Abstract: The present invention provides a composition which is able to form a layer having excellent surface slip property and friction durability in addition to water-repellency, oil-repellency and antifouling property. The present invention provides a surface-treatment composition comprising (A) at least one fluorine-containing polymer having a curable moiety, and (B) at least one silicon-containing polymer having a curable moiety.
Abstract: The present invention relates to a method of regenerating an ion exchange material loaded with chromate ions and nitrate ions in an ion exchange column, the method comprising subjecting the loaded ion exchange column to a regeneration sequence comprising the following steps: (i) passing a first salt solution through the column forming a first effluent solution; (ii) passing a second salt solution through the column to at least partially remove the chromate ions from the column forming a second effluent solution, wherein the second salt solution has a higher salt concentration than the first salt solution; (iii) passing a third salt solution through the column to at least partially remove nitrate ions from the column forming a third effluent solution, wherein the third salt solution has a salt concentration higher than the second salt solution.
Abstract: The present invention provides a polytetrafluoroethylene powder having high dispersibility in lubricants. The polytetrafluoroethylene powder includes polytetrafluoroethylene containing a tetrafluoroethylene unit alone or a tetrafluoroethylene unit and a modifying monomer unit based on a modifying monomer copolymerizable with the tetrafluoroethylene, and has a specific surface area of 32 m2/g or larger.
Abstract: A curable composition is provided. The curable composition has at least one functionalized fluoropolyether and at least one radical curing system. Further provided are fluoroelastomer compositions having a glass transition temperature of less than ?40° C. and shaped articles comprising fluoroelastomers having glass transition temperatures of less than ?40° C. obtained by curing the curable compositions. Also described are methods of making fluoroelastomer compositions having glass transition temperatures of less than ?40° C.
Type:
Grant
Filed:
March 13, 2012
Date of Patent:
February 27, 2018
Assignee:
3M INNOVATIVE PROPERTIES COMPANY
Inventors:
Steven G. Corveleyn, Miguel A. Guerra, Rudolf J. Dams, Tom Opstal
Abstract: A polymeric ionic liquid has a formula (I), where A1, A2, B, k, Q, and Z are as defined in the specification. An intermediate polymer for making the polymeric ionic liquid, a process for producing the polymeric ionic liquid, a process for producing a polymer membrane including the polymeric ionic liquid, a process for preparing a gel polymer electrolyte including the polymer membrane, and a binder including the polymeric ionic liquid are also disclosed.
Type:
Grant
Filed:
September 28, 2015
Date of Patent:
February 13, 2018
Assignees:
NATIONAL CHENG KUNG UNIVERSITY, RISING CHEMICAL CO., LTD.
Abstract: Antenna modules that contain composite meta-material dielectric bodies that have high effective values of real permittivity and reductions in physical lengths of electrically conducting elements.
Abstract: A fluorinated copolymer excellent in adhesion and elongation deformation processability. This fluorinated copolymer has carbonyl groups, its melting point is from 120 to 230° C., the ratio (X/W) of the melt tension X (N) to the load W (N) at the time of measuring the melt tension X, is from 0.5×10?4 to 2.0×10?4, it contains units derived from the following monomers (a), (b), and (c), the molar ratio of the units derived from the monomer (a) to the units derived from the monomer (b) is from 30/70 to 70/30, and the total content of the units derived from the monomer (a) and the units derived from the monomer (b) is from 80 to 99.995 mol % based on the total of all units (a), (b) and (c): Monomer (a): tetrafluoroethylene; Monomer (b): ethylene; Monomer (c): a monomer having two or more polymerizable carbon-carbon double bonds.
Abstract: A method for making a device with a fibrous sheet includes a step of combining a fiber-forming resin with a carrier resin to form a resinous mixture. The fiber forming resin has a fluorinated backbone with a pendent CF2CF2—X group where X is a SO3H or SO2F. The carrier resin is a soluble polyamide. The resinous mixture is extruded to form an extruded resinous mixture. The extruded resinous mixture has fiber strands of the fiber-forming resin within the carrier resin. The extruded resinous mixture is contacted with water to separate the fiber strands of the fiber-forming resin from the carrier resin. Fiber forming strands are optionally cross-linked with ammonia and then are hydrolyzed to form ionomers.
Type:
Grant
Filed:
July 26, 2016
Date of Patent:
January 16, 2018
Assignee:
GM Global Technology Operations LLC
Inventors:
Timothy J. Fuller, Frank D. Coms, Cristin L. Keary
Abstract: A multi-acid monomer disclosed herein has the formula wherein R is one or more units of a non-SO2F or non-SO2Cl portion of a polymer precursor in sulfonyl fluoride or sulfonyl chloride form, X is a non-sulfonyl halide group of a multi-sulfonyl halide compound having a minimum of two acid giving groups, and Y is remaining sulfonyl halide groups of the multi-sulfonyl halide compound.
Abstract: An improved process for forming a PTFE mat is described. The process includes providing a dispersion with PTFE, a fiberizing polymer and a solvent wherein said dispersion has a viscosity of at least 50,000 cP. An apparatus is provided which comprises a charge source and a target a distance from the charge source. A voltage source is provided which creates a first charge at the charge source and an opposing charge at the target. The dispersion is electrostatically charged by contact with the charge source. The electrostatically charged dispersion is collected on the target to form a mat precursor which is heated to remove the solvent and the fiberizing polymer thereby forming the PTFE mat.
Type:
Grant
Filed:
March 3, 2015
Date of Patent:
January 2, 2018
Assignee:
Zeus Industrial Products, Inc.
Inventors:
Bruce L. Anneaux, Robert L. Ballard, David P. Garner
Abstract: An anion-conducting polymeric membrane comprises a terpolymer of styrene, vinylbenzyl-Rs and vinylbenzyl-Rx. Rs is a positively charged cyclic amine group. Rx is at least one constituent selected from the group consisting Cl, OH and a reaction product between an OH or Cl and a species other than a simple amine or a cyclic amine. The total weight of the vinylbenzyl-Rx groups is greater than 0.3% of the total weight of the membrane. In a preferred embodiment, the membrane is a Helper Membrane that increases the faradaic efficiency of an electrochemical cell into which the membrane is incorporated, and also allows product formation at lower voltages than in cells without the Helper Membrane.
Type:
Grant
Filed:
January 6, 2017
Date of Patent:
December 26, 2017
Assignee:
Dioxide Materials, Inc.
Inventors:
Richard I. Masel, Syed Dawar Sajjad, Yan Gao, Zengcai Liu, Qingmei Chen
Abstract: The amorphous inorganic anion exchanger of the present invention is represented by Formula (1) and has an average primary particle size observed with an electron microscope of at least 1 nm but no greater than 500 nm and an NO3 content of no greater than 1 wt % of the whole: BiO(OH)??Formula (1).
Type:
Grant
Filed:
June 13, 2013
Date of Patent:
December 26, 2017
Assignee:
TOAGOSEI CO., LTD.
Inventors:
Kentarou Miyamura, Tomohisa Iinuma, Yasuharu Ono
Abstract: A polymer composition containing a polymer (B) obtained by polymerizing a monomer composition containing: a methacrylic acid ester macromonomer (b1) represented by the following formula (1); and another monomer (b2). Also, a porous membrane formed from a membrane forming polymer (A) and the aforementioned polymer composition.
Abstract: Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.
Type:
Grant
Filed:
July 26, 2016
Date of Patent:
December 19, 2017
Assignee:
The United States of America, as represented by the Secretary of the Navy
Abstract: Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.
Type:
Grant
Filed:
July 26, 2016
Date of Patent:
December 12, 2017
Assignee:
The United States of America, as represented by the Secretary of the Navy
Abstract: An underfill film material and a method for manufacturing a semiconductor device using the same which enables voidless mounting and favorable solder bonding properties are provided. An underfill material is used which contains an epoxy resin, an acid anhydride, an acrylic resin and an organic peroxide, the underfill material exhibits non-Bingham fluidity at a temperature ranging from 60° C. to 100° C., a storage modulus G? measured by dynamic viscosity measurement has an inflection point in an angular frequency region below 10E+02 rad/s, and the storage modulus G? in the angular frequency below the inflection point is 10E+05 Pa or more and 10E+06 Pa or less. This enables voidless packaging and excellent solder connection properties.
Abstract: The invention relates to a method of producing monodisperse amidomethylated vinylaromatic bead polymers, to ion exchangers prepared from these monodisperse amidomethylated vinylaromatic bead polymers by alkaline hydrolysis, to the method of using said monodisperse amidomethylated vinylaromatic bead polymers in the manufacture of ion exchangers and chelating resins, and also to the method of using these ion exchangers in the removal of heavy metals and noble metals from aqueous solutions or gases.
Type:
Grant
Filed:
August 8, 2014
Date of Patent:
December 5, 2017
Assignee:
LANXESS DEUTSCHLAND GMBH
Inventors:
Reinhold Klipper, Wolfgang Zarges, Olaf Halle, Michael Schelhaas
Abstract: Provided is a cation exchange membrane having a stable ion exchange performance during usage, being excellent in basic properties such as membrane resistance and ion transportation as well as strength, and useful for electrodialysis and a method for producing the same. The cation exchange membrane is composed of a polyvinyl alcohol copolymer including an anionic group-containing anionic polymer segment and a vinyl alcohol polymer segment, and having a microphase separation structure having a domain size (X) in a range from 0 nm<X?150 nm. The method is composed of forming a membrane from a polyvinyl alcohol copolymer which is adjusted to contain salts in a proportion that the salt weight (C) relative to the polyvinyl alcohol copolymer weight (P) is [(C)/(P)] of 4.5/95.5 or lower.
Type:
Grant
Filed:
April 8, 2015
Date of Patent:
December 5, 2017
Assignees:
KURARAY CO., LTD., YAMAGUCHI UNIVERSITY
Abstract: Provided is a fluorine-containing resin particle dispersion including: fluorine-containing resin particles, a resin which is not dissolved in at least one solvent in a group of hydroxyl group-containing solvents including an alcohol-based solvent having 1 to 10 carbon atoms, containing no aromatic ring in the molecule structure, and a water-based medium, and which is adhered on the surface of the fluorine-containing resin particles, and at least one solvent, in which the resin is not dissolved, in the group of hydroxyl group-containing solvents, in which the fluorine-containing resin particles having the resin adhered on the surface thereof are dispersed.
Abstract: A process for the reactivation of an acidic ion exchange resin is described. The invention relates to the treatment of an at least partially deactivated resin which has been deactivated by contact with an impure ethylenically unsaturated acid or ester containing target impurities. The reactivation includes the step of contacting the at least partially deactivated resin with an alcohol to thereby increase the activity thereof. The invention extends to reactivating a resin deactivated by contact with an impure ethylenically unsaturated acid, ester or nitrile containing target impurities by contacting the at least partially deactivated resin with an alcohol and a carboxylic acid to thereby increase the activity thereof. A reactivated resin and a process for preparing and purifying an ethylenically unsaturated acid or ester of the following formula: R1—C(?(CH2)m)—COOR2 are also described.