Abstract: The present invention is directed to a golf ball comprising a core and a cover, wherein the cover comprises a blend of two or more high acid ionomer resins. Each high acid ionomer resin utilized in the blend of the cover composition comprises generally of greater than 16% by weight acid, preferably from about 17 to about 25% by weight acid and more preferably from about 18.5% to about 21.5% by weight acid. The acid groups of the high acid ionomers utilized in the cover compositions of the invention are partially (i.e. generally 10-75 percent, preferably 30-70 percent) neutralized by metal ions such as by sodium, zinc and magnesium ions. When the blend of two or more high acid ionomer resins is utilized to manufacture a golf ball, the golf ball produced thereby, exhibits properties of improved distance without sacrificing characteristics such as playability and/or durability when compared to low acid ionomer and/or low acid/high acid ionomer blends.
Abstract: A process for producing a fluorine-containing acrylic or methacrylic polymer, comprises polymerizing a fluorine-containing acrylate or methacrylate in a solution phase formed of an organic solvent and dissolved therein a monomer containing a fluorine-containing acrylate or methacrylate having a polyfluoroalkyl group having 6 to 16 carbon atoms. A non-halogen type solvent is used as the organic solvent and the fluorine-containing acrylate or methacrylate is so polymerized that a polymer-containing liquid phase comprised of the fluorine-containing acrylic or methacrylic polymer formed with progress of polymerization and the organic solvent is separated from the solution phase.
This process enables production of a fluorine-containing acrylic or methacrylic polymer having a fluorine monomer in a high proportion by the use of a commonly available general-purpose solvent, without using any fluorine type solvent.
Abstract: A fluoropolymer composition is provided. The polymer comprises interpolymerized units derived from (i) tetrafluoroethylene, (ii) vinylidene fluoride, (iii) at least one ethylenically unsaturated monomer of the formula CF2═CFRf where Rf is a perfluoroalkyl or a perfluoroalkoxy of 1 to 8 carbon atoms, and (iv) a perfluorovinyl ether of the formula CF2═CF—(OCF2CF(Rf))aOR′f where Rf is as described in (iii), R′f is a perfluoroaliphatic, preferably a perfluoroalkyl or a perfluoroalkoxy, of 1 to 8, preferably 1 to 3, carbon atoms, and a has a value of 0 to 3.
Type:
Grant
Filed:
June 27, 2000
Date of Patent:
December 3, 2002
Assignee:
Dyneon LLC
Inventors:
Denis Duchesne, Harald Kaspar, Lisa P. Chen, Klaus Hintzer, Attila Molnar, Ludwig Mayer, Gernot Löhr
Abstract: The invention is a catalytic ion exchange resin bed with low pressure drop, low catalyst breakage and low catalyst deactivation as well as an improved process for the production of bisphenol A employing such a catalytic ion exchange resin bed.
Type:
Grant
Filed:
April 9, 2001
Date of Patent:
November 26, 2002
Assignee:
General Electric Company
Inventors:
Gaylord M. Kissinger, Sheldon J. Shafer, Harish R. Acharya, Rudy Francois Alain J. Peemans, Eduard H. Schlarmann
Abstract: Polymerization process of unsaturated pefluoromonomers, fluoro-containing monomers and optionally in the presence of hydrogen containing olefins, for obtaining polymers contaning hydrogen and fluorine, which utilizes a microemulsion comprising the following components:
(a) water;
(b) a fluoropolyoxyalkylene having hydrogen-containing end groups and/or hydrogen-containing repeating units;
(c) a fluorine-free organic radicalic initiator for the polymerization of fluoro-containing monomers, soluble in component (B);
(d) a fluoro-containing surfactant.
Abstract: A fluorine-containing adhesive comprising a fluorine-containing ethylenic polymer (A) having functional group which has a crystalline melting point or glass transition temperature of not more than 270° C. and is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of carboxyl and a carboxylic salt group and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers which do not have the above-mentioned functional group and is copolymerizable with the component (a). To provide the fluorine-containing adhesive maintaining chemical resistance, solvent resistance, weather resistance and stain-proofing property and giving direct strong adhesion particularly to a substrate of metal, glass, resin, etc. and an adhesive film and laminated article which are produced from the fluorine-containing adhesive.
Abstract: A method of treating a fabric or fabric blend to impart soil release properties is disclosed comprising application to the surface of the fabric or fabric blend of a copolymer composition comprising three monomers copolymerized in certain weight percentages wherein the hydrophilic and oleophobic properties of the treated fabric or fabric blend are varied by varying the relative amounts of the monomers employed.
Abstract: A radiation absorbing polymer having chemically bonded thereto a radiation absorbing dye, which has high absorption at a predetermined wavelength radiation, which shows good adhesion to a substrate and good thin film-forming, which has no dependence upon resists, which is soluble in a solvent for photoresists but becomes insoluble after being baked; a composition for radiation absorbing coating containing this polymer, and a radiation absorbing coating such as an anti-reflective coating formed from this composition are disclosed. The radiation absorbing polymer comprises a copolymer containing at least both a recurring unit composed of a monomer containing a keto group and a divalent group (preferably a methylene group) in its side chain and a recurring unit composed of a monomer containing an organic chromophore bonded directly or through a linkage group to the main chain. This radiation absorbing polymer is dissolved in a solvent such as alcohol, aromatic hydrocarbon, ketone, ester, etc.
Type:
Grant
Filed:
February 4, 1999
Date of Patent:
October 22, 2002
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Wen-Bing Kang, Munirathna Padmanaban, Hatsuyuki Tanaka, Ken Kimura, Takanori Kudo, Georg Pawlowski
Abstract: Amorphous fluoropolymer selfsupported manufactured articles obtained by casting from solution in a single step, characterized in that they are obtained by the polymerization of a structure (I), optionally and preferably with a monomer having a structure (II):
CF2=CY1Y2 (II)
wherein: Rf is a C1-C5 perfluoroalkyl radical; X1 and X2 are selected from F and CF3; Y1 and Y2 are selected from F, Cl, H, CF3, ORf; having refractive index lower than 1.35, transmittance higher than 90% in the radiation field 300-2,000 nm wave length, and thickness higher than 20-25 &mgr;m.
Abstract: A fluoroelastomer composition having improved compression set. The fluoroelastomer composition comprises: (1) a fluoroelastomer containing interpolymerized units of at least one perfluoroolefin, at least one perfluorovinyl ether, and a cure site component capable of participation in a peroxide cure reaction; (2) an additive selected from the group consisting of organo-oniums, phosphates, phosphine oxides, amine oxides, alkyl amines, and heterocyclic amines and salts of heterocyclic amines; (3) a peroxide curative, and (4) optionally a coagent.
Abstract: The present invention is related to a resin for use in an antifouling coating which is a polymer obtained by polymerizing a polymerizable unsaturated monomer(s) and having, at side chain terminals thereof, a trisubstituted borane-amine complex and an azomethine group, or a group represented by the following general formula (1):
(wherein M represents a metal selected from the group consisting of copper, zinc, nickel and cobalt, - - - means a chemically bound state, W represents —N(R1)R2— (in which R1 and R2 may be the same or different and each represents a hydrogen atom or an alkyl group containing 1 to 4 carbon atoms), —OCO—, —OSO2— or
L represents an alkylene group containing 1 to 4 carbon atoms, and m represents an integer of 0 to 4).
Abstract: The present invention relates to a fiber which comprises at least one partly crystalline cycloolefin copolymer which can be prepared by polymerization of a symmetrical polycyclic olefin, an acyclic olefin and, if desired, a monocyclic olefin in the presence of a catalyst system comprising an aluminoxane and a metallocene compound of the formula
Abstract: Compositions comprising a polymer of organometallic polymerizable monomer acid or ester are useful as resists and are sensitive to imaging irradiation while exhibiting enhanced resistance to reactive ion etching.
Type:
Grant
Filed:
October 3, 2000
Date of Patent:
October 1, 2002
Assignee:
International Business Machines Corporation
Inventors:
Marie Angelopoulos, Ari Aviram, C. Richard Guarnieri, Ranee W. Kwong
Abstract: Poly(p-arylene-vinylenes) comprising repeating units of the formula (I),
where the symbols and indices have the following meanings:
Y1, Y2, Y3: identical or different, CH, N;
Aryl: an aryl group having from 4 to 14 carbon atoms;
R′, R″: identical or different, each a straight-chain or branched or cyclic alkyl or alkoxy group having from 1 to 20 carbon atoms, where one or more non-adjacent CH2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR1—, —(NR2R3)+—A−, or —CONR4— and one or more H atoms may be replaced by F, or else CN, F, Cl or an aryl group having from 4 to 14 carbon atoms which may be substituted by one or more nonaromatic radicals R′;
R1, R2, R3, R4: identical or different, aliphatic or aromatic hydrocarbon radicals having from 1 to 20 carbon atoms or else H;
A−: a singly charged anion or its equivalent;
m: 0, 1 or 2;
n: 1, 2, 3,
Type:
Grant
Filed:
December 16, 1997
Date of Patent:
October 1, 2002
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Hubert Spreitzer, Willi Kreuder, Heinrich Becker, Harmannus Schoo, Robert Demandt
Abstract: Polyolefin compositions in powder form suited for metal coating, including (percentage by weight):
1) from 1% to 40% of hollow microspheres;
2) from 60% to 99% of a composition comprising:
a) from 25% to 95% of polypropylene, polyethylene or crystalline propylene copolymers or mixtures thereof;
b) from 0% to 70% of an elastomeric copolymer;
c) from 0.5% to 10% of propylene or polyethylene modified with polar groups;
d) from 0% to 10% of titanium dioxide.
Abstract: A fluorine-containing copolymer comprising ethylene, tetrafluoroethylene, a fluorovinyl compound of the formula: CH2═CFRf in which Rf is a fluoroalkyl group having 2 to 10 carbon atoms, and hexafluoropropylene, in which a molar ratio of tetrafluoroethylene to ethylene is from 40:60 to 90:10, the content of the above fluorovinyl compound of the formula: CH2═CFRf is from 0.1 to 10 mole % based on the whole copolymer, and the content of hexafluoropropylene is from 0.1 to 30 mole % based on the whole copolymer. This fluorine-containing copolymer can provide films having good transparency and high tear strength, and such films are useful as weather-resistant protective films, films for agricultural housings, films for constructions, and the like.
Type:
Grant
Filed:
March 9, 1999
Date of Patent:
September 24, 2002
Assignee:
Daikin Industries, Ltd.
Inventors:
Ken Okanishi, Keizo Shiotsuki, Ryoichi Fukagawa
Abstract: A method for regenerating strong-base anion exchange resins utilizing a sequential chemical displacement technique with new regenerant formulation. The new first regenerant solution is composed of a mixture of ferric chloride, a water-miscible organic solvent, hydrochloric acid, and water in which tetrachloroferrate anion is formed and used to displace the target anions on the resin. The second regenerant is composed of a dilute hydrochloric acid and is used to decompose tetrachloroferrate and elute ferric ions, thereby regenerating the resin. Alternative chemical displacement methods include: (1) displacement of target anions with fluoroborate followed by nitrate or salicylate and (2) displacement of target anions with salicylate followed by dilute hydrochloric acid. The methodology offers an improved regeneration efficiency, recovery, and waste minimization over the conventional displacement technique using sodium chloride (or a brine) or alkali metal hydroxide.
Type:
Grant
Filed:
January 25, 2000
Date of Patent:
September 10, 2002
Assignee:
U.T. Battelle, LLC
Inventors:
Gilbert M. Brown, Baohua Gu, Bruce A. Moyer, Peter V. Bonnesen
Abstract: Pressure sensitive adhesive (PSA) polymers, especially low Tg, high tack, nonpolar and polar polymers useful in formulating PSA can be solubilized or dispersed in a supercritical fluid (SCF), such as liquid CO2 or supercritical CO2, using an organic cosolvent such as toluene. PSA polymers can be polymerized in SCF fluids to make unique adhesive products. Inclusion of a fluorinated reactant in the SCF polymerization process yields a PSA with improved resistance to mineral oil.
Type:
Grant
Filed:
October 28, 1998
Date of Patent:
September 3, 2002
Assignee:
Nitto Denko Corporation
Inventors:
Vincent D. McGinniss, Bhima R. Vijayendran, Kevin B. Spahr, Kazuhiko Shibata, Takayuki Yamamoto
Abstract: (Meth)acrylic polymers having alkenyl or curable silyl groups at the chain ends in high functionality ratios are prepared by a process which comprises (i) preparing a (meth)acrylic polymer having halogen atoms at the chain ends, using an organohalogenated compound or a halosulfonyl compound as an initiator and a metal complex catalyst wherein the central metal atom is selected from the group consisting of the elements of Groups 8, 9, 10 and 11 of the periodic table; and (ii) transforming the halogen atom into an alkenyl group- or a curable silyl group-containing substituent.
The obtained (meth)acrylic polymers form homogeneous curing materials.