Abstract: Novel substituted decahydroquinolines are prepared and used as ultraviolet (UV) light stabilizers for materials subject to UV light degradation, particularly for polyolefins. Compositions containing the decahydroquinoline compounds exhibit excellent stability to UV light.
Abstract: A plastic composition degradable under the influence of weather or light, comprising a plastic material and finely divided titanium dioxide with a specific surface of more than about 20 m.sup.2 /g. Preferably the titanium dioxide is obtained by hydrolyzing titanium sulfate in aqueous solution, has a predominantly anatase structure, a lightening power of less than about 400, a specific surface of about 60 to 400 m.sup.2 /g and is present in about 0.5 to 5% by weight of the composition, and the plastic material is selected from the group consisting of polyethylene, ethylene-vinyl acetate copolymer, polystyrene, polyvinyl chloride, polyamides and ABS-polymers.
Type:
Grant
Filed:
July 18, 1975
Date of Patent:
February 14, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Heinz-Peter Hemmerich, Gerhard Winter, Hans J. Rosenkranz, Peter Woditsch
Abstract: In a process for preparing a smoke-retardant polyisocyanurate foam by reacting an organic polyisocyanate in the presence of a blowing agent and an isocyanate-trimerization catalyst, an improvement is characterized in that the reaction is conducted in the presence of an organosilicate having the formula Si(OR).sub.4 or R.sub.n Si(OR').sub.4-n wherein R and R' are the same or different and represent aliphatic, alicyclic and aromatic hydrocarbon groups having 1-12 carbon atoms or substituted derivatives thereof and n is an integer of 1 to 3.
Abstract: Polyamide resins of fatty acids are prepared by reacting polymeric fatty acids, an alkylene diamine, monoaminoalcohol and a chain stopping agent which includes a particular branched chain monocarboxylic fatty acid which is liquid at room temperature. The use of this particular chain stopping agent provides polyamide resins which are resistant to gelling during storage.
Abstract: Highly flame-resistant polyurethane foams of improved friability and reduced brittleness without a corresponding substantial increase in flame-spread or smoke-generation characteristics are prepared by incorporating into a foamable polyurethane composition an amount of a liquid organic carbonate, such as ethylene or propylene carbonate.
Abstract: The invention relates to bichromophoric benzotriazole-styrene compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
Type:
Grant
Filed:
August 16, 1976
Date of Patent:
January 24, 1978
Assignee:
Eastman Kodak Company
Inventors:
Gether Irick, Jr., Charles A. Kelly, James C. Martin
Abstract: The invention relates to bichromophoric benzotriazole-styrene ester compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
Type:
Grant
Filed:
August 16, 1976
Date of Patent:
January 24, 1978
Assignee:
Eastman Kodak Company
Inventors:
Gether Irick, Jr., Charles A. Kelly, James C. Martin
Abstract: This invention relates to a process for the production of polyurethane foams in closed molds using mixtures of organic polyisocyanates with certain compounds which liberate carbon dioxide under the catalytic influence of basic compounds. In this process a mixture of polyisocyanates and compounds which liberate carbon dioxide under the catalytic influence of basic compounds is reacted with organic compounds containing hydrogen atoms which are reactive with isocyanate groups, which organic compounds are mixed with basic compounds and/or have basic compounds chemically built into them. The process is suitable for the production of any polyurethane foams in a closed mold, but is preferably applied to the production of semi-hard and particularly of hard polyurethane foams having a dense outer skin.
Type:
Grant
Filed:
May 28, 1976
Date of Patent:
January 24, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Heinz-Georg Schneider, Helmut Kleimann, Bruno Luckas
Abstract: This invention relates to inks, ink emulsions, and to transfer elements as well as their methods of manufacture. The transfer elements provided by the invention are useful in providing imprints, including infra-red scannable imprints which are sharp, well defined prints with no feathering and which have fast dry and have excellent smudge resistance. The transfer elements comprise a substantially non-absorbent base having a coating comprising a continuous phase containing, as a discontinuous phase, a colorant carried by a vehicle comprising at least one C.sub.12 to C.sub.20 alcohol, said vehicle having a melting point below about 20.degree. C.
Abstract: A composition including a diisocyanate and 1-methyl-2-vinyl-4,6-heptadienol. This composition is capable of curing in air at room temperature after aging in a dry nitrogen atmosphere.
Abstract: Flame retardant elastomeric compositions comprised of either spandex type polyurethane having incorporated into the polymer chain halogen containing polyols, conventional spandex type polyurethanes in physical admixture with flame retardant additives or fluoroelastomeric resins in physical admixture with flame retardant additives, methods of preparing fibers of the flame retardant elastomeric materials and articles of manufacture comprised of the flame retardant elastomeric materials and non-elastic materials such as polybenzimidazoles, fiberglass, nylons, etc.
Type:
Grant
Filed:
February 13, 1976
Date of Patent:
January 17, 1978
Inventors:
James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, John T. Howarth, Suresh Sheth, Kenneth R. Sidman, Arthur A. Massucco
Abstract: Novel substituted decahydroquinolines are prepared and used as ultraviolet (UV) light stabilizers for plastic materials subject to UV light degradation, particularly for polyolefins. Compositions containing the decahydroqinoline compounds exhibit excellent stability to UV light.
Abstract: Covers novel urethane-modified polyisocyanurate rigid foams comprising the reaction product obtained by bringing together in the presence of a blowing agent an aromatic polyisocyanate, an isocyanurate group formation catalyst, and a polyol comprising a specific alkylene oxide adduct of aniline. The novel foams are useful in preparing rigid foam material such as panels, slabs, or sprayed foam surfaces.
Abstract: Mixtures comprising a low molecular weight diol, a liquid modifier compound having a boiling point above about 150.degree. C, such as a fatty acid or fatty oil, a polyisocyanate having a functionality of at least about 2.5 and an organotin catalyst instantly set, after a brief induction period, to a solid, dense, rigid polymeric product which can be demolded within a period of from less than 1 minute to about 5 minutes.
Abstract: Compounds (aminimides) of the class wherein a negatively charged nitrogen atom of an acylamide is directly bonded to a cationic nitrogen atom having one hydroxyethyl and two methyl substituents represent uniquely effective catalysts for the trimerization of the isocyanate radical. These aminimides are especially useful as catalysts for the preparation of rigid polyisocyanate-polyisocyanurate foams.
Abstract: Protective coatings, such as paints and liquid formulations therefor, containing a masked chromogen which signals contact with a body fluid when the protective coating is masticated or ingested are disclosed. The chromogen is capable of producing a contrasting color when masticated and/or ingested, thereby signaling that the individual who masticated and/or ingested the chromogen may have ingested an undesirable or hazardous substance, e.g., a lead-based paint, that has been covered by the protective coating. The chromogen is substantially indiscernible in the paint and converts by reaction with an activator substance, e.g., by reaction with saliva, gastric juices, or the like, to a colored form which then stains the body fluids and/or the body tissues, and which may also stain the original source of the undesirable substance.
Abstract: An environmentally degradable polymer based composition which has been exposed to actinic or ionizing radiation and which comprises an ethylene polymer base resin, and a synergistic combination of an auto-oxidative polymer or low molecular weight organic compound, certain polyvalent metal salts, and an antioxidant additive for the ethylene polymer; and a process for making such composition.
Type:
Grant
Filed:
August 20, 1975
Date of Patent:
January 10, 1978
Assignee:
Union Carbide Corporation
Inventors:
James Edward Potts, Stephen Watson Cornell, Albert Martin Sracic
Abstract: Flexible, light-stable polyurethane foam. Aliphatic diisocyanates are reacted with polyether polyols and polyfunctional cross-linking agents in the presence of water, a metal catalyst and a strong base catalyst. The polyether polyols must have an equivalent weight of at least 2,000 while the cross-linking agent must have at least three primary hydroxyl groups and have an equivalent weight of less than 100. The strong base catalyst must be present at from about 3.8 .times. 10.sup.-4 to about 1.25 .times. 10.sup.-3 equivalents per 100 parts polyether polyol.
Abstract: Intaglio and flexographic printing processes employing solvent-free inks, solid at room temperature but molten at printing temperatures, are disclosed, as are inks suitable therefor, said inks comprising a pigment and a thermoplastic binder having a softening point between 90.degree. C. and 160.degree. C., said binder comprising a synthetic polyamide resin or synthetic polyesteramide resin, each resin being the condensation product of (1) an acid component comprising a dimerized fatty acid and a monocarboxylic acid and (2) an amine component comprising a diamine and, in the case of the polyesteramide resin, additionally comprising a diol and/or alkanolamine.