Abstract: A polyester pressure-sensitive adhesive composition is provided including a polyester resin having a predetermined amount of a structural unit derived from a hydrogenated polybutadiene structure-containing compound, or a polyester resin having a structural unit derived from a hydrogenated polybutadiene structure-containing compound and a predetermined amount of a structural unit derived from an aromatic ring structure-containing compound. The polyester pressure-sensitive adhesive composition has superior adhesion to a polyolefin base material and is highly transparency.
Abstract: A process for polymerizing ?-butyrolactone that includes contacting racemic ?-butyrolactone or an enantiomer thereof with a catalyst/initiator system which includes a rare earth metal, a chiral ligand, at least one nucleophilic ligand, optionally at least one solvent ligand, and optionally an alkali based co-catalyst. The chiral ligand is an enantiomer of a unit of formula I Each Rz independently is substituted or unsubstituted linear C1-C20 alkyl, or substituted or unsubstituted branched, or cyclic C3-C20 alkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C5-C20 heteroaryl, or halogen. Each Ra independently is H, Me+, (MeZ)+, wherein Z is a charge equalizing anion, or wherein two Ra together are alkaline earth metal, wherein Me+ is alkali metal or alkaline earth metal.
Abstract: Polycarbonate block copolymers are provided, which have: (A) a polyester block of chemical formula 1; and (B) a polycarbonate block derived from a dihydric phenol of chemical formula 3 compound and phosgene. The copolymers may be prepared by (1) polymerizing ester oligomers to form a compound of chemical formula 1; and (2) copolymerizing the ester oligomer obtained in (1) with a polycarbonate oligomer prepared from a dihydric phenol compound of chemical formula 3 and phosgene, in the presence of a polymerization catalyst. The block copolymer may have a viscosity average molecular weight (Mv) of 10,000 to 200,000.
Type:
Grant
Filed:
January 19, 2017
Date of Patent:
September 27, 2022
Assignee:
SAMYANG CORPORATION
Inventors:
Kyung Moo Shin, Jin Sik Choi, Young Do Kwon
Abstract: A process for recycling thermoplastic polymer material to produce polymer pre-form, the process comprising the steps of pre-treating a polymer material for example by separating, sorting, cleaning and/or shaping; shredding the pre-treated polymer to produce polymer flakes; and processing the polymer material to produce a pre-form, characterised in that prior to the step (iii) of producing the pre-form, the polymer flakes are compacted to form pellets.
Abstract: Calendered films or sheets obtained from a composition comprising at least one polyester which has the L* color value of greater than 90 and comprises terephthalic acid residues, optional aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; glycol component comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and ethylene glycol residues; a catalyst/stabilizer component which comprises titanium atoms, manganese atoms, phosphorous atoms; fillers; release additives and does not comprises tin atoms. Calendered films or sheets can be used in a wide range of applications including packaging, pool liners, graphic arts, transaction cards, security cards and others.
Type:
Grant
Filed:
August 17, 2017
Date of Patent:
September 20, 2022
Assignee:
Eastman Chemical Company
Inventors:
Marc Alan Strand, Robert Erik Young, James Thomas Goetz, Douglas Weldon Carico, Jr.
Abstract: Two part sole structures are provided having a first foam component containing a polyolefin resin with a polyurethane resin component adhered to a surface of the first foam component. For example, in some aspects, a sole structure or a portion thereof is provided having a first sole component containing a foam composition and a second sole component adhered to a surface of the first sole component, where the second sole component includes a polyurethane resin. The second sole component is in some aspects printed or extruded onto the surface of the foam. In particular, midsoles including the foams and having an outsole component on the ground facing portion are provided for use in an article of footwear. Methods of making the sole structures are provided, as well as methods of making an article of footwear including one of the sole structures.
Abstract: A graphene oxide Janus nanosheets relative permeability modifier (RPM) for carbonate formations. The graphene oxide Janus nanosheets RPM may be used to treat a water and hydrocarbon producing carbonate formation to reduce water permeability in the formation and increase the production of hydrocarbons. The graphene oxide Janus nanosheet RPM includes a first side having negatively charged functional groups and a second side having alkyl groups. The alkyl groups may include C8 to C30 alkyls. The negatively charged functional groups may include carboxyl groups, epoxy groups, and hydroxyl groups. Methods of reducing water permeability of a carbonate formation using the graphene oxide Janus nanosheets RPM and methods of manufacturing the graphene oxide Janus nanosheets RPM are also provided.
Abstract: A method of designing compressible particles for a fluid mixture. The compressible particles are intended to be used for attenuating pressure within a confined volume such as a trapped annulus. Preferably, the compressible particles reside buoyantly within an aqueous fluid, forming a fluid mixture. Each of the compressible particles is fabricated to collapse in response to fluid pressure within the confined volume, and comprises carbon. The particles may each have a porosity of between 5% and 40%, and a compressibility of between 10% and 30%, at 10,000 psi. The particles are tuned to have a buoyancy that is lower than the carrier fluid while still having resiliency.
Type:
Grant
Filed:
November 12, 2019
Date of Patent:
September 6, 2022
Assignee:
ExxonMobil Upstream Research Company
Inventors:
Ward E. Narhi, Sandeep A. Kibey, David A. Stiles, Michael R. Awe, Adam W. Aylor
Abstract: A method of manufacturing a molded article by a low shear manufacturing process that includes: placing a solid polyester in a mold having mold surfaces; heating said polyester until it becomes molten; dispersing said molten polyester over said mold surfaces; solidifying said molten polyester to form a solid molded article; and removing said molded article from said mold; where the polyester is obtained by polymerization of dimethylcyclohexane dicarboxylic acid, cyclohexane dimethanol, polytetramethylene ether glycol and branching agent and has a steep melting curve evidenced by a puddling curve slope of ?2 to ?10.
Type:
Grant
Filed:
November 21, 2019
Date of Patent:
August 30, 2022
Assignee:
Eastman Chemical Company
Inventors:
Marc Alan Strand, Laura Bauerle Weaver, Robert Erik Young
Abstract: A method for removing hydrogen sulfide from a hydrocarbon. The method comprises introducing methylmorpholine-N-oxide to a vessel, wherein the vessel comprises the hydrocarbon, and wherein the hydrocarbon comprises hydrogen sulfide; and treating the hydrocarbon by allowing the methylmorpholine-N-oxide to react with the hydrogen sulfide.
Abstract: A heat-resistant, bio-based polycarbonate ester prepared by melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate, 1,4-cyclohexanedicarboxylate, or a terephthalate is disclosed. The heat-resistant, bio-based polycarbonate ester includes a repeat unit 1 of Formula 1, a repeat unit 2 of Formula 2, and a repeat unit 3 of Formula 3: The polycarbonate ester has excellent heat resistance, transparency, and processability. A method of producing the polycarbonate includes a step of melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate, 1,4-cyclohexanedicarboxylate, or a terephthalate.
Abstract: A polyester resin, including: (a) a constitutional unit derived from at least one tetravalent carboxylic acid selected from Compounds (A) and (B); a constitutional unit derived from a bisphenol A-alkylene oxide adduct; and a constitutional unit derived from an aliphatic alcohol having a boiling point of lower than or equal to 290° C.
Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.
Abstract: A drilling fluid formulation is provided, which includes a fluid phase, an organophilic phyllosilicate as an anti-sagging additive, and a weighting agent (e.g. barite). The organophilic phyllosilicate contains an ion-exchange reaction product of a clay material (e.g. smectite) and quaternary ammonium cations. The organophilic phyllosilicate is effective in preventing barite sagging as demonstrated by low sag factor when drilling at elevated temperatures. Rheology properties of the drilling fluid including gel strength, yield point, plastic viscosity, and storage modulus are also specified.
Type:
Grant
Filed:
August 20, 2019
Date of Patent:
August 16, 2022
Assignee:
King Fahd University of Petroleum and Minerals
Abstract: There are provided recycled polystyrene polymers having a melt flow index of less than about 25 g/10 min. There are provided processes for recycling polystyrene waste. The processes can comprise dissolving said polystyrene waste in p-cymene under conditions to obtain a polystyrene/p-cymene mixture, adding the polystyrene/p-cymene mixture to a hydrocarbon polystyrene non-solvent under conditions to obtain precipitated polystyrene and washing the precipitated polystyrene with additional portions of hydrocarbon polystyrene non-solvent under conditions to obtain twice-washed polystyrene. The twice-washed polystyrene can optionally be dried and formed into polystyrene pellets. There is also provided recycled polystyrene obtained from such processes for recycling polystyrene waste.
Abstract: A polyester resin and a coating composition containing the polyester resin are disclosed. The polyester resin includes a repeating unit obtained by copolymerizing (a) a divalent acid component and (b) a diol component containing (b-1) an isosorbide and (b-2) a cycloaliphatic diol, and has excellent heat resistance and solubility in a solvent. The cycloaliphatic diol may be one or more diol derivatives of a tricycle C7-14 alkane. A coating formed from a coating composition containing the polyester shows excellent heat resistance, hardness, chemical resistance, pollution resistance, and hydrolysis resistance.
Abstract: A fluid mixture for attenuating pressure within a confined volume. The fluid mixture comprises an aqueous carrier fluid. The fluid mixture further comprises a plurality of compressible particles dispersed in the carrier fluid. Each of the compressible particles is fabricated to collapse in response to fluid pressure within a confined volume. Each of the compressible particles has a density that is less than a density of the carrier fluid and has a compressibility of between 10% and 30%, up to 10,000 psi. A column of fluid within a trapped annulus of a wellbore is also presented, wherein the column of fluid has a plurality of compressible particles dispersed in a carrier fluid.
Abstract: A copolymerized saturated polyester resin is formed by polycondensation of an acid component and an alcohol component. The acid component contains (a-1) 90 to 99% by mole of an aromatic dicarboxylic acid or a C1-2 alkyl ester thereof and (a-2) 0.5 to 2% by mole of a trifunctional or higher functional carboxylic acid or an anhydride thereof. The alcohol component contains (b-1) 45 to 80% by mole of an alicyclic polyhydric alcohol and (b-2) 20 to 55% by mole of an aliphatic polyhydric alcohol having a C1-3 alkyl side chain. A coating composition containing the copolymerized saturated polyester resin shows excellent corrosion resistance and chemical resistance. A coating film formed from the coating composition shows excellent processability and resin solubility, and is useful for coating a can and pre-coated metal.
Type:
Grant
Filed:
January 31, 2019
Date of Patent:
August 2, 2022
Assignee:
SK CHEMICALS CO., LTD.
Inventors:
Hyung-Gon Kim, Jong-Ki Sim, Soon-Ki Kim
Abstract: A reversibly crosslinked polymer and methods for producing and using the obtained polymer are disclosed. In particular, reversibly crosslinked polymers of the invention comprise polyesters formed by the reaction of mercaptosuccinic acid and a diol to form a monomeric unit that includes thiol groups as crosslinking moieties. Oxidation of the thiol groups affords crosslinked polymer comprising a disulfide linkage that, upon reduction of the disulfide linkage, provides a non-crosslinked polymer. In some embodiments, polymers of the invention are degradable and are biocompatible.
Abstract: Vents and micro-structures of rubber molds may become clogged with rubber that is difficult to remove. These vents and micro-structures can be cleaned of rubber, even if heat aged, by subjecting the mold to high temperatures in the presence of a solvent to devulcanize any rubber present. If the rubber used with the mold being cleaned includes carbon black, a solvent may be used to dissolve the devulcanized polymer, leaving the carbon black which can be removed by water jets or other cleaning means.
Type:
Grant
Filed:
July 30, 2018
Date of Patent:
July 5, 2022
Assignee:
Rubreco, Inc.
Inventors:
Brian H. Harrison, Hurdon A. Hooper, Mathew Ness