Patents Examined by Christopher A. Henderson
  • Patent number: 6147176
    Abstract: Water-soluble, branched, high molecular weight, cationic and non-ionic polymeric flocculants capable of manifesting their full performance potential without shearing are produced by polymerizing ethylenically unsaturated cationic and non-ionic monomers and a branching agent in the presence of a chain-transfer agent. They are useful as flocculating agents for releasing water from dispersions of suspended solids.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: November 14, 2000
    Assignee: Cytec Technology Corp.
    Inventors: Roger Edgar Neff, Joseph Jacinto Pellon, Roderick Glyn Ryles
  • Patent number: 6147164
    Abstract: Cold flow is a problem that is commonly encountered in the handling and storage of low molecular weight linear rubbers, such as low vinyl polybutadiene rubber and isoprene-butadiene rubber. This invention is based upon the unexpected discovery that the cold flow of such rubbery polymers can be greatly reduced by incorporating a small block of polystyrene therein. The rubbery polymers of this invention which exhibit a low level of cold flow can be synthesized by simply terpolymerizing 1,3-butadiene, isoprene and from about 0.5 phm to about 3 phm of styrene under anionic polymerization conditions in the absence of a polar modifier. It is preferred to utilize batch polymerization techniques. However, continuous polymerization techniques can also be utilized. This invention more specifically disclosed a rubbery polymer which is comprised of polymer chains containing repeat units which are derived from 1,3-butadiene, isoprene and from about 0.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: November 14, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Wen-Liang Hsu, Adel Farhan Halasa
  • Patent number: 6140427
    Abstract: New vulcanization accelerators, corresponding to the formula ##STR1## are particularly suitable for the production of vulcanized rubbers modified with lateral polar groups.
    Type: Grant
    Filed: September 22, 1993
    Date of Patent: October 31, 2000
    Assignee: Bayer AG
    Inventors: Thomas Scholl, Hermann-Josef Weidenhaupt, Stefan Kelbch, Hans-Wilhelm Engels
  • Patent number: 6140424
    Abstract: Thermoplastic elastomer compositions which have good high temperature end use and good oil swell resistance are made by blending a high melting thermoplastic polymer containing a non-polar rubber and a polar rubber. Alternatively, a high melting thermoplastic polymer containing a non-polar rubber or a polar rubber or both is blended with a polyolefin thermoplastic polymer containing a non-polar rubber, or a polar rubber, or both. The composition is dynamically vulcanized. The cured multi-component thermoplastic elastomer compositions exhibit good end use properties such as hardness, tensile strength, modulus, flexibility.
    Type: Grant
    Filed: March 26, 1999
    Date of Patent: October 31, 2000
    Assignees: Advanced Elastomer Systems, L.P., Exxon Chemical Patents, Inc.
    Inventors: Raman Patel, Sabet Abdou-Sabet, Hsien-Chang Wang
  • Patent number: 6136925
    Abstract: The invention relates to separating materials based on supports containing hydroxyl groups, whose surface [sic] are coated with covalently bound polymers, and to processes for their preparation. The separating materials are characterized in that the polymers consist of identical recurring units of the formula I.brket open-st.CH.sub.2 --CHX.brket close-st..sub.n (I)in whichX is CO--NH--CH.sub.2 --CH.sub.2 --SO.sub.3 H andn is 2-100.
    Type: Grant
    Filed: July 22, 1997
    Date of Patent: October 24, 2000
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Egbert Muller, Margot Mack, Lothar Britsch
  • Patent number: 6133413
    Abstract: Devulcanized rubber in which sulfuric crosslinking bonds are cut and which contains carbon black particles having very small diameters. Vulcanized rubber of discarded products is devulcanized by heating it at a temperature of 180.degree. C. --350.degree. C. and applying a shearing pressure of 10-150 kg/cm.sup.2 thereto. Reclaimed rubber products are manufactured by vulcanizing and molding, into desired shapes, a material made of only devulcanized rubber in which sulfuric crosslinking bonds are cut and which contains carbon black particles having very small diameters or a material made of the devulcanized rubber mixed with virgin unvulcanized rubber.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: October 17, 2000
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Toyoda Gosei Co., Ltd.
    Inventors: Makoto Mouri, Arimitsu Usuki, Atsushi Murase, Norio Sato, Yasuyuki Suzuki, Masao Owaki, Kazuya Watanabe, Hidenobu Honda, Katsumi Nakashima, Katsumasa Takeuchi, Masayoshi Ichikawa
  • Patent number: 6121390
    Abstract: There is provided a polymer scale deposition preventive agent, comprising an alkaline solution of a condensation product having a molecular weight of 500 to 1,000,000 obtained by condensing a dimer compound of 2,3-dihydroxynaphthalene with formaldehyde. By polymerizing vinyl chloride or a monomer mixture containing vinyl chloride in a polymerization vessel wherein a coating film made of said polymer scale deposition preventive agent has been formed on the inner wall surface and the like, polymer scale is effectively prevented from depositing not only on an agitation apparatus but also on areas near the interface between a gas phase and a liquid phase, which prevention of the polymer scale deposition is conventionally difficult. Thus, a vinyl chloride polymer can be obtained which contains colored foreign matters, fish eyes, etc. in small amounts and is small in initial discoloration and is good in quality.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: September 19, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshihide Shimizu, Tatsuya Fujimoto, Seiji Fukuda
  • Patent number: 6121397
    Abstract: A process for the preparation of a thermoplastic resin, or thermoplastic resins comprising:forming, or providing a miniemulsion comprised of a mixture of an oligomeric compound of the formula R-SFR, wherein R is an oligomeric compound comprised of from about 1 to about 30 monomer units and optionally a covalently bonded free radical initiator compound, -SFR is a covalently bound stable free radical end group, and at least one free radical polymerizable monomer compound, and a surfactant; andheating the miniemulsion wherein there results a latex thermoplastic resin or a latex of thermoplastic resins with a high monomer to polymer conversion of about 85 to about 100 percent and a narrow polydispersity of from about 1.1 to about 2.0.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: September 19, 2000
    Assignee: Xerox Corporation
    Inventors: Paula J. MacLeod, Peter G. Odell, Francisco E. Torres, Michael K. Georges
  • Patent number: 6117222
    Abstract: Water-based, water-fast ink compositions are provided. The compositions contain an aqueous liquid vehicle, a colorant, e.g., a pigment, dye or stain, and a binder material capable of ionically or physically entrapping the selected colorant. The binder material contains two ionically associated components which form a matrix, and comprises either a combination of a monomeric polyacid and a monomeric polybase, or a combination of a basic polymer and an organic acid.
    Type: Grant
    Filed: November 18, 1997
    Date of Patent: September 12, 2000
    Assignee: SRI International
    Inventors: Asutosh Nigam, Subhash Narang, Sei-ichi Yokoi, Sivapackia Ganapathiappan, Jitender Mohan Khurana
  • Patent number: 6114459
    Abstract: An acrylic elastomer obtained by copolymerization of about 60 to about 99.9% by weight of at least one of alkyl acrylate and alkoxyalkyl acrylate; about 10 to about 0.1% by weight of a halogen-containing vinyl compound having a secondary or tertiary halogenoalkyl group; and about 30 to 0% by weight of a monomer copolymerizable with the acrylate and the vinyl compound, sum total being 100% by weight, is an acrylic elastomer containing the halogen-containing vinyl compound as a cross-linking site monomer capable of forming an active halogen group cross-linkable with an organic peroxide or the like, and has a high vulcanization torque.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: September 5, 2000
    Assignee: Nippon Mektron Limited
    Inventors: Yoshihiro Kuzumaki, Eiji Komiyama, Kuniyoshi Saito, Jun Okabe
  • Patent number: 6114499
    Abstract: A process for the preparation of branched thermoplastic resins comprising: heating a mixture of an unsaturated resin, a free radical initiator, and a stable free radical agent; adding to the heated mixture at least on polymerizable monomer; and cooling the mixture, wherein the resulting product is a branched thermoplastic resin with arms or branches comprised of polymerized monomer with substantially uniform length and narrow polydispersity.
    Type: Grant
    Filed: April 21, 1999
    Date of Patent: September 5, 2000
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Karen A. Moffat, Marko D. Saban, Richard P. N. Veregin, Michael K. Georges, Gordon K. Hamer, Toyofumi Inoue, Stephan V. Drappel
  • Patent number: 6111026
    Abstract: The invention relates to monomers derived from perhalogenated sultones, to a process for their preparation, to the polymers obtained from the said monomers and to their use for the production of ion-conductive materials.The monomers are compounds corresponding to the formula A--CFX--SO.sub.2 Z in which A denotes one groups [sic] R.sup.3 --O--CF.sub.2 -- or R.sup.3 -- or R.sup.1 R.sup.2 N--CO--; Z denotes F, Cl, --OSi(CH.sub.3).sub.3 or an ionic group, Z being other than F when A denotes R.sup.3 --O--CF.sub.2 -- or R.sup.3 --; X denotes F, Cl, H or R.sub.F, X being R.sub.F when A denotes R.sup.3 --; the radicals R.sup.1, R.sup.2 and R.sup.3 are chosen from polymerizable nonperfluorinated organic radicals; R.sub.F is chosen from perfluoroalkyl radicals and perfluoroaryl radicals.The polymers obtained from these monomers can be employed for the production of ion-conductive materials.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: August 29, 2000
    Assignees: Centre National de la Recherche Scientifique, Hydro-Quebec
    Inventors: Michel Armand, Jean-Yves Sanchez, Salime Sylla
  • Patent number: 6111019
    Abstract: This invention is for LLDPE blends with an ethylene-norbornene copolymer for resins and improved toughness and processibility for film production. This invention provides LLDPE based resins which are significantly improved with respect to their capability to be fabricated into a film layer, particularly by a blown bubble extrusion technique. Films prepared of the LLDPE/E-NB melt blended resins of this invention are significantly improved with respect to certain of their film properties, such as tear strength, without detracting from the beneficial properties that a LLDPE otherwise provides to a film.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: August 29, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Palanisamy Arjunan, Wai Yan Chow, Bruce Allan Harrington, Yu Feng Wang, Henry Yang
  • Patent number: 6107425
    Abstract: The invention provides inter alia new methods to produce aqueous developable resin binders for negative-acting photoresists. The methods in general comprise free radical polymerization of one or more types of monomers in the presence of a free radical polymerization control agent, particularly a nitroxide polymerization control agent such as a piperidinyloxy (N-oxy) free radical, and wherein at least one of the monomer types contains a moiety that enables aqueous solution development of a photoresist composition containing the formed polymer.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: August 22, 2000
    Assignee: Shipley Company, L.L.C.
    Inventors: Roger F. Sinta, George G. Barclay, Jacque H. Georger, Jr., Mark D. Denison, Sheri L. Ablaza
  • Patent number: 6103633
    Abstract: A new method of cleaning metal precipitates after the etching of metal lines using a two-step process is described. Semiconductor device structures are provided in and on a semiconductor substrate. The semiconductor device structures are covered with an insulating layer. A barrier metal layer is deposited overlying the insulating layer. A metal layer is deposited overlying the barrier metal layer wherein metal precipitates form at the interface between the barrier metal layer and the metal layer. The metal layer is covered with a layer of photoresist which is exposed to actinic light and developed and patterned to form the desired photoresist mask. The metal layer is etched away where it is not covered by the photoresist mask to form metal lines whereby the metal precipitates are exposed on the surface of the barrier metal layer.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: August 15, 2000
    Assignee: Taiwan Semiconductor Manufacturing Company
    Inventors: Yun-Hung Shen, Sheng-Liang Pan
  • Patent number: 6100355
    Abstract: Process for the polymerization of acrylic monomers in aqueous suspension, wherein at least a comonomer has a solubility in water of at least 5 g per 100 g of water, to obtain copolymers containing the hydrosoluble comonomer up to 60% by weigh, in the presence of a radical initiator soluble in The monomer and of a polymeric suspending agent selected from the homopolymer of a compound of formula: ##STR1## wherein: R.sub.1 is H or CH.sub.3 ; R.sub.2 and R.sub.3, equal or different, are H or alkyls C.sub.1 -C.sub.8, optionally branched when possible; M is an alkaline or alkaline-earth metal or ammonium and A is NH, O or NCH.sub.
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: August 8, 2000
    Assignee: Atohaas Holdings C.V.
    Inventors: Pasquale Relvini, Fabio Giberti
  • Patent number: 6096847
    Abstract: The present invention relates to novel low molecular weight, structured polymer compositions. The invention also relates to methods for inhibiting scale formation, precipitation or deposition; increasing dispersion of insoluble precipitates in process waters; treating cooling and boiler water; and reducing the viscosity of mineral slurries using the aforementioned polymer compositions.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: August 1, 2000
    Inventor: Janice E. LoSasso
  • Patent number: 6096233
    Abstract: The present invention provides a wet etching method applied to a thin, including the steps of (a) setting in advance an etching rate of said thin film in view of a kind of the thin film to be etched, components of said etchant solution, and temperature, (b) loading the substrate on a spin chuck such that the surface having the thin film formed thereon faces upward and, (c) detecting a thickness of the thin film in at least a peripheral portion and a central portion of the substrate.
    Type: Grant
    Filed: September 23, 1997
    Date of Patent: August 1, 2000
    Assignee: Tokyo Electron Limited
    Inventors: Hiroki Taniyama, Miyako Yamasaka, Hiroyuki Kudou, Akira Yonemizu
  • Patent number: 6090899
    Abstract: A high-flow concrete additive comprises a polymer of 10-100 wt % of an N-vinylacetamide, 0-50 wt % of a compound CH.sub.2 .dbd.CR.sup.3 X.sup.1 R.sup.4 SO.sub.3 X.sup.2 wherein R.sup.3 is hydrogen or methyl, R.sup.4 is alkylene of 1 to 4 carbon atoms, X.sup.1 is CONH or COO, and X.sup.2 is hydrogen, an alkali metal, ammonium salt or organic ammonium salt, and 0-40 wt % of a compound CH.sub.2 .dbd.CR.sup.5 X.sup.3 wherein R.sup.5 is hydrogen or methyl and X.sup.3 is CN, COOR.sup.6, CONH.sub.2, CONHR.sup.7, CONR.sup.8 R.sup.9, COR.sup.10, OCOR.sup.11 or OR.sup.12, in which R.sup.6 is hydrogen, an alkali metal, ammonium salt, organic ammonium salt or alkyl group of 1 to 4 carbon atoms, R.sup.7, R.sup.8 and R.sup.9 are alkyl groups of 1 to 4 carbon atoms, and R.sup.10, R.sup.11 and R.sup.12 are alkyl groups of 1 to 4 carbon atoms.
    Type: Grant
    Filed: August 7, 1996
    Date of Patent: July 18, 2000
    Assignee: Showa Denko K.K.
    Inventors: Takanori Futami, Tetsuhiko Yamaguchi, Hirotaka Tagoshi
  • Patent number: 6090193
    Abstract: Water-based, water-fast ink compositions are provided. The compositions contain an aqueous liquid vehicle, a colorant, e.g., a pigment, dye or stain, and a binder material capable of ionically or physically entrapping the selected colorant. Certain novel polymers are provided as well.
    Type: Grant
    Filed: October 3, 1997
    Date of Patent: July 18, 2000
    Assignee: SRI International
    Inventors: Asutosh Nigam, Subhash Narang, Sei-ichi Yokoi, Sivapackia Ganapathiappan, Jitender Mohan Khurana