Abstract: A cake of soap (10) provided with a cavity (12) for receiving a remnant of soap, the cavity (12) extends into the interior region of the cake of soap (10).
Abstract: Thermal decoking of cracking gas coolers which operate with low gas pressure is accomplished by controlling the temperature of a cleaning gas delivered to the cooler. The temperature control is achieved by mixing a cleaning gas, which has been heated in a cracking oven, with a stream of relatively cool cleaning gas upstream of the cooler.
Abstract: A composition of matter comprising both (1) zeolite Beta and a (2) Y zeolite having either a unit cell size below about 24.45 angstroms or a water vapor sorption capacity at 25.degree. C. at P/P.sub.o of 0.10 of less than 10.00 weight percent. Typical of the Y zeolites used in the composition of the invention is a UHP-Y zeolite such as LZ-10 zeolite. The composition is especially suited for use in combination with one or more hydrogenation components as a catalyst for hydrocracking various types of feedstocks to produce either gasoline or middle distillate products.
Abstract: The invention concerns a catalyst containing a support comprising at least one metal from group VIII of the periodic classification of elements such as platinum, palladium, ruthenium, rhodium, nickel, osmium or iridium, at least one additional metal selected from the group formed by groups IIB, IIIA, IVA, IVB, VA, VB, VIIB and VIII and at least one metal selected from the group formed by alkali and alkaline-earth metals, characterized in that said alkali or alkaline-earth metal is at least partially contained in the support in the form of an aluminate. The invention also concerns the preparation and use of said catalyst for dehydrogenation of C.sub.3 -C.sub.20 paraffins.
Type:
Grant
Filed:
December 16, 1994
Date of Patent:
July 16, 1996
Assignee:
Institut Francais Du Petrole
Inventors:
Franck Blejean, Fabienne Le Pettier, Blaise Didillon
Abstract: Described are novel processes for treating high-ash coal tars to produce coal tars which are suitable for distillation to form binder pitch. Preferred processes of the invention involve multi-stage centrifugations to reduce ash and preferably also quinoline insoluble levels. Processes of the invention also provide for the treatment of coal tar sludges to recover valuable coal tar distillate and dried, free-flowing coal related material having high fuel value.
Abstract: A method and apparatus for extracting bitumen whereby tar sand containing bitumen components is contacted with a heated thinning oil mixture to reduce the tar sand viscosity and dissolve bitumen to form a lower viscosity feed slurry. The feed slurry is contacted with a light oil in a separator wherein the mixture is separated into product oil and oil sand. The oil sand is washed with solvent in a countercurrent fashion to extract occluded oil to form the light oil. Washed sand containing solvent is heated above the boiling point of the solvent in a multi-hearth solvent recovery furnace to vaporize the solvent. The solvent vapors are stripped from the sand by flowing inert gas through the sand in the multi-hearth solvent recovery furnace. Inert gas containing solvent vapors is directed from the multi-hearth solvent recovery furnace to a heat exchanger/scrubber where the inert gas and solvent vapors are contacted with product oil from the separator.
Abstract: A novel alkylation catalyst is described which is used in processes for alkylating olefin hydrocarbons with isoparaffin hydrocarbons to produce high octane alkylate products suitable for use as blending components of gasoline motor fuel. The novel catalyst comprises a mixture of a hydrogen halide, a sulfone and water and has suitable corrosion properties which permit its utilization in alkylation process systems. The novel alkylation catalyst is utilized in a novel process for alkylating olefin hydrocarbons with isoparaffin hydrocarbons.
Type:
Grant
Filed:
January 20, 1995
Date of Patent:
July 9, 1996
Assignee:
Phillips Petroleum Company
Inventors:
Bruce B. Randolph, Ronald G. Abbott, Jonathan E. Child, Kenneth J. Del Rossi
Abstract: A method and structure for enhancing electromagnetic barrier properties including a substrate, a coating deposited upon the substrate, and a plurality of sets of patterns microembossed upon the surface of the coating layer for increasing the barrier properties of the structure. The plurality of sets of microembossed patterns each having a line density between about 100 and 50,000 lines per square centimeter.
Abstract: A process for isomerizing a mixture of alkanes containing pentanes and at least one alkane having from 6 to about 8 carbon atoms and no more than one methyl branch has been developed.
Abstract: Formulations for transparent soaps and methods of preparation are disclosed. The transparent soaps are prepared by combining high and low molecular weight fatty acids in the presence of polyhydric alcohols. Citric acid is added to adjust pH. The formulations do not require volatile, short-chain monohydric alcohols to achieve transparency and the end products are able to retain transparent qualities when exposed to hot water conditions. Suitable formulations can be remelted to reduce waste.
Abstract: A process for the continuous isomerization of an alkane to produce an isomerized product through contacting the alkane with a simulated moving bed acting as a catalyst for isomerization and an adsorbent for the alkanes has been developed. The alkane may be n-butane and the isomerized product 2-methylpropane, the alkane may be n-pentane and the isomerized product 2-methylbutane or 2,2-dimethylpropane, the alkane may have from 6 up to about 8 carbon atoms with no more than one methyl branch and the isomerized product having the same number of carbon atoms and at least two methyl branches, or the reactant may be a mixture of the foregoing alkanes with the corresponding isomerized products being formed. In a zone of the simulated moving bed, the alkanes are catalytically isomerized to form the isomerized products. The unreacted alkanes are adsorbed, and the isomerized products are collected.
Type:
Grant
Filed:
November 3, 1994
Date of Patent:
June 25, 1996
Assignee:
UOP
Inventors:
Gregory A. Funk, Hermant W. Dandekar, Masami Kojima, Simon H. Hobbs
Abstract: The invention relates to a process for the regeneration of a deactivated, carbon-covered, fine-grained, heat-resistant catalyst, a pumpable suspension of deactivated catalyst being injected into a hot gas stream and the regenerated catalyst then being separated off from the gas stream.
Abstract: There is provided a process for the alkylation of ethylbenzene with ethylene to selectively produce para-diethylbenzene over a catalyst which has been selectivated by multiple treatments with a siliceous material.
Type:
Grant
Filed:
June 6, 1995
Date of Patent:
June 25, 1996
Assignee:
Mobil Oil Corporation
Inventors:
Jeffrey S. Beck, Stephen H. Brown, Sharon B. McCullen, David H. Olson, David L. Stern
Abstract: There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is passed into a reactor containing both an equilibrium dehydrogenation catalyst and a reducible metal oxide, whereby the alkane is dehydrogenated and the hydrogen produced is simultaneously and selectively combusted in oxidation/ reduction (REDOX) reaction with the reducible metal oxide. This particular mode of operation is termed a same reactor, REDOX mode. The equilibrium dehydrogenation catalyst may comprise platinum and the reducible metal oxide may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.
Type:
Grant
Filed:
April 17, 1995
Date of Patent:
June 25, 1996
Assignee:
Mobil Oil Corporation
Inventors:
Pradyot A. Agaskar, Robert K. Grasselli, James N. Michaels, P. Thomas Reischman, David L. Stern, John G. Tsikoyiannis
Abstract: An improved process for the regeneration of an ASO-containing HF catalyst by the removal of ASO from said catalyst through the utilization of a separation column equipped with fixed valve fractionation trays. The separation column defines a separation zone having a top zone, an intermediate zone, and a bottom zone wherein contained within the bottom zone is a series of vertically spaced, fixed valve fractionation trays, wherein each of the fixed valve fractionation trays includes a plate defining a plurality of apertures and wherein fixedly spaced above each of the apertures is a valve having a shape substantially the same as the apertures for directing the flow of gas passing upwardly through the apertures of the plate into the direction substantially parallel to the plate.
Abstract: There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilbrium dehydrogenation catalyst in a first reactor, and the effluent from the first reactor, along with oxygen, is then passed into a second reactor containing a metal oxide catalyst which serves to selectively catalyze the combustion of hydrogen. This particular mode of operation is termed a separate reactor, cofed oxygen mode. The equilibrium dehydrogenation catalyst may comprise platinum and the selective metal oxide combustion catalyst may contain bismuth, antimony, indium, molybdenum, or a mixture thereof.
Type:
Grant
Filed:
April 17, 1995
Date of Patent:
June 18, 1996
Assignee:
Mobil Oil Corporation
Inventors:
Pradyot A. Agaskar, Robert K Grasselli, James N. Michaels, P. Thomas Reischman, David L. Stern, John G. Tsikoyiannis
Abstract: There is disclosed a catalyst composition prepared by reacting together:(a) a source of a Group VIII metal,(b) a compound of the formula (I)R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3 (I)where R.sup.1 and R.sup.2 are independently an unsubstituted or substituted alkyl, cycloalkyl or aryl group, R.sup.3 is hydrogen, an unsubstituted or substituted alkyl, cycloalkyl or aryl group and R.sup.4 is a divalent organic group and(c) a source of an anion which is either non-coordinating or weakly-coordinating to the Group VIII metal.The catalyst compositions are used in the preparation of polyketones from carbon monoxide and one or more olefins. Novel compounds of the formula [(.eta..sup.3 -allyl)Pd(R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3)]Y where Y is a weakly or non-coordinating anion are useful as such catalysts.
Abstract: Zeolite cracking catalyst compositions and additives that contain a Lewis acid supported on alumina are useful to process hydrocarbon feedstocks. The compositions are especially useful for the production of reduced sulfur gasoline.
Abstract: Naphtha is selectively hydrodesulfurized using selectively poisoned hydrotreating catalyst to remove sulfur while minimizing loss in octane level due to olefin saturation.
Type:
Grant
Filed:
October 6, 1994
Date of Patent:
June 11, 1996
Assignee:
Texaco Inc.
Inventors:
Chakka Sudhakar, Max R. Cesar, R. Anthony Heinrich
Abstract: The present invention relates to a process for producing a metallic catalyst layer or coating which serves for effectuating the removal of hydrogen from a gas mixture containing hydrogen and oxygen. The catalyst layer itself which is porous, comprises a metal, such as palladium (Pd) or platinum (Pt), or alloys of these metals, which catalytically influence the oxidation of hydrogen. The metal or the metal alloy is applied as a catalyst layer or coating onto a carrier material or substrate by either plasma spraying or flame spraying. The present invention also provides a catalyst through the intermediary of a catalyst layer which is produced in accordance with the process of the instant invention.
Type:
Grant
Filed:
September 22, 1994
Date of Patent:
June 11, 1996
Assignees:
Forschungszentrum Julich GmbH, Gesellschaft fur Reaktorsicherhait (GRS)mbH
Inventors:
Amiya K. Chakraborty, Jurgen Rohde, Karl-Heinz Klatt, Helmut Wenzl, Ralf Konrad