Abstract: A process for recovering a nickel cobalt manganese hydroxide from recycled lithium-ion battery (LIB) material such as black mass, black powder, filter cake, or the like. The recycled LIB material is mixed with water and either sulfuric acid or hydrochloric acid at a pH less than 2. Cobalt, nickel, and manganese oxides from the recycled lithium-ion battery material dissolve into the acidic water with the reductive assistance of gaseous sulfur dioxide. Anode carbon is filtered from the acidic water, leaving the dissolved cobalt, nickel, and manganese oxides in a filtrate. The filtrate is mixed with aqueous sodium hydroxide at a pH greater than 8. Nickel cobalt manganese hydroxide precipitates from the filtrate. The nickel cobalt manganese hydroxide is filtered from the filtrate and dried. The filtrate may be treated ammonium fluoride or ammonium bifluoride to precipitate lithium fluoride from the filtrate.
Abstract: A positive electrode active material for a non-aqueous electrolyte secondary battery according to a configuration includes a lithium-transition metal composite oxide containing nickel (Ni) in an amount of greater than or equal to 80 mol %, in which boron (B) is present at least on a particle surface of the lithium-transition metal composite oxide. In the lithium-transition metal composite oxide, when particles having a larger particle size than a volume-based 70% particle size (D70) are first particles and particles having a smaller particle size than a volume-based 30% particle size (D30) are second particles, a coverage ratio of B on surfaces of the second particle is larger than a coverage ratio of B on surfaces of the first particle by 5% or greater.
Type:
Grant
Filed:
October 27, 2020
Date of Patent:
July 4, 2023
Assignees:
PANASONIC HOLDINGS CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA
Abstract: The present invention relates to a positive electrode active material which has the structural stability of a lithium composite oxide constituting a positive electrode active material and a lithium secondary battery including the same. The lithium composite oxide constituting the positive electrode active material according to the present invention is able to reduce the surface area and grain boundary of secondary particles having a side reaction with an electrolyte solution, thereby improving high-temperature stability and reducing gas generation caused by the positive electrode active material, and the structural stability of the lithium composite oxide may be improved using a cation-mixing layer covering the surface of a primary particle.
Type:
Grant
Filed:
November 13, 2020
Date of Patent:
July 4, 2023
Assignee:
ECOPRO BM CO., LTD.
Inventors:
Moon Ho Choi, Hyun Jong Yu, Jung Bae Park
Abstract: The present application relates to an electrochemical device. Specifically, the present application provides a cell, wherein the cell is formed by winding or stacking a first electrode and a second electrode which are arranged at an interval, and a separator is disposed between the first electrode and the second electrode. Wherein the first electrode includes a first current collector, and the first current collector includes a coated region coated with a first active material and an uncoated region without the first active material; the uncoated region is at least partially provided with an insulating layer. The adhesion between the insulating layer and the first current collector is not less than about 0.5 N/m. The electrochemical device provided by the present application has improved safety performance.
Abstract: Disclosed are a battery cell and a manufacturing method thereof, and a battery using the battery cell. The battery cell comprises a plurality of laminated plate sets, and each plate set is formed by laminating a positive plate, a separator and a negative plate; the positive plate is provided with a positive tab extending outwardly along the plate, and the positive tab is provided with a positive tab bend; or, the negative plate is provided with a negative tab extending outwardly along the plate, and the negative tab is provided with a negative tab bend; and a plurality of positive tab bends and/or negative tab bends of the plurality of laminated plate sets are laminated to form a bent book page-shaped structure.
Type:
Grant
Filed:
October 12, 2022
Date of Patent:
June 20, 2023
Assignee:
Shenzhen Greensun Technology Co., Ltd.
Inventors:
Shuli Lu, Yajun Li, Qingyi Wang, Jin Zhang, Yangqing Luo, Yongchang Tang, Bainong Zhu, Fazuan Le
Abstract: A lithium foil laminating apparatus for an anode material of a lithium metal battery comprises a pair of lithium foil unwinders; a pair of tension guide rolls; a pair of horizontal guide rolls; a pair of first release film winders; a copper foil unwinder; a copper foil tension regulator; a pair of lithium foil cutters; a pair of guide plates; a pair of guide rolls; a pair of press rolls; a first release film unwinder; and an anode material winder.
Abstract: A nickel-based active material precursor for a lithium secondary battery includes: a secondary particle including a plurality of particulate structures, wherein each particulate structure includes a porous core portion and a shell portion, the shell portion including primary particles radially arranged on the porous core portion; and the secondary particle has a plurality of radial centers. When the nickel-based active material precursor is used, a nickel-based positive active material having a short lithium ion diffusion distance, in which intercalation and deintercalation of lithium are facilitated, may be obtained. A lithium secondary battery manufactured using the positive active material may exhibit enhanced lithium availability, and may exhibit enhanced capacity and lifespan due to suppression of crack formation in the active material during charging and discharging.
Type:
Grant
Filed:
June 25, 2019
Date of Patent:
June 6, 2023
Assignee:
Samsung SDI Co., Ltd.
Inventors:
Pilsang Yun, Jangsuk Hyun, Wooyoung Yang
Abstract: Provided are a binder aqueous solution for a lithium-ion battery electrode, a slurry for a lithium-ion battery negative electrode, a negative electrode for a lithium-ion battery, and a lithium-ion battery. The binder aqueous solution for a lithium-ion battery electrode contains an acidic group-containing water-soluble polymer (A) and an amino group-containing water-soluble polymer (B). The acidic group-containing water-soluble polymer (A) is a polymer of a monomer group containing, with respect to 100 mol % of the monomer group, 30 mol % to 90 mol % of a (meth)acrylamide group-containing compound (a), 3 mol % to 20 mol % of an unsaturated organic acid (b), and 5 mol % to 40 mol % of an alkali metal or alkaline earth metal salt (c) of the unsaturated organic acid. A 1% by mass aqueous solution of the amino group-containing water-soluble polymer (B) has a pH of 9 or higher.
Abstract: The present application provides an electrochemical device. The electrochemical device, comprising: a positive electrode; a negative electrode; and the separator, disposed between the positive electrode and the negative electrode, wherein the separator comprising a porous substrate, a first coating layer and a second coating layer, the first coating layer and the second coating layer are on a surface of the porous substrate, the first coating layer is disposed on at least one side of the second coating layer, the first coating layer includes a first binder, and the second coating layer includes a second binder, the adhesive force between the first coating layer and the positive electrode or the negative electrode is greater than the adhesive force between the second coating layer and the positive electrode or the negative electrode. The electrochemical device provided by the present application can further improve the cycle performance of the electrochemical device.
Abstract: A lithium ion secondary battery that includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolytic solution. Among resistance values of at least three of the following resistance components: diffusion resistance of Li ions in the nonaqueous electrolytic solution; ohmic resistance of the nonaqueous electrolytic solution; ohmic resistance of a positive electrode mixture layer, ohmic resistance of a negative electrode mixture layer; reaction resistance of a surface of a positive electrode active material, reaction resistance of a surface of a negative electrode active material; and diffusion resistance of Li ions in the positive electrode mixture layer, diffusion resistance of Li ions in the negative electrode mixture layer, the resistance values at a position of a mixture layer nearest a current collector are smaller than the resistance values at a position of a mixture layer nearest a separator.
Abstract: A negative electrode sheet includes a current collector, and a first active material layer and a second active material layer that are sequentially provided on at least one surface of the current collector. The first active material layer includes a first negative electrode active material. Particle sizes of the first negative electrode active material satisfy: 0.02?A1=(Dn10)1/(Dv50)1?0.2. The second active material layer includes a second negative electrode active material. Particle sizes of the second negative electrode active material satisfy: 0.02?A2=(Dn10)2/(Dv50)2?0.3; and A1 and A2 satisfy 1<A2/A1<2.5.
Abstract: Provided is a positive electrode material that allows reducing the low-temperature resistance of a secondary battery. The positive electrode material of a secondary battery includes positive electrode active material particles each having a void in the interior, and a compound (A) that is present at least within the void. The average diameter of the void is not less than 0.01 ?m and not more than 1 ?m. The compound (A) is a nitrile group-containing polymer, and the proportion of nitrogen atoms, relative to metal atoms included in the positive electrode active material particles, other than lithium, is not less than 1 atom % and not more than 10 atom %; alternatively, the compound (A) is an alkoxysilane compound, and then the proportion of silicon atoms, relative to metal atoms included in the positive electrode active material particles, other than lithium, is not less than 1 atom % and not more than 10 atom %.
Abstract: A cathode active material for a lithium secondary battery includes a lithium-transition metal composite oxide particle having a lattice strain (?) of 0.18 or less, which is calculated by applying Williamson-Hall method defined by Equation 1 to XRD peaks measured through XRD analysis, and having an XRD peak intensity ratio of 8.9% or less, which is defined by Equation 2. By controlling the lattice strain and XRD peak intensity ratio of the lithium-transition metal composite oxide particle, a lithium secondary battery with improved life-span characteristics as well as output characteristics is provided.
Type:
Grant
Filed:
August 12, 2021
Date of Patent:
April 25, 2023
Assignee:
SK ON CO., LTD.
Inventors:
Sang Han Lee, Min Gu Kang, Jeong Bae Yoon, Yong Hyun Cho
Abstract: A separator, a method of manufacturing the same, and a lithium secondary battery including the same are disclosed herein. In some embodiments, a separator includes a non-crosslinked polyolefin layer; and a crosslinked polyolefin layer disposed on one surface of the non-crosslinked polyolefin layer and having at least one crosslinking bond represented by the following Chemical Formula 1, wherein the separator is configured such that the non-crosslinked polyolefin layer of the separator faces a positive electrode. In some embodiments, a lithium secondary battery includes a positive electrode, a negative electrode and the separator interposed between the positive electrode and the negative electrode. The lithium secondary battery has a high melt-down temperature and shows high oxidation stability under high-voltage/high-temperature environment.
Abstract: An ionic liquid additive for lithium-ion battery An ionic liquid for adding to an electrolyte of a lithium-ion battery, the ionic liquid comprises a compound with a dual core structure having the general formula (I): wherein each of cationic group X1 and X2 are heterocyclic aromatic and amine.
Abstract: The present disclosure relates to an electrolyte for a lithium secondary battery, and in particular, to a liquid electrolyte capable of stabilizing lithium metal and suppressing lithium dendrite growth, and a lithium secondary battery including the same. The lithium secondary battery provided with the electrolyte according to the present disclosure has an excellent cycle-dependent capacity retention rate, and accordingly, is effective in improving a battery lifespan property.
Type:
Grant
Filed:
December 1, 2016
Date of Patent:
April 18, 2023
Assignee:
LG ENERGY SOLUTION, LTD.
Inventors:
In Tae Park, Doo Kyung Yang, Yun Kyoung Kim
Abstract: A positive electrode for this non-aqueous electrolyte secondary battery is provided with: a positive electrode current collector; a positive electrode active material layer formed on the positive electrode current collector; a positive electrode tab connected to an exposed portion at which the positive electrode current collector is exposed and on which the positive electrode active material layer is not formed; and a protective layer covering the exposed portion and the positive electrode tab on the exposed portion. The protective layer is composed of a base material including a curable resin.
Abstract: An ionic liquid for adding to an electrolyte of a lithium-ion battery, the ionic liquid comprises a compound with a dual core structure having the general formula (I): wherein each of cationic group X1 and X2 are heterocyclic aromatic and amine.
Abstract: The invention relates to an acrylonitrile copolymer binder and application thereof in lithium ion battery, belonging to the field of lithium ion battery. The technical problem to be solved by the invention is to provide an acrylonitrile copolymer binder comprising the following structural units in percentage by weight: 78-95% of acrylonitrile unit, 1-10% of acrylic ester unit and 2-15% of acrylamide unit.
Type:
Grant
Filed:
December 9, 2016
Date of Patent:
March 14, 2023
Assignee:
SICHUAN INDIGO TECHNOLOGY CO., LTD.
Inventors:
Zhonglai Pan, Xiaozheng Zhang, Chuan Lyu, Hongchang Du
Abstract: A secondary battery capable of improving cycle characteristics, conservation characteristics, and load characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. A separator provided between the cathode and the anode is impregnated with an electrolytic solution. The electrolytic solution includes one or more of a dicarbonic ester compound, a dicarboxylic compound, a disulfonic compound, a monofluoro lithium phosphate, and difluoro lithium phosphate and one or more of fluorinated lithium phosphate, fluorinated lithium borate, and imide lithium.