Patents Examined by Christopher D. Rodee
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Patent number: 9377705Abstract: A toner containing a toner particle containing a binder resin, wherein the binder resin contains a styrene-acrylic resin and a crystalline resin, and the crystalline resin is a block polymer or a graft polymer in which the mass ratio between the crystalline segment and an amorphous segment is 30:70 to 90:10, and wherein, in the total heat flow measured for the binder resin by a temperature-modulated differential scanning calorimeter, the peak temperature of an endothermic peak is from 55.0° C. to 90.0° C., and the percentage of the endothermic quantity of the endothermic peak in the reversing heat flow with respect to the endothermic quantity of the endothermic peak in the total heat flow is from 0.0% to 35.0%.Type: GrantFiled: November 26, 2014Date of Patent: June 28, 2016Assignee: CANON KABUSHIKI KAISHAInventors: Tsutomu Shimano, Masatake Tanaka, Naoya Isono, Shintaro Noji, Yu Yoshida
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Patent number: 9377708Abstract: A toner has toner particles including a binder resin, a colorant, an ester wax and a hydrocarbon wax; and inorganic fine particles. The ester wax includes an ester compound having a structure represented by formula (1): R1—CO—O—(CH2)x—O—OC—R2; or formula (2): R3—O—OC—(CH2)x—CO—O—R4. The ester wax includes an ester compound having a highest abundance rate in an amount of 40% to 80% by mass with respect to a total amount of the ester wax in a composition distribution. The ester wax has, in differential scanning calorimetry, a peak top temperature of an endothermic peak of 65° C. to 80° C. In differential scanning calorimetry, the toner has only one endothermic peak derived from the waxes. A relationship: 3.0?(Tw?Tt)?8.0 is satisfied.Type: GrantFiled: September 3, 2014Date of Patent: June 28, 2016Assignee: CANON KABUSHIKI KAISHAInventors: Michihisa Magome, Tomohisa Sano, Kozue Uratani
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Patent number: 9360785Abstract: Disclosed are a toner for electrostatic image development and an image formation process using the same which can achieve high varnish application property and high adhesion of a heat-fixed image to a varnish layer even when the varnish layer is formed on the fixed image formed by an image formation process of an electrophotographic system. The toner for electrostatic image development includes toner particles containing at least a binder resin, a colorant and a parting agent, and the binder resin contains a polyfunctional acrylate-modified polyester resin obtained by modification with a polyfunctional acrylate compound. In the toner for electrostatic image development, it is preferable that the toner particles have a core-shell structure, in which the surface of a core particle is coated with a shell layer, and the polyfunctional acrylate-modified polyester resin is contained in the shell layer.Type: GrantFiled: May 21, 2014Date of Patent: June 7, 2016Assignee: KONICA MINOLTA, INC.Inventors: Hitomi Motani, Ito Koga, Tomomi Oshiba, Kishio Tamura
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Patent number: 9335647Abstract: An electrostatic charge image developing toner includes toner particles containing a binder resin containing a polyester resin, a particle of at least one selected from a styrene-(meth)acrylic resin particle and an acrylic resin particle, and a brilliant pigment.Type: GrantFiled: September 3, 2014Date of Patent: May 10, 2016Assignee: FUJI XEROX CO., LTD.Inventors: Daisuke Noguchi, Masaru Takahashi, Atsushi Sugitate, Shuji Sato
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Patent number: 7348115Abstract: An electrophotographic photoconductor, including an electrically conductive substrate, an undercoat layer containing a filler and a binder resin and provided on the substrate, and a photoconductive layer provided on the undercoat layer and containing a binder resin. At least one compound selected from crown ethers, polyalkyleneglycol ethers, polyethyleneglycol monocarboxylic acid esters, polyethyleneglycol dicarboxylic acid esters, and hydroxy-terminated random or block copolymers containing oxypropylene and oxyethylene groups is incorporated into (a) the undercoat layer or (b) into a charge generating layer of the photoconductive layer. In the case of (a), the photoconductive layer is a dried coating of a composition containing at least one solvent selected from cyclic ethers, ketones and aromatic hydrocarbons.Type: GrantFiled: March 29, 2005Date of Patent: March 25, 2008Assignee: Ricoh Company, Ltd.Inventors: Hirofumi Yamanami, Yukari Yamada
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Patent number: 7314695Abstract: A toner for developing electrostatic charge images that exhibits superior fixability at low temperature so as to realize satisfactory fixing performance even with less energy, that exhibits high stress resistance so as to be free from blade contamination by molten toner, and that exhibits excellent performances in any environmental conditions. In particular, a toner for developing an electrostatic charge images, comprising at least a binder resin, a colorant and a charge control agent, wherein a low-molecular-weight polymer having functional groups is used at least as the charge control agent and a cycloolefin copolymer resin is used at least as the binder resin.Type: GrantFiled: April 10, 2003Date of Patent: January 1, 2008Assignees: Tomoegawa Paper Co., Ltd, Ticona GmbHInventors: Yoshiaki Harada, Toru Nakamura
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Patent number: 7306885Abstract: The present invention provides toners of different colors in which coloring agents of at least four unicolors are internally added to, respectively, and hydrophobic silica particles and metallic soap particles are externally added to toner mother particles, wherein color superposition of the toners is conducted during development of latent images on a latent image carrier or during transfer to a recording medium after the development, being characterized in that the difference (absolute value) between the work functions of two of said toners is 0.02 eV or more, the color superposition is conducted with the toners sequentially from the toner having the largest work function in descending order of work function of the toners, and the difference (absolute value) between the work function of the toner mother particles and the work function of the metallic soap particles is 0.Type: GrantFiled: August 17, 2006Date of Patent: December 11, 2007Assignee: Seiko Epson CorporationInventor: Nobuhiro Miyakawa
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Patent number: 7300737Abstract: The present invention provides a toner that exhibits excellent low-temperature fixing properties, offset resistance, and has excellent storage stability in a developing machine. The toner has, in a DSC curve obtained by measuring the toner with differential scanning calorimeter, a glass transition temperature (Tg1) measured in a first scan of 50.0 to 70.0° C. and a temperature difference (Tg1?Tg2) between the glass transition temperature (Tg1) measured in the first scan and a glass transition temperature (Tg2) measured in a second scan ranging from 3.0 to 20.0° C.Type: GrantFiled: March 20, 2007Date of Patent: November 27, 2007Assignee: Canon Kabushiki KaishaInventors: Yasukazu Ayaki, Koji Abe
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Patent number: 7291437Abstract: A toner process comprising mixing a colorant dispersion with a latex, a wax dispersion, and a coagulant, and wherein the polymer latex selected possesses a weight average molecular weight of from about 20,000 to about 55,000, a number average molecular weight of from about 5,000 to about 18,000, an onset glass transition temperature Tg of from about 40° C. to about 80° C., and a particle size distribution PSD of from about 50 to about 500 nanometers.Type: GrantFiled: April 14, 2003Date of Patent: November 6, 2007Assignee: Xerox CorporationInventors: Amy A. Grillo, Peter V. Nguyen, Donald Riley, Allan K. Chen, Emily L. Moore, Tie Hwee Ng, Chieh-Min Cheng
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Patent number: 6790572Abstract: An electrophotographic photoreceptor including an electroconductive substrate, a photosensitive layer located overlying the electroconductive substrate, and optionally a protective layer overlying the photosensitive layer, wherein an outermost layer of the photoreceptor includes a filler, a binder resin and an organic compound having an acid value of from 10 to 700 mgKOH/g. The photosensitive layer can be the outermost layer. A coating liquid for an outermost layer of a photoreceptor including a filler, a binder resin, an organic compound having an acid value of from 10 to 700 mgKOH/g and plural organic solvents. A method for preparing a photoreceptor including forming a photosensitive layer, and coating the coating liquid on the photosensitive layer. An image forming method and apparatus and a process cartridge using the photoreceptor are also provided.Type: GrantFiled: November 2, 2001Date of Patent: September 14, 2004Assignee: Ricoh Company LimitedInventors: Nozomu Tamoto, Tetsuro Suzuki, Hiroshi Tamura, Tatsuya Niimi, Akihiko Matsuyama, Eiji Kurimoto, Hidetoshi Kami
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Patent number: 6391506Abstract: The present invention discloses a carrier, which comprises a core and a resin coating layer formed thereon containing electroconductive powder, wherein, when the magnetic brush is formed only of the core, the dynamic electrical resistance of the core forming the magnetic brush under an electric field of 104 V/cm is 1 &OHgr;·cm or less and the electrical resistance of the resin coating layer is from 10 to 1×108 &OHgr;·cm, a developer using the carrier, and an image-forming method using the developer. Owing to the present invention, a superior solid image, which is free of brush marks and carrier beads carry over, can be obtained.Type: GrantFiled: July 2, 1997Date of Patent: May 21, 2002Assignee: Fuji Xerox Co., Ltd.Inventors: Kazuhiko Yanagida, Suk Kim, Shigeru Inaba, Taku Fukuhara, Yasuhiro Oda
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Patent number: 6329115Abstract: A toner for use in electrophotography has toner particles, each toner particle containing a resin, a colorant, a fluidity-imparting agent and a volatile organic component which is in an amount of 100 ppm or less per unit amount of the toner particles, and having an average spherical degree in a range of 100 to 150. In addition, the above-mentioned toner is produced by preparing primary particles, each particle including a resin and a colorant, depositing a fluidity-imparting agent on the surface of the primary particles, dispersing the fluidity-imparting agent deposited primary particles in a liquid containing a dispersant, in which liquid the resin is insoluble, thereby preparing a dispersion of the primary particles, heating the dispersion with stirring, and cooling the dispersion, thereby obtaining toner particles for use in the toner.Type: GrantFiled: September 11, 1997Date of Patent: December 11, 2001Assignee: Ricoh Company, Ltd.Inventor: Hiroshi Yamashita
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Patent number: 6326110Abstract: In accordance with the present invention, a method of electrophotographically manufacturing a luminescent screen assembly on an interior surface of a faceplate panel 17 of a color CRT 10 includes the steps of: coating the surface of the panel with a conductive solution to form a volatilizable organic conductive layer 32, and overcoating the organic conductive layer 32 with a photoconductive solution to form a volatilizable photoconductive layer 34. The conductive solution comprises the organic polymer 3,4-polyethylene dioxythiophene polystyrene sulphonate (PEDT/PSS); a methanol-soluble polymer or co-polymer selected from the group consisting of polyvinylpyrrolidone (PVP), poly (vinyl pyridine-co-vinyl acetate) (PVPy-VAc), polymethacrylic acid (PMAA), poly (hydroxyethylacrylate-co-methacrylic acid) (PHEA-MAA) and poly (hydroxyethyl methacrylate) (PHEMA) to reduce organic residue; and a solvent.Type: GrantFiled: August 23, 1999Date of Patent: December 4, 2001Assignee: Thomson Licensing S.A.Inventors: Pabitra Datta, Gregory James Cohee, Nitin Vithalbhi Desai, Steven Anthony Colbert, Kangning Liang
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Patent number: 6232027Abstract: A toner having a negative triboelectric chargeability is constituted by at least a binder resin, a colorant and an organic metal compound. The toner is characterized by: (a) the organic metal compound is an organic zirconium compound comprising a coordination or/and a bonding of zirconium and an aromatic compound as a ligand or/and an acid source selected from the group consisting of aromatic diols, aromatic hydroxycarboxylic acids, aromatic monocarboxylic acids, and aromatic polycarboxylic acids, (b) the binder resin is a resin selected from the group consisting of (i) a polyester resin and (ii) a hybrid resin component comprising a polyester unit and a vinyl polymer unit, (c) the binder resin has an acid value of 2-50 mgKOH/g, and (d) the toner contains a TFT (tetrahydrofuran)-soluble content providing a GPC (gel permeation chromatography) chromatogram exhibiting a main peak in a molecular weight range of 3,000-20,000 and including 3-25% of a component having molecular weights of at least 5×105.Type: GrantFiled: May 26, 1999Date of Patent: May 15, 2001Assignee: Canon Kabushiki KaishaInventors: Satoshi Matsunaga, Toshiaki Nakahara, Yuichi Mizoh, Hirohide Tanikawa, Minekazu Endo, Tadashi Doujo, Nene Shibayama
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Patent number: 6214507Abstract: A toner composition comprised of binder, colorant, and a surface additive of a coated silica and wherein said silica possesses a BET surface area, in m2/g of from about 35 to about 65, a bulk density, in grams/liter, of from about 40 to about 60, and wherein the size diameter determined from the BET measurement is from about 20 to about 100 nanometers.Type: GrantFiled: August 11, 1998Date of Patent: April 10, 2001Assignee: Xerox CorporationInventors: Jeffrey H. Sokol, Edward J. Gutman
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Patent number: 6214512Abstract: In an image forming method having the step of developing an electrostatic latent image on an electrostatic latent image carrying member using a toner layer on a developer carrying member, the step of transferring the developed toner image onto a belt transfer body 7 which is a first transfer body, and the step of transferring the toner image formed on the belt transfer body 7 onto a second transfer body 11, the surface resistance of the belt transfer body 7 is 108 to 1015 &OHgr;·cm, the toner is composed of at least resin particles containing a binding resin and a coloring material, and an additive, and the additive contains particles whose volume resistance is 107 to 1013 &OHgr;·cm.Type: GrantFiled: January 14, 1998Date of Patent: April 10, 2001Assignee: Fuji Xerox Co., Ltd.Inventors: Hiroshi Takano, Yuka Ishihara, Takashi Imai, Masanori Ichimura
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Patent number: 6200714Abstract: An electrophotographic photoconductor includes a phosphinate additive in a photosensitive film that improves the stability of the coating liquid for the photosensitive film. The electrophotographic photoconductor includes an electrically conductive substrate and a photosensitive film on the substrate. The photosensitive film contains a charge generation agent and a phosphinate compound. The photoconductor may be of either a monolayer or a laminate construction. In the case of a laminate type photoconductor, the phosphinate compound is incorporated into the charge transport layer. A method of making an electrophotographic photoconductor adds a phosphinate additive to the coating liquid for a photosensitive film to improve stability of the coating liquid. The method involves producing a coating liquid containing a phosphinate compound and coating a conductive substrate with the coating liquid to form a photosensitive film.Type: GrantFiled: December 1, 1999Date of Patent: March 13, 2001Assignee: Fuji Electric Imaging Device Co., Ltd.Inventors: Yoichi Nakamura, Teruo Sasaki, Kenichi Hara, Hideki Kina, Akira Ootani
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Patent number: 6200715Abstract: An electrophotographic imaging member including a support member, a charge generating layer and a charge transport layer, the charge transport layer including a cross linked matrix derived from a cross linkable aromatic polymer with substituent groups containing unsaturated carbon to carbon double bond, the substituent groups being free of any urethane linkage and attached to phenylene.Type: GrantFiled: July 29, 1999Date of Patent: March 13, 2001Assignee: Xerox CorporationInventors: Timothy J. Fuller, John F. Yanus, Damodar M. Pai, Markus R. Silvestri, Ram S. Narang, William W. Limburg, Dale S. Renfer
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Patent number: 6197467Abstract: Charge control agent comprising a metal complex salt compound having a monoazo compound as a ligand, wherein the metal complex salt compound is amorphous, and which is excellent in charge control properties, heat resistance and light fastness, good in dispersibility in, and wettability with, toner resins, hardly damages the photoreceptor when used in a toner, and is unlikely to drop from toner particles during charging; process for manufacturing the charge control agent, comprising subjecting a crystalline metal complex salt compound having a monoazo compound as a ligand to wet milling in an organic solvent, or dissolving the crystalline metal complex salt compound in an organic solvent, and subsequently re-dispersing it in water; and toner for developing electrostatic images comprising said charge control agent, a toner resin, and a coloring agent, and method of use thereof.Type: GrantFiled: April 22, 1998Date of Patent: March 6, 2001Assignee: Orient Chemical IndustriesInventors: Shun-ichiro Yamanaka, Kazuaki Sukata, Masashi Yasumatsu
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Patent number: 6197470Abstract: A toner is disclosed which contains toner particles and a hydrophobic fine silica powder. The hydrophobic fine silica powder has the following hydrophobic properties: the transmittance of the measuring sample fluid as defined in the specification at a methanol content of from 60% by volume to 72% by volume is 95% or more, and the transmittance of the measuring sample fluid at a methanol content of 74% by volume is 90% or more. Also, disclosed are an image forming method and an apparatus unit making use of the toner.Type: GrantFiled: February 22, 2000Date of Patent: March 6, 2001Assignee: Canon Kabushiki KaishaInventor: Osamu Tamura