Patents Examined by Asok Pal
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Patent number: 5849967Abstract: Binderless zeolite L particles are prepared by a method in which particles are formed from silica and from 0 to 95 wt % preformed zeolite L crystallites, and the particles are thereafter reacted with an alkaline solution comprising a source of alumina to convert the silica binder to zeolite L. These particles may comprise cylindrical zeolite L crystallites with a mean diameter of at least 0.05 micron in a zeolite L matrix and may be used as catalyst. Also acyclic hydrocarbons are dehydrocyclized and/or isomerized by contacting them at a temperature of from 370.degree. C. to 600.degree. C. with this catalyst incorporating at least one Group VIII metal having dehydrogenating activity to convert at least part of the acyclic hydrocarbons into aromatic hydrocarbons.Type: GrantFiled: June 7, 1995Date of Patent: December 15, 1998Assignee: Exxon Chemical Patents Inc. (ECPI)Inventors: Johannes Petrus Verduijn, Pieter Ernst Gellings
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Patent number: 5770539Abstract: Immobilized Lewis Acid catalyst comprising porous polymer film substrate having at least one Lewis Acid immobilized on pore surfaces thereof, said polymer film substrate prior to having said Lewis Acid immobilized thereon comprising a porous film of functionalized polymer and, optionally, unfunctionalized polymer, said functionalized polymer having within its structure units represented by the formula ##STR1## and said unfunctionalized polymer having within its structure repeating monomer units represented by the formula ##STR2## wherein D represents OH, halide, NH.sub.2, NHR.sup.3, OM', or OM";R.sup.1 represents hydrogen, C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl or C.sub.7 -C.sub.30 alkylaryl;R.sup.2 represents C.sub.3 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl or C.sub.7 -C.sub.30 alkaryl;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl or C.sub.7 -C.sub.Type: GrantFiled: January 18, 1996Date of Patent: June 23, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Frank Joung-Yei Chen, Tze-Chiang Chung, Jon Edmond Stanat, Soon Hong Lee
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Patent number: 5723707Abstract: Disclosed are methods for dehydrogenation in reactor systems of improved resistance to carburization under dehydrogenation conditions.Type: GrantFiled: December 12, 1994Date of Patent: March 3, 1998Assignee: Chevron Chemical CompanyInventors: John V. Heyse, Paul G. Johnson, Bernard F. Mulaskey
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Patent number: 5665669Abstract: A metallic honeycomb body for supporting a catalyst comprises a flat plate and a corrugated plate; these plates are formed by a foil of stainless steel in which the steel contains more than 1% of Si and the surface of the steel is covered by a film which is mainly formed by an oxide chrome at a high temperature, and are mutually bonded by diffusion bonding.The chemical composition of the foil material is comprised of up to 0.2% of C, more than 1 to 5% of Si, 9 to 22% of Cr, up to 0.8% of Al, and as necessary, at least one member selected from the group of Nb, V, Mo W and REM (rare earth member) including Y.The metallic honeycomb body is formed by which said body is annealed at a vacuum degree of 10.sup.-2 to 10.sup.-4 Torr and in a temperature range of 1200.degree. to 1300.degree. C. for 1 to 30 minutes in a vacuum annealing furnace.Type: GrantFiled: October 12, 1994Date of Patent: September 9, 1997Assignee: Nippon Steel CorporationInventors: Mikio Yamanaka, Masuhiro Fukaya, Nobuhiro Fujita, Yasushi Ishikawa, Toshikazu Nakagawa, Masao Yashiro, Hitoshi Ohta
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Patent number: 5651829Abstract: The invention relates to a novel crystalline maltitol composition which essentially exhibits a porous and honeycombed structure and which possesses a very high degree of maltitol purity and a low density.This composition possesses outstanding functional properties, making its use particularly recommended for manufacturing tablets or various powders to be dissolved in water.The invention also relates to a novel process for enabling the crystalline maltitol composition to be manufactured.Type: GrantFiled: June 6, 1995Date of Patent: July 29, 1997Assignee: Roquette FreresInventor: Jean-Jacques Caboche
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Patent number: 5639928Abstract: The present invention relates to the improved liquid phase dehydration of 1-phenyl ethanol to styrene monomer, the improvement comprising the use of a residue formation inhibiting agent during the liquid phase dehydration.Type: GrantFiled: August 26, 1994Date of Patent: June 17, 1997Assignee: ARCO Chemical Technology, L.P.Inventors: Walter S. Dubner, Lawrence M. Candela
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Patent number: 5626685Abstract: A method of removing a water insoluble surface coating from a surface comprising applying to the coating a liquid comprising between about 0.25 weight percent to about 99.9 weight percent of a fatty acid selected from the group consisting of unsaturated fatty acids, saturated fatty acids, polyunsaturated fatty acids and mixtures thereof, an organic or inorganic alkaline builder present in an amount effective to saponify the fatty acid and still maintain the constituents in solution, and the balance of the liquid is water.Type: GrantFiled: May 24, 1994Date of Patent: May 6, 1997Inventor: William E. Spindler
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Patent number: 5625113Abstract: A process is disclosed for alkylating an isoparaffin with an olefin comprising the steps of:(a) reacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in a first alkylation reaction stage at temperature from about -40.degree. C. to about 500.degree. C. and overall isoparaffin:olefin feed weight ratio of from about 1:1 to about 250:1 with a solid alkylation catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.Type: GrantFiled: December 28, 1994Date of Patent: April 29, 1997Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, James H. Beech, Jr., Albin Huss, Jr., Robert A. Ware, Altaf Husain
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Patent number: 5625013Abstract: A process for the preparation of a supported catalyst for the polymerization of .alpha.-olefins, in which(1) a silicon dioxide-containing support gel is prepared by(1.1) introducing a sodium water glass or potassium water glass solution into a swirling stream of an aqueous mineral acid longitudinally and tangentially to the stream, spraying the resultant silica hydrosol in drop form into a gaseous medium and allowing it to solidify to form a hydrogel, and freeing the resultant hydrogel from salts by washing without prior ageing,(1.2) drying the hydrogel resulting from (1.1) to form the support gel,(2) the support gel (1) is charged with chromium trioxide or a chromium compound which can be converted into chromium trioxide under the conditions of process step (3), giving a chromium-containing support gel, and(3) the chromium-containing support gel (2) is heated at from 400.degree. to 1100.degree. C.Type: GrantFiled: May 24, 1995Date of Patent: April 29, 1997Assignee: BASF AktiengesellschaftInventors: Hans-Joachim Mueller, Godofredo Follmer, Rainer Konrad, Roland Saive, Martin Lux, Hans-Helmut Goertz, Guido Funk
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Patent number: 5622907Abstract: A method is provided for improving the catalytic activity of an alcohol synthesis catalyst. In this method, the catalyst, after activation by exposure to a reducing atmosphere, is improved by contacting with a carbon dioxide-containing gas to convert the zinc oxide in the catalyst to zinc carbonate. This improvement step occurs in situ preferably in the same reactor as used for the synthesizing of the alcohol.Type: GrantFiled: February 23, 1990Date of Patent: April 22, 1997Assignee: Electric Power Research Institute, Inc.Inventors: Sunggyu Lee, Vetkav R. Parameswaran, Byung G. Lee, Conrad J. Kulik
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Patent number: 5620588Abstract: A process for dewaxing including the steps of mixing a waxy feedstock near its pour point with an ambient or below ambient temperature solvent essentially free of a selected cosolvent, to form a solvent/feedstock mixture, essentially free of a selected cosolvent, and subsequently adding the cosolvent to the solvent/feedstock mixture to cause instantaneous precipitation of wax on addition of cosolvent with the amount of wax precipitation being controlled by the quantity and temperature of cosolvent added. The cosolvent is essentially completely miscible with the solvent, but immiscible with the oil and wax. For example, alcohols (methanol, ethanol, propanol), ketones (ketene, acetone), amines, etc. The process of the present invention provides the advantages of lower solvent ratios (higher solvent recovery), higher filtration temperatures, "environmentally compatible" solvents, rapid filtration rates, and debottlenecking of existing dewaxing plants.Type: GrantFiled: June 6, 1995Date of Patent: April 15, 1997Inventors: Michael D. Ackerson, Seyed-Hamid Arabshahi, Robert E. Babcock
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Patent number: 5621154Abstract: Methods are provided for cleaning and inhibiting the formation of fouling deposits on jet engine components during the combustion of turbine combustion fuel oils. Methods are also provided for inhibiting the formation and emission of soot and smoke from jet engine exhaust during turbine combustion fuel oil combustion. The methods employ a derivative of polyalkenylthiophosphonic acid added to the turbine combustion fuel oil. The preferred derivative is pentaerythritol ester of polyisobutenylthio-phosphonic acid.Type: GrantFiled: January 3, 1995Date of Patent: April 15, 1997Assignee: BetzDearborn Inc.Inventors: Bruce E. Wright, William L. Witzig
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Patent number: 5616532Abstract: A photocatalyst composition containing a substantially non-oxidizable binder which allows large amounts of photocatalytic particles to be adhered to a surface. Upon application to a surface, the composition dries or cures to form an adherent, abrasion-resistant, thermostable, and photocatalytic coating.Type: GrantFiled: October 21, 1994Date of Patent: April 1, 1997Assignee: E. Heller & CompanyInventors: Adam Heller, Michael V. Pishko, Ephraim Heller
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Patent number: 5614456Abstract: The interaction of silica, previously calcined at 600.degree. C., with dibutylmagnesium (DBM), 1-butanol and titanium tetrachloride and a solution of methylalumoxane (MAO) and (BuCp).sub.2 ZrCl.sub.2 provides a catalyst that, in the absence of a trialkylaluminum (AlR.sub.3) cocatalyst, produces polyethylene with a bimodal MWD.Type: GrantFiled: November 3, 1994Date of Patent: March 25, 1997Assignee: Mobil Oil CorporationInventors: Robert I. Mink, Thomas E. Nowlin, Sandra D. Schregenberger, Pradeep P. Shirodkar, Grace O. Tsien
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Patent number: 5612485Abstract: A carotenoid composition derived from a natural source wherein at least 50% by weight of the carotenoid content of the composition is cis beta-carotene and preferably 9 cis beta-carotene. Typically, the beta-carotene content of the composition is predominantly 9 cis beta-carotene.Type: GrantFiled: December 5, 1994Date of Patent: March 18, 1997Assignee: Betatene Ltd of CheltenhamInventor: Lance E. Schlipalius
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Patent number: 5609750Abstract: A catalyst composition for converting hydrocarbons in a hydrotreatment process (hydrodesulfurization and/or hydrodenitrogenization) and simultaneously cracking them, containing an alumina-silica-alumina carrier built up from alumina and silica-alumina, on which hydrogenation metals, such as molybdenum, nickel, and/or cobalt, have been provided and which also contains a catalytically active amount of boron, generally in the range of 1 to 20 wt. %. The invention also relates to a process for the preparation of such a catalyst, with boron being provided ahead of the Group VIII component. The carrier material used may be made up of mixtures of alumina and amorphous silica-alumina or of mixtures of alumina and silica-coated alumina. The catalyst composition is highly suitable for converting vacuum gas oil into middle distillate oils by hydrotreating.Type: GrantFiled: April 26, 1994Date of Patent: March 11, 1997Assignee: Akzo Nobel NVInventors: Pieter J. Nat, Jacob L. de Booys, Johannes W. F. M. Schoonhoven
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Patent number: 5607892Abstract: Zirconium/cerium mixed oxides (optionally including thermally stabilizing dopant values), comprising solid solutions thereof, having contents of zirconium of up to 99% by weight, and having high specific surface areas, are well suited as catalysts and/or catalyst supports, notably for the treatment/conversion of vehicular exhaust gases; such ZrO.sub.2 /CeO.sub.2 mixed oxides are conveniently prepared by (i) intimately admixing a zirconium sol with a cerium sol, the ratio r of the mean diameter r.sub.1 of the particles of the zirconium sol to the diameter r.sub.2 of the particles of the cerium sol being at least 5, (ii) adding a precipitating amount of a base thereto, (iii) recovering the precipitate thus formed, and (iv) calcining the recovered precipitate.Type: GrantFiled: February 10, 1994Date of Patent: March 4, 1997Assignee: Rhone-Poulenc ChimieInventors: Thierry Chopin, Gabriel Vilmin
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Patent number: 5608134Abstract: An improved process for preparing a difunctional catalyst active in the hydroisomerization of long-chain normal paraffins is disclosed, which is constituted by an amorphous silica-alumina gel and one or more metals belonging to Group VIIIA,Type: GrantFiled: June 1, 1995Date of Patent: March 4, 1997Assignee: Eniricerche S.p.A.Inventors: Carlo Perego, Giuseppe Bellussi, Vincenzo Calemma
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Patent number: RE35632Abstract: In an improved method for converting methane to at least one higher hydrocarbon product and coproduct water which comprises contacting a gas comprising methane and at least one added gaseous oxidant with nonacidic solid, the improvement comprising conducting at least a portion of said contacting in the presence of added water.Type: GrantFiled: January 19, 1993Date of Patent: October 14, 1997Assignees: Atlantic Richfield Company, Phillips Petroleum CompanyInventor: David W. Leyshon
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Patent number: RE35633Abstract: In an improved method for converting methane to at least one higher hydrocarbon product and coproduct water which comprises contacting a gas comprising methane and at least one added gaseous oxidant with nonacidic solid, the improvement comprising conducting at least a portion of said contacting in the presence of added water.Type: GrantFiled: January 19, 1995Date of Patent: October 14, 1997Assignee: Atlantic Richfield CompanyInventor: David W. Leyshon