Patents Examined by Christina Ildebrando
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Patent number: 6756339Abstract: A catalyst for the nonoxidative production of alkenylaromatics from alkylaromatics, wherein the catalyst is predominantly iron oxide, an alkali metal compound, copper oxide, cerium oxide and less than about 100 ppm of a source for a noble metal, such as palladium, platinum, ruthenium, rhenium, osmium, rhodium or iridium. Additional components of the catalyst may include compounds based on molybdenum, tungsten, calcium, magnesium, chromium and other such promoters.Type: GrantFiled: August 29, 2002Date of Patent: June 29, 2004Assignees: Sud-Chemie Inc., Sud-Chemie Catalysts Japan, Inc.Inventors: Andrzej Rokicki, Dennis Smith, David L. Williams
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Patent number: 6750168Abstract: A catalyzed adsorber that is effective and durable in treating exhaust gas from internal combustion engines, and in particular, for adsorbing hydrocarbons contained in engine exhaust gas during cold start, releasing these hydrocarbons when the engine exhaust gas has heated the adsorber to normal operating temperature and catalyzing the conversion of these hydrocarbons to carbon dioxide and water. The catalyzed adsorber has a catalyst overlayer with a non-catalyst overcoat loading of about 1.0 g/in3 or less.Type: GrantFiled: December 5, 2000Date of Patent: June 15, 2004Assignee: Delphi Technologies, Inc.Inventors: JiYang Yan, Heinz J. Robota
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Patent number: 6743745Abstract: A process for the production of a molecular sieve adsorbent blend product with improved performance characteristics produced by preparing a zeolite powder, preparing a highly dispersed attapulgite fiber binder, mixing the zeolite powder with the highly dispersed attapulgite binder to form a mixture, forming molecular sieve adsorbent products into a shaped material and calcining the shaped material, wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml.Type: GrantFiled: January 22, 2002Date of Patent: June 1, 2004Assignee: ZeochemInventors: Dave Jaussaud, Kerry Weston, Armin Pfenninger, Beat Kleeb
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Patent number: 6743405Abstract: A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200° C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.Type: GrantFiled: May 6, 2002Date of Patent: June 1, 2004Assignee: The United States of America as represented by the United States Department of EnergyInventor: Ranjani Siriwardane
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Patent number: 6740616Abstract: A process for preparing glycol monoethers from olefins comprises reacting the olefins with an epoxidizing reagent in the simultaneous presence of hydroxyl-containing organic compounds over a mixture of epoxidation catalysts and alkoxylation catalysts.Type: GrantFiled: March 7, 2001Date of Patent: May 25, 2004Assignee: Oxeno Olefinchemie GmbHInventors: Ulrich Müller, Georg Heinrich Grosch, Andreas Walch, Norbert Rieber
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Patent number: 6740764Abstract: Oxide comprising at least the elements Si and Ti, at least noncrystalline silicon dioxide and at least one crystalline silicate phase which has at least one zeolite structure, with noncrystalline silicon dioxide being applied to at least one crystalline silicate phase having at least one zeolite structure, wherein the oxide has no silicon-carbon bonds.Type: GrantFiled: May 9, 2002Date of Patent: May 25, 2004Assignee: BASF AktiengesellschaftInventors: Yi Chen, Weiping Ding, Yuan Chun, Ma Lian, Ulrich Müller
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Patent number: 6737032Abstract: A second reaction medium is introduced into a first reaction medium flowing in a flow channel and the reaction media are intensively mixed. The second reaction medium (which may be one or more reaction media) is introduced at a plurality or even a multiplicity of positions that are distributed over a cross section of the flow channel. Turbulence flow is induced in the first reaction medium (which may also be one or more reaction media) at the positions where the second reaction medium is introduced. As a result, the intense mixing of the reaction media with one another takes place directly at the locations where the second reaction medium is introduced into the flow channel.Type: GrantFiled: July 16, 1999Date of Patent: May 18, 2004Assignee: ENVIRGY Environment Energy Engineering and Construction GmbHInventors: Ansgar Aspalter, Richard Budin, Krzysztof Krotla, Christian Lechner, Robert Reiter, Helmut Wenzl
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Patent number: 6734323Abstract: The present invention relates to a process for the preparation of zeolitic catalysts comprising zeolite and oligomeric silica, which can be used in industrial reactors. The process consists in directly mixing the suspension, resulting from the synthesis of the zeolite, with an oligomeric silica sol, obtained from the hydrolysis of a tetra-alkyl ortho silicate in the presence of tetra-alkylammonium hydroxide, and in subjecting the mixture to rapid drying, by feeding to a spray-dry.Type: GrantFiled: November 29, 2000Date of Patent: May 11, 2004Assignees: Enichem S.P.A., Enitecnologie S.P.A.Inventors: Giuseppe Botti, Angela Carati, Leonardo Dalloro
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Patent number: 6734129Abstract: The invention is related to a zeolite membrane composite composition comprising a first zeolite or zeolite-like layer, a second independently selected catalytic, permselective, or combined catalytic-permselective layer, and a porous support, the porous support having a first surface in contact with the first zeolite layer and a second surface in contact with the second layer. In another embodiment, the invention is directed toward a zeolite membrane composite composition comprising a supported zeolite or zeolite-like layer, the support having a catalytic functionality contained thereon.Type: GrantFiled: November 22, 2002Date of Patent: May 11, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Wenyih F. Lai, Edward William Corcoran, Jr.
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Patent number: 6730625Abstract: There is described a process and a catalyst for the hydroalkylation of an aromatic hydrocarbon, particularly benzene, wherein the catalyst comprises a first metal having hydrogenation activity and a crystalline inorganic oxide material having a X-ray diffraction pattern including the following d-spacing maxima 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07.Type: GrantFiled: November 9, 1999Date of Patent: May 4, 2004Assignee: ExxonMobil Oil CorporationInventors: Clarence D. Chang, Jane C. Cheng, Terry E. Helton, Michael A. Steckel, Scott A. Stevenson
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Patent number: 6726890Abstract: The present invention provides a catalyst for oxidizing reformed gas, which catalyst can selectively oxidize carbon monoxide—which is contained in the reformed gas used as a fuel of a solid polymer fuel cell and which acts as a catalyst poison of the fuel cell—into carbon dioxide with high performance. The reformed gas is oxidized by use of the catalyst of the present invention, which catalyst is characterized in that M-type mordenite, among different types of zeolite, is used as a carrier and a bimetallic alloy metal system containing platinum and an alloy-forming metal other than platinum is supported by the carrier, wherein the amount of the alloy-forming metal in the alloy is 20-50 at. %.Type: GrantFiled: January 14, 2000Date of Patent: April 27, 2004Assignees: Tanaka Kikinzoku Kogyo K.K.Inventor: Masahiro Watanabe
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Patent number: 6720282Abstract: Trace impurities such as organic compounds and carbon monoxide in reactive fluids such as ammonia, hydrogen chloride, hydrogen bromide, and chlorine are reduced to sub-ppb levels using gas purifying systems that contain a preconditioned ultra-low emission (P-ULE) carbon. P-ULE is capable of removing impurities from a reactive fluid down to parts-per-billion (ppb) and sub-ppb levels without concurrently emitting other impurities such as moisture or carbon dioxide into the purified reactive fluid. The P-ULE carbon is prepared by heating a carbon material to temperatures from 300° C. to about 800° C. in an ultra-dry, inert gas stream, to produce an ultra-low emission (ULE) carbon material, subjecting the ULE carbon to a second activation process under a reactive gas atmosphere to produce a P-ULE carbon and storing the P-ULE carbon in an environment that minimizes contamination of the P-ULE prior to its use in a gas purifier system.Type: GrantFiled: October 2, 2002Date of Patent: April 13, 2004Assignee: Matheson Tri-Gas, Inc.Inventors: Hans H. Funke, Dan Fraenkel, Virginia H. Houlding
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Patent number: 6716337Abstract: The invention pertains to a carrier composition comprising (a) at least 30 wt % of a synthetic cracking component, based on the total weight of the carrier composition, which comprises oxidic compounds of one or more trivalent metallic elements, tetravalent metallic elements, and divalent metallic elements, said cracking component comprising elemental clay platelets with an average diameter of 1 &mgr;m or less and an average degree of stacking of 20 platelets per stack or less, and/or comprising a cogel with a saponite content CA of less than 60%, in which the total of sodium and potassium amounts to less than 1 wt %, based on the total weight of the cogel, and (b) 1-25 wt % of a zeolite Y, based on the total weight of the carrier composition, with a unit cell size below 24.35 Å. The invention further pertains to a catalyst comprising said carrier composition and at least a hydrogenation metal, and a process for converting heavy feedstock into middle distillates using said catalyst.Type: GrantFiled: January 31, 2001Date of Patent: April 6, 2004Assignee: Akzo Nobel NVInventors: Jan Nieman, Johannes Wilhelmus Maria Sonnemans, Bas De Kroes
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Patent number: 6716784Abstract: Catalytic compositions are described for hydrocarbons cracking containing at least two zeolitic components of which at least one zeolitic component containing aluminium in its structure is selected from among ITQ-7 zeolites, intergrowths of ITQ-7 zeolites, ITQ-7 zeolites exchanged with rare earths, intergrowths of ITQ-7 zeolites exchanged with rare earths, and combinations of them. These combinations are of utility as catalysts for cracking in FCC units and permit C3 and C4 olefins to be efficiently obtained along with high yields of gasoline. Also described is the use of a zeolitic material containing aluminium in its structure and selected from among ITQ-7 zeolites, intergrowths of ITQ-7 zeolites, ITQ-7 zeolites exchanged with rare earths, intergrowths of ITQ-7 zeolites exchanged with rare earths, and combinations of them, as a catalytic material in hydrocarbon catalytic cracking processes.Type: GrantFiled: September 23, 2002Date of Patent: April 6, 2004Assignees: Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de ValenciaInventors: Avelino Corma Canós, María Diaz Caba{overscore (n)}as, Joaquín Martinez Triguero
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Patent number: 6716338Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally spinel, or mullite, or both spinel and mullite made via kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.Type: GrantFiled: July 8, 2002Date of Patent: April 6, 2004Assignee: Engelhard CorporationInventors: Rostam Madon, David H. Harris, Mingting Xu, David Stockwell, Bruce Lerner, Glenn W. Dodwell
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Patent number: 6712262Abstract: The invention provides a water-soluble preflux that can solve problems with a soldering land array having a narrow spacing in that fused solder is likely to cause soldering bridges with defective soldering, a printed circuit board with its film formed thereon, and a surface treatment process for a metal in that circuit. The water-soluble preflux comprises given two different benzimidazoles compound and an iodine-based compound optionally with an amino acid, etc. The invention provides a printed circuit board with a film of that preflux formed thereon, and a surface treatment process for the metal in that circuit.Type: GrantFiled: July 18, 2002Date of Patent: March 30, 2004Assignee: Tamurakaken CorporationInventors: Shinichi Akaike, Kazutaka Nakanami, Yoshiyuki Takahashi, Takao Ono
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Patent number: 6713658Abstract: A process for producing a catalyst for olefin cracking, the process comprising the steps of providing an MFI-type crystalline silicate catalyst, heating the catalyst in steam to remove aluminum from the crystalline silicate framework and extracting aluminum from the catalyst by contacting the catalyst with a complexing agent for aluminum to remove from pores of the framework aluminum deposited therein during the steaming step thereby to increase the silicon/aluminum atomic ratio of the catalyst; and calcining the catalyst at elevated temperature.Type: GrantFiled: December 5, 1998Date of Patent: March 30, 2004Assignee: Fina Research, S.A.Inventors: Jean-Pierre Dath, Luc Delorme, Jacques-François Grootjans, Xavier Vanhaeren, Walter Vermeiren
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Patent number: 6712953Abstract: The invention relates to a catalyst that contains at least one matrix, at least one zeolite and at least one hydro-dehydrogenating element that is located at the matrix (deposited on the catalyst or contained in the matrix), in which the zeolite contains in its porous network at least one element of group VIB and/or group VIII. Said hydro-dehydrogenating element preferably belongs to group VIB and/or to group VIII of the periodic table. The catalyst contains at least one promoter element)phosphorus, boron, silicon).Type: GrantFiled: October 16, 2000Date of Patent: March 30, 2004Assignee: Institut Francais du PétroleInventors: Slavik Kasztelan, Nathalie Marchal-George, Tivadar Cseri, Pierre Leyrit, Philippe Dascotte, Elisabeth Rosenberg
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Patent number: 6712974Abstract: This invention relates to filterable composite adsorbents comprising one or more adsorbent components and one or more filtration components, and methods for preparing and using same. More particularly, this invention pertains to filterable composite adsorbents and filterable composite adsorbent products which are suitable for use in filtration applications, and which comprise one or more microparticulate or colloidal adsorbent components selected from the group consisting of silica gel, fumed silica, neutral clay, alkaline clay, zeolite, solid catalyst, alumina, adsorbent polymer, alkaline earth silicate hydrate, and combinations thereof, which bear the property of adsorption, which are intimately bound to one or more functional filtration components selected from the group consisting of biogenic silica (e.g., diatomite, rice hull ash, sponge spicules), natural glass (e.g.Type: GrantFiled: September 2, 1998Date of Patent: March 30, 2004Assignee: Advanced Minerals CorporationInventors: Scott K. Palm, Timothy R. Smith, Jerome C. Shiuh, John S. Roulston
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Patent number: 6710002Abstract: A process for regenerating a zeolite catalyst comprises the following stages: (I) Heating a partially or completely deactivated catalyst to 250-600° C. in an atmosphere which contains less than 2% by volume of oxygen, (II) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from 0.1 to 4% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof, and (III) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from more than 4 to 100% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof.Type: GrantFiled: February 4, 2002Date of Patent: March 23, 2004Assignee: BASF AktiengesellschaftInventors: Georg Heinrich Grosch, Ulrich Mueller, Andreas Walch, Norbert Rieber, Wolfgang Harder