Abstract: A block copolymer composed of polyphenylene sulfide segments and aromatic sulfide sulfone polymer segments and having a logarithmic viscosity [.xi.], determined at 206.degree. C. for its solution in alpha-chloronaphthalene in a polymer concentration of 0.4 g/100 ml of solution and calculated in accordance with the equation [.xi.]=ln (relative viscosity)/polymer concentration, of 0.03 to 1.0. A resin composition comprising the block copolymer and polyphenylene sulfide and/or an aromatic sulfide sulfone polymer and optionally a filler. The block copolymer and the resin composition have improved mechanical strength and are suitable, for example, for encapsulation of electronic component parts.
Abstract: A process for producing a polyoxymethylene-polyurethane type alloy, which comprises allowing a polyisocyanate compound, a short chain polyol with a molecular weight of 62 to 350, a long chain polyol with a number-average molecular weight of 400 to 5,000, and optionally additives to react with each other in the presence of at least one or polyoxymethylene polymers.
Abstract: Composites of graphite dispersed in a solid matrix of a polymeric resin, wherein intercalated graphite flakes are mixed with a liquid polymeric resin and exfoliated in-situ in the liquid resin during the curing of the resin before complete solidifcation of the resin.
Abstract: Process characterized by dissolving a dye in a solution of organic solvent and an epoxy type polymer, which requires a curing agent in order to create a resultant nanosphere that will crosslink through the action of the curing agent, and not simply as the result of a solvent removal which defined each nanosphere. The dye may be in concentration range of 1% to 50% by weight of solvent, and the organic solvent must have limited solubility in water, typically less than 20%. An initial intermolecular mixing step dissolves dye and epoxy resin within a solvent so as to make a homogeneous solvent/polymer/dye intermediate mixture, that then is dispersed as nanoparticles in water, and thereafter crosslinked. Surfactants may be used to assist in dispersing the dye/polymer/solvent solution into the water continuous phase.
Abstract: A process for preparing a copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sbsb.nwherein x is in the range of 0.5 to 0.001 by reacting a mixture of a diiodoaromatic compound and elemental sulfur which contains less than 0.05 weight percent carbon.
Type:
Grant
Filed:
September 8, 1989
Date of Patent:
July 3, 1990
Assignee:
Eastman Kodak Company
Inventors:
David R. Fagerburg, Joseph J. Watkins, Paul B. Lawrence, Mark Rule
Abstract: Modified polyolefin comprising a polyolefin linked to a hydrolyzable silane which is reactable with polyvinyl alcohol and being chemically bound to polyvinyl alcohol by the silane, and method for preparing the same.
Abstract: A thermosetting powder coating composition which has good handling properties and which has a good blend of physical properties such as appearance, flexibility, hardness, solvent resistance, corrosion resistance and exterior durability is disclosed. The composition comprises a co-reactable particulate mixture of a carboxylic acid group-containing acrylic polymer, a second carboxylic acid group-containing material having sufficient crystallinity to assist in flow of the powder coating compositions and a beta-hydroxalkylamide crosslinking agent.
Type:
Grant
Filed:
September 18, 1989
Date of Patent:
June 26, 1990
Assignee:
PPG Industries, Inc.
Inventors:
Paul H. Pettit, Jr., Debra L. Singer, Marvin L. Kaufman
Abstract: A process is disclosed for preparing an aqueous paint composition including the steps of(a) mixing a pigment powder having a particle size less than about 20 micrometers, a cross-linking agent and an epoxy resin to form a liquid, solvent-free paste;(b) reacting the resultant paste with a secondary amine to provide at least one N-H function per epoxy group of the epoxy resin; and(c) neutralizing the resulting suspension of particles coated with an epoxy-amine adduct and a cross-linking agent.Also provided is a coating process employing the invention aqueous paint composition containing a transesterification-promoting metal compound.
Type:
Grant
Filed:
September 15, 1988
Date of Patent:
June 12, 1990
Assignee:
Shell Oil Company
Inventors:
Henricus P. H. Scholten, Tette J. Dijkstra, Roeland Van Iperen
Abstract: A composition for the adhesive activation of polymeric material. The composition is comprised of a non-resinous quaternary ammonium salt of a polyepoxide wherein the nitrogen atom of the ammonium group is bonded directly to a carbon atom of the polyepoxide and wherein the composition is substantially free of free amine. The composition may be used as a spin finish or topcoat composition and is particularly useful in the preparation of polyethylene terephthalate tire cord which is ultimately incorporated into rubber.
Type:
Grant
Filed:
September 11, 1987
Date of Patent:
June 12, 1990
Assignee:
Celanese Corporation
Inventors:
Norman S. Anderson, Gunilla E. Gillberg-La Force, Edward J. Powers, Anthony W. Yankowsky
Abstract: A process for preparing a substantially straight-chain polyarylene thioether by polymerizing a diphenyldisulfide of the formula ##STR1## in the presence of a lewis acid catalyst at temperatures of between -20.degree. C. and 50.degree. C.
Type:
Grant
Filed:
February 26, 1988
Date of Patent:
June 5, 1990
Assignee:
Idemitsu Petrochemical Company, Limited
Inventors:
Eishun Tsuchida, Hiroyuki Nishide, Kimihisa Yamamoto, Shu YHoshida
Abstract: A composition stabilized against oxidative degradation comprising: a polyolefin, carbon black homogeneously incorporated in said polyolefin, a stabilizing amount of a N-phenyl-N'-(p-toluenesulfonyl)-p-phenylenediamine first stabilizer component incorporated into said polyolefin and a second stabilizer component of at least one amine antioxidant selected from the group consisting of a para-substituted aralkyl-substituted diphenylamine; a para-phenylenediamine and a polymerized dihydroquinoline incorporated into said polyolefin.
Abstract: The invention relates to powder compositions based on polyarylene sulphides, in particular polyphenylene sulphides (PPS) and thermoplastic vinyl polymers and to their use for the preparation of thermoplastic moulding compounds.
Type:
Grant
Filed:
March 31, 1988
Date of Patent:
May 8, 1990
Inventors:
Klaus Struss, Christian Lindner, Karl-Erwin Piejko, Hans-Jurgen Kress, Dieter Wittmann
Abstract: Poly(arylene sulfide)/long carbon fiber laminates containing small amounts of added crack inhibiting agent such as polyethylene have reduced levels of microcracking. The polyethylene can be introduced as a finely divided powder in a slurry prepreg process or can be compounded with the poly(arylene sulfide) and extruded as a film for stacking with carbon fabric.
Abstract: Anionic Emulsions of asphalt, bitumen, or tar which may optionally contain a latex of a rubbery polymer may be set using a destablizing system comprising either an alkali silicofluoride in the presence of a sulfamate or a mixture of an amine in the presence of a divalent metal ion. The setting time for such emulsions can be reduced to less than half an hour.
Type:
Grant
Filed:
September 30, 1987
Date of Patent:
May 1, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Richard B. Moore, Paul L. Fitzgerald, Ernest G. Pole
Abstract: Compositions and a method are provided for forming a coated wood product having the appearance and texture of wood grain, which conceals joints on the wood surface and which is capable of accepting conventional wood stain.
Abstract: Hydrophilic silicone rubber article, the surface of which is hydrophilized partly or completely by reaction (equilibration reaction) with organosiloxanes, the organosiloxanes being synthesized by the reaction of SiH-group-containing siloxanes with allyl compounds which contain protected OH groups. These articles are particularly useful as contact lenses and intraocular lenses.
Type:
Grant
Filed:
August 5, 1988
Date of Patent:
April 24, 1990
Assignee:
Ciba-Geigy Corporation
Inventors:
Horst Schafer, Gerhard Kossmehl, Walter Neumann
Abstract: In a process for partially curing a powdery polyarylene sulfide resin which comprises heating the powdery resin either in the absence or presence of oxygen while agitating so as to attain an increased melt viscosity in a range suitable for further processing or molding of the resin, an improvement comprising that the resin together with an added specific inorganic additive undergoes the partial curing treatment at temperatures in the range of from a temperature just below the melting point of the starting resin down to a temperature lower by 80.degree. C. than said melting point. The additive is selected from the group consisting of silica, hydrophobic silica, talc and calcium carbonate and mixtures thereof.
Abstract: The tendency of poly(arylene sulfide) resin to cause mold corrosion upon molding is inhibited by mixing, prior to said molding, the poly(arylene sulfide) resin and lithium sulfite alone, or a combination of lithium sulfite and alkali or alkaline earth metal carbonates, alkali metal or alkaline earth metal borates, or mixtures thereof.
Abstract: This invention relates to a process for the preparation of polyarylene sulphides by melt condensation, in which the sulphide bridges of the polymer are formed by the splitting off of a compound which is volatile under the reaction conditions.
Type:
Grant
Filed:
November 3, 1988
Date of Patent:
March 27, 1990
Assignee:
Bayer Aktiengesellschaft
Inventors:
Ernst-Ulrich Dorf, Hans-Rudolph Dicke, Volker Eckhardt, Joachim Genz