Patents Examined by Gary L. Geist
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Patent number: 5008038Abstract: Solubility of chlorhexidine free base and hydrocarbon substituted lactams in water is substantially enhanced by forming an aqueous solution of a complex of chlorhexidine free base and lactam. This is preferably done by dissolving chlorhexidine free base in lactam and then mixing the resulting solution with water. The resulting aqueous solution contains between about 1 and about 25 wt % of a complex of lactam and chlorhexidine with chlorhexidine being present in amounts between about 0.08 and about 0.25 wt % based on lactam. Lactam used is defined by the formula ##STR1## wherein n is an integer having a value of from 1 to 3 and R is a linear alkyl radical containing from 10 to 14 carbon atoms.Type: GrantFiled: October 10, 1989Date of Patent: April 16, 1991Assignee: GAF Chemicals CorporationInventors: John J. Merianos, Robert B. Login
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Patent number: 5002672Abstract: An aqueous-based composition comprising a glycerophosphoric acid ester and a diacetyltartaric acid ester of mono and/or diglycerides when combined with viscosifier, sealant and weighting agent is suitable for use as a spotting fluid for downhole drilling operations for releasing stuck drill string. The present invention also enhances drill fluid lubricity, is nontoxic to marine life, non-polluting and may be safely disposed of in off-shore waters.Type: GrantFiled: June 1, 1990Date of Patent: March 26, 1991Assignee: Turbo-Chem International, Inc.Inventors: James R. Hayes, Gale J. Campbell
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Patent number: 5002694Abstract: Nitrogen-containing heterocyclic compounds of the formula II ##STR1## wherein R.sup.1 and R.sup.2 in each case denote an alkyl group having 1 to 15 C atoms, wherein one or more CH.sub.2 groups may also be replaced by a grouping selected from the group comprising --O--, --S--, --CO--, --O--CO--, --O--COO--, --CO--O--, --CH.dbd.CH--, --CH--halogen and --CHCN--, or else by a combination of two suitable groupings, two heteroatoms not being directly linked to each other,m denotes 0 or 1,Ar denotes 1,4-phenylene, 4,4'-biphenylyl or 2,6-naphthylene, wherein one or more CH groups are in each case replaced by N,Z denotes --C--O--, --O--CO--, --CH.sub.2 O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CH.sub.2 CHCN--, --CHCNCH.sub.2 --, --CH.dbd.CH or a single bond, andA denotes unsubstituted 1,4-cyclonexylene or 11,4-cyclohexylene substituted in position 1 or position 4 by CN,with the proviso that if A=unsubstituted 1,4-cyclonexylene, Z denotes --CHCNCH.sub.2 -- or --CH.sub.2 CHCN-- and/or at least one CH.sub.Type: GrantFiled: May 13, 1987Date of Patent: March 26, 1991Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Andreas Wachtler, Rudolf Eidenschink, Joachim Krause, Bernhard Scheuble
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Patent number: 5000886Abstract: There is disclosed a process for preparing compositions comprising microcapsules by phase separation microencapsulation wherein the hardening agent employed is a volatile silicone fluid and with the compositions prepared thereby. The use of the volatile silicone fluid as a hardening agent permits the production of microcapsules substantially free of any alkane hardening agent, eliminating potential combustability problems of the prior art processes and toxicity problems of the prior art compositions.Type: GrantFiled: May 26, 1987Date of Patent: March 19, 1991Assignee: American Cyanamid CompanyInventors: James R. Lawter, Michael G. Lanzilotti
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Patent number: 4997580Abstract: A method of inhibiting the deposition of paraffin wax, asphaltene, or mixtures thereof in a crude oil contaminated with paraffin wax, asphaltene, or mixtures thereof and susceptible to such depositions comprising the step of incorporating into said crude oil an effective deposition inhibiting amount of an oil soluble organic compound having at least one oleophobic and hydrophobic fluoroaliphatic group, and antideposition stabilized crude oil compositions containing said compound, are disclosed.Type: GrantFiled: July 17, 1989Date of Patent: March 5, 1991Assignee: Ciba-Geigy CorporationInventors: Athanasios Karydas, Thomas W. Cooke, Robert A. Falk
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Patent number: 4992208Abstract: A method and composition are described for the prevention of the mushing or the disintegration of solid sodium chloride in an aqueous medium.Type: GrantFiled: April 18, 1989Date of Patent: February 12, 1991Assignee: Cargill, IncorporatedInventor: Donald T. Ireland
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Patent number: 4990269Abstract: A surface active compound for use in microemulsions useful in oil recovery, wood impregnating, dry cleaning, cleaning of hard surfaces and for floor polishing, which has one hydrophobic group, containing 9-50, preferably 12-35 carbon atoms and 2-6 separate hydrophilic end groups, at least one of the hydrophilic end groups being a nonionic group obtained by reacting a compound having a reactive hydrogen atom with an alkylene oxide having 2-4 carbon atoms and at least one being an anionic group.Type: GrantFiled: September 21, 1989Date of Patent: February 5, 1991Assignees: Berol Kemi AB, Tendex Kjemi Service A/SInventors: Eva M. Andreasson, Krister A. Holmberg, Borje Nystrom, Eva M. Osterberg, Finn Egeli
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Patent number: 4988461Abstract: Novel water-dispersed compositions are prepared containing (1) 100 parts by weight of an amine-containing polymer, (2) at least 25 parts by weight of a solvent which is soluble in both water and organics and has a boiling point above about 100.degree. C., (3) at least about 0.8 equivalent of an organic acid having a pk.sub.a value of less than 5, and (4) from about 50 to about 750 parts by weight of water. The compositions are useful as a component in water-borne resin systems such as epoxies and polyesters.Type: GrantFiled: March 22, 1990Date of Patent: January 29, 1991Assignee: The BFGoodrich CompanyInventor: Carl S. Nichols
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Patent number: 4986354Abstract: Oil field chemicals are incorporated in microcapsules of the condensation product of hydroxyacetic acid or the co-condensation product of hydroxyacetic acid and other compounds containing hydroxy-, carboxylic acid-, or hydroxycarboxylic acid moieties. The microcapsules are then introduced into an oil well bore and/or subterranean oil formation where the microcapsules dissolve over a period of time and release the oil field chemicals.Type: GrantFiled: September 14, 1988Date of Patent: January 22, 1991Assignees: Conoco Inc., E. I. DuPont de Nemours and CompanyInventors: Lisa A. Cantu, Marvin E. Yost
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Patent number: 4986353Abstract: Oil field chemicals are incorporated in polymeric particles of the condensation product of hydroxyacetic acid or the co-condensation product of hydroxyacetic acid and other compounds containing hydroxy-, carboxylic acid-, or hydroxycarboxylic acid moieties. The particles are introduced into an oil well bore and/or subterranean oil formation where the polymeric particles dissolve over a period of time and release the oil field chemicals.Type: GrantFiled: September 14, 1988Date of Patent: January 22, 1991Assignees: Conoco Inc., E. I. DuPont de Nemours and CompanyInventors: Charles R. Clark, Donald L. Whitfill, D. Philip Cords, Edward F. McBride, Harold E. Bellis
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Patent number: 4985154Abstract: A process for the extraction of crude oil from an underground deposit which is penetrated by at least one injection well and at least one production well is disclosed. The process comprises forcing a solution or a dispersion of a surfactant co-solvent mixture into the injection well, wherein the surfactant is an alkyl (poly)glycoside of formula (I)R--O--Z.sub.nwherein R is a linear or branched, saturated or unsaturated C.sub.7-24 alkyl radical, and Z.sub.n is an (oligo)glycosyl radical having, on average, n=1 to 10 hexose or pentose units or a mixture thereof.Type: GrantFiled: March 26, 1990Date of Patent: January 15, 1991Assignee: Huels AktiengesellschaftInventors: Dieter Balzer, Harald Lueders
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Patent number: 4981601Abstract: An improved method and composition for reducing the production of sludge when contacting a subterranean formation containing oil which is subject to sludging with an aqueous acid solution. An anti-sludging agent such as a quaternary ammonium salt of a fatty amine, and one or more other additives are combined with the aqueous acid solution along with a dispersing agent which forms the aqueous acid solution and additives into a long-term homogeneous composition.Type: GrantFiled: February 2, 1989Date of Patent: January 1, 1991Assignee: Halliburton CompanyInventor: William G. F. Ford
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Patent number: 4971720Abstract: Foam is formed from a solution of demineralized make-down water and foaming agent, and the foam contacted with solid materials to suppress process dust emissions. The foaming agent may be a low salt tolerant surfactant which loses its surface active properties in typical aqueous process streams, or end uses, thereby minimizing subsequent foam related problems. The low salt tolerant surfactant may be part of a combination of components for forming foam which is low salt tolerant.Type: GrantFiled: June 22, 1988Date of Patent: November 20, 1990Assignee: Betz LaboratoriesInventor: Donald C. Roe
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Patent number: 4971707Abstract: A method for producing a homogeneous oil-in-water microemulsion by first creating a surfactant, oil and water mixture, adding salt to the mixture in a sufficient quantity to drive the mixture into a Type III or Type II(+) phase regime, preparing a solution having a selected salinity lower than the salinity of the Type III or Type II(+) phase regime, and mixing a sufficient amount of the lower salinity solution with the Type III or Type II(+) regime to invert the Type III or Type II(+) regime into a Type II(-) oil-in-water microemulsion. The microemulsion may be used in a surfactant flood to recover hydrocarbons from underground formations.Type: GrantFiled: June 1, 1988Date of Patent: November 20, 1990Assignee: Texaco Inc.Inventor: William T. Osterloh
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Patent number: 4963273Abstract: The present invention provides a modified liquid phase drilling fluid having desirable properties of shale swelling inhibition, lubrication, and high temperature performance. The fluid does not rely on the incorporation of inorganic salts or high molecular weight water soluble polymers for control of shale swelling or shale disintegration and exhibits performance characteristics, approaching those of oil base drilling fluids, without the objectionable properties of hydrocarbon oils or its potential hazardous impact on the environment.Type: GrantFiled: September 16, 1988Date of Patent: October 16, 1990Assignee: Baker Hughes IncorporatedInventors: Alphonse C. Perricone, Dennis K. Clapper, Dorothy P. Enright
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Patent number: 4961466Abstract: A controllable breaker for use in viscosified fluids utilized in the treatment of subterranean formations comprising a low molecular weight condensation product of hydroxyacetic acid with up to 15 wt % cocondensing compounds containing other hydroxy-, carboxylic-acid, or hydroxycarboxylic-acid moieties. The condensation product has an average molecular weight in the range of from about 200 to about 4000, a generally crystalline structure, a melting point above about 100.degree. C. and is substantially insoluble in the viscosified fluid at ambient temperatures. The breaker is admixed with the viscosified fluid in an amount sufficient to effect controlled breaking of the fluid upon being heated to a temperature above 70.degree. F. within a subterranean formation.Type: GrantFiled: January 23, 1989Date of Patent: October 9, 1990Assignee: Halliburton CompanyInventors: Ronald E. Himes, John A. Knox
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Patent number: 4959164Abstract: The enhancement of rock fragmentation and rock excavation by neutralizing the rock surface charge with respect to the drilling, tunneling, cutting, grinding, or polishing fluid. Water-soluble, high-molecular-weight, nonionic polymers are employed to neutralize the surface charge on the rock, thereby promoting increased drilling, cutting, tunneling, grinding and polishing performance resulting in increases in drilling, tunneling, cutting, grinding and polishing penetration rate, extensions in bit, cutting tool, grinding media, and polishing tool life and dust suppression.Type: GrantFiled: June 27, 1988Date of Patent: September 25, 1990Assignee: The United States of America as represented by the Secretary of the InteriorInventors: William H. Engelmann, Pamela J. Watson, Patrick A. Tuzinski, John E. Pahlman, Sanaa E. Khalafalla
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Patent number: 4959163Abstract: A method and composition for stimulating high temperature subterranean formations. The composition comprises a novel crosslinkable polymer containing anionic and cationic functional groups (a polyampholyte). The polyampholyte comprises a mixture of at least one from each of the following groups:Group I acrylamide, partially hydrolyzed acrylamide, N,N-dimethylacrylamide, N-substituted-(N'-dialkylaminoalkyl) acrylamides, aminoalkylacrylates, dialkylaminoalkylacrylates or mixtures thereof;Group II 2-acrylamido-2-methylpropane sulfonic acid, sodium salt, vinylphosphonic acid, partially hydrolyzed acrylamide or mixtures thereof; andGroup III methacrylamidopropyldimethyl-2,3-dihydroxypropylammonium sulfate having the formula ##STR1## In the performance of the method, the polyampholyte is inverted into an aqueous liquid to form a viscous liquid which is buffered to about 4 to 6.5 and admixed with a crosslinking agent capable of crosslinking dihydroxypropyl functionalities.Type: GrantFiled: November 3, 1988Date of Patent: September 25, 1990Assignee: Halliburton CompanyInventors: Marlin D. Holtmyer, Charles V. Hunt
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Patent number: 4957639Abstract: A method for enhancing recovery of oil from wells by introducing into an oil-bearing formation the reaction products obtained by reacting silicon metal, alkali metalhydroxide and at least one organic di-, tri- or tetramine in an aqueous medium. The products of said reaction are also claimed.Type: GrantFiled: June 1, 1987Date of Patent: September 18, 1990Assignee: Emox High Technology, Inc.Inventor: J. Thomas Fox
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Patent number: 4957646Abstract: An improved process for recovering oil by flowing a mixture of steam and steam foam surfactant into an oil-containing subterranean reservoir, the improvement provided by using surfactants enriched in olefin disulfonate. The surfactants may be used in either a steam drive or a steam soak process. Disulfonate-enriched steam foam surfactants and mixtures are also described.Type: GrantFiled: August 26, 1987Date of Patent: September 18, 1990Assignee: Shell Oil CompanyInventors: John K. Borchardt, Hon C. Lau