Patents Examined by Caroline D. Liott
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Patent number: 6214059Abstract: A liquid alkali composition for use in fiber reactive dyeing of cotton and cotton blended fabrics or the like. The liquid alkali is a solution of sodium hydroxide, potassium hydroxide, and potassium carbonate formed by reaction of CO2 with the potassium hydroxide solution, and adding sodium hydroxide to the resultant mixture. The resulting supersaturated solution has a high enough Total Alkalinity to achieve reaction between the dye, including vinyl sulfone dyes, and fiber but is sufficiently buffered to achieve this reaction slowly so that the fiber reactive dyes fix in a level, uniform fashion. Preferably the composition includes potassium carbonate, potassium citrate, and potassium polyacrylate. The citrate and polyacrylate act as dispersants in the dyeing process and also act as crystallization inhibitors in solution. The use of the carbonate compounds of the present invention in place of conventional silicates or phosphorus prevents the discharge of untreatable toxic wastewater into natural waterways.Type: GrantFiled: February 14, 1997Date of Patent: April 10, 2001Assignee: Burlington Chemical Co., Inc.Inventor: Samuel B. Moore
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Patent number: 6211131Abstract: Sequestering agents for use as a whitening and fabric strength enhancer for aqueous hypochlorite bleach compositions are provided. It was found that the sequesterants when used with hypochlorite in the presence of soluble heavy metal ions, particularly iron and manganese ions, provide significantly improved whitening and fabric protection. Most preferably, the sequesterants are selected from polyacrylic acid, a polyacrylic acid derivative, a copolymer of acrylic acid or methacrylic acid and a comonomer which is maleic acid or maleic anhydride and mixtures thereof.Type: GrantFiled: November 13, 1997Date of Patent: April 3, 2001Assignee: The Clorox CompanyInventors: Thomas W. Kaaret, William L. Smith
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Patent number: 6210447Abstract: The present invention relates to a composition for dyeing keratin fibers, in particular human hair, containing, in a medium which is suitable for dyeing: as coupler, at least one compound of formula: or one of the addition salts thereof with an acid; and at least one oxidation base.Type: GrantFiled: February 10, 1999Date of Patent: April 3, 2001Assignee: L'OrealInventors: Laurent Vidal, GĂ«rard Malle
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Detergent composition comprising a cationic surfactant and a hydrophobic peroxyacid bleaching system
Patent number: 6207632Abstract: There is provided a detergent composition suitable for use in laundry or dish washing methods comprising: (a) a quaternary ammonium cationic surfactant; and (b) a hydrophobic organic peroxyacid bleaching system, capable of providing a hydrophobic organic peroxyacid compound.Type: GrantFiled: March 11, 1999Date of Patent: March 27, 2001Assignee: The Procter & Gamble CompanyInventors: Alan Thomas Brooker, Michael Alan John Moss, Richard Timothy Hartshorn, Christiaan Arthur Jacques Kamiel Thoen, Ian Martin Dodd -
Patent number: 6203579Abstract: A colorant composition for coloring keratin-containing fibers is disclosed having (a) at least one isatin derivative corresponding to the formula I: where R1 and R2 independently of one another represent a hydrogen atom, a halogen atom, a hydroxy group, a (C1-4)-alkyl, hydroxy-(C1-4)-alkyl, tertiary amino-(C1-4)-alkyl, (C1-4)-alkoxy group, an amino group optionally substituted by one or two (C1-4)-alkyl or hydroxy-(C1-4)-alkyl groups, a nitro, carboxy, or sulfo group, and Y is a hydroxy group, a (C1-4)-alkoxy group or an amino group which may be substituted by (C1-4)-alkyl, (C1-4)-alkoxy-(C1-4)-alkyl, carboxy-(C1-4)-alkyl, sulfo-(C1-4)-alkyl or hydroxy-(C1-4)-alkyl groups or which may be part of a heterocyclic 5-, 6- or 7-membered ring, or physiologically compatible salts thereof, and (b) at least one compound containing a primary or secondary amino group or hydroxy group selected from the group consisting of primary or secondary aliphatic or aromatic amines, nitrogen-containing heterocyclicType: GrantFiled: October 22, 1999Date of Patent: March 20, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hinrich Moeller, Horst Hoeffkes, Bernd Meinigke, David Rose
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Patent number: 6203580Abstract: Compositions for the oxidation dyeing of keratin fibers, comprising, as oxidation base, at least one para-aminophenol, of formula (I) and/or at least one acid-addition salt thereof: in which: R1 represents a hydrogen atom, a linear or branched C1-C4 alkyl radical or a C1-C4 trifluoroalkyl radical, R2 and R3 independently represent a hydrogen atom, a C1-C4 alkyl radical or a C1-C4 monohydroxyalkyl radical, and X, Y and Z independently represent a carbon, nitrogen, oxygen or sulphur atom, wherein the bonds XY and YZ are single or double bonds; a dyeing process using these compositions, novel para-aminophenols and a process for their preparation.Type: GrantFiled: February 24, 1998Date of Patent: March 20, 2001Assignee: L'OrealInventors: Jean Jacques Vandenbossche, Alain Lagrange
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Patent number: 6200944Abstract: A solid bleach precursor composition is provided comprising a bleach precursor and a surfactant system, whereby the composition exhibits effective solublisation of its bleach precursor component.Type: GrantFiled: December 22, 1998Date of Patent: March 13, 2001Assignee: The Procter & Gamble CompanyInventors: Anthony Dovey, Sanjeev Sharma
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Patent number: 6200353Abstract: Couplers for hair coloring compositions for oxidative dyeing of hair are compounds of the formula at least one coupler comprising a compound of the formula: wherein R is selected from the group consisting of C1 to C2 alkyl and hydroxyethyl, R1 is selected from the group consisting of hydrogen, chlorine, bromine, C1 to C3 alkyl, C1 to C3 alkoxy, C1 to C3 hydroxyalkyl and C1 to C3 hydroxyalkoxy, and X is O, S or NH.Type: GrantFiled: February 1, 2000Date of Patent: March 13, 2001Assignee: Bristol Myers Squibb CompanyInventors: Mu-Ill Lim, Linas R. Stasaitis, Yuh-Guo Pan
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Patent number: 6197071Abstract: Formulations for the oxidation dyeing of keratin fibers comprising a coupler and oxidation base. The couplers are represented by the following structure: wherein: Z represents the elements of C, N, O, or S necessary to complete a substituted or unsubstituted heterocyclic 5 or 6 member ring along with nitrogen; R1 represents a substituent group; and, X represents a hydrogen or a coupling off group.Type: GrantFiled: October 12, 1999Date of Patent: March 6, 2001Assignee: Eastman Kodak CompanyInventors: Donald R. Diehl, Mbiya Kapiamba, Stanley W. Cowan
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Patent number: 6190421Abstract: A method for dyeing keratin fibers, particularly human keratin fibers, and more particularly hair. When the method is used, an extemporaneous mixture is applied on the fibers of a composition (A) containing one or more oxidation dye precursors and optionally one or more couplers, of a composition (B), in powder form, containing one or more direct dyes, preferably cationic, optionally dispersed in an organic pulverulent excipient and/or a mineral pulverulent excipient, and a composition (C) containing one or more oxidizing agents. The invention also features a ready-to-use composition of three components (A), (B), and (C) stored separately and mixed at the time of use to be applied on keratin fibers.Type: GrantFiled: December 15, 1998Date of Patent: February 20, 2001Assignee: L'OrealInventors: Christine Rondeau, Nicole Zemori
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Patent number: 6187058Abstract: A low or no VOC hair lightener or dying composition with a low water content and a high organic content comprising: (a) a developer phase comprising: (i) water; (ii) an oxidizing agent; and (iii) optionally a thixotropic control agent; and (b) a tint phase comprising: (i) 0-50 weight percent water; (ii) 0-10 weight percent dye; (iii) 10-50 weight percent of a non VOC solvent; (iv) 5-60 weight percent of a thickener; (v) a sufficient amount of an alkalizer so that the hair coloring composition has a pH of 6-12.Type: GrantFiled: May 20, 1998Date of Patent: February 13, 2001Assignee: Combe, Inc.,Inventor: Jack Massoni
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Patent number: 6187057Abstract: The invention discloses a capillary dyeing composition comprising at least one direct dye, characterised in that it further contains a cross-linked polymer with acrylic and/or acrylate units and with acrylamide units. The invention also discloses the use of a cross-linked polymer with acrylic and/or acrylate units and with acrylamide units, in or for the production of a dyeing composition containing at least one direct dye, to improve the tinctorial power of the said composition, particularly after storage at below about 10° C., and particularly at about 4° C. The invention also discloses a method for preserving the tinctorial power, in particular after storage at a temperature below about 10° C., of a dyeing composition containing at least one direct dye, characterised in that an effective amount of the said cross-linked polymer is added to the composition.Type: GrantFiled: May 20, 1998Date of Patent: February 13, 2001Assignee: L'OrealInventor: Mireille Maubru
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Patent number: 6179881Abstract: Azo compounds of the 2-(4-amino)phenyldiazinecarboximidamide type and 2-(4-amino)phenylhydrazinecarboximidamide type, a process for their synthesis, their use for dyeing keratin fibers, dye compositions containing them, and dyeing processes.Type: GrantFiled: November 23, 1998Date of Patent: January 30, 2001Assignee: L'OrealInventors: Jean-Christophe Henrion, Michel Philippe
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Patent number: 6179883Abstract: Novel 2-imino-2,3-dihydro-1H-indole derivatives of formula (I) or (II) below: in which: R1, R2 and R3 denote hydrogen, alkyl, carboxyl, alkoxycarbonyl, monohydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl, monoalkylaminoalkyl or dialkylaminoalkyl; R′3 and R4 denote alkyl, carboxyl, alkoxycarbonyl, monohydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl, monoalkylaminoalkyl or dialkylaminoalkyl; R5 denotes hydrogen, alkyl, monohydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl, monoalkylaminoalkyl or dialkylaminoalkyl; and the addition salts thereof with an acid, as well as their uses for dyeing keratin fibres.Type: GrantFiled: August 22, 1997Date of Patent: January 30, 2001Assignee: L'OrealInventors: Eric Terranova, Aziz Fadli, Alain Lagrange
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Patent number: 6179882Abstract: The present invention relates to a composition for dyeing keratin fibres, in particular human hair, containing, in a medium which is suitable for dyeing: as coupler, at least one compound of formula or one of the addition salts with an acid, with R1 denotes, in particular, hydrogen, alkyl, aryl, a heterocycle, halogen, R2 denotes, in particular, hydrogen, halogen, alkoxy, aryloxy, acyloxy, arylthio, alkylthio, R3 has the same meanings as those for R1, Za and Zb, which are different, denote C═O or CR4, with R4 having the same meanings as R1; and at least one oxidation base.Type: GrantFiled: June 16, 1999Date of Patent: January 30, 2001Assignee: L'OrealInventors: Laurent Vidal, G{acute over (e)}rard Malle
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Patent number: 6171516Abstract: A treatment agent for elastic polyurethane fibers comprising a dispersion in which a higher fatty acid magnesium salt is colloidally dispersed in a silicone mixture consisting of a silicone oil with a viscosity of 5×10−6−50×10−6 m2/S at 25° C. as a dispersion medium and a dispersant mainly comprising a modified silicone at a ratio by weight of the dispersion medium/the dispersant=100/0.5−100/4.5, wherein the amount of the higher fatty acid magnesium salt is 1 to 10 parts by weight per 100 parts by weight of the silicone oil.Type: GrantFiled: November 6, 1998Date of Patent: January 9, 2001Assignees: Takemoto Oil & Fat Co., Ltd., Du Pont Toray Co., Ltd.Inventors: Yoshinobu Inuzuka, Yasushi Miyamoto, Eiji Kawanishi, Noboru Watanabe
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Patent number: 6171347Abstract: A multicomponent kit for coloring and later removing color from fibers is described, which consists of a first component and a second component. The first component includes a composition for oxidative dyeing of hair and the second component includes an aqueous or aqueous-alcoholic composition for reductive removal of color from dyed hair. The composition for reductive removal of color from hair has a pH of from 1.8 to 6 and is in the form of a gel, cream, emulsion, foam or solution. It contains from 1 to 50% by weight of one or more reductones, advantageously ascorbic and/or isoascorbic acid or salts thereof, and, in addition to the reductones, from 0.1 to 10% by weight of one or more thiols or a combination of from 0.1 to 10% by weight of one or more thiols and from 0.001 to 5% by weight of one or more sulfites. It also includes one or more pH adjusting agents and standard cosmetic additive ingredients.Type: GrantFiled: July 1, 1998Date of Patent: January 9, 2001Assignee: Wella AktiengesellschaftInventors: Manuela Kunz, Dominique Le Cruer
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Patent number: 6165230Abstract: A 1,4-diazacycloheptane derivative and an oxidative hair colorant containing the derivative as a primary intermediate is presented. The 1,4-diazacycloheptane derivative is of the formula: ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another represent hydrogen, a C.sub.1-4 alkyl or hydroxyalkyl group or a C.sub.2-4, dihydroxyalkyl group, X and Y independently of one another represent hydrogen, chlorine, fluorine, a C.sub.1-4 alkyl, hydroxyalkyl, aminoakyl or alkoxy group, a C.sub.2-4 dihydroxyalkyl group or an allyl group and R.sup.5 and R.sup.6 independently of one another represent hydrogen or a C.sub.1-4 alkyl group. Natural color tones can be obtained in keratin fibers with oxidative hair colorants containing the 1,4-diazacycloheptane derivative, without the use of additional primary intermediates.Type: GrantFiled: August 25, 1999Date of Patent: December 26, 2000Assignee: Henkel Kommanditgesellschaft auf AktienInventors: David Rose, Horst Hoeffkes, Bernd Meinigke
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Patent number: 6165229Abstract: The present invention relates to a composition for dyeing keratin fibers, in particular human hair, containing, in a medium which is suitable for dyeing, at least:as coupler, at least one compound of formula: ##STR1## in which: R.sub.1 denotes, in particular, hydrogen, alkyl, phenyl, substituted phenyl, cyano; carbonyl; etc.R.sub.2 denotes, in particular, hydrogen, halogen, alkoxy, aryloxy, acyloxy, acetamido, dialkylamino, etc.Z.sub.a and Z.sub.b denote a nitrogen atom or a carbon bearing a group R.sub.3 or R.sub.4 or R.sub.5, with the proviso that at least one of the two is a carbon atom;R.sub.3 and R.sub.4, which are independent, denote cyano; trifluoroalkyl; alkoxycarbonyl; aryloxycarbonyl, hydrogen; alkyl; carboxyl; etc.R.sub.5 denotes, in particular, hydrogen, aryl, alkoxy, alkylthio, etc.at least one oxidation base.Type: GrantFiled: February 8, 1999Date of Patent: December 26, 2000Assignee: L'OrealInventors: Laurent Vidal, Gerard Malle
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Patent number: 6159919Abstract: The bleaching detergent composition in a form of granules or powders containing an organic peracid precursor which produces an organic peracid upon reaction with hydrogen peroxide in water, the organic peracid having an alkyl group with 7 to 19 carbon atoms, and a hydrogen peroxide releasing material, wherein the bleaching detergent composition comprises the following components a) to c): a) one or more surfactants; b) one or more crystalline alkali metal silicates; and c) one or more agents for capturing metal ions other than the crystalline alkali metal silicates b), wherein a total amount of the above a), b), and c) components in the bleaching detergent composition occupies from 70 to 99% by weight, and wherein the weight ratio of component b) to component a) is b/a=90/10 to 45/55, and the weight ratio of component b) to component c) is b/c=7/93 to 75/25, and wherein the weight ratio of the organic peracid precursor to nonionic surfactants used as component a) is from 10/90 to 70/30.Type: GrantFiled: April 19, 1996Date of Patent: December 12, 2000Assignee: Kao CorporationInventors: Shu Yamaguchi, Nobuyosi Yamaguchi, Muneo Aoyagi, Noriaki Ushio, Shigeru Tamura, Masaki Tsumadori