Patents Examined by David W. Wu
  • Patent number: 9067866
    Abstract: The invention relates to amino(meth)acrylates obtained from the reaction of amines with a mixture of epoxy(meth)acrylates and (meth)acrylated diluent and there use for making flexible varnishes, coatings, adhesives and inks.
    Type: Grant
    Filed: June 22, 2007
    Date of Patent: June 30, 2015
    Assignee: ALLNEX BELGIUM S.A.
    Inventors: Francis Bergiers, Thierry Randoux
  • Patent number: 9062132
    Abstract: The present invention provides a dispersion stabilizer having an excellent polymerization stability. When used for suspension polymerization of vinyl compounds even in small amounts, the dispersion stabilizer according to the present invention attains the effects that: with respect to vinyl polymer particles to be obtained, the plasticizer absorptivity is high, leading to easy processing; residual monomer components such as a vinyl compound can be removed easily; the number of coarse particles is small; the obtained particles are as uniform as possible in particle size so that formation of fish-eyes can be prevented. The present invention provides a dispersion stabilizer for suspension polymerization including a polyvinyl alcohol polymer (A) having a saponification degree of 60 mol % or more and a polymerization degree of 200 or more, and a polyvinyl alcohol polymer (C) obtained by esterifying a polyvinyl alcohol polymer (B) having a saponification degree of less than 60 mol % with a carboxylic acid compound.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: June 23, 2015
    Assignee: KURARAY CO., LTD.
    Inventors: Masaki Kato, Masato Nakamae
  • Patent number: 9061441
    Abstract: A method of producing a vinyl alcohol resin having a water content of not higher than 10 wt % by performing a multistage dewatering process by means of a kneading machine. The method permits efficient dewatering of a highly hydrous vinyl alcohol resin to ensure easy production of a lower water content vinyl alcohol resin having a water content of not higher than 10 wt %, thereby reducing production costs.
    Type: Grant
    Filed: April 22, 2011
    Date of Patent: June 23, 2015
    Assignee: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Keisuke Fujimura, Osamu Hommura, Yasufumi Beniya, Satoshi Matsunuma
  • Patent number: 9062143
    Abstract: Polymer powders comprising in copolymerized form a) one or more vinyl aromatic comonomers, b) one or more 1,3-diene comonomers, c) from 0.1 to 15 percent, based on the total comonomer weight, of one or more comonomers selected from the group consisting of ethylenically unsaturated mono- and dicarboxylic acids and their salts, wherein at least 75 percent of the total number of carboxylic groups present in the polymer are located at the surface of the polymer particles in the powder and at least 75 percent of the carboxylic groups located at the surface of the polymer particles in powder are present in their salt form, and d) from 0 to 40 percent, based on the total comonomer weight, of one or more additional comonomers have an excellent redispersibility in water.
    Type: Grant
    Filed: July 29, 2010
    Date of Patent: June 23, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Margarita Perello, Harmut Kühn, Jürgen Dombrowski, Francois M. Casati, Etienne Lazarus, Gerold Lohmüller
  • Patent number: 9056974
    Abstract: The invention relates to the use of an impact-modified acrylic blend with a low level of fluoropolymer to achieve impact resistance and solvent resistance in a capstock formulation. Preferably the acrylic blend contains a methyl methacrylate-based acrylic polymer and polyvinylidene fluoride.
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: June 16, 2015
    Assignee: Arkema France
    Inventors: Adam Toft, Charles C. Crabb, Harold Reid Banyay, Michael Burchill
  • Patent number: 9056303
    Abstract: The present invention relates to a process for the continuous preparation of a catalytic system that can be used for the polymerization of at least one conjugated diene monomer, said catalytic system being based on at least: a preforming conjugated diene; an organic phosphoric acid salt of one or more rare-earth metal(s), said salt being in suspension in at least one saturated aliphatic or alicyclic and inert hydrocarbon-based solvent; an alkylating agent comprising an alkylaluminium having the formula AlR3 or HAlR2; and a halogen donor comprising an alkylaluminium halide; characterized in that it comprises successively in one line (L): (i) a reaction between the preforming conjugated diene, with the solution of the salt of rare-earth element(s) and the alkylating agent, with the alkylation reaction being carried out for a characteristic minimum period of at least 5 minutes in an alkylation reactor (30) composed of at least one well-mixed dynamic mixer; (ii) the addition of said halogen donor to the mixtur
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: June 16, 2015
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Helene Parola, Fanny Barbotin, Pierre Kiener, Bernard Anselme, Fabrice Martinet
  • Patent number: 9056801
    Abstract: The present invention provides a method for producing a slurry composition which realizes excellent dispersibility through simple steps. In addition, the present invention provides a slurry composition produced using this method. The present invention provides a method for producing a slurry composition containing inorganic powder, a polyvinyl acetal resin, and an organic solvent, the method comprising the steps of: mixing inorganic powder, a polyvinyl acetal resin (A) and an organic solvent for inorganic dispersion to prepare an inorganic dispersion; mixing a polyvinyl acetal resin (B) and an organic solvent for resin solution to prepare a resin solution; and adding the resin solution to the inorganic dispersion, the polyvinyl acetal resin (A) having a polymerization degree of 200 to 600, the polyvinyl acetal resin (B) having a polymerization degree of 800 to 4000, and an amount of the polyvinyl acetal resin (A) used in preparation of the inorganic dispersion being 0.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: June 16, 2015
    Assignee: SEKISUI CHEMICAL CO., LTD.
    Inventors: Kenichi Ootsuki, Yuki Hirose, Motokuni Ichitani
  • Patent number: 9034987
    Abstract: Disclosed is an adhesive for a polarizing plate that comprises a polyvinyl alcohol-based resin with an acetoacetyl group and an amine-based metal compound crosslinking agent, and a method of manufacturing the same.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: May 19, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Seung-Ae Kim, Kyun-Il Rah
  • Patent number: 9023943
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: May 5, 2015
    Assignee: Ethox Chemicals LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Patent number: 9023930
    Abstract: The present invention provides a method for producing a slurry composition which realizes excellent dispersibility through simple steps and can maintain high dispersibility over a long term. In addition, the present invention provides a slurry composition produced using this method. The present invention provides a method for producing a slurry composition containing an inorganic powder, a polyvinyl acetal resin, and an organic solvent. The method contains the steps of mixing an inorganic powder, a mixed polyvinyl acetal resin (A) and an organic solvent (i) to prepare an inorganic dispersion; mixing a polyvinyl acetal resin (B) and an organic solvent (ii) to prepare a resin solution; and adding the resin solution to the inorganic dispersion.
    Type: Grant
    Filed: September 16, 2011
    Date of Patent: May 5, 2015
    Assignee: Sekisui Chemical Co., Ltd.
    Inventor: Kenichi Ootsuki
  • Patent number: 9012542
    Abstract: Disclosed herein are a homogeneous sulfur-modified polymer composition, a method of preparing sulfur-modified polymer, and an asphaltic concrete mixture.
    Type: Grant
    Filed: March 29, 2010
    Date of Patent: April 21, 2015
    Assignee: Saudi Arabian Oil Company
    Inventors: Ibnelwaleed A. Hussein, Mohammed H. Al Mehthel, Hamad I. Al-Abdul Wahhab, Saleh H. Al Idi, Junaid Saleem Akhtar
  • Patent number: 9012570
    Abstract: The present invention provides a method for continuously producing poly(vinyl butyral) in which the acetalization of poly(vinyl butyral) is carried out using a poly(vinyl alcohol) varnish provided to a mixing region of a high shear mixer at an elevated temperature, which reduces the amount of energy required compared to conventional processing because at least one cooling and heating cycle is eliminated, or makes the recuperation of energy more straightforward.
    Type: Grant
    Filed: April 18, 2009
    Date of Patent: April 21, 2015
    Assignee: Eastman Chemical Company
    Inventors: Ling Tao, Pol D'Haene, Philippe Moniotte, Paul Van Lierde
  • Patent number: 9006329
    Abstract: An aqueous dispersion of a vinyl ester/ethylene copolymer is prepared by emulsion copolymerization of a monomer mixture comprising a vinyl ester, ethylene and a polyvinyl alcohol stabilizing system consisting essentially of (a) about 0.5 to about 3 wt. % based on the total monomer weight of a first polyvinyl alcohol having a degree of hydrolysis of at least 98 mole % and (b) about 1 to about 4 wt. % based on the total monomer weight of a second polyvinyl alcohol having a degree of hydrolysis of about 85 to about 90 mole % and a weight average molecular weight of at least 85,000 g/mol.
    Type: Grant
    Filed: June 7, 2012
    Date of Patent: April 14, 2015
    Assignee: Celanese Emulsions GmbH
    Inventors: Jörg Schulte, Alexander Madl, Hans Uwe Faust
  • Patent number: 8993822
    Abstract: A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.
    Type: Grant
    Filed: October 4, 2010
    Date of Patent: March 31, 2015
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Ronald D. Knudsen, Bruce E. Kreischer, Ronald G. Abbott, Steven D. Bridges, Eduardo J. Baralt, Brooke L. Small
  • Patent number: 8993668
    Abstract: What are described are polyvinyl ester dispersions which are prepared in a multistage process and have a low content of polymerized acids or acid anhydrides. They can be obtained by a multistage process in which a polyvinyl ester dispersion is obtained in a first stage, monomers in dissolved or pure form are added to the reaction mixture in a second stage and then the polymerization is started again. The polymer dispersions obtained in this way are notable for a low coagulum content and for increased tensile strengths of the films formed therefrom.
    Type: Grant
    Filed: July 15, 2008
    Date of Patent: March 31, 2015
    Assignee: Celanese Emulsions GmbH
    Inventor: Ivan Cabrera
  • Patent number: 8980997
    Abstract: Disclosed is an adhesive composition in which a solid component is dissolved in a solvent, the solid component being dissolved in the solvent to have a solid component content of not less than 20% by weight with respect to a total amount of the solid component and the solvent, the solid component containing resin obtained by polymerizing a monomer composition that contains a cycloolefin monomer, the solvent having no carbon-carbon double bond, and an alcohol content contained in the solvent being not more than 0.45% by weight with respect to an entire amount of the solvent.
    Type: Grant
    Filed: June 10, 2011
    Date of Patent: March 17, 2015
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Koki Tamura, Takahiro Asai, Atsushi Kubo, Hirofumi Imai, Takahiro Yoshioka
  • Patent number: 8981021
    Abstract: Various methods and systems for using oxygen in a polyolefin polymerization reactor system are provided. In certain embodiments, the methods are performed in conjunction with a polymerization reactor system such as a gas-phase reactor system.
    Type: Grant
    Filed: February 21, 2008
    Date of Patent: March 17, 2015
    Assignee: Univation Technologies, LLC
    Inventors: Ronald S. Eisinger, Mark G. Goode
  • Patent number: 8975320
    Abstract: A flame retardant additive for polymers is disclosed which additive comprises a polyacrylate in combination with a) at least one zinc borate, b) at least one silicone resin, and c) alumina trihydrate or magnesium hydroxide or a mixture thereof, said additive being free of halogens, antimony oxide and phosphorus-containing substances. A flame retardant composition comprising a polymer and a flame retardant additive is also disclosed as well as a method of reducing the flammability of a polymer by mixing said polymer with said flame retardant additive.
    Type: Grant
    Filed: October 25, 2006
    Date of Patent: March 10, 2015
    Assignee: PP Polymer AB
    Inventor: Swaraj Paul
  • Patent number: 8975353
    Abstract: The present invention provides a process for producing an ?-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher ?-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: March 10, 2015
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tooru Tanaka, Tetsunori Shinozaki
  • Patent number: 8969474
    Abstract: Provided is a thermoplastic acrylic resin composition comprising a methacrylic resin (A) and a polyvinyl acetal resin (B) obtained by acetalizing a polyvinyl alcohol resin with an aldehyde having 4 or more carbon atoms and an aldehyde having 3 or less carbon atoms in which the total amount of the vinyl alcohol units acetalized with the aldehyde having 4 or more carbon atoms and the aldehyde having 3 or less carbon atoms is 65 to 85 mol % of all repeating units, and the molar ratio of the vinyl alcohol unit acetalized with the aldehyde having 4 or more carbon atoms to the vinyl alcohol unit acetalized with the aldehyde having 3 or less carbon atoms is from 90/10 to 0/100. Furthermore, provided are an article molded from the thermoplastic acrylic resin composition and a method of producing the thermoplastic acrylic resin composition comprising the steps of mixing a methacrylic resin (A) and a polyvinyl acetal resin (B), increasing the resin temperature to 160° C.
    Type: Grant
    Filed: April 21, 2009
    Date of Patent: March 3, 2015
    Assignee: Kuraray Co., Ltd.
    Inventors: Kazuki Tokuchi, Wataru Tsuji, Nobuhiro Moriguchi, Noboru Higashida