proliferation of microorganisms by direct or indirect heat exchange with captured catches. The antifreeze solution contains edible alcohol, propylene glycol, glycerol, calcium chloride, sodium chloride, amino acids, Antarctic krill protein hydrolysate with average molecular weight of 50-100 KDa, surfactant and water, and the mass percentage of each component is as follows: edible alcohol 15%-30%, propylene glycol 10%-30%, glycerol 2%-15%, calcium chloride 1%-10%, sodium chloride 3%-10%, amino acid 0.1%-0.15%, Antarctic krill protein hydrolysate 0.01%-0.3%, surfactant 0.005%-0.5%, and the balance is water.
    Type: Grant
    Filed: June 25, 2019
    Date of Patent: April 4, 2023
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yuting Ding, Shulai Liu, Xuxia Zhou, Jianhua Liu, Fei Lv, Jianyou Zhang, Yanbo Wang, Zhenyu Zhang
  • Patent number: 11578096
    Abstract: The present invention relates to a method for preparing 7?-methyl-19-aldehyde-4-androstene-3,17-dione by electrocatalytic oxidation. The method specifically includes: adopting an H-shaped electrolytic cell for reaction, in an anode chamber, using a metal oxide catalyst as a working electrode, using 7?-methyl-17,19-dihydroxy-4-androstene-3-one as a reaction substrate, and dissolving it in a mixed solvent to be used as an anolyte, and adding nitroxide radicals to be used as a medium; and in a cathode chamber, using a platinum sheet as a counter electrode, using a weakly alkaline solution as a catholyte, carrying out an electrocatalytic oxidation reaction in a constant temperature water bath, adding an organic solvent at the end of the reaction for extraction to obtain an organic extract liquor, and taking an organic layer and carrying out distilling under a reduced pressure to obtain 7?-methyl-19-aldehyde-4-androstene-3,17-dione.
    Type: Grant
    Filed: December 1, 2021
    Date of Patent: February 14, 2023
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Jianguo Wang, Suiqin Li, Xing Zhong, Jiahui He
  • Patent number: 11535839
    Abstract: The present invention discloses encoding genes of nitrilase mutants and application thereof. The nucleotide sequence of the gene is shown in SEQ ID No.5, and the amino acid sequence of the mutant is shown in SEQ ID No.6. In the present invention, by the protein molecular modification, thermostability of the purified nitrilase LNIT5 is increased by up to 4.5 folds; and by utilizing recombinant E. coli containing the nitrilase mutant to hydrolyze 1-cyanocyclohexylacetonitrile at a high temperature, product tolerance is increased, activity of NIT5-L201F is increased by 20%, and the mutant NITLNIT5-AcN can completely hydrolyze 750 mM 1-cyanocyclohexylacetonitrile within 8 hours and achieve an doubled conversion rate. Therefore, the mutants obtained by the present invention have a good application prospect in efficiently catalyzing 1-cyanocyclohexylacetonitrile to synthesize gabapentin intermediate, 1-cyanocyclohexyl acetic acid.
    Type: Grant
    Filed: February 2, 2021
    Date of Patent: December 27, 2022
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yaping Xue, Yuguo Zheng, Zhe Xu, Zhiqiang Liu
  • Patent number: 11528925
    Abstract: The present invention discloses an antifreeze solution for food preservation, which comprises edible alcohol, propylene glycol, glycerin, calcium chloride, sodium chloride, amino acid, Antarctic krill protein hydrolysate with an average molecular weight of 50-100 KDa, surfactant and water, wherein the surfactant is one or more of phospholipid, Tween-20, Tween-60, and Tween-80; each component is food grade, and the mass percentage is expressed as follows: alcohol 15-30%, propylene glycol 10-30%, glycerol 2-15%, calcium chloride 1-10%, sodium chloride 3-10%, amino acid 0.1-0.15%, Antarctic krill protein hydrolysate 0.01-0.3%, surfactant 0.005-0.5%, and the balance is water. The antifreeze solution provided by the present invention can lower the freezing point, improve the heat transfer efficiency, inhibit the crystallization of antifreeze solution during the low temperature stirring process and improve the stability of the antifreeze solution.
    Type: Grant
    Filed: June 25, 2019
    Date of Patent: December 20, 2022
    Assignees: HANGZHOU QIANDAO LAKE DEVELOPMENT GROUP CO., LTD., ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yuting Ding, Shulai Liu, Zhenyu Zhang, Jianmin Wang, Guangxi He, Hongzheng Yao
  • Patent number: 11525131
    Abstract: The present invention discloses a recombinant vector constructed from an encoding gene of a nitrilase mutant, a recombinant genetic engineered strain and application thereof the nucleotide sequence of the gene is shown in SEQ ID No. 5, and the amino acid sequence of the mutant is shown in SEQ ID No. 6. In the present invention, by the protein molecular modification, thermostability of the purified nitrilase LNIT5 is increased by up to 4.5 folds; and by utilizing recombinant E. coli containing the nitrilase mutant to hydrolyze 1-cyanocyclohexylacetonitrile at a high temperature (45° C.), product tolerance is increased, activity of NITS-L201F is increased by 20%, and the mutant NITLNIT5-AcN can completely hydrolyze 750 mM 1-cyanocyclohexylacetonitrile within 8 hours and achieve an doubled conversion rate.
    Type: Grant
    Filed: February 2, 2021
    Date of Patent: December 13, 2022
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yaping Xue, Yuguo Zheng, Zhe Xu, Zhiqiang Liu
  • Patent number: 11512057
    Abstract: The present invention discloses unsaturated hydrocarbon pyrimidine thioether compounds of formula (I) and preparation method and application thereof, the compounds of formula (I) exhibit high insecticidal and acaricidal activity against adults, larvae and eggs of harmful mites and insects in the agriculture, civil use and animal technology fields, meanwhile, the compounds also exhibit good bactericidal activity, and can be widely applied as an insecticide, an acaricide and/or a bactericide in agriculture or other fields
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: November 29, 2022
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Xiaohua Du, Shulin Hao
  • Patent number: 11492606
    Abstract: The present invention discloses a nitrilase mutant and its construction method and its application in the synthesis of chiral intermediate of pregabalin in the technical field of bioengineering. The present invention, respectively, takes turnip nitrilase BrNIT and arabidopsis nitrilase AtNIT as parent, using peptide fragment displacement method, displaces the sites 226-286 of BrNIT amino acid sequence and sites 225-285 of AtNIT amino acid sequence with sites 225-285 of Arabis alpina L. nitrilase AaNIT, obtain nitrilase mutants BrNIT225-285 and AtNIT225-285 of which the amino acid sequence is as shown in SEQ ID NO.1 or SEQ ID NO.3.
    Type: Grant
    Filed: January 31, 2019
    Date of Patent: November 8, 2022
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Renchao Zheng, Yuguo Zheng, Qin Zhang, Zheming Wu, Xiaoling Tang, Xiafeng Lu
  • Patent number: 11464746
    Abstract: This invention provides a method for preparing electrospraying particles to improve stability of polyphenol including the following steps: preparing a pectin-silica composite; adding polyphenolic compounds into the pectin-silica composite to prepare a core solution; and coaxial electrospraying the core solution and a shell solution to prepare electrospraying particles loaded polyphenol. This method utilizes a pectin-silica composite as a polyphenol loading carrier, improves the encapsulating efficiency of polyphenols, reduces the contact probability of polyphenols with oxygen and water, and improves the stability of polyphenols; and an acidic aqueous solution is used as a shell solution to synergize with the pectin-silica composite to further improve the stability of polyphenols.
    Type: Grant
    Filed: May 22, 2019
    Date of Patent: October 11, 2022
    Assignee: Zhejiang University of Technology
    Inventors: Ping Shao, Ben Niu, Ligang Jiang
  • Patent number: 11420991
    Abstract: A confined porphyrin Co(II), which is prepared by the following method: Equimolar amounts of aromatic aldehyde and pyrrole are condensed under acidic conditions to synthesize phenyl porphyrin compounds; the phenyl porphyrin compounds are metallized in a chloroform-methanol solution to obtain porphyrin Cu(II), which is brominated and demetallized to obtain confined porphyrin; the confined porphyrin is stirred and refluxed in a methanol solution for 12.0-24.0 h to obtain confined porphyrin Co(II). Its application is as follows: The confined porphyrin Co(II) is dissolved in cycloalkanes; the reaction system is sealed, and heated to 100 to 130° C. with stirring, to which oxygen is introduced to 0.2 to 3.0 MPa; the reaction is carried out for 3.0 to 24.0 h with stirring with the set temperature and oxygen pressure being maintained; and then the reaction solution is subjected to post-treatment to obtain the products.
    Type: Grant
    Filed: July 14, 2020
    Date of Patent: August 23, 2022
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Haimin Shen, Lei Ning, Yuanbin She
  • Patent number: 11407948
    Abstract: A device for pyrolysis reactions includes a feeding pump, a flow meter, an atomizer, a pyrolysis reactor, electromagnetic coils, an electromagnetic induction heating power, a temperature sensor, a temperature controller, a condenser and a product tank. The feeding pump is connected with the flow meter which is connected to the inlet of the atomizer in the pyrolysis reactor. There is a port at the bottom of the pyrolysis reactor, with the port at the top of the pyrolysis reactor connected with the condenser. The condenser is connected with the product tank. The external wall of the pyrolysis reactor is surrounded by electromagnetic coils which are connected with the electromagnetic induction heating power. The temperature sensor is placed between the pyrolysis reactor and the coils, which is connected with the temperature controller. The contact resistance between the atomized material and the hot surface can be.
    Type: Grant
    Filed: December 28, 2018
    Date of Patent: August 9, 2022
    Assignee: Zhejiang University of Technology
    Inventors: Yong Nie, Qinglong Xie, Ying Duan, Fan Xia, Meizhen Lu, Shangzhi Yu, Xiaojiang Liang, Jianbing Ji
  • Patent number: 11408016
    Abstract: The present invention discloses an amino acid dehydrogenase mutant and application thereof in synthesizing L-glufosinate-ammonium, the amino acid dehydrogenase mutant is obtained by a single mutation or a multi-site mutation of the amino acid at position 95, 108, 172, 303 of the amino acid sequence shown in SEQ ID No. 2. The amino acid dehydrogenase mutant DyGDH-F95I-A108T-R172P-R303H prepared by the present invention has a specific enzyme activity that is 33 times higher than that of the original Aldo-keto reductase, and the concentration of the largest substrate, 2-carbonyl-4-(hydroxymethylphosphinyl)-butyric acid reaches 500 mM, the amino acid dehydrogenase mutant has more industrial application prospects.
    Type: Grant
    Filed: June 28, 2019
    Date of Patent: August 9, 2022
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Yaping Xue, Feng Cheng, Heng Li, Yuguo Zheng, Jianmiao Xu
  • Publication number: 20220240551
    Abstract: A method for rapid low-salted pickling of aquatic products is disclosed, which includes preliminary processing of raw materials, bacteria-reducing treatment of plasma activation gas, marinade adding and plasma treatment, cyclic bacteria-reducing treatment with the plasma activation gas and vacuum pickling. The marinade adding and plasma treatment include respectively injecting the marinade and plasma working gas into a tumbler, with a flow rate of ionic working gas injected into the tumbler of 1.5-2 L/min and a flow rate of a pickling solution of 0.5-0.8 L/min: and at the same time, starting a plasma power supply, and performing low-temperature plasma treatment on the aquatic products to be pickled, with a plasma treatment voltage of 12000-15000 V, a current of 60-80 mA, a frequency of 8-10 kHz, which is a second bacteria-reducing treatment, with plasma treatment time of 15-20 min.
    Type: Application
    Filed: January 21, 2022
    Publication date: August 4, 2022
    Applicant: Zhejiang University of Technology
    Inventors: Xuxia ZHOU, Yuting DING, Zhigang KE, Yicheng DING, Wenjie WANG, Qi ZHANG, Hao ZHU, Yushan CHU
  • Publication number: 20220204546
    Abstract: The present invention relates to a method for preparing 7?-methyl-19-aldehyde-4-androstene-3,17-dione by electrocatalytic oxidation. The method specifically includes: adopting an H-shaped electrolytic cell for reaction, in an anode chamber, using a metal oxide catalyst as a working electrode, using 7?-methyl-17,19-dihydroxy-4-androstene-3-one as a reaction substrate, and dissolving it in a mixed solvent to be used as an anolyte, and adding nitroxide radicals to be used as a medium; and in a cathode chamber, using a platinum sheet as a counter electrode, using a weakly alkaline solution as a catholyte, carrying out an electrocatalytic oxidation reaction in a constant temperature water bath, adding an organic solvent at the end of the reaction for extraction to obtain an organic extract liquor, and taking an organic layer and carrying out distilling under a reduced pressure to obtain 7?-methyl-19-aldehyde-4-androstene-3,17-dione.
    Type: Application
    Filed: December 1, 2021
    Publication date: June 30, 2022
    Applicant: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: JIANGUO WANG, SUIQIN LI, XING ZHONG, JIAHUI HE
  • Publication number: 20210404139
    Abstract: The present invention discloses a system for bridge scour multi-source monitoring, including an intelligent monitoring system, a data industrial personal computer, a 5G remote communication transmission system and a remote scour depth evaluation center. The intelligent monitoring system consists of three subsystems including a high-frequency real-time bridge dynamic characteristic monitoring system, an adjustable sound velocity underwater depth monitoring system and a scoured seabed soil pressure change testing system, which are coupled with one another to carry out triggering control to acquire lateral pile data, thereby forming a multi-source bridge local scour real-time sensing monitoring system, and realizing integration of clock synchronization, dynamic control of scour environment conditions, contact sensors and non-contact sensors.
    Type: Application
    Filed: June 2, 2021
    Publication date: December 30, 2021
    Applicant: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Jian GUO, Jiyi WU, Bing JIANG
  • Patent number: 11186923
    Abstract: A method for manufacturing an ultra small grain-size nanocrystalline diamond film having a SiV photoluminescence, comprises: (1) manufacturing, on a single crystal silicon substrate, a nanocrystalline diamond film having a SiV photoluminescence by using a microwave plasma chemical vapor deposition method; (2) performing oxygen plasma etching treatment on the nanocrystalline diamond film obtained in step (1) for 5-30 min by using an oxygen plasma bombardment method in a mixed gas plasma having an oxygen-nitrogen gas volume ratio of 1:4-6 and at an atmospheric pressure of 0.5-6 torr and a microwave power of 600-1000 W, thereby obtaining the ultra small grain-size nanocrystalline diamond film having the SiV photoluminescence.
    Type: Grant
    Filed: October 16, 2020
    Date of Patent: November 30, 2021
    Assignee: ZHEJIANG UNIVERSITY OF TECHNOLOGY
    Inventors: Xiaojun Hu, Chengke Chen