Patents Examined by Gary L. Geist
  • Patent number: 5008038
    Abstract: Solubility of chlorhexidine free base and hydrocarbon substituted lactams in water is substantially enhanced by forming an aqueous solution of a complex of chlorhexidine free base and lactam. This is preferably done by dissolving chlorhexidine free base in lactam and then mixing the resulting solution with water. The resulting aqueous solution contains between about 1 and about 25 wt % of a complex of lactam and chlorhexidine with chlorhexidine being present in amounts between about 0.08 and about 0.25 wt % based on lactam. Lactam used is defined by the formula ##STR1## wherein n is an integer having a value of from 1 to 3 and R is a linear alkyl radical containing from 10 to 14 carbon atoms.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: April 16, 1991
    Assignee: GAF Chemicals Corporation
    Inventors: John J. Merianos, Robert B. Login
  • Patent number: 5002672
    Abstract: An aqueous-based composition comprising a glycerophosphoric acid ester and a diacetyltartaric acid ester of mono and/or diglycerides when combined with viscosifier, sealant and weighting agent is suitable for use as a spotting fluid for downhole drilling operations for releasing stuck drill string. The present invention also enhances drill fluid lubricity, is nontoxic to marine life, non-polluting and may be safely disposed of in off-shore waters.
    Type: Grant
    Filed: June 1, 1990
    Date of Patent: March 26, 1991
    Assignee: Turbo-Chem International, Inc.
    Inventors: James R. Hayes, Gale J. Campbell
  • Patent number: 5002694
    Abstract: Nitrogen-containing heterocyclic compounds of the formula II ##STR1## wherein R.sup.1 and R.sup.2 in each case denote an alkyl group having 1 to 15 C atoms, wherein one or more CH.sub.2 groups may also be replaced by a grouping selected from the group comprising --O--, --S--, --CO--, --O--CO--, --O--COO--, --CO--O--, --CH.dbd.CH--, --CH--halogen and --CHCN--, or else by a combination of two suitable groupings, two heteroatoms not being directly linked to each other,m denotes 0 or 1,Ar denotes 1,4-phenylene, 4,4'-biphenylyl or 2,6-naphthylene, wherein one or more CH groups are in each case replaced by N,Z denotes --C--O--, --O--CO--, --CH.sub.2 O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CH.sub.2 CHCN--, --CHCNCH.sub.2 --, --CH.dbd.CH or a single bond, andA denotes unsubstituted 1,4-cyclonexylene or 11,4-cyclohexylene substituted in position 1 or position 4 by CN,with the proviso that if A=unsubstituted 1,4-cyclonexylene, Z denotes --CHCNCH.sub.2 -- or --CH.sub.2 CHCN-- and/or at least one CH.sub.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: March 26, 1991
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Andreas Wachtler, Rudolf Eidenschink, Joachim Krause, Bernhard Scheuble
  • Patent number: 5000886
    Abstract: There is disclosed a process for preparing compositions comprising microcapsules by phase separation microencapsulation wherein the hardening agent employed is a volatile silicone fluid and with the compositions prepared thereby. The use of the volatile silicone fluid as a hardening agent permits the production of microcapsules substantially free of any alkane hardening agent, eliminating potential combustability problems of the prior art processes and toxicity problems of the prior art compositions.
    Type: Grant
    Filed: May 26, 1987
    Date of Patent: March 19, 1991
    Assignee: American Cyanamid Company
    Inventors: James R. Lawter, Michael G. Lanzilotti
  • Patent number: 4997580
    Abstract: A method of inhibiting the deposition of paraffin wax, asphaltene, or mixtures thereof in a crude oil contaminated with paraffin wax, asphaltene, or mixtures thereof and susceptible to such depositions comprising the step of incorporating into said crude oil an effective deposition inhibiting amount of an oil soluble organic compound having at least one oleophobic and hydrophobic fluoroaliphatic group, and antideposition stabilized crude oil compositions containing said compound, are disclosed.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: March 5, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanasios Karydas, Thomas W. Cooke, Robert A. Falk
  • Patent number: 4992208
    Abstract: A method and composition are described for the prevention of the mushing or the disintegration of solid sodium chloride in an aqueous medium.
    Type: Grant
    Filed: April 18, 1989
    Date of Patent: February 12, 1991
    Assignee: Cargill, Incorporated
    Inventor: Donald T. Ireland
  • Patent number: 4990269
    Abstract: A surface active compound for use in microemulsions useful in oil recovery, wood impregnating, dry cleaning, cleaning of hard surfaces and for floor polishing, which has one hydrophobic group, containing 9-50, preferably 12-35 carbon atoms and 2-6 separate hydrophilic end groups, at least one of the hydrophilic end groups being a nonionic group obtained by reacting a compound having a reactive hydrogen atom with an alkylene oxide having 2-4 carbon atoms and at least one being an anionic group.
    Type: Grant
    Filed: September 21, 1989
    Date of Patent: February 5, 1991
    Assignees: Berol Kemi AB, Tendex Kjemi Service A/S
    Inventors: Eva M. Andreasson, Krister A. Holmberg, Borje Nystrom, Eva M. Osterberg, Finn Egeli
  • Patent number: 4988461
    Abstract: Novel water-dispersed compositions are prepared containing (1) 100 parts by weight of an amine-containing polymer, (2) at least 25 parts by weight of a solvent which is soluble in both water and organics and has a boiling point above about 100.degree. C., (3) at least about 0.8 equivalent of an organic acid having a pk.sub.a value of less than 5, and (4) from about 50 to about 750 parts by weight of water. The compositions are useful as a component in water-borne resin systems such as epoxies and polyesters.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: January 29, 1991
    Assignee: The BFGoodrich Company
    Inventor: Carl S. Nichols
  • Patent number: 4986354
    Abstract: Oil field chemicals are incorporated in microcapsules of the condensation product of hydroxyacetic acid or the co-condensation product of hydroxyacetic acid and other compounds containing hydroxy-, carboxylic acid-, or hydroxycarboxylic acid moieties. The microcapsules are then introduced into an oil well bore and/or subterranean oil formation where the microcapsules dissolve over a period of time and release the oil field chemicals.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: January 22, 1991
    Assignees: Conoco Inc., E. I. DuPont de Nemours and Company
    Inventors: Lisa A. Cantu, Marvin E. Yost
  • Patent number: 4986353
    Abstract: Oil field chemicals are incorporated in polymeric particles of the condensation product of hydroxyacetic acid or the co-condensation product of hydroxyacetic acid and other compounds containing hydroxy-, carboxylic acid-, or hydroxycarboxylic acid moieties. The particles are introduced into an oil well bore and/or subterranean oil formation where the polymeric particles dissolve over a period of time and release the oil field chemicals.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: January 22, 1991
    Assignees: Conoco Inc., E. I. DuPont de Nemours and Company
    Inventors: Charles R. Clark, Donald L. Whitfill, D. Philip Cords, Edward F. McBride, Harold E. Bellis
  • Patent number: 4985154
    Abstract: A process for the extraction of crude oil from an underground deposit which is penetrated by at least one injection well and at least one production well is disclosed. The process comprises forcing a solution or a dispersion of a surfactant co-solvent mixture into the injection well, wherein the surfactant is an alkyl (poly)glycoside of formula (I)R--O--Z.sub.nwherein R is a linear or branched, saturated or unsaturated C.sub.7-24 alkyl radical, and Z.sub.n is an (oligo)glycosyl radical having, on average, n=1 to 10 hexose or pentose units or a mixture thereof.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: January 15, 1991
    Assignee: Huels Aktiengesellschaft
    Inventors: Dieter Balzer, Harald Lueders
  • Patent number: 4981601
    Abstract: An improved method and composition for reducing the production of sludge when contacting a subterranean formation containing oil which is subject to sludging with an aqueous acid solution. An anti-sludging agent such as a quaternary ammonium salt of a fatty amine, and one or more other additives are combined with the aqueous acid solution along with a dispersing agent which forms the aqueous acid solution and additives into a long-term homogeneous composition.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: January 1, 1991
    Assignee: Halliburton Company
    Inventor: William G. F. Ford
  • Patent number: 4971720
    Abstract: Foam is formed from a solution of demineralized make-down water and foaming agent, and the foam contacted with solid materials to suppress process dust emissions. The foaming agent may be a low salt tolerant surfactant which loses its surface active properties in typical aqueous process streams, or end uses, thereby minimizing subsequent foam related problems. The low salt tolerant surfactant may be part of a combination of components for forming foam which is low salt tolerant.
    Type: Grant
    Filed: June 22, 1988
    Date of Patent: November 20, 1990
    Assignee: Betz Laboratories
    Inventor: Donald C. Roe
  • Patent number: 4971707
    Abstract: A method for producing a homogeneous oil-in-water microemulsion by first creating a surfactant, oil and water mixture, adding salt to the mixture in a sufficient quantity to drive the mixture into a Type III or Type II(+) phase regime, preparing a solution having a selected salinity lower than the salinity of the Type III or Type II(+) phase regime, and mixing a sufficient amount of the lower salinity solution with the Type III or Type II(+) regime to invert the Type III or Type II(+) regime into a Type II(-) oil-in-water microemulsion. The microemulsion may be used in a surfactant flood to recover hydrocarbons from underground formations.
    Type: Grant
    Filed: June 1, 1988
    Date of Patent: November 20, 1990
    Assignee: Texaco Inc.
    Inventor: William T. Osterloh
  • Patent number: 4963273
    Abstract: The present invention provides a modified liquid phase drilling fluid having desirable properties of shale swelling inhibition, lubrication, and high temperature performance. The fluid does not rely on the incorporation of inorganic salts or high molecular weight water soluble polymers for control of shale swelling or shale disintegration and exhibits performance characteristics, approaching those of oil base drilling fluids, without the objectionable properties of hydrocarbon oils or its potential hazardous impact on the environment.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: October 16, 1990
    Assignee: Baker Hughes Incorporated
    Inventors: Alphonse C. Perricone, Dennis K. Clapper, Dorothy P. Enright
  • Patent number: 4961466
    Abstract: A controllable breaker for use in viscosified fluids utilized in the treatment of subterranean formations comprising a low molecular weight condensation product of hydroxyacetic acid with up to 15 wt % cocondensing compounds containing other hydroxy-, carboxylic-acid, or hydroxycarboxylic-acid moieties. The condensation product has an average molecular weight in the range of from about 200 to about 4000, a generally crystalline structure, a melting point above about 100.degree. C. and is substantially insoluble in the viscosified fluid at ambient temperatures. The breaker is admixed with the viscosified fluid in an amount sufficient to effect controlled breaking of the fluid upon being heated to a temperature above 70.degree. F. within a subterranean formation.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: October 9, 1990
    Assignee: Halliburton Company
    Inventors: Ronald E. Himes, John A. Knox
  • Patent number: 4959164
    Abstract: The enhancement of rock fragmentation and rock excavation by neutralizing the rock surface charge with respect to the drilling, tunneling, cutting, grinding, or polishing fluid. Water-soluble, high-molecular-weight, nonionic polymers are employed to neutralize the surface charge on the rock, thereby promoting increased drilling, cutting, tunneling, grinding and polishing performance resulting in increases in drilling, tunneling, cutting, grinding and polishing penetration rate, extensions in bit, cutting tool, grinding media, and polishing tool life and dust suppression.
    Type: Grant
    Filed: June 27, 1988
    Date of Patent: September 25, 1990
    Assignee: The United States of America as represented by the Secretary of the Interior
    Inventors: William H. Engelmann, Pamela J. Watson, Patrick A. Tuzinski, John E. Pahlman, Sanaa E. Khalafalla
  • Patent number: 4959163
    Abstract: A method and composition for stimulating high temperature subterranean formations. The composition comprises a novel crosslinkable polymer containing anionic and cationic functional groups (a polyampholyte). The polyampholyte comprises a mixture of at least one from each of the following groups:Group I acrylamide, partially hydrolyzed acrylamide, N,N-dimethylacrylamide, N-substituted-(N'-dialkylaminoalkyl) acrylamides, aminoalkylacrylates, dialkylaminoalkylacrylates or mixtures thereof;Group II 2-acrylamido-2-methylpropane sulfonic acid, sodium salt, vinylphosphonic acid, partially hydrolyzed acrylamide or mixtures thereof; andGroup III methacrylamidopropyldimethyl-2,3-dihydroxypropylammonium sulfate having the formula ##STR1## In the performance of the method, the polyampholyte is inverted into an aqueous liquid to form a viscous liquid which is buffered to about 4 to 6.5 and admixed with a crosslinking agent capable of crosslinking dihydroxypropyl functionalities.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: September 25, 1990
    Assignee: Halliburton Company
    Inventors: Marlin D. Holtmyer, Charles V. Hunt
  • Patent number: 4957639
    Abstract: A method for enhancing recovery of oil from wells by introducing into an oil-bearing formation the reaction products obtained by reacting silicon metal, alkali metalhydroxide and at least one organic di-, tri- or tetramine in an aqueous medium. The products of said reaction are also claimed.
    Type: Grant
    Filed: June 1, 1987
    Date of Patent: September 18, 1990
    Assignee: Emox High Technology, Inc.
    Inventor: J. Thomas Fox
  • Patent number: 4957646
    Abstract: An improved process for recovering oil by flowing a mixture of steam and steam foam surfactant into an oil-containing subterranean reservoir, the improvement provided by using surfactants enriched in olefin disulfonate. The surfactants may be used in either a steam drive or a steam soak process. Disulfonate-enriched steam foam surfactants and mixtures are also described.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: September 18, 1990
    Assignee: Shell Oil Company
    Inventors: John K. Borchardt, Hon C. Lau