Abstract: A method of removing carbon dioxide from an atmosphere and generating hydrogen includes capturing carbon dioxide from the atmosphere in an alkaline capture solution, sending the alkaline capture solution to a series of electrolyzers in a CO2-rich path, wherein each electrolyzer cell raises the acidity of the input CO2-rich solution to produce an acidified CO2-rich solution, removing carbon dioxide from the acidified CO2-rich solution at a carbon dioxide removal unit operation to produce a CO2-poor solution, sending the CO2-poor solution to the series of electrolyzers in a return path, wherein each electrolyzer raises the alkalinity of the return CO2-poor solution to produce a basified CO2-poor solution, wherein a difference in pH between the CO2-rich solution and the CO2-poor solution within each electrolyzer is less than 3, and returning the basified CO2-poor solution to the carbon dioxide capture unit operation.
Type:
Grant
Filed:
July 9, 2020
Date of Patent:
December 28, 2021
Assignee:
PALO ALTO RESEARCH CENTER INCORPORATED
Inventors:
Francisco E. Torres, Eugene Shin Ming Beh, Jessica Louis Baker Rivest
Abstract: One or more embodiments relates to a method of catalytically converting a reactant gas mixture for pollution abatement of products of hydrocarbon fuel combustion. The method provides substituted mixed-metal oxides where catalytically active metals are substituted within the crystal lattice to create an active and well dispersed metal catalyst available to convert the reactant gas mixture. Embodiments may be used with gasoline and diesel fueled internal combustion engine exhaust, although specific embodiments may differ somewhat for each.
Type:
Grant
Filed:
May 20, 2020
Date of Patent:
December 28, 2021
Assignee:
U.S. Department of Energy
Inventors:
David A. Berry, Dushyant Shekhawat, Daniel J. Haynes, Mark W. Smith
Abstract: An ammonia slip catalyst having an SCR catalyst and an oxidation catalyst comprising at least two metals, each of which is selected from a specific group, and a substrate upon which at least oxidation catalyst is located is described. The ammonia slip catalyst can have dual layers, with one of the layers containing an SCR catalyst, a second layer containing the oxidation catalyst with comprises at least two metals, each of which is selected from a specific group, and the ammonia slip catalyst does not contain a platinum group metal. Methods of making and using the ammonia slip catalyst to reduce ammonia slip are described.
Abstract: In accordance with the present invention, there are provided simplified systems and methods for catalytically deactivating, removing, or reducing the levels of reactive component(s) from the vapor phase of fuel storage tanks. The simple apparatus described herein can be utilized to replace complex OBIGGS systems on the market. Simply stated, in one embodiment of the invention, the vapor phase from the fuel tank is passed over a catalytic bed operated at appropriate temperatures to allow the reaction between free oxygen and the fuel vapor by oxidation of the fuel vapor, thus deactivating reactive component(s) in the gas phase.
Type:
Grant
Filed:
August 16, 2019
Date of Patent:
December 14, 2021
Assignee:
Phyre Technologies, Inc.
Inventors:
Stephen Walker, Santosh Limaye, Wesley Jung, Stuart Robertson
Abstract: A method for cleaning an off-gas from viscose production, essentially containing H2S and CS2, comprises passing the gas through a catalytic reactor containing a direct oxidation type catalyst, such as V2O5 on silica, to convert H2S in the gas to elemental sulfur, SO2 or mixtures thereof, either via the oxygen present in the gas or via oxygen added to the gas stream. Elemental sulfur and SO2 are removed from the effluent gas from the catalytic reactor, and the unconverted CS2 is recycled to the viscose production process.
Type:
Grant
Filed:
September 11, 2017
Date of Patent:
December 14, 2021
Assignee:
HALDOR TOPSØE A/S
Inventors:
Niklas Bengt Jakobsson, Peter Bo Olsen, Per Aggerholm Sørensen, Anders Theilgaard Madsen
Abstract: A portable gas separator assembly utilizing carbon molecular sieve absorbents or elements to separate a compressed air stream to extract nitrogen and oxygen molecules. Components of the assembly include at least two charging towers so that one tower can be charged with compressed gas while the other of the at least two towers is purged.
Abstract: A system for high-value utilization of organic solid waste includes an anaerobic digestion unit, a biogas measurement and collection unit and a methane purification and liquefaction unit. The anaerobic digestion unit includes an organic solid waste pretreatment system and an anaerobic digestion device. The biogas measurement and collection unit includes a gas flow meter and a high-pressure biogas collection device. The methane purification and liquefaction unit includes a high-pressure separation tank, a liquefaction pretreatment system, a heavy hydrocarbon and benzene removal device, a two-stage rectification system, a low-temperature pressure liquid storage tank device and a buffer storage tank. The organic solid waste undergoes an anaerobic digestion treatment to produce methane followed by collection, purification and liquefaction.
Abstract: A process and apparatus for removing hydrogen sulphide from a gas is disclosed. The process comprises the steps of: providing a gas comprising hydrogen sulphide; supplying oxygen for the process if the gas does not comprise oxygen, or does not comprise sufficient oxygen for converting hydrogen sulphide to elementary sulphur; leading the mixture of gas and, if supplied, oxygen to a tank comprising i) a foam forming liquid, such as a scrubber liquid and ii) a foam layer made from said foam forming liquid on the top of the foam forming liquid where the hydrogen sulphide in the gas is oxidized to elementary sulphur to form a cleaned gas removed from hydrogen sulphide.
Abstract: The absorption agent of the present invention contains water, an amine compound, and an organic solvent, and a value obtained by subtracting a solubility parameter of the organic solvent from a solubility parameter of the amine compound is 1.1 (cal/cm3)1/2 or more and 4.2 (cal/cm3)1/2 or less. The method for separation and recovery of an acidic compound of the present invention includes the steps of: bringing a mixed gas containing an acidic compound into contact with an absorption agent containing water, an amine compound, and an organic solvent to absorb the acidic compound into the absorption agent; causing the absorption agent that has absorbed the acidic compound to be phase-separated into a first phase containing the acidic compound in a high content and a second phase containing the acidic compound in a low content; and heating the first phase to release the acidic compound from the first phase.
Type:
Grant
Filed:
December 13, 2016
Date of Patent:
November 30, 2021
Assignees:
KOBE STEEL, LTD., NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITY
Abstract: Fuel tank inerting systems and methods for aircraft are provided. The systems include a fuel tank, a first reactant source fluidly connected to the fuel tank, the first source arranged to receive fuel from the fuel tank, a second reactant source, a catalytic reactor arranged to receive a first reactant from the first source and a second reactant from the second source to generate an inert gas that is supplied to the fuel tank to fill a ullage space of the fuel tank, and an inert gas recycling system located downstream of the catalytic reactor and upstream of the fuel tank, wherein the inert gas recycling system is arranged to direct a portion of the inert gas to the catalytic reactor.
Abstract: A process for absorbing carbon dioxide from a gas stream containing carbon dioxide, including contacting the gas stream with an aqueous composition having a substituted heteroaromatic compound including a six-membered heteroaromatic ring comprising from 1 to 3 nitrogen atoms in the heteroaromatic ring and at least one substituent wherein at least one of the substituents is of formula —R1NH2 wherein R1 is selected from C1 to C6 alkylene and ethers of formula —R2—O—R3— wherein R2 and R3 are C1 to C3 alkylene.
Type:
Grant
Filed:
May 22, 2018
Date of Patent:
September 21, 2021
Assignee:
COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
Inventors:
Graeme Douglas Puxty, William Conway, Qi Yang, Paul Hubert Maria Feron
Abstract: Embodiments described herein provide materials and methods for the absorption or filtration of various species and analytes. In some cases, the materials may be used to remove or reduce the amount of a substance in vapor sample (e.g., cigarette smoke).
Abstract: The present invention discloses a CoFe2O4-WTRs composite magnetic catalyst for efficiently degrading atrazine by activating peroxymonosulfate, preparation method and application thereof. The CoFe2O4-WTRs composite magnetic catalyst is prepared by three steps: the first step is acid-leaching of WTRs, using the WTRs as iron source to provide the iron ions required for the synthesis of CoFe2O4; the second step is preparing of a precursor, synthesizing CoFe2O4 by chemical co-precipitation method and uniformly loading the prepared CoFe2O4 on the WTRs; and the third step is calcining the precursor to synthesize the CoFe2O4-WTRs composite magnetic catalyst. The catalytic performance of the CoFe2O4-WTRs composite magnetic catalyst prepared by the present invention is evaluated using PMS as an oxidant and atrazine as a target pollutant. The CoFe2O4-WTRs can efficiently remove atrazine from the actual water, exhibiting good potential for practical application.
Abstract: The present disclosure provides compositions and methods that are useful in removing, lowering the amount of, or otherwise controlling hydrogen sulfide and mercaptans. The compositions and methods can be used in any industry where hydrogen sulfide poses problems, such as when dealing with crude oil based, natural gas based, and/or coal based products. The present disclosure provides compositions and methods that can reduce the amount of or eliminate hydrogen sulfide in a variety of mediums.
Type:
Grant
Filed:
March 19, 2019
Date of Patent:
August 10, 2021
Assignee:
ChampionX USA Inc.
Inventors:
Geeta Rana, Julian M. Gallardo, Matthew Trevino
Abstract: Systems and methods for body-proximate recoverable capture of mercury vapor emitted during cremation of human remains having dental amalgam fillings containing mercury. In various embodiments, one or more recoverable mercury sorbent packets comprise a combination of nanoparticles of one or more chalcogens and a particulate refractory material contained in a refractory material packaging. The recoverable packets capture and contain elemental mercury vapor emitted during cremation from dental amalgam fillings containing mercury. The recoverable packets are placed external to the body and within the combustion chamber during cremation, and not within the flue or exhausts exiting the combustion chambers. In various embodiments, the recoverable packets are positioned within the casket or primary combustion chamber, and may be preferably positioned proximate the head and neck of the body with the aid of selectively-refractory containment structures.
Type:
Grant
Filed:
September 5, 2017
Date of Patent:
August 3, 2021
Assignee:
Regents of the University of Minnesota
Inventors:
Sandra L. Myers, David R. Bowles, James Joseph Marti
Abstract: Methods are disclosed for achieving the catalytic combustion of a gaseous species in low temperature humid environments. The methods comprise the steps of obtaining a combustion catalyst composition comprising an amount of a precious metal supported on an ion-exchangeable alkali metal titanate substrate, and then exposing the species to the combustion catalyst composition in the presence of an oxygen containing gas and water vapour at a catalysis temperature below 200° C. and at a relative humidity above 0.5%. A novel desiccant-coupled catalytic combustion process and system are also disclosed.
Abstract: The present application relates to a novel method for reductive degradation of perfluoroalkyl-containing compounds, such as perfluoroalkyl sulfonates, by activated carbon (AC) supported zero valent iron-nickel nanoparticles (nNi0Fe0).
Abstract: A method for removing at least one contaminant from a fluid stream by filtering the fluid stream with a filtration medium. The filtration medium includes an impregnate. The impregnate includes a surfactant such as sulfamic acid. The medium has from about 0.1 to about 25% by weight of impregnate. The method is useful for removing one or more volatile organic compounds, particularly formaldehyde, from the fluid stream. In some embodiments, the method includes removing at least two volatile organic compound contaminants from the fluid stream.
Abstract: A process for the absorption of a target gaseous component from a gas stream comprising the steps of: contacting the gas stream with an absorber comprising an liquid absorbent for absorbing the target gaseous component to produce a rich liquid absorbent stream and a non target gaseous component, said non target gaseous component including water vapour; treating the rich liquid absorbent stream in a desorber to thereby release the target gaseous component and a water vapour component into a desorber gas stream and produce a lean liquid absorbent stream; and forming a recovered water stream from the output of a water separator for separating the water vapour from the target gaseous component, said water separator forming part of the absorber and/or the desorber.
Type:
Grant
Filed:
September 1, 2017
Date of Patent:
June 15, 2021
Assignee:
COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
Inventors:
Paul Hubert Maria Feron, Ramesh Thiruvenkatachari, Ashleigh Jane Cousins
Abstract: A membrane method processing system and process for a high-concentration salt-containing organic waste liquid incineration exhaust gas is described. The system consists essentially of a waste liquid incinerator (I), a gas-solid separator (II), a heat exchanger (III), an air blower (IV), an anti-caking agent storage tank (V), a membrane method dust cleaner (VI), an induced draft fan (VII), a check valve (VIII), and a desulfurization tower (IX). The present invention introduces the dust collecting membrane into the tail gas treatment system and utilizes the small pore size and high porosity of the dust collecting membrane to prevent inorganic salt particles from entering the internal of the filter material and agglomerating there. When the humidity of the gas entering the dust collector increases during the dust removing process, the anti-caking agent is also introduced into the tail gas treatment system to change the surface structure of the inorganic salt crystal to prevent the crystal from agglomeration.