Patents Examined by Carman J. Seccuro, Jr.
  • Patent number: 5548028
    Abstract: Blends of previously-vulcanized fluoroelastomer with fluorine-free elastomer can be cured to have unexpectedly excellent physical properties.
    Type: Grant
    Filed: February 24, 1995
    Date of Patent: August 20, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: David L. Tabb
  • Patent number: 5543467
    Abstract: A golf ball having excellent hit feeling, control properties and flying performance. The golf ball has a core and a cover covering the core, and the base material of the cover comprises a heated mixture of an ionomer resin, a maleic anhydride-modified olefinic copolymer and a glycidyl group-containing olefinic copolymer.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: August 6, 1996
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Akihiko Hamada, Yoshikazu Yubuki, Akira Kato
  • Patent number: 5541260
    Abstract: Disclosed is a polymer composition containing:(A) from 70 to 98 parts by weight of a crystalline propylene homopolymer, or a crystalline random copolymer of propylene with ethylene and/or C.sub.4 -C.sub.10 .alpha.-olefins, containing from 0.5 to 10% by weight of ethylene and/or .alpha.-olefins [fraction (A)]; and(B) from 2 to 30 parts by weight of elastomeric copolymer of ethylene with one or more C.sub.4 -C.sub.10 .alpha.-olefins, containing from 60 to 85% by weight of ethylene, and partially soluble in xylene at 25.degree. C. [fraction (B)];wherein the composition has an intrinsic viscosity value in tetrahydronaphthalene at 135.degree. C. of the fraction soluble in xylene at 25.degree. C. ranging from 0.8 to 1.1 dl/g.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: July 30, 1996
    Assignee: Montell North America Inc.
    Inventors: Anteo Pelliconi, Antonio Ciarrocchi, Paola Massari
  • Patent number: 5532282
    Abstract: A composition useful for rotational molding and method of rotomolding are provided. The composition advantageously includes particulate matter of significantly different sizes. A first polymer is provided as particulate matter of one size, and a second polymer is provided as particulate matter of a smaller size. During rotomolding, the first polymer forms an inner layer and the second polymer forms an outer layer. Beneficially, foaming may be provided during rotomolding to foam the inner layer.
    Type: Grant
    Filed: December 16, 1994
    Date of Patent: July 2, 1996
    Assignee: Neeco, Inc.
    Inventor: Donald G. Needham
  • Patent number: 5530055
    Abstract: A polyolefin-based composition useful for rotational molding, is provided. A polyethylene resin blend is beneficially used. The composition advantageously includes a nucleating agent. Rotomolded containers having improved resistance to puncture are beneficially provided. Also provided is a method of rotomolding the composition.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: June 25, 1996
    Inventor: Donald G. Needham
  • Patent number: 5525426
    Abstract: Hot-melt adhesives based upon a mixture composed of poly(vinylmethylether), greater than about 10 weight percent of a thermoplastic resin and, optionally a tackifier resin and/or extender, are found to be superior for the binding of polyolefins such as polyethylene, polypropylene, and ethylene-propylene copolymers to themselves and to other substrates. In particular, the hot-melt adhesives are useful for bonding polyethylene-backed and latex-backed carpet to polyethylene, polypropylene, or ethylene-propylene copolymer.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: June 11, 1996
    Assignee: Amoco Corporation
    Inventors: Matthew A. Kulzick, Wayne R. Pretzer, Tsuei-Yun Lynch, Paul A. Koning
  • Patent number: 5525675
    Abstract: Described is a thermoplastic elastomer comprising (A) 10-90 wt. % of polypropylene having substantially a syndiotactic structure, and (B) 90-10 wt. % of an ethylene-propylene-nonconjugated diene copolymer rubber and/or ethylene-propylene copolymer rubber, said (B) having been partially crosslinked. The elastomer according to the present invention is useful for obtaining formed products, particularly automotive bumper fascias, automotive mud guards and automotive trim skin material, which are excellent not only in flexibility, rubber elasticity and mechanical strength but also in external appearance and touch, and are substantially free from bleeding and fogging.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kazuhiko Masuda, Sachio Yokote, Masatoshi Kumagai
  • Patent number: 5521251
    Abstract: A propylene random copolymer composition which contains a mixture of 0.05-2.7% by weight of a crystalline propylene homopolymer (A) and 97.3-99.95% by weight of a random copolymer (B) of propylene and at least one .alpha.-olefin other than propylene which copolymer has a bound propylene content of 40-85% by weight and a Mw/Mn of not more than 5.5 meets both of the two mutually conflicting requirements of further improving the transparency inherent to polypropylene sheet and film, and attaining excellent solvent resistance.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: May 28, 1996
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Makoto Satoh, Ritsuo Setoh
  • Patent number: 5519090
    Abstract: Propylene polymer blends containinga) a propylene homopolymer having a melt flow index of from 0.001 to 5 g/10 min, as determined at 230.degree. C. under a load of 2.16 kg,b) a propylene/ethylene copolymer having an ethylene content of from 5 to 80% w/w, andc) a propylene homopolymer having a melt flow index of from 1 to 10.sup.4 g/10 min, as determined at 230.degree. C. under a load of 2.16 kg,the ratio of the melt flow index of the propylene homopolymer c) to that of the propylene homopolymer a) being within the range 10:1 to 10.sup.7 :1.The blends of the invention are high-flow materials showing a broad molecular weight distribution, and are thus readily processible.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: May 21, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Harald Schwager, Klaus-Dieter Hungenberg
  • Patent number: 5519091
    Abstract: In accordance with the present invention, there is provided a method for the preparation of an ethylene polymer composition having a density of 0.86-0.94 g/cm.sup.3 and an intrinsic viscosity [.eta.] of 1-6 dl/g using an olefin polymerization catalyst composed of a transition metal compound containing a ligand having a cycloalkadienyl skeleton and an organoaluminium oxy-compound, and there is also provided a method for the preparation of an ethylene polymer composition having density of 0.87-0.93 g/cm3 and an intrinsic viscosity [.eta.] of 0.5-6 dl/g.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: May 21, 1996
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Takashi Ueda
  • Patent number: 5516845
    Abstract: A thermoplastic basic polymers in pourable form are mixed with similarly pourable carrier polymers dispersable or soluble in the basic polymers with a cross-linking agent to produce cross-linked polymer moldings. These mutually compatible components are heated under further mixing to a reaction temperature above the melting range of the basic polymer and processed. The reaction of free radicals leads to bonds between polymer chains and/or the degradation of polymer chains.Porous carrier polymers which contain at least one organic peroxide and/or coagent incorporated in the fine pore structure as a fluid silane-free cross-linking agent are mixed in the basic polymer. Peroxide-containing carrier polymers are heated, coagent-containing carrier polymers are irradiated.The moldings are used for example for cable and sheath isolation, pipes for hot water lines and highly stressed injection moldings.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: May 14, 1996
    Assignee: Brugg Kabel AG
    Inventors: Ulrich Heese, Renato Salvel
  • Patent number: 5516848
    Abstract: This invention relates to polypropylene blends, particularly blends of high molecular weight amorphous polypropylene with lower molecular weight isotactic polypropylene. These blends exhibit unusual elastomeric properties.
    Type: Grant
    Filed: January 31, 1995
    Date of Patent: May 14, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jo Ann M. Canich, Henry W. Yang, Gary F. Licciardi
  • Patent number: 5516847
    Abstract: The present invention is directed to a golf ball cover comprising a blend of copolymers wherein one or more of the copolymers is a low cost non-ionic copolymer and one or more of the copolymers is an ionic copolymer. Surprisingly, a golf ball cover comprising the non-ionic/ionic copolymer blend exhibits no loss in C.O.R., and has equal resistance to cutting and cracking when compared to top grade golf ball covers made with one of the conventional 100% ionic copolymer blends. In particular, the present golf ball cover comprises from about 95 to about 80 pphr of one or more ionic copolymers, and from about 5 to about 20 pphr of one or more non-ionic copolymers, the latter being selected from the group consisting of a copolymer or terpolymer of ethylene or propylene; acrylic acid or methacrylic acid; a lower alkyl acrylate, and blends thereof.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: May 14, 1996
    Assignee: Lisco, Inc.
    Inventors: Michael J. Sullivan, Terence Melvin
  • Patent number: 5514455
    Abstract: A film comprising a blend of copolymers, which has been (i) extruded to a gauge in the range of about 0.3 to about 0.9 mil, said film having an Elmendorf Tear Strength in the machine direction of at least about 25 grams per mil greater than the Elmendorf Tear Strength in the machine direction of the same blend of copolymers, which has been extruded to a gauge of one mil, or (ii) extruded to a heavy gauge of at least about 5 mils and then biaxially oriented and reduced to a gauge of about 1.5 mils or less, first in the machine direction at a gauge reduction ratio of at least about 2:1, and then in the transverse direction at a gauge reduction ratio of at least about 1.5:1, said blend having been produced in situ by contacting ethylene and at least one alpha-olefin comonomer having 3 to 8 carbon atoms with a magnesium/titanium based catalyst system in each of two reactors connected in series, under polymerization conditions.
    Type: Grant
    Filed: July 8, 1994
    Date of Patent: May 7, 1996
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: William J. Michie, Jr., Guylaine St. Jean
  • Patent number: 5514751
    Abstract: A polymeric composition particularly suitable for obtaining heat sealable soft polypropylene fibers comprises a propylene homopolymer modified with a propylene homopolymer having an isotacticity index higher than 80, an ethylene-propylene copolymer insoluble in xylene at 23.degree. C. and a propylene copolymer soluble in xylene at 23.degree. C.
    Type: Grant
    Filed: October 8, 1993
    Date of Patent: May 7, 1996
    Assignee: Moplefan S.p.A.
    Inventor: Giampiero Barsotti
  • Patent number: 5508318
    Abstract: Disclosed is a polyolefin composition comprising (A) an irradiated, normally solid, high molecular weight, amorphous to predominantly crystalline olefin polymer material and (B) a non-irradiated propylene polymer material or a mixture thereof with an olefin copolymer rubber.The polyolefin composition of this invention also provides improved retention of embossing definition commonly referred to as grain retention, when the composition is extruded and embossed, with or without subsequently thermoforming.
    Type: Grant
    Filed: July 15, 1993
    Date of Patent: April 16, 1996
    Assignee: Montell North America Inc.
    Inventor: Jerome P. Comer
  • Patent number: 5506307
    Abstract: Polymer melt blends of a homopolymer of propylene or a copolymer of propylene with up to 40 weight percent of another monoolefin, with a homopolymer of one or more of a C.sub.10 to C.sub.30 alkyl (meth)acrylate or a copolymer containing at least 70 weight percent of the one or more C.sub.10 to C.sub.30 ester of an alkyl (meth)acrylate with up to 30 weight percent of one or more of a C.sub.1 to C.sub.9 alkyl (meth)acrylate, the homopolymer or copolymer having a weight-average molecular weight of at least 670,000, exhibit a relative characteristic time, as herein described, at least five (5) times that for the unmodified homo- or copolymer of polypropylene, and a melt strength ratio (as judged by relative sag resistance) at least 5 times that of the unmodified homo- or copolymer of polypropylene. Such blends are useful in thermoforming operations wherein sheet is thermoformed into cartons, containers, appliance housings, and the like.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: April 9, 1996
    Assignee: Rohm and Haas Company
    Inventor: Nazir A. Memon
  • Patent number: 5506306
    Abstract: Polyethylene has a number of desirable properties. However, for some thin film applications it is desirable to increase the stiffness of the film. This may be accomplished by incorporating a polymer of a vinyl aromatic monomer into the alloy. Such two-component blends have a low impact and low tear resistance. These deficient properties of the alloy may be significantly increased, without any significant loss of stiffness by further incorporating into the alloy a polymer based on a copolymer of ethylene and an alkyl ester of an ethylenically unsaturated carboxylic acid.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: April 9, 1996
    Assignee: Novacor Chemicals Ltd.
    Inventor: Kyosaku Sato
  • Patent number: RE35293
    Abstract: Disclosed is a solid golf ball containing at least one rubber portion formed from a rubber composition comprising a base rubber, a co-crosslinking agent and an organic peroxide; an improvement being present in that the base rubber is a mixture of(A) a solid polybutadiene rubber containing cis-1,4 bonds in an amount of at least 40%, and(B) either a liquid polybutadiene rubber or a liquid isoprene-butadiene copolymer rubber, or both.
    Type: Grant
    Filed: March 16, 1995
    Date of Patent: July 9, 1996
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Hidenori Hiraoka, Akihiko Hamada
  • Patent number: RE35308
    Abstract: A block copolymer of polyalkylene and halogenated polystyrene comprises the formula:S'--A--(A--S').sub.min which m is 0, 1, 3 or 4, A is a saturated polyalkylene, and S' is a nuclear brominated polystyrene having from about 0.5 to about 5 bromines per styrene unit. The polystyrene blocks are substantially free of halogen other than bromine and chlorine, and the polyalkylene is substantially free of halogen. The compositions retain the elastomeric properties of the non-halogenated form of the compounds while having significantly reduced flammability.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: July 30, 1996
    Assignee: Shell Oil Company
    Inventors: Nicolai A. Favstritsky, Rastko I. Mamuzic