Abstract: An integrated process for maximizing recovery of hydrogen is provided. The process comprises: providing a hydrocarbonaceous feed comprising naphtha, and a hydrogen stream to a reforming zone, wherein the hydrogen stream is obtained from at least one of a hydrocracking zone, a transalkylation zone, and an isomerization zone. The hydrocarbonaceous feed is reformed in the reforming zone in the presence of the hydrogen stream and a reforming catalyst to provide a reformate effluent stream. At least a portion of the reformate effluent stream is passed to a debutanizer column of the reforming zone to provide a net hydrogen stream and a fraction comprising liquid petroleum gas (LPG). At least a portion of the net hydrogen stream is recycled to the reforming zone as the hydrogen stream.

Abstract: Provided is a method for separating normal paraffin and isoparaffin from raffinates of a benzene, toluene, and xylene (BTX) reforming process including C5 to C8 light naphtha, the method including: a liquid hydrogenation process for removing olefin by feeding raffinates in which hydrogen is dissolved into a reactor filled with a hydrogenation catalyst.

Abstract: The present application discloses a device for multistage continuous preparation of deuterium depleted water, which includes a feeding pump, a plurality of stages of separation systems connected in series, and a receiver, all of which are connected in sequence. Each stage of separation system comprises a distillation column, a vapor-liquid separator, a low-pressure steam compressor, a stream delivery pump, a three-way valve, and a stream output pipe. The present application further discloses a method for preparing deuterium depleted water, wherein natural water is fed into the device of the present disclosure, and the liquid phase stream continuously flows backwards stage by stage under the combined action of the low-pressure steam compressors and the stream delivery pumps. In a single-stage system, the deuterium is deprived depending on the difference in vapor pressure between 1H2O and 2H2O (and/or 1H2HO), and finally, the deuterium depleted water is produced.

Abstract: Contaminated wastewater from the preparation of isophorone, isophoronenitrile and isophoronediamine is treated by A) 1. treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by alkaline hydrolysis of isophoronenitrile to isophorone, and the salts of hydrogen cyanide within a pH range of 12.0 to 13.7 and at temperatures of 60 to 200° C. and 2. processing the wastewater from A) 1. by an oxidation, or B) treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by an oxidation, or C) processing the wastewater from A) 1. and the wastewater from the preparation of isophorone and/or the wastewater from the preparation of isophoronediamine by an oxidation.

Abstract: A process is provided that is directed to integrated steam pyrolysis and hydroprocessing including residual bypass to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics.

Abstract: A method of desalinating an aqueous composition includes forming a hetero-azeotrope mixture by combining the aqueous composition with an entrainer, the aqueous composition including at least one salt, and subjecting the hetero-azeotrope mixture to distillation at a distillation temperature of less than the boiling temperature of the aqueous composition for an operating distillation pressure, resulting in separating the hetero-azeotrope mixture into a distillation bottoms liquid and a multi-phase condensate. The method includes recovering the multi-phase condensate having an entrainer-rich phase and an aqueous phase, the aqueous phase comprising desalinated water, and removing a portion of the aqueous phase from the multi-phase condensate to recover the desalinated water. Systems for conducting the method of desalinating an aqueous stream are also disclosed.

Abstract: The present invention relates to Delayed Coking of heavy petroleum residue producing petroleum coke and lighter hydrocarbon products. The invented process utilizes a pre-cracking reactor for mild thermal cracking of the feedstock and intermediate multistage separation system before being subjected to higher severity thermal cracking in delayed coking process, resulting in reduction in overall coke yield.

Abstract: A process and apparatus provides alternative hydrotreating reactor trains for hydrotreating a hydrocarbon stream. One hydrotreating reactor train is smaller than the other and the smaller train comes on stream to allow replacement or regeneration of catalyst in the larger train. A sulfide system also sulfides the catalyst volume in the reactor train that is off stream to prepare it for renewed hydroprocessing of feed when back on stream. The process and apparatus can be used to keep hydroprocessing reactors on stream to continuously provide feed to an FCC unit which has a longer period before shut down.

Abstract: A system and method to partially vaporize a process or feed water stream does so in a liquid pool zone of a vessel as the stream comes into contact with a heating medium that is less volatile than the process stream. To keep the pool hot, the heating medium can be recirculated through a heater of a pump-around loop or a heater can be placed in the liquid pool. As the process stream is partially vaporized, any solids present in the process stream together with the unvaporized process or feed water stream move into the heating medium. These solids and unvaporized liquids may be further removed from the heating medium in the pool or in the pump-around loop. The vaporized process stream can be further condensed. Any heat recovered can be used to pre-heat the process stream or in the pump-around loop's heater in case of mechanical vapor recovery.

Abstract: The present invention relates to a Fischer-Tropsch derived residual base oil having a kinematic viscosity at 100° C. according to ASTM D445 in the range of from 15 to 35 mm2/s, an average number of carbon atoms per molecule Fischer-Tropsch derived residual base oil according to 13C-NMR in a range of from 25 to 50.

Abstract: The present invention provides a method for separating HFC-245cb and (E)-HFO-1234ze having close boiling points, i.e., boiling points with only 1° C. difference, by extractive distillation from a composition containing the HFC-245cb and the (E)-HFO-1234ze. More specifically, the present invention is a method for separating HFC-245cb and (E)-HFO-1234ze from a composition containing the HFC-245cb and the (E)-HFO-1234ze, the method comprising subjecting the composition to extractive distillation using at least one extractant selected from the group consisting of halogenated hydrocarbons, halogenated unsaturated hydrocarbons, nitriles, ketones, carbonates, alcohols, hydrocarbons, esters and ethers.

Abstract: An automatic dehydration, extraction and transportation apparatus for petroleum coke, includes a bottom cover device, crusher, coke chute and extracting device. The bottom cover device is at the bottom of a coke tower and connected to a coke storage pool via the chute. A grid net for filtering petroleum coke is horizontally provided in the lower part of the pool. A partition door is on an end, away from the chute, of a side pool wall of the pool. The extracting device enters and exits the coke storage pool through the partition door. A partition wall is between the partition door and the chute. The surface of the partition wall is opposite the chute, such that a corridor is formed between the other pool wall opposite the chute and the partition wall. One end of the partition wall is connected to the pool wall provided with the partition door.

Abstract: The present invention is related a square packed tower for collection of flue gas CO2. The square packed tower comprises an initial absorbent distributor on the lower end of the flue gas outlet, a vertical plate packer on the lower end of the initial absorbent distributor and a radial diversion gas distributor at the bottom of the square packed tower for delivery of carbon dioxide contained in the flue gas. The radial diversion gas distributor comprises a gas inlet pipe, a butterfly base plate, a butterfly seal plate and numerous radial deflectors. The butterfly base plate is connected with outlet of the gas inlet pipe. The radial deflectors are in radial arrangement between the butterfly base plate and butterfly seal plate along the outlet of gas inlet pipe.

Abstract: A method for separating dimethyl carbonate from methanol includes subjecting a raw material containing dimethyl carbonate and methanol to extractive distillation. The extractant contains an ionic liquid and a compound having a general formula of CH3O(CH2CH2O)nCH3, n being an integer of 2-8. The ionic liquid is an imidazole ionic liquid, a pyridine ionic liquid, or a mixture thereof.

Abstract: An integrated refinery process for producing diesel fuel blending stock from olefinic heavy naphtha streams that contain gasoline and compounds with carbon numbers in the range of from 9-14 are oxidized and converted into their corresponding oxides in the presence of a homogeneous or heterogeneous catalyst, or both, and optionally an acid phase transfer agent for the liquid reactants, the product oxides having boiling points about 34° C. higher than the corresponding olefins, and as a result, in the diesel blending component boiling point range. The oxygenates produced have lubricating properties that enhance the typically poor lubricity characteristics of ultra-low sulfur diesels and reduce the need for additives to improve the lubricity of the blended diesel fuels.

Abstract: This invention describes a novel and efficient processing scheme that can be used to transform a vacuum residue feedstock into 0.5 wt % sulfur bunker fuel that fulfills the specifications required by the International Maritime Organization (IMO).

Abstract: A system for obtaining purified water includes a heat exchanger fluidly coupled to the heat source for receiving a thermal management fluid from the heat source, and a reservoir fluidly coupled with the heat exchanger to supply water, at an ambient temperature, for receiving heat from the thermal management fluid at the heat exchanger. A pump provides a pre-defined flow rate of the water from the reservoir to the heat exchanger based on a temperature gradient of the thermal management fluid across the heat exchanger. A purification device has a cold side chamber in fluid communication with the pump and the heat exchanger while a hot side chamber is in fluid communication with the heat exchanger and the reservoir. The cold and hot side chambers of the purification device thermally co-operate with each other to develop condensate therebetween from moisture present in the ambient air for forming water.

Abstract: A method for separating a mixture of materials A and B by extractive distillation, using an extraction medium having a higher affinity to B than to A, collecting a liquid fraction on a collecting tray and heated and partially evaporated in a first indirect heat exchanger, collecting the resultant vapor is released into the column and a non-evaporated proportion of the liquid fraction in the sump of the column, and a series of heating, separation and cooling where partially cooled extraction medium fraction is used as heating medium for a heat exchanger.

Abstract: Provided is a dust collection method using a dust collection device. The dust collection method includes: a step of forming a rotating airflow by means of suction with a suction device, the rotating airflow progressing while spiraling along an inner wall surface of a main body; a step of supplying liquid from a supply nozzle; a step of spreading out the liquid with the rotating airflow on the inner wall surface thereby to continuously form a liquid catcher, the liquid catcher rotating as a film of the liquid; and a step of separating smoke and/or dust to outside by centrifugal force due to the rotating airflow and capturing the smoke and/or dust with the liquid catcher, the smoke and/or dust being contained in air introduced to the inside of the main body.

Abstract: Disclosed are methods and modular devices for processing hydrocarbon feedstocks. In particular, the methods and modular devices disclosed herein provide for increasing the amounts of light fractions obtainable from a hydrocarbon feedstock.