Abstract: An integrated upgrading process for upgrading a heavy oil, the process comprising the steps of introducing a heavy oil to a visbreaker unit; processing the heavy oil in the visbreaker unit to produce a visbreaker product stream; feeding the visbreaker product stream to a fractionator; separating the visbreaker product stream in the fractionator to produce a bottoms stream, a gas oil stream, a naphtha stream, and a gas product stream; feeding the bottoms stream to a supercritical water unit; and processing the bottoms stream in the supercritical water unit to produce an upgraded bottoms stream.

Abstract: An integrated method for mesophase pitch and petrochemicals production. The method including supplying crude oil to a reactor vessel; heating the crude oil in the reactor vessel to a predetermined temperature for a predetermined amount of time; reducing asphaltene content in the crude oil by allowing polymerization reactions to occur in the reactor vessel at an elevated pressure in the absence of oxygen; producing a three-phase upgraded hydrocarbon product comprising gas, liquid, and solid hydrocarbon components, where the liquid hydrocarbon component comprises deasphalted oil and the solid hydrocarbon component comprises mesophase pitch; separating the gas, liquid, and solid hydrocarbon components; directly utilizing the liquid hydrocarbon component for petrochemicals production; and directly utilizing the solid hydrocarbon component for carbon artifact production.

Abstract: The present invention relates to a process for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products, said lighter boiling hydrocarbon products being suitable as a feedstock for petrochemicals processes, said converting process comprising the following steps of: feeding a hydrocarbon feedstock having a boiling point of >350 deg Celsius to a cascade of hydrocracking unit(s), feeding the bottom stream of a hydrocracking unit as a feedstock for a subsequent hydrocracking unit, wherein the process conditions in each hydrocracking unit(s) are different from each other, in which the hydrocracking conditions from the first to the subsequent hydrocracking unit(s) increase from least severe to most severe, and processing the lighter boiling hydrocarbon products from each hydrocracking unit(s) as a feedstock for one or more petrochemicals processes.

Abstract: Fouling in a hydrocarbon refining process is reduced by adding to a crude hydrocarbon for a refining process, an additive combination including: (A) a polyalkenyl-substituted carboxylic acid or anhydride, and (B) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent, where the mass:mass ratio of (A) to (B) is in the range of 10:1 to 1:10, and the treat rate of the additive combination is in the range of 5 to 1000 ppm by mass.

Abstract: A process for operating a thermal or catalytic cracking unit is described. The process entails generating a product that includes cracked hydrocarbon vapor and solid coke-particles from a heavy hydrocarbon input. The product is communicated towards a fractionator and a quench liquid is introduced into the product for creating a two-phase flow of cracked hydrocarbon vapor and the quench liquid with solid coke-particles entrained in the quench liquid. The two-phase flow is introduced into the fractionator and the cracked hydrocarbon vapor are separated from the quench liquid and the solid coke-particles entrained therein by gravity separation. The two-phase flow can reduce or remove the requirement of a wash zone within the fractionator. A recirculation loop is included in a wash-zone circulation system. The recirculation loop bypasses one or more spray headers of the wash zone and returns to a first end of the wash-zone circulation system.

Abstract: A method for sulfur removal and upgrading comprising the steps of mixing a heated oil feed and a supercritical water feed in a feed mixer, allowing conversion reactions to occur in the supercritical water reactor, reducing the temperature in the cooling device to produce a cooled fluid, reducing the pressure in the depressurizing device to produce a discharged fluid, separating the discharged fluid in the gas-liquid separator to produce a liquid phase product, increasing the pressure to produce pressurized liquid product, the pressure of pressurized liquid product is greater than the critical pressure of water, processing the pressurized liquid product in the hydration reactor to produce a hydrated oil stream, separating the hydrated oil stream to produce an extracted upgraded oil and an oxygenate concentrated stream, the oxygenate concentrated stream comprises the oxygenates, and processing the extracted upgraded oil in the hydrotreater to produce a desulfurized upgraded oil.

Abstract: This invention has as its object a method for selective hydrogenation of a feedstock comprising a pyrolysis gasoline carried out in a three-phase reactor.

Abstract: Apparatuses, systems, and methods are disclosed for shale pyrolysis. A retort for shale pyrolysis may include a pyrolysis zone, a combustion zone, and a cool down zone. The pyrolysis zone may include one or more pyrolysis zone heat exchangers that transfer heat from a working fluid to shale for heating and pyrolyzing the shale. The combustion zone may include one or more injectors that inject oxygen to combust coke residue in the pyrolyzed shale. The cool down zone may include one or more cool down zone heat exchangers that cool the shale by transferring heat to the working fluid. In a further embodiment, the working fluid is circulated to heat the pyrolysis zone heat exchangers.

Abstract: A process for production of gasoline comprising separating a naphtha feed in a naphtha splitter into a stream comprising i-C5, a stream comprising C6 and lighter boiling hydrocarbons, a C7 stream comprising C7 hydrocarbons, and a heavy stream comprising C8 and heavier hydrocarbons; isomerizing at least a portion of the stream comprising C6 and lighter boiling hydrocarbons in a C5-C6 isomerization zone at isomerization conditions to form a C5-C6 isomerization effluent; dehydrogenating at least a portion of the stream comprising C7 hydrocarbons to form a C7 dehydrogenation effluent comprising C7 olefins; reforming the heavy stream in a reforming zone under reforming conditions forming a reformate stream; and blending one or more of the stream comprising i-C5, the C5-C6 isomerization effluent, the C7 dehydrogenation effluent and the reformate stream to form a gasoline blend.

Abstract: Treatment of crude oil with basic ionic liquids (ILs), results in scavenging of any hydrochloric acid (HCl) that is present to remove the HCl. The IL is a quaternary ammonium compound having the formula R4N+X? or R3N+R?N+R3, where R is independently an alkyl group, an alkylbenzyl group, a hydroxyalkyl group, or a hydroxyalkylbenzyl group, and R is straight or branched and has 1-22 carbon atoms, R? is a straight or branched alkylene or oxyalkylene having 1 to 10 carbon atoms, and where X? is selected from the group consisting of hydroxide, carbonate, alkylcarbonate, bicarbonate or alkoxide, where the alkyl group of the alkyl-carbonate or alkoxide, if present, is straight or branched and has 1 to 8 carbon atoms. The ILs are introduced into the crude oil after the refinery desalters and before the crude distillation tower to prevent or inhibit HCl from distilling to the crude tower overhead.

Abstract: The present invention relates to a process for cracking a hydrocarbon feedstock in a steam cracker unit, comprising the following steps of: feeding a liquid hydrocarbon feedstock to a hydrocracking unit, separating the stream thus hydrocracked in said hydrocracking unit into a high content aromatics stream and a gaseous stream comprising C2-C4 paraffins, hydrogen and methane, separating C2-C4 paraffins from said gaseous stream, feeding said C2-C4 paraffins thus separated to the furnace section of a steam cracker unit.

Abstract: A process is presented for the management of sulfur on a catalyst. The catalyst is a dehydrogenation catalyst, and sulfur accumulates during the dehydrogenation process. Sulfur compounds are stripped from the spent catalyst and the catalyst is cooled before the regeneration process. The process includes controlling the amount of sulfur that needs to be removed from the catalyst before regeneration.

Abstract: A system for treating liquids and solutions for separating components thereof, the system including a treatment vessel having a treatment chamber therein, a device for generating a gas-infused liquid under elevated pressure, and a device for stabilizing the gas-infused liquid such that most of the gas infused into the liquid by the device for generating a gas-infused liquid will remain in the liquid if pressure of the liquid is reduced to atmospheric pressure, and for flowing the stabilized gas-infused liquid into the treatment chamber so as to form a liquid layer including the stabilized, gas-infused liquid in the treatment chamber. The treatment vessel includes a discharge port through which some of the stabilized, gas-infused liquid in the liquid layer may be discharged from the treatment vessel, the withdrawn liquid is infused with an additional amount of the gas, again stabilized, and again flown the liquid into the treatment chamber.

Abstract: Methods of extracting 1-4 cycle heterocyclic compounds and 2-5 cycle polynuclear aromatic hydrocarbons from a hydrocarbon feedstock are described. The methods include providing a hydrocarbon feedstock containing crude oil fractions, and determining an A/R ratio and an asphaltene concentration of the hydrocarbon feedstock. Based upon the A/R ratio and the asphaltene concentration, the treatable hydrocarbon feedstock undergoes one or more of cracking and fractionating. Subsequently, at least one targeted portion of the heterocyclic compounds is extracted from the fractionated stream with an aqueous solvent. A stream containing the 2-5 cycle polynuclear aromatic hydrocarbons is transferred to an extractor and the 2-5 cycle polynuclear aromatic hydrocarbons are extracted with a solvent system comprising an aprotic solvent.

Abstract: A catalytic cracking process includes the following steps: i) subjecting a heavy feedstock oil to flail catalytic cracking; ii) separating the catalytic cracking reaction product obtained from step i) to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iii) splitting the catalytic cracking gasoline to obtain a light gasoline fraction, a medium gasoline fraction and a heavy gasoline fraction; iv) subjecting the catalytic cracking light cycle oil to hydrogenation to obtain a hydrogenated light cycle oil); v) mixing a portion of the light gasoline fraction with at least a portion of the hydrogenated light cycle oil to obtain a mixed fraction; vi) subjecting the mixed fraction to catalytic cracking; and vii) subjecting a portion of the medium gasoline fraction to flail catalytic cracking. The process is capable of producing more catalytic cracking gasoline, reducing the olefin content of the catalytic cracking gasoline, and increasing its octane number.

Abstract: Methods are provided for forming lubricant base stocks from feeds such as vacuum resid or other 510° C.+ feeds. A feed can be deasphalted and then catalytically and/or solvent processed to form lubricant base stocks, including bright stocks that are resistant to haze formation.

Abstract: A process is presented for the management of sulfur on a catalyst. The catalyst is a dehydrogenation catalyst, and sulfur accumulates during the dehydrogenation process. Sulfur compounds are stripped from the spent catalyst and the catalyst is cooled before the regeneration process. The process includes controlling the amount of sulfur that needs to be removed from the catalyst before regeneration.

Abstract: A process using a dealkylated aromatic liquid improves a heavy hydrocarbon liquid used for supporting molybdenum carbonized catalyst. Dealkylated aromatic liquid can be derived from heavy hydrocarbon materials that have been subjected to cracking, such as fluid catalytic cracking or slurry hydrocracking. The heavy hydrocarbon liquid can comprise a portion of resid SHC feed and a portion of a gas oil stream from SHC effluent.

Abstract: The present disclosure provides a method for separating soluble organic matter in petroleum coke, including: drying the petroleum coke to obtain pretreated petroleum coke; extracting the pretreated petroleum coke sequentially with petroleum ether, carbon disulfide, ethanol, acetone-carbon disulfide mixture and tetrahydrofuran to obtain an extract and the treated petroleum coke, wherein the extract includes soluble organic matter. The method provided by the present disclosure employs extractants with different polarities, i.e., petroleum ether, carbon disulfide, ethanol, acetone-carbon disulfide mixture and tetrahydrofuran, to extract petroleum coke sequentially, so as to detect the composition of the soluble organic matter in petroleum coke at the molecular level, realizing the separation of soluble organic matter in petroleum coke at the macro molecular level, as well as the determination of molecular structure of soluble organic matter in petroleum coke by modern detection processes.

Abstract: A medium separator is used to recover a gaseous stream from a hydroprocessed liquid stream for hydrogen recovery in a hydrogen recovery unit. A medium flash drum may further remove liquid components from the gaseous stream prior to hydrogen recovery in the hydrogen recovery unit.