Abstract: There is provided a material for a soft intraocular lens, which has excellent transparency and flexibility, can be inserted from a small incision and has an high refractive index independent on a water content. The material comprises (A) 5-25 % by weight of acrylate containing an aromatic ring, (B) 50-90 % by weight of 2-hydroxyethyl (meth)acrylate, and (C) 5-45 % by weight of a (meth)acrylate monomer having the coefficient of water absorption of the homopolymer thereof of not more than 30 % by weight, except for (A) acrylate containing an aromatic ring and (B) 2-hydroxyethyl (meth)acrylate.
Abstract: A polymer processing aid composition, a melt processable polymer composition that uses the polymer processing aid, and a method of improving the melt processability of a thermoplastic polymer are provided. The polymer processing aid composition comprises a multimodal fluoropolymer that preferably comprises interpolymerized units derived from an ethylenically unsaturated fluoromonomer tetrafluoroethylene and at least one ethylenically copolymerizable alpha-olefin monomer.
Type:
Grant
Filed:
May 13, 1999
Date of Patent:
August 21, 2001
Assignee:
Dyneon LLC
Inventors:
Maria P. Dillon, Susan S. Woods, Kirsten J. Fronek, Claude Lavallée, Stephen E. Amos, Karl-Dieter Weilandt, Harald Kaspar, Bernhard Hirsch, Klaus Hintzer, Peter J. Scott
Abstract: Fluoroelastomers having copolymerized units of vinylidene fluoride major monomer, at least one other fluorinated major monomer, and at least one cure site monomer are prepared in an aqueous suspension polymerization process using an initiator consisting essentially of a solution of an oil soluble peroxide in a water-soluble hydrocarbon solvent.
Abstract: The present invention is directed to new metal cation neutralized high acid ionomer resins and to golf ball cover compositions containing these new resins. When the new high acid ionomer resins are utilized to manufacture a golf ball, the golf ball produced thereby exhibits properties of improved distance without sacrificing characteristics such as playability and/or durability when compared to low acid ionomer and/or low acid/high acid ionomer blends.
Abstract: This invention relates to molecularly imprinted polymers (MIPs) using an amide as the hydrogen bonding functional group. The amide MIPs made according to this invention exhibited enantiomeric recognition of the imprinted species when evaluated by high performance liquid chromatography (HPLC) even in an aqueous phase. In addition, the amide MIPs demonstrated improved enantiomeric resolution and load capacity.
Abstract: An interpolymer consisting essentially of units derived from vinyl fluoride and at least two highly fluorinated monomers, at least one of the highly fluorinated monomers introducing into the polymer a side chain of at least one carbon atom. Films from these interpolymers have substantially reduced haze, low surface tension, and can be made to form solutions in common polar organic solvents that are stable at room temperature. The extremely low surface tensions obtained with these interpolymer films provide enhanced stain resistance and improved release properties compared to polyvinyl fluoride or known vinyl fluoride interpolymers.
Abstract: Water-soluble polymers whose characteristic structural elements comprise units of the formulae I and/or II
where
R1 is H, alkyl, cycloalkyl, aryl or aralkyl,
R2 and R3 independently are as defined for R1 or are selected from substituted alkyl, substituted cycloalkyl, substituted aryl or substituted aralkyl, the substituents being selected from OH, O-alkyl, O-aryl, SH, S-alkyl, S-aryl, NH2, NH-alkyl, NH-aryl, N(alkyl)2, possibly in protinated form,
N(Alkyl)3+3Z−, where Z is the radical of an inorganic or
organic acid, COOH, COO-alkyl, CONH2, CONH-alkyl, CON(alkyl)2, CN and SO3H; and
the indices x are each independently an integer from 1 to 20; and the acid addition salts of these polymers, (processes for whose preparation are also described), are used in cosmetic compositions.
Type:
Grant
Filed:
January 25, 1999
Date of Patent:
August 7, 2001
Assignee:
BASF Aktiengesellschaft
Inventors:
Manfred Niessner, Martin Rübenacker, Claudia Nilz, Peter Hössel
Abstract: The present invention is directed to a golf ball comprising a core and a cover, wherein the cover comprises a blend of two or more high acid ionomer resins. Each high acid ionomer resin utilized in the blend of the cover composition comprises generally of greater than 16% by weight acid, preferably from about 17 to about 25% by weight acid and more preferably from about 18.5% to about 21.5% by weight acid. The acid groups of the high acid ionomers utilized in the cover compositions of the invention are partially (i.e. generally 10-75 percent, preferably 30-70 percent) neutralized by metal ions such as by sodium, zinc and magnesium ions. When the blend of two or more high acid ionomer resins is utilized to manufacture a golf ball, the golf ball produced thereby, exhibits properties of improved distance without sacrificing characteristics such as playability and/or durability when compared to low acid ionomer and/or low acid/high acid ionomer blends.
Abstract: A low molecular weight, tertiary amide terminated polyamide may be blended with a liquid hydrocarbon to form a transparent composition having gel consistency. The tertiary amide terminated polyamide may be prepared by reacting “x” equivalents of dicarboxylic acid wherein at least 50% of those equivalents are from polymerized fatty acid, “y” equivalents of diamine such as ethylene diamine, and “z” equivalents of a monofunctional reactant having a secondary amine group as the only reactive functionality. The stoichiometry of the reaction mixture is preferably such that 0.9≦{x/(y+z)}≦1.1 and 0.1≦{z/(y+z)}≦0.7. The gel contains about 5-50% tertiary amide terminated polyamide, with the remainder preferably being pure hydrocarbon. The gels are useful in formulating personal care products and other articles wherein some degree of gel-like or self-supporting consistency is desired.
Abstract: Coagulated particles having a low water content are separated and recovered from an emulsified dispersion of fluorine-containing polymer particles. A solid-liquid separation method comprising: a step for adding a coagulant in an emulsified dispersion of fluorine-containing polymer particles to coagulate the fluorine-containing polymer particles with stirring and obtain a slurry of coagulated particles, a step for filtrating the slurry, and a step for pressing the obtained cake. It is preferable to continuously carry out the filtration step and pressing step with a filter press or a belt press. Also a washing step may be provided after the filtration step.
Abstract: Phosphonomethylated poly-vinylamines which contain as characteristic structural elements units of the formula
where R1 is hydrogen, C1-C6-alkyl or
and X is hydrogen, an alkali metal, ammonium or one equivalent of an alkaline earth metal, are obtainable by phosphonomethylation of polymers which contain N-vinyl-amide or vinylamine groups and are useful as detergent additives and water treatment agents.
Type:
Grant
Filed:
July 12, 1993
Date of Patent:
July 24, 2001
Assignee:
BASF Aktiengesellschaft
Inventors:
Juergen Mohr, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann, Richard Baur, Charalampos Gousetis, Alexander Kud
Abstract: A polymerizabie composition, comprising
a) at least one ethylenically unsaturated monomer or oligomer, and
b) an initiator compound of formula (I)
wherein n is O or 1. The compounds of formula (I) are prepared from a free radical
and a compound of formula R10NO or
Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, novel initiator compounds and their use for polymerization, intermediate compounds and also the polymer or copolymer produced by this process.
Type:
Grant
Filed:
July 13, 1998
Date of Patent:
July 17, 2001
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Peter Nesvadba, Andreas Kramer, Alfred Steinmann, Werner Stauffer
Abstract: A zwitterionic monomer having amino-multicarboxylic acid functionality having Structure (I)
wherein R1 is selected from the group consisting of H, an alkyl group having 1 to 6 carbon atoms; R2 is (CH2)n where n is 2 to 12; R3 and R4 are independently an alkyl group having 1 to 6 carbon atoms; R5 is (CH2)m where m is 2 or 3; R6 and R7 are independently selected from
wherein R20 is selected from the group consisting of H, CH3, and COOY; R21 is selected from H or CH3; X is oxygen or nitrogen; A is a halide; and Y is independently a cation. The zwitterionic monomer is the reaction product of an amino-multicarboxylic acid and an amine containing monomer.
Type:
Grant
Filed:
July 6, 1999
Date of Patent:
July 17, 2001
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: Method for preparing modified PTFE by suspension, wherein as comonomers perfluoroalkylvinylethers in which the alkyl has from 1 to 5 carbon atoms, and/or a perfluorodioxole are used, characterized by the following conditions:
a part of the comonomer, from 15 to 90% by weight of the total amount is to be fed at the beginning of the reaction; the remaining part of the comonomer is to be distributed during the reaction so as to obtain a constant speed of the comonomer incorporation in the polymer chain;
a perfluorinated surfactant and a buffering salt are used;
a persulphate with a reducing agent is used as initiator in such a ratio as to generate a part of the radicals from the redox reaction and another one from the persulphate thermal decomposition;
one operates with a polymerization pressure from 15 to 30 bar.
Abstract: A composite membrane is provided in which a porous substrate is impregnated with a polymeric composition comprising various combinations of &agr;, &bgr;, &bgr;-trifluorostyrene, substituted &agr;, &bgr;, &bgr;-trifluorostyrene and ethylene-based monomeric units. Where the polymeric composition includes ion-exchange moieties, the resultant composite membranes are useful in electrochemical applications, particularly as membrane electrolytes in electrochemical fuel cells.
Abstract: A non-aqueous, heterogeneous polymerization process comprises heating a reaction mixture of about 5-70%, preferably 10-30%, by weight, of a vinyl monomer in an oil as solvent, and a free radical initiator, optionally in the presence of a crosslinking agent and/or a surfactant, wherein the oil solvent is present in an amount sufficient to keep the resultant polymer in a stirrable state throughout the polymerization. The polymer reaction product is capable of forming a uniform emulsion or gel upon addition of water thereto.
Type:
Grant
Filed:
December 10, 1997
Date of Patent:
July 3, 2001
Assignee:
ISP Investments Inc.
Inventors:
Krystyna Plochocka, Jui-Chang Chuang, Jenn S. Shih
Abstract: Selected novel partially fluorinated &agr;,&ohgr;-dienes can be free radically (co)polymerized to form polymers in which cyclic structures are present. The polymers are useful for films, coatings and molded parts.
Abstract: Acrylic polymers are typically difficult to cure unless they contain specific curing sites, such as carbon-carbon double bonds. This invention offers a technique to rapidly cure acrylic polymers containing nitrile groups that do not possess typical curing sites, such as carbon-carbon double bonds. By utilizing the process of this invention, heat resistant thermoplastic vulcanizates with high-resistance to solvents can easily be prepared. The present invention more specifically discloses a process for curing an acrylic polymer which comprises distributing an aromatic compound having at least two nitrile oxide groups bonded thereto throughout the acrylic polymer, wherein the acrylic polymer contains nitrile groups, and wherein a bulky group is in at least one ortho position to the nitrile oxide group and wherein the bulky group is a moiety which is larger than a hydrogen atom.
Type:
Grant
Filed:
February 24, 1999
Date of Patent:
June 26, 2001
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
François Jean-Marie Breton, Dane Kenton Parker
Abstract: A process for producing a microporous oil sorbent polymer comprising the steps of:
dissolving a polyunsaturated monomer in a silicone organic solvent to provide a monomer mixture containing more than 90% by weight polyunsaturated monomer;
polymerizing said monomers by precipitation polymerization, under an inert atmosphere to precipitate microporous, micro-particles in the form of micro-particles, agglomerates and aggregates having a bulk density of about 0.02 gm/cm3 to about 0.01 gm/cm3 and capable of adsorbing at least about 20% by weight organic materials based on the total weight of polymer plus adsorbed organic material.
Abstract: Anion-exchange compositions are provided comprising anion-exchange functional groups comprising at least a first and a second nitrogen group, wherein the first nitrogen group is a quaternary amine and the second nitrogen group is selected from the group consisting of primary, secondary, tertiary or quaternary amines. Methods of making and using the compositions are also provided.
Type:
Grant
Filed:
November 23, 1998
Date of Patent:
June 19, 2001
Assignee:
Dionex Corporation
Inventors:
Rosanne W. Slingsby, Christopher A. Pohl, Jacek J. Jagodzinski, Latha P. Narayanan, Michael Weitzhandler