Patents Examined by Elizabeth D. Wood
  • Patent number: 10512903
    Abstract: The present invention relates to a catalyst composition comprising a modified crystalline aluminosilicate of the Framework Type FER having Si/Al framework molar ratio greater than 20 characterized in that in said modified crystalline aluminosilicate the ratio between the strong acid sites and the weak acid sites, S/W, is lower than 1.0 and having the extra framework aluminum (EFAL) content lowered to less than 10 wt % preferably 5 wt % even more preferably less than 2 wt % measured by 27 Al MAS NMR. The present invention further relates to a process for producing olefins from alcohols in presence of said catalyst composition.
    Type: Grant
    Filed: September 24, 2015
    Date of Patent: December 24, 2019
    Assignees: TOTAL RESEARCH & TECHNOLOGY FELUY, IFP ENERGIES NOUVELLES
    Inventors: Nikolai Nesterenko, Delphine Minoux, Nadiya Danilina, Jean-Pierre Dath, Vincent Coupard, Sylvie Maury
  • Patent number: 10507460
    Abstract: A microspherical fluid catalytic cracking catalyst includes zeolite, and alkali metal alkaline earth metal ion.
    Type: Grant
    Filed: November 18, 2016
    Date of Patent: December 17, 2019
    Assignee: BASF CORPORATION
    Inventor: Karl C. Kharas
  • Patent number: 10500574
    Abstract: Provided are compositions, articles, systems and methods that comprise or use a catalyst composition comprising a zeolite having an LTA structure with iron, manganese or a combination thereof as an extra-framework metal. The zeolite can have a mole ratio of silica-to-alumina (SAR) of about 15 to about 70 and can contain about 0.5 to about 10 weight percent, based on the total weight of the zeolite, of extra-framework iron, manganese or a combination thereof.
    Type: Grant
    Filed: October 30, 2017
    Date of Patent: December 10, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventor: Joseph Fedeyko
  • Patent number: 10487024
    Abstract: The present invention relates to a zeolite catalyst for preparing light alkene by dehydrogenation of light alkane including a cocatalyst metal selected from tin (Sn), germanium (Ge), lead (Pb), gallium (Ga) and indium (In), and a preparation method of the same. The catalyst of the present invention is prepared by using the zeolite having a relatively high pore diameter, a structure of at least 12-membered ring, and a low acidity due to a SiO2/Al2O3 ratio of at least 50, so that it can suppress the inactivation of a catalyst caused by pore clogging due to the formation of coke. Therefore the catalyst of the present invention can be effectively used as a catalyst for the preparation of light alkene by dehydrogenation of light alkane.
    Type: Grant
    Filed: April 11, 2018
    Date of Patent: November 26, 2019
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Jeong-Rang Kim, Soo Jin Kwon, Hyung Ju Kim
  • Patent number: 10487027
    Abstract: The invention relates to zeolitic absorbents based on at least one zeolite with hierarchical porosity, containing barium or barium and potassium, to the uses thereof for separating para-xylene from aromatic fractions containing 8 carbon atoms, and to the method for separating para-xylene from aromatic fractions containing 8 carbon atoms.
    Type: Grant
    Filed: August 4, 2015
    Date of Patent: November 26, 2019
    Assignee: Arkema France
    Inventors: Catherine Laroche, Ludivine Bouvier, Cecile Lutz, Arnaud Baudot
  • Patent number: 10487025
    Abstract: A method of preparing a bound zeolite support comprising: contacting a zeolite powder with a binder and water to form a paste; shaping the paste to form an wet extruded base; removing excess water from the wet extruded base to form an extruded base; contacting the extruded base with a fluorine-containing compound to form a fluorinated extruded base; calcining the extruded base to form a calcined fluorinated extruded base; washing the calcined fluorinated extruded base to form a washed calcined fluorinated extruded base; drying the washed calcined fluorinated extruded base to form a dried washed calcined fluorinated extruded base; and calcining the dried washed calcined fluorinated extruded base to form a bound zeolite support.
    Type: Grant
    Filed: December 21, 2016
    Date of Patent: November 26, 2019
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: An-Hsiang Wu
  • Patent number: 10486145
    Abstract: The present invention relates to a process for the manufacture of a copper containing small-pore zeolite which comprises?preparing a reaction mixture comprising a zeolite of the faujasite framework type, Cu-tetraethylenepentamine (Cu-TEPA) and at least one compound M(OH)x, which does not comprise the tetraethylammonium cation and?heating the reaction mixture to form a copper containing small-pore zeolite.
    Type: Grant
    Filed: October 6, 2016
    Date of Patent: November 26, 2019
    Assignee: Umicore AG & Co. KG
    Inventors: Johan Adriaan Martens, Sreeprasanth Pulinthanathu Sree, Stef Jules Peter Kerkhofs, Elke Jane June Verheyen, Frank-Walter Schuetze
  • Patent number: 10486146
    Abstract: The present disclosure provides a zeolite-based compound having a high crystallinity, a method for producing the zeolite-based compound, and a method for producing methyl acetate using the zeolite-based compound. The zeolite-based compound includes a zeolite-based core; and a surface-portion formed on at least a portion of a surface of the zeolite-based core and made of ferrierite.
    Type: Grant
    Filed: April 30, 2018
    Date of Patent: November 26, 2019
    Assignee: Research & Business Foundation Sungkyunkwan University
    Inventors: Jong Wook Bae, Ji Hyeon Kim
  • Patent number: 10486147
    Abstract: A catalyst for converting dimethyl ether into light olefins, including ethylene and propylene. The catalyst comprises a mixture of two zeolites, ZSM-5 and ZSM-35, intimately mixed and kept in close proximity in a porous extruded binder system. The resulting combination of zeolites demonstrates a synergistic effect with respect to the conversion of the dimethyl ether and has improved resistance to deactivation due to carbon and coke formation than the individual zeolites alone when operating in this reaction. The catalyst is used to produce ethylene and propylene from a feed mixture containing methanol, dimethyl ether and water.
    Type: Grant
    Filed: August 8, 2019
    Date of Patent: November 26, 2019
    Assignee: Enerkem, Inc.
    Inventors: Stephane Marie-Rose, Ludovic Pinard, Jennifer Lorena Gil Coba
  • Patent number: 10478810
    Abstract: A zeolite catalyst capable of maintaining a high conversion of raw materials over a long period of time, and a method of producing a lower olefin stably over a long period of time using the zeolite catalyst is to be provided. A CON zeolite catalyst containing aluminum (Al) as a constituent element, wherein the CON zeolite catalyst has a ratio ((A2/A1)×100 (%)) of an integrated intensity area (A2) of signal intensity in a range from 57.5 ppm to 70 ppm to an integrated intensity area (A1) of signal intensity in a range from 45 ppm to 70 ppm is not less than 49.0% when analyzed by 27Al-MAS-NMR is prepared, and a lower olefin is produced by a MTO process using the zeolite catalyst.
    Type: Grant
    Filed: May 24, 2018
    Date of Patent: November 19, 2019
    Assignees: Mitsubishi Chemical Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Hiroaki Onozuka, Masahiro Hara, Masato Yoshioka, Toshiyuki Yokoi
  • Patent number: 10464053
    Abstract: A method to make a phosphorus modified zeolite can include providing a zeolite having at least one ten member ring, making an ion-exchange, steaming the zeolite, and introducing phosphorus on the zeolite. The zeolite can be mixed with one or more binders and shaping additives, and then shaped. A metal can be introduced, and the catalyst can be washed, calcined, and steamed in an equilibration step. The steaming can be at performed at a steam severity (X) of at least about 2. The steaming can be performed at a temperature above 625° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: November 5, 2019
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Nikolai Nesterenko, Delphine Minoux, Cindy Adam, Jean-Pierre Dath
  • Patent number: 10464863
    Abstract: Improved alkylation catalysts, alkylation methods, and methods of making alkylation catalysts are described. The alkylation method comprises reaction over a solid acid, zeolite-based catalyst and can be conducted for relatively long periods at steady state conditions. The alkylation catalyst comprises a crystalline zeolite structure, a Si/Al molar ratio of 20 or less, less than 0.5 weight percent alkali metals, and further having a characteristic catalyst life property. Some catalysts may contain rare earth elements in the range of 10 to 35 wt %. One method of making a catalyst includes a calcination step following exchange of the rare earth element(s) conducted at a temperature of at least 575° C. to stabilize the resulting structure followed by an deammoniation treatment. An improved method of deammoniation uses low temperature oxidation.
    Type: Grant
    Filed: June 22, 2016
    Date of Patent: November 5, 2019
    Assignee: Exelus, Inc.
    Inventors: Mitrajit Mukherjee, Eric Daniel Gauthier, Kelly Ann Coley
  • Patent number: 10456746
    Abstract: A selective catalytic reduction filter (SCRF) including a wall-flow substrate having inlet channels and outlet channels is provided. A first selective catalytic reduction (SCR) catalyst zone is present in the inlet channels, and a second SCR catalyst zone is present in the outlet channels. The first SCR catalyst zone includes an iron-exchanged zeolite catalyst, and the second SCR catalyst zone includes a copper-exchanged zeolite catalyst. Exhaust gas treatment systems including the SCRF and methods of reducing production of nitrous oxide (N2O) during selective catalytic reduction of an exhaust gas stream using the SCRF are also provided herein.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: October 29, 2019
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Shouxian Ren, Gongshin Qi
  • Patent number: 10449511
    Abstract: The present invention relates to a zeolite absorbent comprising at least one FAU zeolite with hierarchical porosity and comprising barium or barium and potassium, and the external surface area of which is greater than 20 m2·g?1, and the non-zeolite phase content being between 6% and 12% by weight with respect to the total weight of the absorbent. The present invention also relates to the use of such a zeolite absorbent as an adsorption agent, as well as the method for separation of para-xylene from aromatic isomer fractions with 8 carbon atoms.
    Type: Grant
    Filed: August 4, 2015
    Date of Patent: October 22, 2019
    Assignee: Arkema France
    Inventors: Ludivine Bouvier, Cecile Lutz, Catherine Laroche, Arnaud Baudot
  • Patent number: 10449524
    Abstract: The present invention relates to a catalyst product for cracking of heavy hydrocarbon feed stocks predominantly in to light olefins and processes for preparing the catalyst. More specifically the present invention relates to a process of preparing Fluidic Catalytic Cracking (FCC) catalyst additive composition. The FCC catalyst additive composition of the present invention is a LPG selective catalyst particles comprising a medium pore zeolite bonded with clay-phosphate-silica-alumina binder. The catalyst of the present invention exhibits improved selectivity towards high value components like propylene and gasoline and suppressing low value components like dry gas and bottoms.
    Type: Grant
    Filed: August 15, 2016
    Date of Patent: October 22, 2019
    Assignee: Indian Oil Corporation Limited
    Inventors: Mohan Prabhu Kuvettu, Mahesh Kadgaonkar, Biswanath Sarkar, Velusamy Chidambaram, Arumugam Velayutham Karthikeyani, Alex Pulikottil, Jayaraj Christopher, Brijesh Kumar, Biswapriya Das
  • Patent number: 10449525
    Abstract: A hydrocarbon conversion catalyst composition which comprises dealuminated ZSM-48 and/or EU-2 zeolite and a refractory oxide binder essentially free of alumina, processes for preparing such composition and processes for converting hydrocarbon feedstock with the help of such compositions.
    Type: Grant
    Filed: October 20, 2011
    Date of Patent: October 22, 2019
    Assignee: SHELL OIL COMPANY
    Inventors: Laszlo Domokos, Laurent Georges Huve, Hermanus Jongkind, Aan Hendrik Klazinga, Marcello Stefano Rigutto
  • Patent number: 10428280
    Abstract: The present disclosure relates to a method for preparing a multi-level pore zeolite, including: (A) a step of mixing a silicon precursor, an aluminum precursor, a phosphorus precursor, a structure directing agent and water; a step of (B) adding phenylphosphonic acid, carbon black or a mixture thereof to the mixture prepared in the step (A) and mixing the same; a step of (C) crystallizing the mixture prepared in the step (B) by heat-treating the same; and a step of (D) calcining the crystallization product, and utilization of the prepared multi-level pore zeolite as a catalyst for hydroisomerization of normal paraffins. The catalyst exhibits improved isoparaffin yield when it is used as a catalyst for hydroisomerization of normal paraffins such as diesel or lube base oil by supporting an active metal component because residence time of reactants and products in the zeolite crystals are decreased due to mesopores and the proportion of external acid sites to total acid sites is low.
    Type: Grant
    Filed: June 26, 2014
    Date of Patent: October 1, 2019
    Assignees: S-OIL CORPORATION, KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Chan-Ju Song, Sang Cheol Paik, Sang-Goo Lee, Min Kee Choi, Myoung Yeob Kim
  • Patent number: 10427142
    Abstract: Provided here are zirconium-substituted hierarchical zeolite compositions and methods of preparing such catalytic compositions. One such method involves subjecting the zirconium-substituted zeolite to a framework modification process using a single template to produce a framework-modified zeolite, followed by subjecting the framework-modified zeolite to an ion exchange process to produce a hierarchical zeolite composition. Also provided are methods of catalytic cracking of hydrocarbon feedstocks using these zirconium-substituted hierarchical zeolite compositions.
    Type: Grant
    Filed: March 29, 2019
    Date of Patent: October 1, 2019
    Assignees: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS, SAUDI ARABIAN OIL COMPANY
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami, Mohammed Abdul Bari Siddiqui, Mian Rahat Saeed, Rabindran Jermy Balasamy
  • Patent number: 10427141
    Abstract: In an embodiment, A catalyst comprises a zeolite comprising Si, Al, and Ge in the framework with Pt deposited thereon; wherein the catalyst has an Si:Al2 mole ratio of greater than or equal to 125, an Si:Ge mole ratio of 40 to 400, and an Na:Al mole ratio of 0.9 to 2.5; wherein the catalyst has an aluminum content of less than or equal to 0.75 wt %; wherein the catalyst is non-acidic.
    Type: Grant
    Filed: November 2, 2018
    Date of Patent: October 1, 2019
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Alla Khanmamedova, Scott Stevenson
  • Patent number: 10421062
    Abstract: The presently disclosed and claimed inventive concept(s) generally relates to a solid catalyst component comprising a zeolite with a modifier and at least one Group VIII meal alloyed with at least one transition metal. The presently disclosed and claimed inventive concept(s) further relates to a method of making the solid catalyst component and a process of converting mixed waste plastics into low molecular weight organic compounds using the solid catalyst component.
    Type: Grant
    Filed: February 7, 2019
    Date of Patent: September 24, 2019
    Assignee: AMG Chemistry and Catalysis Consulting, LLC
    Inventor: Anne Mae Gaffney