Abstract: A naphtha feed is contacted in a penultimate reforming stage under catalytic reforming conditions with a first catalyst. The effluent from the penultimate reforming stage is contacted in a final reforming stage under catalytic reforming conditions and at substantially the same pressure as is maintained in the penultimate reforming stage with a second catalyst. The reforming pressure is selected to provide optimal OB/CD production of product reformate of a desired RON from the final stage.
Type:
Grant
Filed:
March 2, 1990
Date of Patent:
December 17, 1991
Assignee:
Chevron Research & Technology Company
Inventors:
Jules M. Kline, Stephen J. Miller, Bernard F. Mulaskey
Abstract: A method for improving the activity of a dehydrogenation and dehydrocyclization catalyst composition and a process for improving the conversion and selectivity of paraffin hydrocarbons to olefin and aromatic compounds. The novel processes comprise adding calcium aluminate to a catalyst composition comprising a zinc aluminate support and a catalyst metal, and optionally a promoter metal.
Abstract: A terpene compound having the formula (III) is produced by reacting an allylic halide having the formula (I) with a Grignard reagent having the formula (II) in the presence of anhydrous zinc chloride and a copper compound or an organic zinc halide compound having the formula (IV) in the presence of a copper compound, provided that when A-A is C-C, R' is hydrogen and when A-A is C=C, X is chlorine.
Abstract: A method for preparing one or more specific dimethyltetralins from either 5-(o-, m-, or p-tolyl)-pent-1-or -2-ene or 5-phenyl-hex-1- or -2-ene, and optionally for preparing one or more specific dimethylnaphthalenes from the aforesaid dimethyltetralins is disclosed.
Type:
Grant
Filed:
July 20, 1990
Date of Patent:
December 17, 1991
Assignee:
Amoco Corporation
Inventors:
David L. Sikkenga, Joyce D. Lamb, Ian C. Zaenger, Gregory S. Williams
Abstract: Methods are provided for the recovery of aromatic hydrocarbons from the extract phase of aromatic-selective solvent extraction processes which involve withdrawing a vapor side-cut fraction containing aromatic hydrocarbons and solvents from a stripping zone and passing the side-cut fraction to a rectification zone which can be refluxed with aromatic hydrocarbons or aqueous condensate.
Abstract: A MFI-based gallosilicate type catalyst is described.The catalyst is characterized by the following composition expressed by weight:a) 0.1 to 99.49% of a matrix,b) 0.5 to 99.99% of a zeolite having the following approximate chemical formula:M.sub.2/n O, Ga.sub.2 O.sub.3, xSiO.sub.2whereinM represents a proton and/or a metallic cation,n is the valence of said cation,x is a number ranging from 12 to 1,00,the zeolite of MFI structure synthesized in a fluoride medium having a fluorine content ranging from 0.02 to 1.5% by weight incorporated during synthesis.The catalyst is notably used in aromatization reactions of light C.sub.2 -C.sub.4 gases in the presence or not of olefins.
Abstract: Process for the alkylation of aromatic substrates with a C.sub.2 -C.sub.4 alkylating agent over an alkylation catalyst comprising zeolite omega at moderate temperature conditions and under pressure to provide liquid phase conditions.The liquid phase alkylation process is carried out using a plurality of series connected reaction stages operated at an average temperature of no more than 300.degree. C. with the interstage injection of the C.sub.2 -C.sub.4 alkylating agent in a manner to maintain at least 2 mole percent of alkylating agent solubilized in the aromatic substrate.The reaction stages of a multistage system temperature and pressure conditions effective to cause are operated at a pressure above the vapor pressure of the aromatic substrate and below the vapor pressure of the alkylating agent at the alkylation reaction conditions.
Abstract: Inhibition of popcorn polymer growth by treatment with a compound including a Group IV element, and at least one hydrogen bonded to the Group IV element. This compound can be admixed with organic material from which popcorn polymer is formed, or added to a system for the recovery, use or storage of such organic material.
Abstract: Inhibition of popcorn polymer growth by treatment with an inorganic acid ester. This compound can be admixed with organic material from which popcorn polymer is formed, or added to a system for the recovery, use or storage of such organic material.
Abstract: Inhibition of popcorn polymer growth by treatment with an alkyl halide. This compound can be admixed with organic material from which popcorn polymer is formed, or added to a system for the recovery, use or storage of such organic material.
Abstract: An improved process for the hydroconversion of coal comprising pretreating coal in an aqeuous carbon monoxide-containing environment, followed by extracting a soluble hydrocarbon material from the coal, and subsequently hydroconverting the extracted material in a hydroconversion reactor with a high catalyst loading to obtain a nearly finished product with low heteroatom levels. The extracted material consists of a relatively hydrogen-rich material which is readily converted to valuable liquid products in high yield. The residue from the extraction stage is relatively hydrogen deficient material which can be gasified to produce hydrogen and carbon monoxide for the hydroconversion and pretreatment stages, respectively.
Abstract: A method for suppressing dust in grain handling includes applying an edible foam so that it penetrates the grain to reach the dust particles.
Abstract: A process for preparing 1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene of the formula I ##STR1## comprises reacting p-cymene of the formula II ##STR2## with a hexene of the formula IIIa, IIIb and/or IIIc ##STR3## in the presence of a catalytic amount of aluminum halide and a catalytic amount of a triphenylmethyl compound of the formula IV ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 are each, independently of one another, hydrogen, C.sub.1 -C.sub.4 -alkyl, nitro or halogen and X is hydrogen or halogen.
Type:
Grant
Filed:
March 13, 1991
Date of Patent:
November 26, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Huellmann, Herbert Mayr, Rainer Becker
Abstract: A process for ethylating detergent-range olefins which comprises contacting a detergent-range olefin with ethylene in the presence of a catalyst prepared by impregnating a porous alumina support with a metal compound decomposable to an oxide upon calcination wherein said metal is selected from the group consisting of potassium, rubidium, cesium and mixtures thereof, and subsequently calcining the resulting material at a temperature of from about 450.degree. C. to about 750.degree. C.
Abstract: A hydrocarbon is converted to a higher-molecular-weight hydrocarbon having greater unsaturation in compact and efficient apparatus, which provides for recirculating materials in a continuous process.
Abstract: A process for making an .alpha.-olefin oligomer comprises contacting an .alpha.-olefin monomer containing from about 6 to 20 carbon atoms with a catalyst comprising boron trifluoride and an alcohol alkoxylate so as to form an oligomer product.
Abstract: The present invention relates to a process and apparatus for injecting sludge into the vapor phase of a coking process to vaporize the sludge while minimizing the carryover of solids and coke to downstream equipment. The process and apparatus are applicable to use in both fluid and delayed coking operations and are useful on various sludges which can be found in refineries or petrochemical plants.
Abstract: The invention relates to a process for dewaxing an atomspheric or a vacuum gas oil in the presence of at least one catalyst comprising:a/ 2 to 99.4% by weight of a synthetic crystalline zeolite of the ferrisilicate type, the approximate chemical formula of the zeolite being M.sub.2/n O, Fe.sub.2 O.sub.3, xSiO.sub.2 where M represents a proton and/or a metal cation, n is the valence of M and x is a number ranging from 40 to 1,000, the zeolite having been synthetized in a fluoride medium and showing a fluorine content ranging from about 0.01 to 1.6% by weight, the zeolite having an X-ray diffraction diagram represented in Table 1 of the description;b/ 0.1 to 97.5% by weight of a matrix; andc/ at least one promoter selected from the group consisting of Pd, Pt, NiO, CoO, MoO.sub.3 and WO.sub.3.
Abstract: Disclosed is a process for preparing n-hexenes and high octane blending components from a mixture of C.sub.6 olefin isomers. Also disclosed is a process for preparing 1-hexene from a mixture of C.sub.6 olefin isomers which provides high octane blending components as a by-product.