Abstract: A crystalline polymer microporous membrane containing a crystalline polymer microporous film containing a crystalline polymer, and having an asymmetric pore structure; fluorine alcohol covering at least part of an exposed surface of the crystalline polymer microporous film; and a crosslinking agent, wherein the fluorine alcohol is crosslinked with assistance of the crosslinking agent.
Abstract: A water treatment system including a reverse osmosis module and a control valve controlling communication between a water source and the module. A feedwater biased storage tank stores permeate and its pressurization by feedwater is controlled by a feedwater control valve. Flow of signal pressure to a signal pressure chamber of the feedwater control valve is restricted to reduce the rate at which a fluid generated force is applied. A check valve in parallel with the restriction allows relatively unrestricted flow out of the signal chamber when signal pressure is terminated. A tank pressurization control valve controls the operation of the feedwater control valve and controls the pressurization of a feedwater biasing chamber in the storage tank. Per-meate is stored in an accumulator for flushing the reverse osmosis module when the storage tank reaches a predetermined limit. Cleaning substances or additives can be introduced into the system.
Type:
Grant
Filed:
December 12, 2008
Date of Patent:
June 3, 2014
Assignee:
Kinetico Incorporated
Inventors:
Stuart Park, Stephen Goff, Steven Hoopes, Peter Halemba
Abstract: Composite membranes including a coating of polyalkylene oxide and biguanide compounds along with various methods for making and using the same. In one embodiment, the composite membrane comprises a thin film polyamide layer including a coating of a reaction product of a polyalkylene oxide compound and a biguanide-type compound. In another embodiment, the coating comprises a polymer including alkylene oxide repeating units and one or more biguanide functional groups.
Type:
Grant
Filed:
February 23, 2011
Date of Patent:
May 27, 2014
Assignee:
Dow Global Technologies LLC
Inventors:
William E. Mickols, Chunming Zhang, Christopher T. Hamilton
Abstract: A composition comprises a crosslinked poly(meth)acrylate comprising two or more poly(meth)acrylate backbones covalently linked to a bridging group, the backbones comprising i) respective first repeat units, each of which comprises a first side chain ester moiety comprising a hydrophilic poly(alkylene oxide) chain segment, ii) respective second repeat units, each of which comprises a second side chain ester moiety directly linked to the bridging group through a linking group selected from the group consisting of carbamate groups, urea groups, and thiocarbamate groups, and iii) respective third repeat units, each of which comprises a hydrophobic side chain moiety not directly linked to any bridging group. Composite filtration membranes having a selective layer that comprises the composition exhibit useful anti-fouling and/or salt rejection characteristics.
Type:
Grant
Filed:
September 1, 2010
Date of Patent:
May 20, 2014
Assignee:
International Business Machines Corporation
Inventors:
Joy Cheng, Ratnam Sooriyakumaran, Ankit Vora
Abstract: A zeolite membrane excellent in separation performance and having an acid resistance, and a separation membrane employing the zeolite membrane are provided. A zeolite membrane comprising a layer wherein at least two different types of zeolite crystals are present in mixed state, wherein at least two types of the above at least two different types of zeolite crystals are detectable by an X-ray pattern obtained by X-ray diffraction under the conditions that (A) the output of X-ray is 1.2 kW, (B) an X-ray bulb of copper (Cu) is employed, and (C) the wavelength of X-ray is 1.54058 A. As an alternative, the zeolite membrane comprising a first layer containing zeolite crystals and a second layer containing different type of zeolite crystals from the zeolite crystals of the first layer, wherein the first layer and the second layer constitute a laminate structure, and the thickness of the laminate structure is at most 20 pm.
Abstract: A dehydrating system using multiple water separation membranes aims to prevent damage to the water separation membrane units and also to take appropriate measures against decrease in water permeation rate of the water separation membranes. Provided is a dehydrating system (100) for removing water from a target fluid, including at least two water separation membrane units (1, 2, 3) connected in series in a flow direction of the target fluid; two or more heat exchangers (11, 21, 31) respectively provided in front of the water separation membrane units (1, 2, 3), each of the heat exchangers (11, 21, 31) raising a temperature of the target fluid to a temperature which is lower than a boiling point of the target fluid but close to the boiling point.
Abstract: Composite membranes including a coating of polyalkylene oxide and acetophenone compounds along with various methods for making and using the same. In one embodiment, the composite membrane comprises a thin film polyamide layer including a coating of a reaction product of a polyalkylene oxide compound and an acetophenone compound. In another embodiment, the coating comprises a polymer including alkylene oxide repeating units and one or more acetophenone functional groups.
Abstract: A method of making a water vapor transport membrane is described. The method can include providing two sheets, each sheet comprising a support layer with an ionomer layer thereon; applying a solvent to at least one sheet; and contacting the ionomer layers of the two sheets to form a composite membrane comprising a composite ionomer layer between the two support layers. A composite membrane is also described.
Type:
Grant
Filed:
September 13, 2011
Date of Patent:
April 29, 2014
Assignee:
GM Global Technology Operations LLC
Inventors:
Annette M. Brenner, Shawn M. Clapham, Lijun Zou, Timothy J. Fuller
Abstract: A method comprises disposing, on a porous support membrane, an aqueous mixture comprising a crosslinkable polymer comprising a poly(meth)acrylate and/or poly(meth)acrylamide backbone, thereby forming an initial film layer, wherein the crosslinkable polymer comprises a side chain nucleophilic amine group capable of interfacially reacting with a multi-functional acid halide crosslinking agent to form a crosslinked polymer; contacting the initial film layer with a mixture comprising i) the multi-functional acid halide crosslinking agent, ii) an optional accelerator, and iii) an organic solvent, the organic solvent being a non-solvent for the crosslinkable polymer; and allowing the crosslinkable polymer to interfacially react with the crosslinking agent, thereby forming a composite filtration membrane comprising an anti-fouling selective layer comprising the crosslinked polymer.
Type:
Grant
Filed:
September 1, 2010
Date of Patent:
April 29, 2014
Assignee:
International Business Machines Corporation
Abstract: A microporous organic-inorganic hybrid membrane based on silica of the invention has an average pore diameter of less than 0.6 nm, and comprises bridging organosilane moieties of the formula ?O1.5Si—CHR—SiO1.5? or ?O1.5Si—CH(CH3)—SiO1.5?. The membrane can be used in the separation of hydrogen from mixtures comprising hydrogen and CH4, CO2, CO, N2, and the like, and in the separation of water from alcohols having 1-3 carbon atoms, optionally in the presence of an inorganic or organic acid.
Type:
Grant
Filed:
July 14, 2009
Date of Patent:
April 29, 2014
Assignee:
Stichting Energieonderzoek Centrum Nederland
Inventors:
Rob Kreiter, Hessel Lennart Castricum, Jaap Ferdinand Vente, Johan Evert Ten Elshof, Maria Dirkje Anna Rietkerk, Henk Martin Veen
Abstract: A water-proof sound-transmitting membrane 10 includes a polytetrafluoroethylene porous membrane 1 and has a surface density of 1 to 20 g/m2. The polytetrafluoroethylene porous membrane 1 includes a first porous layer 1a, and a second porous layer 1b stacked on and integrated with the first porous layer 1a by a binding force acting between polytetrafluoroethylene matrices.
Abstract: Product, method of making product, and technique for using product to separate oil from water via a filter, such as cotton, polyester, or leather, coated with a chemical that blocks oil while allowing water to pass therethrough.
Type:
Grant
Filed:
June 10, 2011
Date of Patent:
April 15, 2014
Assignee:
University of Pittsburgh—Of the Commonwealth System of Higher Education
Abstract: A high efficiency water purification system is provided incorporating recovery of a portion concentrate wastewater associated with the reverse osmosis unit. This reduces the overall volume of concentrate wastewater requiring discharge/disposal by reusing the purified concentrate of a concentrate recovery units as RO feed water. Initial feedwater is pressurized and passed through an RO membrane, and separated into a permeate flow and a concentrate flow. A portion of the higher pressure concentrate is then directed to an additional set of thin film composite membranes (concentrate recovery membranes). The concentrate recovery membranes are arranged in an array such that the concentrate pressure is adequate to provide the force required to drive the concentrate through the recovery system membranes. The permeate produced by the concentrate recovery system is directed back to the feed of the primary RO unit; thereby, reducing the volume of raw feed water required for system operation.
Abstract: A polyamide membrane including reaction product of an anhydrous solution comprising an anhydrous solvent, at least one polyfunctional secondary amine and a pre-polymer deposition catalyst, and an anhydrous, organic solvent solution comprising a polyfunctional aromatic amine-reactive reactant having one ring. A composite semipermeable membrane including the polyamide membrane on a porous support.
Abstract: A hydrophilic filtration membrane having high chemical resistance, high strength, high water permeability and high blocking performance, and being superior in fouling resistance is provided. A hydrophilic filtration membrane containing a hydrophilic polyethersulfone having a contact angle of 65 to 74 degree, a molecular weight of 10,000 to 100,000, and the number of hydroxy groups of 0.6 to 1.4 per 100 polymerization repeating units. The hydrophilic filtration membrane may additionally contain a polyvinylpyrrolidone having a molecular weight of 10,000 to 1,300,000.
Abstract: The present invention provides a hollow fiber membrane module having fixing layers to which one or more hollow fiber membrane bundles each including a plurality of hollow fiber membranes are fixed at respective ends thereof using a casting resin, a hollow portion of each of the hollow fiber membranes being open at one or both of the ends, wherein the hollow fiber membrane bundle is divided into a plurality of small bundles at least one of the fixing layers on the open side of the hollow portion, and an outer circumference of each of the small bundles is covered with an elastic body near a filtration portion interface of the fixing layer.
Abstract: A potable water system (10) comprises a supply line (18) and a water-purification device (20) incorporated thereinto. The water-purification device (20) comprises a microorganism filter (40) having a housing (42) and replaceable cartridge (42). The cartridge's filter media (50) includes a microorganism-capturing membrane (e.g., comprising an electropositive material) and a microorganism-killing membrane (e.g., comprising a biocidal material).
Abstract: Versions of the invention include compositions and methods for making them that include a polymeric porous membrane with one or more atmospheric pressure microwave plasma modified surfaces. The modified porous membrane is stable, non-dewetting, and retains its mechanical strength.
Abstract: A water-proof sound-transmitting membrane 10 includes a polytetrafluoroethylene porous membrane 1 and has a surface density of 1 to 20 g/m2. The polytetrafluoroethylene porous membrane 1 includes a first porous layer 1a, and a second porous layer 1b stacked on and integrated with the first porous layer 1a by a binding force acting between polytetrafluoroethylene matrices.
Abstract: A method for recovering carbon dioxide from acidified seawater using a membrane contactor and passing seawater with a pH less than or equal to 6 over the outside of a hollow fiber membrane tube while applying vacuum or a hydrogen sweep gas to the inside of the hollow fiber membrane tube, wherein up to 92% of the re-equilibrated [CO2]T is removed from the natural seawater.
Type:
Grant
Filed:
August 10, 2012
Date of Patent:
March 4, 2014
Assignee:
The United States of America, as represented by the Secretary of the Navy
Inventors:
Heather D. Willauer, John Barile, Felice DiMascio, Dennis R Hardy, Frederick Williams