Abstract: An object of the present invention is to provide a composite semipermeable membrane which has excellent chemical resistance, separation performance, and water permeability, and the composite semipermeable membrane has the following structure. The present invention provides a composite semipermeable membrane in which an separation function layer is formed on a microporous supporting membrane, wherein the separation function layer is formed from (A) a silicon compound in which a reactive group having an ethylenically unsaturated group and a hydrolyzable group are directly bonded to silicon atoms, and (B) a compound having an ethylenically unsaturated group other than the silicon compound, by condensation of the hydrolyzable group of the silicon compound (A) and polymerization of the ethylenically unsaturated group of the silicon compound (A) and the ethylenically unsaturated group of the compound (B) having the ethylenically unsaturated group.

Abstract: Method and devices for filtering liquid are provided that rely on pressure difference to filter liquid. In one embodiment, a device for filtering liquid includes a feed chamber, a permeate chamber, and a porous membrane that is at least partially hydrophobic and has one or more pores configured to be permeable to vapor. A pressure of a liquid substance in the feed chamber is increased such that vapor of the liquid substance is transported from the feed chamber to the permeate chamber. The resistance of flow in a hydrophilic layer of the membrane can be controlled to make the membrane defect-tolerant. In another embodiment, a second porous membrane is further included and the second porous membrane is spaced apart from the first porous membrane. Various methods for filtering liquid are also provided.

Abstract: A reverse osmosis membrane includes a porous support, a polyamide active layer formed on the porous support, and a coating layer including a copolymer including an amphoteric ionic compound and glycidyl (meth)acrylate. The coating layer makes a chemical bond with the polyamide active layer. A method of manufacturing the reverse osmosis membrane also is disclosed.

Abstract: Composite membranes including a coating comprising a combination of polyalkylene oxide and imidazol compounds along with various methods for making and using the same. In one embodiment, the composite membrane comprises a thin film polyamide layer including a coating of a reaction product of a polyalkylene oxide compound and an imidazol compound. In another embodiment, the coating comprises a polymer including alkylene oxide repeating units and one or more imidazol functional groups.

Abstract: A process for treatment of water. Hardness and non-hydroxide alkalinity are removed from feedwaters to an extent sufficient to avoid scaling when concentrated. Sparingly ionizable components in the feedwater are urged toward increased ionization by increasing the pH of the feedwater. In this manner, species such as silica become highly ionized, and (a) their rejection by membranes used in the process is significantly increased, and (b) their solubility in the reject stream from the membrane process is significantly increased. Sparingly ionized species such as boron, silica, and TOC are highly rejected. Recovery ratios of ninety percent (90%) or higher are achievable with many feedwaters, while simultaneously achieving a substantial reduction in cleaning frequency of membranes used in the process.

Abstract: Composite membranes including a coating of polyalkylene oxide and triazine compounds along with various methods for making and using the same. In one embodiment, the composite membrane comprises a thin film polyamide layer including a coating of a reaction product of a polyalkylene oxide compound and a triazine compound.

Abstract: Embodiments of the invention provide a membrane module including a first plurality of fibers capable of filtering fluids that are helically wound in layers creating a mono helix. Fluids to be treated can flow radially with respect to a longitudinal axis of the mono helix or parallel to the longitudinal axis of the mono helix. The membrane module can further include a second plurality of fibers that are helically wound with the first plurality of fibers to create a dual helix. The second plurality of fibers can have different properties than the first plurality of fibers in order to achieve different filtering functionalities.

Abstract: This invention relates to heterogenous pore polymer nanotube membranes useful in filtration, such as reverse osmosis desalination, nanofiltration, ultrafiltration and gas separation.

Abstract: The disclosure relates generally to nano-filters and methods of forming same, and methods of filtration. The nano-filter includes a substrate and at least one nanowire structure located between an inlet and an outlet. The nanowire structure may include a plurality of vertically stacked horizontal nanowires.

Abstract: The development and application of a novel non-polar oil recovery process utilizing a non-dispersive solvent extraction method to coalesce and recover oil from a bio-cellular aqueous slurry is described herein. The process could apply to recovery of algal oil from a lysed or non-lysed algae slurry, recovery of Omega fatty acids from a bio-cellular aqueous feed, recovery of Beta-carotene from a bio-cellular aqueous feed and for the removal from produced water in oil production and similar type applications. The technique of the present invention utilizes a microporous hollow fiber (MHF) membrane contactor. The non-polar oil recovery process described herein can be coupled to a collecting fluid (a non-polar solvent such as heptane, a biodiesel mixture or the previously extracted oil) that is circulated through the hollow fiber membrane. In cases where the biodiesel mixture or the previously extracted oil is used the solvent recovery step (e.g. distillation) can be eliminated.

Abstract: A process for treatment of water. Hardness and non-hydroxide alkalinity are removed from feedwaters to an extent sufficient to avoid scaling when concentrated. Sparingly ionizable components in the feedwater are urged toward increased ionization by increasing the pH of the feedwater. In this manner, species such as silica become highly ionized, and (a) their rejection by membranes used in the process is significantly increased, and (b) their solubility in the reject stream from the membrane process is significantly increased. Sparingly ionized species such as boron, silica, and TOC are highly rejected. Recovery ratios of ninety percent (90%) or higher are achievable with many feedwaters, while simultaneously achieving a substantial reduction in cleaning frequency of membranes used in the process.

Abstract: A separation membrane includes a membrane comprising a polymer, characterized in that a functional layer is formed on the surface in one side of the membrane, the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface of the preceding functional layer is 0.1% (by atomic number) or more but not more than 10 (% by atomic number), and the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface opposite to the functional layer is not more than 10 (% by atomic number). A separation membrane module suffering from little sticking of organic matters, proteins, platelets and so on is provided with the separation membrane as a built-in membrane.

Abstract: The invention relates to a method and an apparatus for dewatering mixture of ethanol and water. The method comprises steps for feeding mixture of ethanol and water (1) into an evaporator (2), evaporating said mixture of ethanol and water (1) and feeding a stream of vaporized mixture of ethanol and water (3) to a vapor recompression unit (4), pressurizing vaporized mixture of ethanol and water (3) in the vapor recompression unit (4) and feeding a stream of pressurized vaporized mixture of ethanol and water (5) to a membrane unit (6), and dividing said stream of pressurized mixture of ethanol and water (5) in to a stream of mixture of ethanol and water (8) and into a stream of dewatered mixture of ethanol and water (7).

Abstract: A process for preparing a reverse osmosis membrane that includes (A) providing a polyamine, a polyfunctional acid halide, and mono-hydrolyzed trimesoyl chloride; (B) combining the polyamine, polyfunctional acid halide, and mono-hydrolyzed trimesoyl chloride on the surface of a porous support membrane; and (C) interfacially polymerizing the polyamine and the polyfunctional acyl halide on the surface of the porous support membrane to form a reverse osmosis membrane comprising (i) the porous support membrane and (ii) a discrimination layer comprising a polyamide. The reverse osmosis membrane is characterized by a flux that is greater than the flux of the same membrane prepared in the absence of the mono-hydrolyzed trimesoyl chloride.

Abstract: In one embodiment, a membrane comprises: a nonporous, hydrophobic selective layer configured to be on a feed solution side of the membrane and polyethylene layer configured to be on a permeate side of the membrane, wherein the membrane is configured to selectively separate an organic component from an aqueous solution. In some embodiments, the method for separating an organic component from an aqueous stream can comprise: contacting a nonporous, hydrophobic selective layer of a membrane with the aqueous stream comprising the organic component, creating a vacuum on the side of the membrane comprising the support layer, permeating the organic component through the membrane into an exit chamber, and removing the organic component permeate from the exit chamber.

Abstract: Processes for manufacturing a thin film composite membrane comprising multi-walled carbon nanotubes include contacting under interfacial polymerization conditions an organic solution comprising a polyacid halide with an aqueous solution comprising a polyamine to form a thin film composite membrane on a surface of a porous base membrane; at least one of the organic solution and the aqueous solution further including multi-walled carbon nanotubes having an outside diameter of less than about 30 nm.

Abstract: The present invention includes: a water separation membrane device 2 that separates a process-target fluid into a dehydrated product and water; and a temperature monitoring device 3 for the water separation membrane device 2. The temperature monitoring device 3 detects a temperature. Further, a temperature adjustment device 4 is provided in a previous stage of the water separation membrane device 2. The temperature adjustment device 4 controls a temperature of the process-target fluid on the basis of the temperature detected by the temperature adjustment device 3 to thereby optimize an amount of water permeation in a separation process in the water separation membrane device 2.

Abstract: The invention discloses a filtration material for desalination, including a support layer, and a desalination layer formed on the support layer, wherein the desalination layer is a fiber composite membrane and includes at least one water-swellable polymer. The water-swellable polymer is made of hydrophilic monomers and hydrophobic monomers, and the hydrophilic monomers include ionic monomers and non-ionic monomers, and the ionic monomers include cationic monomers and anionic monomers.

Abstract: RO membranes using chlorinated water as a feed stream maybe protected from damage by the chlorine with a protective layer including reactive nitrogen which forms chloromines on the surface of the membrane that reduce chlorine penetration. This protective layer also provides substantial anti-fouling capabilities, whether used with a chlorinated or unchlorinated feed stream because the chloramines are anti-bacterial. Although chlorine is lost in use, the anti-fouling layer or coating can be recharged with additional chlorine without damaging the discrimination layer. The anti-fouling layer or coating may be advantageously used with Thin film composite, TFC, membranes for use in forward and reverse osmosis may include nanoparticles, monohydrolyzed and/or di-hydrolyzed TMC, and/or alkaline earth alkaline metal complexes or other additives.

Abstract: A subsurface wave action harnessing system includes a seabed mounting plate adapted for securing to a seabed, a wing having generally opposed first and second wing surfaces extending between a first and second wing ends, the second wing end being pivotably mounted to the seabed mounting plate such that pivoting motion about a pivot axis generally parallel to the mounting plate is imparted to the wing by subsurface wave action acting on the first and second wing surfaces, and a drive arm pivotably connected to the wing to convert the pivoting motion into reciprocal motion. An electrical generator, water purifier or other wave action load can be driven by the drive arm.