Abstract: A polyamide fiber comprised of (A) a thermoplastic aliphatic polyamide having copolymerized therein a polyalkylene oxide unit and having a melting point of at least 160.degree. C., and (B) a polyoxyalkylene glycol, wherein the ingredient (B) is finely dispersed in the ingredient (A). A polyamide fiber exhibiting a rate of moisture absorption of at least 3.5%/5 minutes at 25.degree. C. and R.H. 90% and/or a triboelectric voltage of not larger than 1.5 kV at 20.degree. C. and R.H. 40% is obtained by removing the ingredient (B) from the above-mentioned polyamide fiber by means of dissolution.
Abstract: The present invention relates to a polycarbonate production method. More specifically, it relates to a polycarbonate production method that is capable of preparing polycarbonates which have excellent residence stability such as hue stability and heat stability at the time of molding, and which have particularly outstanding water resistance.
Abstract: Disclosed herein is a polycarbonate copolymer comprising repeating units respectively made of a bisphenol A and a tetrahalogenobisphenol A and having a trihalogenophenoxy group as an end group at the terminal, particularly both terminals thereof and a method for efficiently producing said polycarbonate copolymer. This polycarbonate copolymer is superior in impact resistance, flame retardance, molding thermostability and the like, is good in hydrolytic resistance, is much less liable to cause a mold rust and has high quality. Therefore, this polycarbonate copolymer will be extensively used in various industrial materials, for example as the flame retardant parts for household electric appliances, office automation apparatuses and the like.
Abstract: The present invention discloses to polyaniline derivatives which are soluble in an organic solvent and with which it is possible to produce a film having flexibility, and to a process for preparing the same. The present invention provides polyaniline derivatives comprising a structural unit which is indicated by the following formula (I) ##STR1## (wherein m is an integer of 0 or greater, and n is an integer of 2 or greater), and a structural unit which is indicated by the following formula (II) ##STR2## (wherein k is an integer from 1 to 2500, and x is a group with at least a 2-butenylene structure).
Abstract: Phosphazene-containing amines having at least one amine or substituted amine moiety reactive with nitrile groups of the phthalonitrile monomers or oligomeric resins are useful curing agents for phthalonitriles. Typically, the phosphazene-containing amines useful as curing agents in the present invention have the formula: ##STR1## wherein each of X.sub.1-6 is a hydrogen, an unsubstituted amine group, or an amine group substituted with C.sub.1 -C.sub.12 alkyl groups or aromatic groups, at least one of X.sub.1-6 includes an amine group, and each of R'.sub.1-6 is an alkyl, aromatic, or alkyl-substituted aromatic moiety, or a linear polymer of the phosphazene-based amine monomer. The curing agents enhance the speed of cure and also add flame retardancy to the cured polymers.
Type:
Grant
Filed:
February 19, 1993
Date of Patent:
April 19, 1994
Assignee:
The United States of America as represented by the Secretary of the Navy
Abstract: A thermotropic liquid crystalline copolyester containing two different recurring units with each of the units linked to another via an ester bond, the two different recurring units having the respective formulae ##STR1## in which X is ##STR2## wherein m is 4-10, inclusive; and Y is ##STR3## wherein n is 11-18, inclusive; and the molar ratio of X to Y in the copolyester ranging from 9:1 to 2:8.
Type:
Grant
Filed:
October 28, 1992
Date of Patent:
April 12, 1994
Assignee:
Industrial Technology Research Institute
Abstract: The diamine, 1,3-diamino-5-pentafluorosulfanylbenzene (DASP), was reacted with various dianhydrides to form polyimides containing an SF.sub.5 moiety. These polyimides exhibit high glass transition temperatures, high density, low solubility, and low dielectric properties. These polymers were used to prepare semi-permeable membranes, wire coatings, and films and are useful for electronic, space and piezoelectric applications.
Type:
Grant
Filed:
May 27, 1993
Date of Patent:
April 12, 1994
Assignee:
The United States of America as represented by the Administrator of the National Aeronautics and Space Adminstration
Abstract: A process for the copolymerization of (1) a carboxylic acid consisting of terephthalic acid and mixtures thereof with isophthalic acid with (2) a mixture of hexamethylene diamine and 2-methyl pentamethylene diamine. The combined amount of isophthalic acid and 2-methyl pentamethylene diamine is controlled so that the resultant copolyamide, when annealed, has less than 1% by weight based on the total weight of the copolyamide of fractions having melting points greater than 320.degree. C. Preferably, the combined amount of isophthalic acid and 2-methyl pentamethylene diamine is greater than 27.5%, molar basis, of the total amount of acid and diamine.
Abstract: A method is provided for making polycarbonate by phosgenating a mixture of bisphenol and phenolic chain-stopper under interfacial reaction conditions in the presence of a phase transfer catalyst. A polycarbonate is obtained which is substantially free of diarylcarbonate.
Abstract: Heterocyclic bis(4-hydroxyphenyl)cycloalkanes, as illustrated by 4,4-bis(4-hydroxyphenyl)thiopyran and the corresponding acetylated piperidine, may be prepared by the reaction of bisphenol A or a similar compound with the corresponding thiopyranone or piperidone. The thio compound may be oxidized to the corresponding sulfone. Polycarbonates prepared from said heterocyclic bis(4-hydroxyphenyl)cycloalkanes have high glass transition temperatures and are expected to be ductile.
Abstract: Polyethers which contain recurring units of the formula I ##STR1## in which A is a divalent aryl or heteroaryl radical,X is O, S or NR,Z is a divalent aryl or heteroaryl radical or an alkynyl, azo or (CF.sub.2) group, andR is arylare synthesized. The polyethers can be used as thermoplastics for the production of injection-molded articles, extrudates, polymer blends and coatings and for the production of films and membranes from solution.
Type:
Grant
Filed:
January 10, 1992
Date of Patent:
April 5, 1994
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Brigitte Helmreich, Klaus Burger, Gerhard Maier, Reinhold Hecht, Oskar Nuyken
Abstract: A method is provided for making flame retardant polycarbonates by phosgenating a mixture of bisphenols having up to about 50 mole % of tetrahalobisphenols, such as tetrabromobisphenols. There is employed a mixture of a phase transfer catalyst and a tertiary organic amine to provide high molecular weight copolymer without excessive phosgene usage.
Abstract: A composition comprising a 1,2-dialkylidenecyclobutane such as 1,2-dimethylenecyclobutane, a polyacrylate monomer and an optional polyimide such as a bismaleimide can be thermally cured to a tough copolymer having a high glass transition temperature.
Abstract: This invention relates to a process of reducing polyketones to polyalcohols using borohydride salts where the reducing agent is suspended in water.
Abstract: A polyamide/copolyamide catalyst composition comprising a primary catalyst which comprises an alkali metal hypophosphite or an alkali-earth metal hypophosphite, and a cocatalyst which comprises an organic salt or an inorganic salt. The catalyst composition of this invention is most useful when used in conjunction with the reactive extrusion technology which requires a very fast polymerization rate to take full advantage of this evolving technology.
Type:
Grant
Filed:
September 18, 1992
Date of Patent:
March 29, 1994
Assignee:
Industrial Technology Research Institute
Inventors:
Wu-Bin Yuo, Ching-Pei Chen, Jeng-Yue Wu, Mao-Song Lee
Abstract: A method for the polymerization of Nylon 6 from caprolactam and water using a catalyst composition comprising a primary catalyst, which can be an alkali metal hypophosphite or an alkali-earth metal hypophosphite, and an organic phosphite as cocatalyst. The catalyst composition used in this invention is most useful when used in conjunction with the reactive extrusion technology which requires a very fast polymerization rate to take full advantage of this evolving technology.
Type:
Grant
Filed:
September 18, 1992
Date of Patent:
March 29, 1994
Assignee:
Chinese Petrochemical Development Corp.
Inventors:
Wu-Bin Yuo, Gwo-Yang Chang, Jeng-Yue Wu, Mao-Song Lee
Abstract: A catalyst composition for the polymerization of polyamide/copolyamide comprising a primary catalyst which comprises an alkali metal hypophosphite or an alkali-earth metal hypophosphite, and an organic phosphite cocatalyst. The catalyst composition of this invention is most useful when used in conjunction with the reactive extrusion technology which requires a very fast polymerization rate to take full advantage of this evolving technology.
Type:
Grant
Filed:
September 18, 1992
Date of Patent:
March 29, 1994
Assignee:
Industrial Technology Research Institute
Inventors:
Wu-Bin Yuo, Der-Tarng Su, Jeng-Yue Wu, Mao-Song Lee
Abstract: A process for preparing polyaryl ethers of the formula I or Ia ##STR1## by condensation of at least one appropriate bisphenol with at least one appropriate aromatic dichloride in the presence of an alkali metal carbonate in a dipolar aprotic solvent, is carried out in the presence of a catalyst selected from the alkali metal nitrites and the group of compounds of the formula II ##STR2## where r.sup.1 and r.sup.3 are each hydrogen, C.sub.7 -C.sub.16 -phenylalkyl, C.sub.1 -C.sub.12 -alkoxy, fluorine, chlorine, bromine, iodine or nitro, and R.sup.2 is nitro or nitroso, or ##STR3## where R.sup.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, fluorine, chlorine, bromine or iodine.
Type:
Grant
Filed:
August 20, 1992
Date of Patent:
March 29, 1994
Assignee:
BASF Aktiengesellschaft
Inventors:
Alexander Aumueller, Wolfgang Eberle, Gerhard Heinz, Bernd Hupfeld, Christiane Husemann, Juergen Koch, Helmut Reichelt
Abstract: Partly aromatic copolyamides contain as essential componentsA) 40-90% by weight of units derived from terephthalic acid and hexamethylenediamine,B) 0-50% by weight of units derived from .epsilon.-caprolactam andC) 0-60% by weight of units derived from adipic acid and hexamethylenediamine,the components B) and/or C) accounting for a total of not less than 10% by weight of the total units and the copolyamide having a triamine content of less than 0.5% by weight.
Type:
Grant
Filed:
February 10, 1993
Date of Patent:
March 29, 1994
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Reimann, Gunter Pipper, Hans-Peter Weiss, Christoph Plachetta, Eckhard M. Koch
Abstract: Production of polysuccinimide by reacting maleic anhydride and ammonia at elevated temperatures. The base hydrolyzed polyaspartic acid product.