Abstract: Processes, systems, and associated control methodologies are disclosed that control the flow of biogas during the biogas cleanup process to create a more consistent flow of biogas through the digester, while also optimizing the output and efficiency of the overall renewable natural gas facility. In representative embodiments, a biogas buffer storage system may be used during the cleanup process to control the pressure and flow rate of biogas. The biogas buffer storage system may monitor and control the biogas flow rate to either bring down or increase the digester pressure, thereby maintaining a normalized biogas flow rate.

Abstract: A system and method for producing methanol via dry reforming and methanol synthesis in the same vessel, including converting methane and carbon dioxide in the vessel into syngas including hydrogen and carbon monoxide via dry reforming in the vessel, cooling the syngas via a heat exchanger in the vessel, and synthesizing methanol from the syngas in the vessel.

Abstract: The present invention provides a Fischer-Tropsch catalyst comprising greater than about 40% by weight of cobalt, and having a packed apparent bulk density greater than about 1.30 g/mL.

Abstract: The present disclosure provides a method for co-production of hydrofluorocarbons, which includes the steps of: preheating a mixture of chlorinated olefin and hydrogen fluoride; transferring the mixture to the top of a reactor; simultaneously introducing 1,1,1,2,3,3-hexafluoropropene and dichloromethane to the middle of the reactor for reaction; dividing the reactor into three to six sections; filling each section with a catalyst; obtaining reaction products at an outlet of the reactor; and separating the reaction products to obtain various hydrofluorocarbon products, respectively. The present disclosure has the advantages of a high yield, an optimal selectivity and a low energy consumption.

Abstract: A method, a system, and an apparatus of certain embodiments are provided to recover water and carbon dioxide from combustion emissions. The recovery includes, among other things, electrolysis and carbon dioxide capture in a suitable solvent. The recovered water and carbon dioxide are subject to reaction, such as a catalytic methanation reaction, to generate at least methane.

Abstract: Device and process for converting a feedstock of aromatic compounds, in which the feedstock is notably treated using a fractionation train (4-7), a xylenes separating unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon-based feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO2 and H2; a WGS water gas shift reaction section (50) suitable for treating the pyrolysis gas and for producing a WGS gas enriched in CO2 and in hydrogen; a CO2 aromatization reaction section (52) suitable for: at least partly treating the WGS gas to produce a hydrocarbon effluent comprising aromatic compounds, and feeding the feedstock with the hydrocarbon effluent.

Abstract: Provided herein are synthetic methods for the preparation of intermediates that are utilized in the synthesis of omecamtiv mecarbil dihydrochloride.

Abstract: The object is to selectively separate a linear compound from a treatment subject containing linear and alicyclic compounds as double bond-containing hydrocarbon compounds in which every hydrogen is replaced with fluorine or chlorine. A method of separating a double bond-containing linear hydrocarbon in which every hydrogen is replaced with fluorine or chlorine includes bringing a treatment subject containing a double bond-containing linear hydrocarbon in which every hydrogen is replaced with fluorine or chlorine and a double bond-containing alicyclic hydrocarbon in which every hydrogen is replaced with fluorine or chlorine into contact with at least one amine compound selected from the group consisting of a heterocyclic aromatic amine compound and a tertiary amine represented by a formula: NR1R2R3 (R1, R2, and R3 are each independently an alkyl group, and two thereof may in combination form an alkylene group that is optionally interrupted by oxygen or sulfur).

Abstract: The present invention features a direct synthesis of light olefins through the hydrogenation of carbon dioxide. In2O3 supported on cubic phase yttria-stabilized zirconia is used as a catalyst and is mixed with a molecular sieve to perform the hydrogenation. The cubic crystal structure of the yttria-stabilized zirconium dioxide is an excellent support for indium oxide particles and prevents their deactivation during CO2 hydrogenation. This direct synthesis route promotes a stable and efficient method for producing light olefins.

Abstract: A method for preparing methyl methacrylate from methacrolein and methanol. The process comprises contacting in a reactor a mixture comprising methacrolein, methanol and oxygen with a heterogeneous catalyst comprising a support and a noble metal, wherein said catalyst has an average diameter of at least 200 microns, liquid and gaseous reactants flow downward in the reactor and wherein the continuous phase in the reactor is a gas which has no more than 7.5 mol % oxygen at reactor inlets.

Abstract: A system and method for producing liquid hydrocarbons is disclosed. In one embodiment, the system includes at least one renewable power system configured to generate a DC electric power output; at least one water electrolysis system in electrical communication with the renewable power system and configured to utilize the DC electric power to produce a hydrogen output; and a liquid hydrocarbon synthesis system in fluid communication with the water electrolysis system and configured to utilize the hydrogen output and a carbon dioxide feed to produce a liquid hydrocarbon product.

Abstract: Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.

Abstract: A system and method for treating flue gas of a boiler based on solar energy are provided, wherein a heat pump is connected with a heat collector via first and second valves, a carbon dioxide electrolysis chamber is connected with a flue gas pretreatment chamber and a power distribution control module for electrolyzing and reducing carbon dioxide, a gas phase separation chamber is connected with a gas phase outlet to separate a mixture, and discharge the separated gas phase products; a Fischer-Tropsch reaction chamber is connected with the gas phase separation chamber to pass the separated carbon monoxide and hydrogen into a flowing reaction cell, a liquid phase product separation chamber is connected with a liquid phase outlet to separate the liquid phase hydrocarbon fuel products, and separate and supplement electrolyte; an electrolyte cooling circulation chamber is connected with the liquid phase product separation chamber.

Abstract: A processing facility is provided. The processing facility includes an asphaltenes and metals (AM) removal system configured to process a feed stream to produce a power generation stream, a hydroprocessing feed stream, and an asphaltenes stream. A power generation system is fed by the power generation feed stream. A hydroprocessing system is configured to process the hydroprocessing feed stream to form a gas stream and a liquid stream. A hydrogen production system is configured to produce hydrogen, carbon monoxide and carbon dioxide from the gas feed stream. A carbon dioxide conversion system is configured to produce synthetic hydrocarbons from the carbon dioxide, and a cracking system is configured to process the liquid feed stream.

Abstract: Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

Abstract: A novel branched fluorine-containing compound represented by formula (1): wherein L represents a predetermined carbon-containing linker moiety; Rf, in each occurrence, is the same or different and represents fluoroalkyl optionally having at least one ether bond; Y, in each occurrence, is the same or different and represents a predetermined divalent linking group or a bond; RY, in each occurrence, is the same or different and represents hydrogen or an organic group; L represents an (n1+n2)-valent carbon-containing linker moiety having at least one carbon atom; n1 represents a number greater than or equal to 1; n2 represents a number greater than or equal to 1; n1+n2 is a number from 3 to 6; X, in each occurrence, is the same or different and represents a divalent linking group or a bond; A, in each occurrence, is the same or different and represents -ArSO3M or the like; M, in each occurrence, is the same or different and represents hydrogen, —NR4, or a metal salt; and R represents hydrogen or a C1-4 organi

Abstract: Described herein are catalysts relating to liquid synthesis, methods of their preparation, and methods of their use. In an embodiment according to the present disclosure, a method of producing a catalyst for liquid synthesis comprises: providing a silica oxide support; pretreating the silica oxide support to remove air and moisture; impregnating the pretreated silica oxide support with cobalt from a cobalt source using a cobalt impregnation method; and calcinating the impregnated silica oxide support in an oven with a temperature ramping profile, wherein the calcinating comprises feeding air into the oven.

Abstract: Proposed are a process and a plant for producing a synthesis gas product stream having an adjustable H2/CO ratio and a pure hydrogen stream, wherein it is provided according to the invention that a substream of a deacidified synthesis gas stream is supplied to a membrane separation plant fitted with a hydrogen-selective membrane and the remaining substream is supplied to a pressure swing adsorption plant, wherein the latter affords a pure hydrogen stream and a fuel gas stream. The hydrogen-enriched permeate stream obtained from the membrane separation is likewise supplied to the pressure swing adsorption plant, thus enhancing the yield of pure hydrogen. The hydrogen-depleted retentate stream obtained from the membrane separation is discharged as a synthesis gas product stream and if of a suitable composition may be utilized as oxo gas.

Abstract: A process produces methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for producing polymers and copolymers with other polymerizable compounds. An optimized workup of the reactor discharge from the oxidative esterification of methacrolein allows for co-discharged fine catalyst particles to be very efficiently separated and optionally removed or recycled. In addition, this process can reduce the formation of byproducts in extended continuous operation compared to known variant. A reactor system contains stirrer configurations which allow virtually abrasion-free operation and thus a catalyst on-stream time of several years.

Abstract: Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.