Abstract: A process for making a high solids content Zeolite A-alkylbenzene sulfonate detergent composition suitable for use in making spray dried detergent compositions includes manufacturing Zeolite A by a hydrogel, clay conversion, natural silica or equivalent process so that the Zeolite A is present in an aqueous medium containing alkali metal hydroxide in solution therein, separating a substantial proportion of the aqueous medium from the Zeolite A so as to produce Zeolite A particles, usually in cake form, containing excess alkali metal hydroxide solution on particle surfaces and occluded by such particles, and at least partially neutralizing said excess alkali metal hydroxide with a high concentration aqueous alkylbenzene sulfonic detergent acid, such as a sulfonic detergent acid resulting from oleum sulfonation or sulfur trioxide sulfonation of a linear higher alkylbenzene.
Type:
Grant
Filed:
April 6, 1979
Date of Patent:
November 15, 1983
Assignee:
Colgate Palmolive Company
Inventors:
Alexander P. Kiczek, Leo A. Salmen, Clark B. Tower
Abstract: A process for producing free flowing spray dried base builder beads comprising inorganic detergent builders. The builder beads comprise alkali metal phosphate, alkali metal silicate and water. The alkali metal phosphate component includes a hydrated and an anhydrous portion. Relatively large amounts of liquid or liquifiable detergent ingredients such as surface active agents etc. can be applied to the base beads after spray drying, without destroying their free flowing properties.
Abstract: Agglomerates of water insoluble builder molecular sieve zeolites are made by tumbling or otherwise suitably mixing very finely divided ion exchanging zeolite powder and a water soluble binder, such as starch, preferably in the presence of a small amount of moisture sufficient to promote desirable agglomeration of the finely divided ion exchanging zeolite particles and the binder into essentially spherical particles, preferably in the 6 to 140 mesh range. The agglomerates are readily disintegrated when agitated in water and rapidly release the separated very finely divided insoluble builder particles to allow them to remove hardness ions from the water. The dispersible and disintegrable agglomerates are especially useful in heavy duty detergent compositions wherein the zeolite of the agglomerate provides all or a substantial proportion of the builder content.
Abstract: A heat resistant cabinet having at least one protected compartment for storing temperature-sensitive articles. The compartment is surrounded by a heat absorbing layer and may also be surrounded by a heat barrier layer. The heat absorbing layer is a solid mixture of a heat absorbing material which becomes liquid under the influence of excessive heat and also contains an additional material which binds said liquid heat absorbing material to form a doughy or solid mass. The additional material is a water-absorbing inorganic material such as plaster of Paris, caustic lime, or cement. The heat absorbing material is a material such as sodium acetate trihydrate or sodium metasilicate.
Type:
Grant
Filed:
March 26, 1981
Date of Patent:
November 8, 1983
Assignee:
Sistemco N.V.
Inventors:
Gunther Pichler, Friedrich Rothhaas, Hans Hock
Abstract: Liquid detergent compositions, particularly for use as hard surface cleaners, comprising 1%-20% surfactant, 0.5%-10% mono- or sesquiterpenes, and 0.5%-10% of a polar solvent having a solubility in water of from 0.2% to 10%, preferably benzyl alcohol. The compositions provide excellent cleaning of both greasy and particulate soils, improved surface appearance, excellent formulation homogeneity, stability and viscosity characteristics as well as good suds control.
Abstract: Hulls of fibreglass boats often become stained above and below the waterline after a period in the water. The present invention provides a method of cleaning fibreglass which comprises applying to a fibreglass surface a composition comprising an aqueous solution of phosphoric or oxalic acid and letting the solution dry on the fibreglass surface. It has been found that the method of the present invention is a quick and effective way of cleaning fibreglass.
Abstract: A high foaming, low eye irritation cleaning composition. The composition contains an alkyl ether sulfate having the following structural formulae:R(A).sub.n OSO.sub.3 M or R.sub.1 (A).sub.n SO.sub.3 Mwherein R is an alkyl, alkylaryl, acyl or alkenyl group having at least 13, preferably 13 to 30, most preferably 14 to 24, carbon atoms in the alkyl chain; R.sub.1 is an acylamide group having at least 13, preferably 13 to 30, most preferably 14 to 24, carbon atoms, A is an alkyl ether group derived from ethylene oxide, propylene oxide, butylene oxide, glycidol and substituted epoxides, the preferred group being ethoxy; n is about 6 to about 100, preferably about 6 to about 20, more preferably about 10 to about 20; and M is a cation such as an alkali metal, an alkaline earth metal, a transition metal, ammonium, an alkylamine, or an alkanolamine. These compositions are particularly useful as cosmetic cleaning compositions, such as shampoos and bubble baths.
Abstract: A free flowing particulate heavy duty laundry detergent containing no more than 8.7% of phosphorus (from phosphate) is comprised of sodium tripolyphosphate particles having nonionic detergent in the interior and on the surface thereof, which adheres a coating of smaller particles of ion-exchanging zeolite to the phosphate. Also within the invention is a method of making such a product by pre-mixing spray dried sodium tripolyphosphate particles and smaller zeolite particles and admixing with them, as by spraying, in liquid form, onto moving particles, a normally liquid or pasty nonionic detergent, such as a higher fatty alcohol polyethylene oxide condensation product, which penetrates the sodium tripolyphosphate particles and adheres zeolite particles to the surfaces thereof.
Abstract: The present invention provides heavy duty detergent compositions, particularly for imparting improved softness and detersive effects to fabrics laundered therewith, said composition including in addition to conventional builder and principally anionic surfactant components, cationic softener of the di-lower-di-higher alkyl quaternary ammonium and/or heterocyclic imide type, e.g., imidazolinium, and a mixture of fatty acid soap and nonionic organic surfactant, the weight ratio of soap to softener being about 8:1 to 1:3 preferably 5:1 to 1:2, more preferably 3:2:2:3, e.g., about unity. The soap nonionic surfactant mixture is in the form of a spaghetti, flake, or other shape and is present in the product composition as substantially homogeneously dispersed, discrete particles. A process of laundering fabrics using the above-mentioned composition is also disclosed.
Abstract: A cleansing composition is disclosed that is particularly suited for compaction into tablet form, and comprises a phosphate salt, an optionally added silicate salt, such as a metasilicate and at least one perborate salt, wherein at least a portion of the perborate salt component is present as a compacted, granulated mixture with from about 0.01% to about 0.70% by weight of the perborate salt, of a polymeric fluorocarbon. Preferably, the perborate salt includes sodium perborate monohydrate and anhydrous sodium perborate, and polytetrafluoroethylene comprises the polymeric fluorocarbon used to prepare the granules.When present, the silicate salt is preferably utilized within a particle size ranging from about 1 to about 25 microns. The silicate aids disintegration and assists in mechanical cleaning, when the composition is prepared in tablet form for use as a denture cleanser.
Abstract: A stable homogeneous paste detergent is provided comprising about 24% of a synthetic nonionic detergent, about 8% of sodium silicate, about 24% of a type A zeolite, about 0.2% of sodium carboxymethyl cellulose, about 34.7% of deionized water and about 9.1% of a synthetic anionic detergent.
Abstract: Detergent compositions stable to chlorine separation are described, which as main constituents contain alkali metal phosphate, alkali metal silicate, a surfactant and granulate chlorinated triazine trione, the granules of the chlorinated triazine trione being coated with a thin layer of a hydrophobic substance. The surface-treated chlorinated triazine trione which constitutes an agent for producing the composition, is also described as is the use of the composition as a machine dish washing detergent or industrial detergent.
Abstract: A cleaner which is particularly suited for use as a bilge cleaner comprises (a) methyl-2 pyrrolidone, (b) an alkylaryl polyether alcohol obtainable as the reaction product of octylphenol and ethylene oxide and containing an average of five ethylene oxide units per molecule, and (c) an alkylaryl polyether alcohol obtainable as the reaction product of octylphenol and ethylene oxide and containing an average of seven to eight ethylene oxide units per molecule. One or more of defoaming and color agents and a fragrance component are included in preferred embodiments of the invention.
Abstract: A free flowing, phosphate free high bulk density particulate heavy duty laundry detergent is prepared by spray-drying an aqueous slurry of ion-exchanging detergent building zeolite particles, sodium carbonate and sodium silicate which has been sheared to reduce the viscosity thereof, followed by mixing nonionic detergent in liquid form with the spray-dried base beads to absorb the detergent into the beads.
Type:
Grant
Filed:
June 4, 1982
Date of Patent:
September 27, 1983
Assignee:
Colgate-Palmolive Company
Inventors:
William J. Gangwisch, Virgil J. Richter, Harold E. Wixon, Joseph B. Wraga
Abstract: A reversible liquid/solid phase change composition comprising hydrated MgCl.sub.2 and one or more of Ba(OH).sub.2, Sr(OH).sub.2, CaO, SrCO.sub.3, BaO, Ca(OH).sub.2, Mg(OH).sub.2, MgO, Na.sub.3 AlF.sub.6 or CaC.sub.2 O.sub.4, added to the composition in an effective amount to suppress supercooling of the MgCl.sub.2 liquid phase.
Abstract: A disinfecting cleaning intensifier for dry cleaning is disclosed, containing--in addition to at least one disinfecting quaternary ammonium chloride surfactant and water--the diammonium salt of an aliphatic linear .alpha., .omega.-dicarboxylic acid having from 2 to 5 methylene groups or the triammonium salt of a tricarboxylic acid, namely citric acid or tricarballylic acid, and a tertiary amine corresponding to the general formula NR.sub.1 R.sub.1 R.sub.2 or NR.sub.1 'R.sub.1 'R.sub.2 ' in whichR.sub.1 represents methyl,R.sub.2 represents a fatty alkyl group containing from 8 to 18 carbon atoms,R.sub.1 ' represents a hydroxy ethyl group --CH.sub.2 --CH.sub.2 --OH, andR.sub.2 ' represents an ethylene glycol monoalkyl ether radical corresponding to the following formula ##STR1## in which R.sub.3 represents a fatty alkyl group containing from 10 to 18 carbon atoms, or a mixture of these tertiary ammonium salts.
Abstract: A cleaning intensifier is disclosed for use in dry-cleaning machines equipped with adsorption filters, which intensifier is not adsorbed by the filters. The cleaning intensifier contains a quaternary ammonium salt in the form of difatty alkyl dimethyl ammonium chloride containing from 12 to 18 carbon atoms in the alkyl radical or a mixture of the homologues, and the triammonium salt of a tricarboxylic acid citric acid or tricarballylic acid, and a tertiary amine in the form of a fatty alkyl dimethylamine containing from 8 to 18 carbon atoms in the alkyl radical or a hydroxy ethyl amine derivative corresponding to the formula ##STR1## where R is a fatty alkyl radical containing from 10 to 18 carbon atoms, or a mixture of these triammonium salts.
Abstract: A method is disclosed for the preparation of granulated perborate salts having improved utility in compressible compositions such as those formed into denture cleanser tablets. The method broadly comprises forming a mixture of one or more perborate salts such as sodium perborate monohydrate and anhydrous sodium perborate, with a polymeric fluorocarbon such as polytetrafluoroethylene, with the polytetrafluoroethylene present in an amount ranging from about 0.01% to about 0.70% by weight of the perborate salt. The particles thus prepared exhibit combination of improved hardness and specific weight that facilitates their participation in the compressible cleanser composition, together with enhanced disintegration characteristics that are favorably imparted to the cleanser tablets.The present invention also includes the granular salts prepared by the method, which have a broad range of utility in detergents, cleansers and the like.
Abstract: A process for making glycerinated toilet bar compositions which are substantially free of hard specks, wherein the soap is worked (e.g., milled) prior to the addition of glycerin.
Type:
Grant
Filed:
March 22, 1982
Date of Patent:
September 20, 1983
Assignee:
The Procter & Gamble Company
Inventors:
John D. Nyquist, Gary K. Kwasniewski, Arthur W. Thornton, Paul E. Vest, Kenneth E. Ducklo
Abstract: Stable liquid detergent compositions containing a surfactant, an aluminosilicate ion exchange material, a water-soluble detergency builder, and a stabilizing agent are prepared by dispersing the aluminosilicate material in an aqueous solution having a pH less than 7, preferably from about 4 to about 5, to partially gelatinize the aluminosilicate material, and mixing the dispersion with the balance of the ingredients to provide a stable composition having a pH greater than 7.