Patents Examined by David W. Wu
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Patent number: 9067866Abstract: The invention relates to amino(meth)acrylates obtained from the reaction of amines with a mixture of epoxy(meth)acrylates and (meth)acrylated diluent and there use for making flexible varnishes, coatings, adhesives and inks.Type: GrantFiled: June 22, 2007Date of Patent: June 30, 2015Assignee: ALLNEX BELGIUM S.A.Inventors: Francis Bergiers, Thierry Randoux
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Patent number: 9062132Abstract: The present invention provides a dispersion stabilizer having an excellent polymerization stability. When used for suspension polymerization of vinyl compounds even in small amounts, the dispersion stabilizer according to the present invention attains the effects that: with respect to vinyl polymer particles to be obtained, the plasticizer absorptivity is high, leading to easy processing; residual monomer components such as a vinyl compound can be removed easily; the number of coarse particles is small; the obtained particles are as uniform as possible in particle size so that formation of fish-eyes can be prevented. The present invention provides a dispersion stabilizer for suspension polymerization including a polyvinyl alcohol polymer (A) having a saponification degree of 60 mol % or more and a polymerization degree of 200 or more, and a polyvinyl alcohol polymer (C) obtained by esterifying a polyvinyl alcohol polymer (B) having a saponification degree of less than 60 mol % with a carboxylic acid compound.Type: GrantFiled: April 7, 2008Date of Patent: June 23, 2015Assignee: KURARAY CO., LTD.Inventors: Masaki Kato, Masato Nakamae
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Patent number: 9061441Abstract: A method of producing a vinyl alcohol resin having a water content of not higher than 10 wt % by performing a multistage dewatering process by means of a kneading machine. The method permits efficient dewatering of a highly hydrous vinyl alcohol resin to ensure easy production of a lower water content vinyl alcohol resin having a water content of not higher than 10 wt %, thereby reducing production costs.Type: GrantFiled: April 22, 2011Date of Patent: June 23, 2015Assignee: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.Inventors: Keisuke Fujimura, Osamu Hommura, Yasufumi Beniya, Satoshi Matsunuma
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Patent number: 9062143Abstract: Polymer powders comprising in copolymerized form a) one or more vinyl aromatic comonomers, b) one or more 1,3-diene comonomers, c) from 0.1 to 15 percent, based on the total comonomer weight, of one or more comonomers selected from the group consisting of ethylenically unsaturated mono- and dicarboxylic acids and their salts, wherein at least 75 percent of the total number of carboxylic groups present in the polymer are located at the surface of the polymer particles in the powder and at least 75 percent of the carboxylic groups located at the surface of the polymer particles in powder are present in their salt form, and d) from 0 to 40 percent, based on the total comonomer weight, of one or more additional comonomers have an excellent redispersibility in water.Type: GrantFiled: July 29, 2010Date of Patent: June 23, 2015Assignee: Dow Global Technologies LLCInventors: Margarita Perello, Harmut Kühn, Jürgen Dombrowski, Francois M. Casati, Etienne Lazarus, Gerold Lohmüller
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Patent number: 9056974Abstract: The invention relates to the use of an impact-modified acrylic blend with a low level of fluoropolymer to achieve impact resistance and solvent resistance in a capstock formulation. Preferably the acrylic blend contains a methyl methacrylate-based acrylic polymer and polyvinylidene fluoride.Type: GrantFiled: November 21, 2006Date of Patent: June 16, 2015Assignee: Arkema FranceInventors: Adam Toft, Charles C. Crabb, Harold Reid Banyay, Michael Burchill
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Patent number: 9056303Abstract: The present invention relates to a process for the continuous preparation of a catalytic system that can be used for the polymerization of at least one conjugated diene monomer, said catalytic system being based on at least: a preforming conjugated diene; an organic phosphoric acid salt of one or more rare-earth metal(s), said salt being in suspension in at least one saturated aliphatic or alicyclic and inert hydrocarbon-based solvent; an alkylating agent comprising an alkylaluminium having the formula AlR3 or HAlR2; and a halogen donor comprising an alkylaluminium halide; characterized in that it comprises successively in one line (L): (i) a reaction between the preforming conjugated diene, with the solution of the salt of rare-earth element(s) and the alkylating agent, with the alkylation reaction being carried out for a characteristic minimum period of at least 5 minutes in an alkylation reactor (30) composed of at least one well-mixed dynamic mixer; (ii) the addition of said halogen donor to the mixturType: GrantFiled: October 16, 2006Date of Patent: June 16, 2015Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: Helene Parola, Fanny Barbotin, Pierre Kiener, Bernard Anselme, Fabrice Martinet
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Patent number: 9056801Abstract: The present invention provides a method for producing a slurry composition which realizes excellent dispersibility through simple steps. In addition, the present invention provides a slurry composition produced using this method. The present invention provides a method for producing a slurry composition containing inorganic powder, a polyvinyl acetal resin, and an organic solvent, the method comprising the steps of: mixing inorganic powder, a polyvinyl acetal resin (A) and an organic solvent for inorganic dispersion to prepare an inorganic dispersion; mixing a polyvinyl acetal resin (B) and an organic solvent for resin solution to prepare a resin solution; and adding the resin solution to the inorganic dispersion, the polyvinyl acetal resin (A) having a polymerization degree of 200 to 600, the polyvinyl acetal resin (B) having a polymerization degree of 800 to 4000, and an amount of the polyvinyl acetal resin (A) used in preparation of the inorganic dispersion being 0.Type: GrantFiled: March 16, 2010Date of Patent: June 16, 2015Assignee: SEKISUI CHEMICAL CO., LTD.Inventors: Kenichi Ootsuki, Yuki Hirose, Motokuni Ichitani
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Patent number: 9034987Abstract: Disclosed is an adhesive for a polarizing plate that comprises a polyvinyl alcohol-based resin with an acetoacetyl group and an amine-based metal compound crosslinking agent, and a method of manufacturing the same.Type: GrantFiled: January 26, 2007Date of Patent: May 19, 2015Assignee: LG Chem, Ltd.Inventors: Seung-Ae Kim, Kyun-Il Rah
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Patent number: 9023943Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.Type: GrantFiled: November 28, 2011Date of Patent: May 5, 2015Assignee: Ethox Chemicals LLCInventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
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Patent number: 9023930Abstract: The present invention provides a method for producing a slurry composition which realizes excellent dispersibility through simple steps and can maintain high dispersibility over a long term. In addition, the present invention provides a slurry composition produced using this method. The present invention provides a method for producing a slurry composition containing an inorganic powder, a polyvinyl acetal resin, and an organic solvent. The method contains the steps of mixing an inorganic powder, a mixed polyvinyl acetal resin (A) and an organic solvent (i) to prepare an inorganic dispersion; mixing a polyvinyl acetal resin (B) and an organic solvent (ii) to prepare a resin solution; and adding the resin solution to the inorganic dispersion.Type: GrantFiled: September 16, 2011Date of Patent: May 5, 2015Assignee: Sekisui Chemical Co., Ltd.Inventor: Kenichi Ootsuki
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Patent number: 9012542Abstract: Disclosed herein are a homogeneous sulfur-modified polymer composition, a method of preparing sulfur-modified polymer, and an asphaltic concrete mixture.Type: GrantFiled: March 29, 2010Date of Patent: April 21, 2015Assignee: Saudi Arabian Oil CompanyInventors: Ibnelwaleed A. Hussein, Mohammed H. Al Mehthel, Hamad I. Al-Abdul Wahhab, Saleh H. Al Idi, Junaid Saleem Akhtar
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Patent number: 9012570Abstract: The present invention provides a method for continuously producing poly(vinyl butyral) in which the acetalization of poly(vinyl butyral) is carried out using a poly(vinyl alcohol) varnish provided to a mixing region of a high shear mixer at an elevated temperature, which reduces the amount of energy required compared to conventional processing because at least one cooling and heating cycle is eliminated, or makes the recuperation of energy more straightforward.Type: GrantFiled: April 18, 2009Date of Patent: April 21, 2015Assignee: Eastman Chemical CompanyInventors: Ling Tao, Pol D'Haene, Philippe Moniotte, Paul Van Lierde
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Patent number: 9006329Abstract: An aqueous dispersion of a vinyl ester/ethylene copolymer is prepared by emulsion copolymerization of a monomer mixture comprising a vinyl ester, ethylene and a polyvinyl alcohol stabilizing system consisting essentially of (a) about 0.5 to about 3 wt. % based on the total monomer weight of a first polyvinyl alcohol having a degree of hydrolysis of at least 98 mole % and (b) about 1 to about 4 wt. % based on the total monomer weight of a second polyvinyl alcohol having a degree of hydrolysis of about 85 to about 90 mole % and a weight average molecular weight of at least 85,000 g/mol.Type: GrantFiled: June 7, 2012Date of Patent: April 14, 2015Assignee: Celanese Emulsions GmbHInventors: Jörg Schulte, Alexander Madl, Hans Uwe Faust
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Patent number: 8993822Abstract: A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.Type: GrantFiled: October 4, 2010Date of Patent: March 31, 2015Assignee: Chevron Phillips Chemical Company LPInventors: Ronald D. Knudsen, Bruce E. Kreischer, Ronald G. Abbott, Steven D. Bridges, Eduardo J. Baralt, Brooke L. Small
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Patent number: 8993668Abstract: What are described are polyvinyl ester dispersions which are prepared in a multistage process and have a low content of polymerized acids or acid anhydrides. They can be obtained by a multistage process in which a polyvinyl ester dispersion is obtained in a first stage, monomers in dissolved or pure form are added to the reaction mixture in a second stage and then the polymerization is started again. The polymer dispersions obtained in this way are notable for a low coagulum content and for increased tensile strengths of the films formed therefrom.Type: GrantFiled: July 15, 2008Date of Patent: March 31, 2015Assignee: Celanese Emulsions GmbHInventor: Ivan Cabrera
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Patent number: 8980997Abstract: Disclosed is an adhesive composition in which a solid component is dissolved in a solvent, the solid component being dissolved in the solvent to have a solid component content of not less than 20% by weight with respect to a total amount of the solid component and the solvent, the solid component containing resin obtained by polymerizing a monomer composition that contains a cycloolefin monomer, the solvent having no carbon-carbon double bond, and an alcohol content contained in the solvent being not more than 0.45% by weight with respect to an entire amount of the solvent.Type: GrantFiled: June 10, 2011Date of Patent: March 17, 2015Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Koki Tamura, Takahiro Asai, Atsushi Kubo, Hirofumi Imai, Takahiro Yoshioka
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Patent number: 8981021Abstract: Various methods and systems for using oxygen in a polyolefin polymerization reactor system are provided. In certain embodiments, the methods are performed in conjunction with a polymerization reactor system such as a gas-phase reactor system.Type: GrantFiled: February 21, 2008Date of Patent: March 17, 2015Assignee: Univation Technologies, LLCInventors: Ronald S. Eisinger, Mark G. Goode
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Patent number: 8975320Abstract: A flame retardant additive for polymers is disclosed which additive comprises a polyacrylate in combination with a) at least one zinc borate, b) at least one silicone resin, and c) alumina trihydrate or magnesium hydroxide or a mixture thereof, said additive being free of halogens, antimony oxide and phosphorus-containing substances. A flame retardant composition comprising a polymer and a flame retardant additive is also disclosed as well as a method of reducing the flammability of a polymer by mixing said polymer with said flame retardant additive.Type: GrantFiled: October 25, 2006Date of Patent: March 10, 2015Assignee: PP Polymer ABInventor: Swaraj Paul
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Patent number: 8975353Abstract: The present invention provides a process for producing an ?-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher ?-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.Type: GrantFiled: November 16, 2005Date of Patent: March 10, 2015Assignee: Mitsui Chemicals, Inc.Inventors: Tooru Tanaka, Tetsunori Shinozaki
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Patent number: 8969474Abstract: Provided is a thermoplastic acrylic resin composition comprising a methacrylic resin (A) and a polyvinyl acetal resin (B) obtained by acetalizing a polyvinyl alcohol resin with an aldehyde having 4 or more carbon atoms and an aldehyde having 3 or less carbon atoms in which the total amount of the vinyl alcohol units acetalized with the aldehyde having 4 or more carbon atoms and the aldehyde having 3 or less carbon atoms is 65 to 85 mol % of all repeating units, and the molar ratio of the vinyl alcohol unit acetalized with the aldehyde having 4 or more carbon atoms to the vinyl alcohol unit acetalized with the aldehyde having 3 or less carbon atoms is from 90/10 to 0/100. Furthermore, provided are an article molded from the thermoplastic acrylic resin composition and a method of producing the thermoplastic acrylic resin composition comprising the steps of mixing a methacrylic resin (A) and a polyvinyl acetal resin (B), increasing the resin temperature to 160° C.Type: GrantFiled: April 21, 2009Date of Patent: March 3, 2015Assignee: Kuraray Co., Ltd.Inventors: Kazuki Tokuchi, Wataru Tsuji, Nobuhiro Moriguchi, Noboru Higashida