Abstract: The present invention relates to a method of removing organic chemicals and organometallic complexes (organic heavy metal complexes) using zeolites from process water or tailings streams of a mineral processing plant where diethylenetriamine (DETA) or triethylenetetramine (TETA) is used as a flotation reagent and DETA-metal complexes are found in process water or tailings streams. The process water or slurry tailings streams of a mineral processing plant containing DETA, DETA-metal complexes and residual heavy metals may be contacted with natural zeolites. This may be carried out by adding the natural zeolites to the process streams or slurries while mixing with a mechanical mixer to efficiently adsorb DETA, DETA-metal complexes and heavy metals from the process streams on the zeolite. The loaded zeolite may then be discarded with the flotation tailings.
Type:
Grant
Filed:
September 13, 2011
Date of Patent:
December 30, 2014
Assignee:
Vale S.A.
Inventors:
Jie Dong, Manqiu Xu, Kenneth Erwin Scholey
Abstract: A method for bioremediation of contaminants, comprising contacting a contaminant with composite particles including at least one microbial available nutrient species and at least one fatty acid species, and contacting the contaminant with oxygenated water including greater than about 4 parts per million dissolved oxygen. Water may be oxygenated on-site using various oxygenating devices, such as an aspirator, aerator, impeller and diffuser. Optionally, the oxygenated water may be prepared with wastewater that is being remediated. The method may be used to maintain a dissolved oxygen concentration of greater than a setpoint concentration, such as at least 4 ppm. A preferred oxygenated water stream or source has a dissolved oxygen concentration of greater than 50 ppm. Where the contaminant is in a wastewater, the dissolved oxygen concentration in the remediation zone or the oxygenated water stream may be measured with a dissolved oxygen sensor.
Abstract: A system for producing and supplying a coolant to a filtration sub-system, and for reconditioning and recombining a return flow of used coolant. A main reservoir is in two way communication with the filtration sub-system via a clean coolant outlet and a dirty coolant return. An inlet feeds an untreated water supply to a de-ionization canister. A mixing valve in communication with the inlet recombines a remaining untreated portion of the water supply with the de-ionized portion. A mixing pump intermixes the water supply with a chemical concentrate to produce a coolant delivered to a main reservoir. A volume of coolant is drawn through an outlet from the reservoir and communicates the coolant to a particle filter, a chiller, and prior to outputting to the filtration sub-systems. The used return coolant is filtered and reintroduced to the main reservoir.
Abstract: In a water environment in conjunction with one or more types of oil, a method of in-situ burning including placing a fire resistant sorbent material in contact with the oil and allowing the oil to wick into the sorbent material. The method further includes burning the oil using the sorbent material as a wick.
Abstract: A method of removal of oil slicks or spills floating on the surfaces of bodies of water is disclosed in which, unlike the traditional methods, a floatable or a non-floatable oil-absorbing substance is pumped into the water under the oil-spill layer. The pumped substance will reach and lie under the oil-spill layer and cannot be blown away by wind or other causes during or after dispersion of the substance. After application of the substance, the oil layer may be naturally or mechanically agitated to facilitate formation of a removable mixture of oil and the substance. In various embodiments, after the removal of the oil-substance mixture, the oil may be separated from the mixture and be reused.
Abstract: A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.
Type:
Grant
Filed:
July 25, 2011
Date of Patent:
November 18, 2014
Assignee:
General Electric Company
Inventors:
James Manio Silva, Hope Matis, William Leonard Kostedt, IV
Abstract: A process for the treatment of water comprising at least the steps of: (a) providing the water in laminar flow; and (b) providing bubblefree aeration to the water. The present invention introduces aerobic treatment into wastewater settlement without any hindrance to the settlement process. The present invention is useable for any settlement step or stage, without limitation, the commonest being primary settlement or final settling.
Type:
Grant
Filed:
December 19, 2008
Date of Patent:
November 11, 2014
Assignee:
The Queen's University of Belfast
Inventors:
Elaine Groom, Simon Murray, Joel Ferguson
Abstract: The present invention includes a system for recycling wash water, having a first separator configured to separate solids from wash water, a second separator configured to separate oil from wash water, a bioreactor configured to bacterially consume solids from wash water, a third separator configured to further separate solids from wash water, an oxidation chamber configured to sterilize and oxygenate wash water, an aeration tray configured to further oxygenate wash water, a storage tank configured to store wash water, and a pump configured to pump wash water from the storage tank to the bioreactor. The present invention also includes a process and method associated with the use and function of the system.
Abstract: Disclosed is a cross-linked molecularly imprinted polymer including cross-linked chitosan having selective binding sites for phosphate ions, phosphate containing molecules, or a combination of both.
Type:
Grant
Filed:
June 3, 2011
Date of Patent:
November 4, 2014
Assignee:
The Johns Hopkins University
Inventors:
Tracy J. Terry, Andrew F. Mason, Carl A. Marrese
Abstract: Embodiments of a water treatment unit are disclosed. An embodiment of a water treatment unit according to the present disclosure comprises a generally vertical riser having a lower end and an upper end, at least one inlet adjacent the lower end, and at least one outlet adjacent the upper end, a substantially spherical housing surrounding the riser, the housing comprising at least one opening in a lower portion of the housing, the housing enclosing a chamber, a motor coupled to the housing, a shaft coupled to the motor, the shaft extending downward from the motor within the riser, the shaft being in general axial alignment with the riser, at least one propeller coupled to the shaft, and a biomedia material within the chamber.
Abstract: The wastewater treatment system includes a hollow, elongate, horizontally disposed, cylindrical body made from plastic is adapted for water storage and treatment. The cylindrical body includes reinforcement ribs formed by a helically wound steel band embedded in the plastic and extending between opposite open ends of the elongate cylindrical body. A voltage source selectively energizes the steel band. A pair of bulkhead members respectively extends across and covers opposite ends of the cylindrical body. A fluid-tight wall is mounted in the cylindrical body, the first bulkhead member, the fluid-tight wall and the cylindrical body forming a fluid-tight tank defining a liquid storage chamber. The second bulkhead member and the fluid-tight wall define a dry liquid treatment equipment chamber. An inlet pipe extends into the tank for admitting the pretreatment liquid into the tank. An outlet pipe extends from the tank and discharges the treated liquid from the tank.
Abstract: Volatile organic compounds (VOCs), such as BTEX methanol and other non-phase separable hydrocarbons may be removed from wastewater obtained from oil or gas exploration or production operations by way of a bioreactor. The bioreactor may employ anaerobic microorganisms that metabolize various VOCs. In some embodiments, such a bioreactor may be configured to treat process flow rates of thousands of barrels of wastewater per hour. Such a bioreactor may comprise a large vessel at a larger water treatment site.
Type:
Grant
Filed:
April 3, 2013
Date of Patent:
October 28, 2014
Assignee:
R N Industries, Inc.
Inventors:
Kerry J. Spiroff, Nathan Zaugg, Huiwei Yu
Abstract: Disclosed is a method for extracting high acyl gellan from the fermentation broth containing gellan gum with a low production cost and high quality of products, comprising the following steps: (1) Treatment of the fermentation broth with an enzyme; (2) flocculation of the treated fermentation broth with acid; (3) wash of the fiber-like material; and (4) drying and milling.
Abstract: Volatile organic compounds (VOCs), such as BTEX methanol and other non-phase separable hydrocarbons may be removed from wastewater obtained from oil or gas exploration or production operations by way of a bioreactor. The bioreactor may employ anaerobic microorganisms that metabolize various VOCs. In some embodiments, such a bioreactor may be configured to treat process flow rates of thousands of barrels of wastewater per hour. Such a bioreactor may comprise a large vessel at a larger water treatment site.
Type:
Grant
Filed:
February 3, 2014
Date of Patent:
October 7, 2014
Assignee:
R N Industries, Inc.
Inventors:
Kerry J. Spiroff, Nathan Zaugg, Huiwei Yu
Abstract: A ballasted anaerobic system for treating wastewater including at least one anaerobic treatment reactor. A weighting agent impregnation subsystem is configured to mix weighting agent with the biological flocs to form weighted biological flocs to create a weighted anaerobic sludge blanket in the at least one anaerobic treatment reactor. A weighting agent recovery subsystem is configured to recover the weighting agent from excess sludge and reintroduce the weighting agent to the weighting agent impregnation subsystem.
Abstract: A method of cleaning a membrane surface immersed in a liquid medium with a fluid flow, including the steps of providing a randomly generated intermittent or pulsed fluid flow along the membrane surface to dislodge fouling materials therefrom. A membrane module is also disclosed comprising a plurality of porous membranes (6) or a set of membrane modules (5) and a device (11) for providing a generally randomly generated, pulsed fluid flow such that, in use, said fluid flow moves past the surfaces of said membranes (6) to dislodge fouling materials therefrom.
Type:
Grant
Filed:
February 12, 2013
Date of Patent:
September 23, 2014
Assignee:
Evoqua Water Technologies LLC
Inventors:
Fufang Zha, Gerin James, Joseph Edward Zuback, Peter Zauner, Roger William Phelps
Abstract: A light weight oriented net or netting assembly is provided for oil capture and containment. The netting assembly is made by biaxially stretching or orienting starting materials to form a pattern of oriented strands and integral junctions that, while being light in weight, is also strong enough to be used to capture and remove oil from contaminated water without an outer stabilizing jacket. The assembly is preferably made from oriented polypropylene netting that is folded, gathered, bunched and/or otherwise layered upon itself on the order of 16-64 times and then crimped in one or more locations to secure the netting layers in a bow tie or tubular configuration that forms net cavities and an open cell structure to capture and contain oil that has been dispersed in water. Oil in the netting assembly can then be removed, such as by pressing or other removal process, after which the netting assembly may be reused.
Type:
Grant
Filed:
August 5, 2011
Date of Patent:
September 9, 2014
Assignee:
The Tensar Corporation
Inventors:
Matthew David Stewart, Brian Edward Connelly, Daniel Charles Habicht
Abstract: A method of conditioning, separating, drying, and comminuting sulfurous acid treated wastewater suspended solids for addition to aerobic and anaerobic digesters to provide electron donor carbon and sulfur compounds to increase the removal rate of ammonia, nitrates/nitrites, and BOD compounds.
Abstract: A filtering device comprises a vessel for containing filtering media such as nutshells. Associated with the filtering device is an eductor for scrubbing and cleaning the media and removing contaminants such as oil from the media. The eductor includes an inlet port for receiving a motive liquid. Further, the eductor includes an inlet port for receiving media held in the vessel. In operation, a motive liquid is directed into the eductor and this induces media in the vessel into the eductor. By continuously directing motive liquid from an external source into the eductor, this results in the media being fluidized and circulated and recirculated through the eductor, giving rise to a slurry that contains liquid, the media and removed contaminants. A portion of the slurry is discharged from the filtering device while the media is retained in the filtering device.
Type:
Grant
Filed:
July 25, 2012
Date of Patent:
September 9, 2014
Assignee:
Veolia Water Solutions and Technologies Support
Abstract: A system of treating high nitrogen content waste water is disclosed, where the system includes a precipitation and conditioning subsystem, an ammonia stripper subsystem, and a denitrification subsystem. The system is adapted to reduce nitrogen contamination to level below about 10 ppm and in certain embodiments below 3 ppm.
Type:
Grant
Filed:
September 20, 2013
Date of Patent:
September 2, 2014
Inventors:
Randy A. Galgon, Allen Ray Stickney, Richard B. Steinberg