Abstract: An antistatic acrylic fiber having an electrical resistivity of about 10.sup.8 .OMEGA. centimeters or less. The fiber comprises (A) an acrylonitrile homopolymer or copolymer and (B) an antistatic polymer comprising a plurality of polyether segments disposed in said polymer (A), and wherein electrically conductive carbon black is dispersed in antistatic polymer (B). Preferably antistatic polymer (B) extends in the form of long and slender stripes in the polymer (A).
Abstract: Low temperature properties of resin-treated textiles are improved by using as the resin an acrylic emulsion polymer wherein the latex particles have a core-shell structure. The monomers forming the core are selected to provide a T.sub.g in the core of -20.degree. C. or lower and the monomer composition forming the shell is selected to provide a T.sub.g in the shell of about 60.degree. C. to about -10.degree. C. The core monomer composition contains a latent crosslinker together with an active crosslinker or a graftlinker, and the shell monomer composition contains a latent crosslinker.
Type:
Grant
Filed:
June 17, 1976
Date of Patent:
August 15, 1978
Assignee:
Rohm and Haas Company
Inventors:
Joseph E. Plamondon, William R. Wilber, Stephen Goth
Abstract: An improved ultraviolet curable aqueous latex paint suitable for use as coil coatings comprises a high molecular weight primary latex binder in combination with minor amounts of an emulsified low molecular weight cross-linking agent adapted to cross-link the high molecular weight latex particles upon exposure to ultraviolet energy.
Type:
Grant
Filed:
December 13, 1976
Date of Patent:
August 15, 1978
Assignee:
SCM Corporation
Inventors:
Vincent Daniel McGinniss, Robert Joseph Seidewand, James Robert Erickson
Abstract: The instant invention relates to an improved process for the production of cold-hardening polyurethane foams through the reaction of modified polyisocyanates with compounds having at least two active hydrogen atoms in the presence of blowing agents. The improved process is characterized by the fact that the modified polyisocyanate is prepared in a preliminary stage immediately before foaming.
Abstract: Tannin migration through a latex paint applied to a tannin-containing wood surface is inhibited by applying to the wood surface a linear, partially deacylated poly(N-acyl)alkylenimine, such as poly(N-propionyl)ethylenimine. The poly(N-acyl)alkylenimine can be applied to the wood surface either prior to or concurrently with the latex paint.
Abstract: A stabilized polyolefine-based polymeric composition is disclosed characterized in that it contains as stabilizer an organic polyamine having the general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are equal to or different from each other and are an alkyl group having from 1 to 4 carbon atoms;R.sub.5 is hydrogen or an alkyl group having from 1 to 4 carbon atoms;A is an alkylene group having from 2 to 10 carbon atoms;B is a divalent aliphatic, cycloaliphatic, aromatic or alkylaromatic radical, which can contain hetero atoms such as O, S, N and P either in the chain or as side substituents; andn is a whole number between 2 and 1000. The organic polyamine has an inherent viscosity of between 0.01 and 1 dl/g, and is employed in an amount equal to or less than 5% by weight. The stabilized polymeric composition may be in the form of fibers, filaments, films or other shaped articles. The organic polyamines themselves are novel, as are certain difunctional amine intermediates.
Abstract: A less colored, water-insoluble, hydrophilic gel which is a saponified product of the copolymer of a vinyl ester and an ethylenically unsaturated carboxylic acid or derivatives thereof, is prepared by drying said saponified product in a hydrated state. This gel is useful as an absorbent polymer material.
Abstract: An improved glossy, aqueous emulsion paint comprised of a mixture of a film-forming latex polymer and dispersed pigment is prepared by incorporating therein, as pigment dispersant, a water-soluble salt of a low molecular weight copolymer of hydroxyalkyl ester of acrylic or methacrylic acid and acrylic or methacrylic acid.
Type:
Grant
Filed:
January 7, 1977
Date of Patent:
July 25, 1978
Assignee:
Rohm and Haas Company
Inventors:
Peter Reeves Sperry, Richard J. Wiersema, Kayson Nyi
Abstract: Polymerization of chloroprene in an alkaline aqueous emulsion provides an improved latex by adding a specific amide to the emulsion, the amide being insoluble in water, soluble in the chloroprene and not being hydrolyzed by NaOH. The presence of an amide of this type makes it possible to obtain polychloroprene latices stabilized against ageing.
Abstract: Polyurethane compositions characterized by being heat curable to yield hard, impact-resistant articles having a high heat distortion temperature are disclosed. The cured polyurethane articles are transparent and also hydrolytic and UV light stable as well as being abrasion resistant. The polyurethane is prepared from a cycloaliphatic polyisocyanate, low molecular weight active hydrogen-containing material and optionally a polycarbonate diol. The weight percentage of the urethane moieties and the crosslinked density are carefully controlled so as to provide the proper balance of physical properties, particularly between hardness, flexibility and heat distortion temperature. The polyurethane articles are particularly useful in glazing applications such as aircraft glazing.
Abstract: There is disclosed a novel degradable plastic composition consisting of an organic polymeric material, said material having dispersed therein at least one organic derivative of a transition metal and at least one readily autoxidizable organic material.
Abstract: Novel bisphenol condensation derivatives including polyphosphorous, polyborate, polycarbonate and polysilicate products which are capped with various capping agents such as phenoxy or alkoxy compounds are efffective stabilizers for a wide spectrum of hydrocarbon polymeric materials against their thermal oxidative and photochemical degradations.
Abstract: Ethylenically unsaturated blocked aromatic diisocyanates are prepared which readily polymerize to form homopolymers and interpolymers with copolymerizable vinylidene monomers. Polymers can be prepared via emulsion polymerization, and exhibit excellent stability to hydrolysis when stored in latex form. The polymers cure at temperatures as low as 80.degree. C., and under acidic, neutral, or basic pH conditions. Homopolymers and interpolymers of the defined diisocyanates are useful as adhesives, and interpolymers of the ethylenically unsaturated blocked aromatic diisocyanates with acrylate monomers are particularly useful as binders for nonwoven fibers.
Abstract: Aqueous emulsions adapted for application to textile fabrics and which provide improved water and soil resistance are supplied using aqueous emulsion copolymers of nonreactive monoethylenically unsaturated monomers providing a T.sub.g below about 20.degree. C. with from 0.5% to 20% of reactive monoethylenically unsaturated monomer providing active hydrogen, preferably OH and most preferably the ##STR1## AND FROM 1 TO 40% OF A TERMINAL-BLOCKED LOWER ALKYL HYDROGEN POLYSILOXANE HAVING A VISCOSITY OF FROM 20 TO 1000 CP at 20.degree. C. In preferred practice, from 0.5 to 4% of the polysiloxane is used, and at least 50% of the copolymer is vinyl acetate.
Abstract: Solid particle-form, polymerizable or cross-linkable, multi-functional polymeric material containing blocked isocyanate groups wherein the blocked isocyanate groups making up said polymeric material comprise only a portion of the total isocyanate groups to produce said polymeric material, such as extrudable, thermosettable powdered blocked polyurethane (PBP) has been prepared. This material is useful per se for the manufacture of articles and may be added in combination with other materials, such as thermoplastic resin, e.g. polyethylene, polyvinyl cloride, for improving the usefulness, versatility and physical and/or chemical properties thereof. The polymeric material, such as PBP, is useful as a coating on metal and non-metallic surfaces, e.g. glass or fibrous surfaces, either as a protective coating or for the purpose of laminating such surfaces to another surface.
Abstract: A tire sealant composition which possesses the added ability of operating as a tire balancing composition is provided. Such composition comprises a fibrous component of asbestos fibers and a polyvinyl alcohol-containing liquid component. The composition has a viscosity of about 1000 to about 2200 cps at 100.degree. F.
Abstract: The specification relates to certain imido-oxamide-type compounds and derivatives thereof which are useful for preventing metal catalyzed oxidative degradation of polyolefins. The specification also relates to olefin homopolymer and copolymer compositions containing such compounds and derivatives thereof and to a method for enhancing the resistance of olefin homopolymers and copolymers against metal-catalyzed oxidative degradation by incorporating these compounds therein.
Abstract: Polymers of the type commonly used in packaging are rendered degradable through the action of sunlight by adding thereto up to 3% of an olefinically unsaturated compound containing at least two double bonds, such as 1,6-diphenylhexatriene.
Type:
Grant
Filed:
December 29, 1975
Date of Patent:
July 11, 1978
Assignee:
Snam Progetti S.p.A.
Inventors:
Nicola Palladino, Marcello Mazzei, Walter Marconi
Abstract: A novel thermosetting resin composition consisting essentially of (a) one equivalent of a polyfunctional epoxy compound containing 10 to 80% by weight of a polyglycidyl ester of a fatty acid, (b) 1.5 to 5 equivalents of a polyfunctional isocyanate compound and (c) 0.01 to 10% by weight of a curing catalyst based on the total weight of the polyfunctional epoxy compound and the polyfunctional isocyanate compound. A cured product having excellent thermal resistance and excellent thermal shock resistance which is suitable for the molding of a large apparatus can be obtained by heating said thermosetting resin composition.
Abstract: The present invention relates to the production in closed molds, of foams with outstanding mold-release properties. These improved properties are obtained by including in the foamable mixture salts of saturated or unsaturated aliphatic or cycloaliphatic carboxylic acids having at least 8 carbon atoms and tertiary amines of the type in which the atom ratio of tertiary amine nitrogen to carbon in the molecule is between 1:3 and 1:12.
Type:
Grant
Filed:
March 7, 1977
Date of Patent:
July 4, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Wulf von Bonin, Helmut Kleimann, Jozsef Ivanyi