Abstract: The present invention generally relates to nonylphenol-free alkoxylated 4-(alkyloxy)phenol/aldehyde resins and processes for making alkoxylated 4-(alkyloxy)phenol/aldehyde resins. The invention also relates to methods of breaking emulsions of oil and water comprising the dosing of an effective amount of an emulsion breaker composition into a stable emulsion to destabilize the emulsion, wherein the emulsion breaker composition comprises an alkoxylated 4-(alkyloxy)phenol/aldehyde resin.

Abstract: The present invention provides an industrial wastewater recovery apparatus (100) aiming at Zero Liquid Discharge (ZLD). The apparatus (100) provides two stages in pre-heating the spiral coil pipe (103) containing wastewater and also conserves the heat by using the two heat exchangers (104, 105). The apparatus (100) agitates the surface wastewater to increase the rate of evaporation for faster heating. The apparatus (100) provides two stages in condensation of distilled water and also provides real-time monitoring of the water quality. The apparatus (100) provides automatic cleaning in the various parts during the operations. Further, a plurality of IoT sensor (201) monitor the real time parameters of the industrial wastewater recovery apparatus (100) and data is available to the user on the electronic display device (204).

Abstract: The present invention relates to a process for preparing a residual base oil from a hydrocarbon feed which is derived from a Fischer-Tropsch process, the process comprises the steps of: (a) providing a hydrocarbon feed which is derived from a Fischer-Tropsch process; (b) subjecting the hydrocarbon feed of step (a) to a hydrocracking/hydroisomerisation step to obtain an at least partially isomerised product; (c) separating at least part of the at least partially isomerised product as obtained in step (b) into one or more lower boiling fractions and a hydrowax residue fraction; (d) catalytic dewaxing of the hydrowax residue fraction of step (c) to obtain a highly isomerised product; (e) separating the highly isomerised product of step (d) into one or more light fractions and a isomerised residual fraction; (f) mixing of the isomerised residual fraction of step (e) with a diluent to obtain a diluted isomerised residual fraction; (g) cooling the diluted isomerised residual fraction of step (f) to a temperature be

Abstract: Methods and systems for manufacturing lubrication oils are disclosed. In one embodiment, a method for manufacturing a lubrication oil includes the steps of receiving into an adsorber unit an unconverted oil (UCO) feedstock comprising five and six ring polynuclear aromatic (PNA) compounds and contacting the UCO feedstock with an adsorbent to remove PNA compounds, thereby forming a treated UCO feedstock with a low concentration of five and six ring PNAs.

Abstract: Waste, such as municipal solid waste (MSF), is separated into a wet fraction and refuse derived fuel (RDF). For example, the waste may be separated in a press. The wet fraction is treated in an anaerobic digester. The RDF is further separated into a cellulosic fraction and a non-cellulosic fraction. The cellulosic fraction is treated by pyrolysis and produces a pyrolysis liquid. The pyrolysis liquid is added to the anaerobic digester.

Abstract: A thin film, direct convection, evaporative apparatus, such as for treating waste water on-site at a production area or waste water processing area, relies on direct exposure of fluid to an open flame in a substantially enclosed burner unit having a burn chamber fed by an air-fuel mixing chamber and a fluid chamber, which apparatus also has gas and air trains and a metered fluid train permitting controlled fluid flow rate.

Abstract: A process and an apparatus for pyrolysis of mixed plastic feedstock producing petroleum products are described. In one example, a process for producing petroleum products includes charging feedstock of mixed polymer materials into a reactor apparatus. Heat energy is applied to the feedstock while advancing the feedstock through the reactor apparatus in an anaerobic operation. The energy input to the reactor apparatus is controlled by controlling a temperature gradient within the reactor vessel to produce petroleum gas product. The process involves in situ chemical reactions comprising cracking and recombination reactions that that are controlled to convert solid hydrocarbonaceous portion of the feedstock to molten fluids and gases inside the reactor vessel and to produce gaseous petroleum products which exit the reactor vessel. The separated solid residue from the pyrolysis process is also removed from the reactions vessel.

Abstract: A system and method for expanding the production capacity of an existing ethanol production facility including: a source of fermented mash (beer); a first beer column configured for receiving beer input from the source and for producing overhead comprising alcohol vapor and water vapor; and a first rectifier receiving an alcohol and water mixture from said first beer column. The system includes a second beer column, first and second condensers receiving overhead from the beer columns and a second rectifier receiving condensed overhead from the second condenser and bottoms from the first rectifier. A processing component receives bottoms from the first and second beer columns and steam condensate. The method includes the steps of retrofitting an existing ethanol production facility with a second beer column, first and second condensers and a second rectifier.

Abstract: Alumina support compositions comprising at least 0.1 wt % of silica are disclosed. The alumina support are characterized by a pore volume of greater than 0.60 cc/g, a median pore size ranging from about 70 to about 120, a pore size distribution such that at least 90% of the total pore volume falls within the range of about 20 to about 250, and a pore size distribution width of no less than about 40. Alumina compositions of the present invention exhibit a primary peak mode at a pore diameter less than the median pore diameter. Also provided are catalysts made from the alumina supports, and processes of preparing and using the supports and catalysts.

Abstract: A distillation apparatus includes an evaporator-condenser heat exchanger in combination with a compressor. The heat exchanger is mounted to float in an at least partially immersed position in a sump of liquid. The liquid may be a sap, or may be soiled water, and may have suspended solid. Heating of the liquid yield steam, the steam is compressed, and the heated, compressed steam is fed back into the heat exchanger to provide further heat to the liquid. The process yields a concentrated in the liquid bath and distilled water, each of which may be a desired product. The system may include a pre-heater that exchanges residual heat from the hot distillate with the cooler input liquid. The apparatus and process may have multiple stages.

Abstract: A system and method to reboil a process or feed water stream in a distillation system does so in a liquid pool zone of a vessel as the stream is removed from a distillation column and comes into contact with a heating medium that is immiscible with and less volatile than the process stream. To keep the pool hot, the heating medium can be recirculated through a heater of a pump-around loop or a heater can be placed in the liquid pool. As the process stream is partially vaporized, any solids present in the process stream together with the unvaporized process or feed water stream move into the heating medium. These solids and unvaporized liquids may be further removed from the heating medium in the pool or in the pump-around loop. The vaporized stream is returned to the distillation column.

Abstract: An electronic waste processing apparatus has a power supply device, a vacuum cracking device, a filter device, and a separation device. The vacuum device is electrically connected to the power supply device, and has a vacuum pump, a vacuum chamber, and a high-frequency furnace body. The vacuum chamber is connected to and communicates with the vacuum pump. The high-frequency furnace body is disposed in the vacuum chamber. The filter device is electrically connected to the power supply device, and is connected to and communicates with the high-frequency furnace body of the vacuum cracking device. The separation device is electrically connected to the power supply device, is connected to and communicates with the vacuum pump and the filter device, and has a condensation cylinder, a cooling cylinder, and an oil storage tank.

Abstract: A system and method removes thermal decomposition components from biphenol and/or diphenyl oxide heat-transfer fluids. Light, volatile decomposition components including benzene, water, hydrogen and phenol leave the system for vapor recovery, chemical adsorption or thermal decomposition. Dimerized and polymerized heavy components such as biphenyl phenyl ether, terphenyl and related isomers are concentrated and recovered. The system can be a continuous, semi-continuous or batch operation. Solar electric plants employing the system can use solar field fluids and heating to operate the system during generator operation hours. A wash system operating at or near atmospheric pressure concentrates heavy thermal decomposition components while allowing removal of light, volatile decomposition components for separation from the majority of the thermal fluid components.

Abstract: A two-step process for treating a sulfur-containing refinery feedstock that includes olefin and diolefin constituents by reacting the feedstock with hydrogen sulfide over a catalyst to produce the corresponding mercaptans and/or thiophenes, which are then desulfurized in a second reactor containing hydrodesulfurization catalysts, thereby avoiding the need for prior selective hydrogenation of the olefin and diolefin constituents.

Abstract: Vacuum distillation apparatus and methods are provided. In an embodiment, an apparatus is provided that includes an evaporation chamber having a bottom flow rate control (FRC) surface that is curved to provide multiple flow rates to a solution as it flows across the bottom surface. The apparatus also includes a wiper that is curved to match the curve of the bottom FRC surface and wipes the bottom FRC surface to distribute the solution. A heater heats the bottom FRC surface to evaporate one or more components from the moving solution.

Abstract: Steam reforming system having a steam cracker and a steam reformer. The steam cracker includes a steam cracking unit to steam crack a feed stream to produce a stream comprising hydrogen, methane and C2+ hydrocarbons; a heat exchanger for cooling the steam cracking product stream; a separation unit for separating the cooled steam cracking product stream into a gas stream including hydrogen and methane and a liquid stream including methane and C2+ hydrocarbons, a demethanizer which is fed the liquid stream producing a third stream containing at least 95% methane and a fourth stream comprising C2+ hydrocarbons. The steam reformer includes a feed preheater which is fed the third stream and steam to provide a preheated stream and a steam reforming unit arranged for heating the preheated stream to at least 800° C. to steam reforming the heated stream and obtain a product stream containing hydrogen and CO2.

Abstract: A system for neutralizing exhaust gases from an aircraft at altitude includes a turbofan jet engine. The turbofan jet engine creates exhaust gases. An exhaust is located within the turbofan jet engine. The exhaust has an interior volume. At least one corona discharge unit is located within the interior volume of the exhaust. The at least one corona discharge unit creates electrical discharges comprising high-speed relativistic electrons and gamma rays within the exhaust. The exhaust gases and the electrical discharges are directed to interact with one another in the interior volume of the exhaust. The interaction generates positively charged plasma ions within the exhaust gases. The exhaust gases are neutralized before leaving the turbofan jet engine.

Abstract: The quick response system and method for removing volatile compounds from contaminated water disclosed herein may comprise, at least, a preconditioning stage, a stripping stage, a condenser stage, a refrigeration stage, and a scrubber stage. The present invention relates to a portable system and method that can be deployed on an emergency or quick response basis to purify aqueous streams containing volatile organic compounds (VOC) and chlorinated hydrocarbons, collectively volatile compounds (VC), emitted from petroleum and chemical processing facilities. The system allows manufacturing facilities having internal cleanup issues to become compliant with environmental standards and guidelines quickly. Once the issues in the petroleum facility are fixed, this method can be demobilized and removed from the site in a short period of time.

Abstract: A heavy hydrocarbon oil is mixed with one or more disulfide oil compounds and/or one or more oxidized disulfide oil compounds and, optionally, a homogeneous catalyst includes dissolved hydrogen, and the mixture is subjected to a delayed coking process to produce a liquid coking unit product stream for recovery and further processing, with the delayed coking being completed in a reduced residence time as compared to the delayed coking of the heavy hydrocarbon oil without the DSO and/or ODSO compounds.

Abstract: The use, as markers of petroleum products, crude oils, biofuels or lubricants, of rare earth complexes or one of the constituents thereof chosen from rare earth ligands or salts, being capable of forming a rare earth complex after the addition of a developing solution. Preferably, the rare earth complex can be detected by time-resolved fluorescence. Also, a marking method and a method for detecting a rare earth complex as a marker of petroleum products, crude oils, biofuels or lubricants.