Patents Examined by Janis L. Dote
  • Patent number: 9841692
    Abstract: Provided is a toner having a toner particle that contains a binder resin, a colorant, a wax, and a crystalline polyester, wherein two or more peak tops for crystallization peaks are present in a temperature range from 40° C. to 80° C. in a first DSC curve obtained by a process or cooling the toner from 100° C. to 20° C. at 0.5° C./min, and using ?H(0.5) for the exothermic quantity for the peak on the lowest temperature side of these crystallization peaks and using ?H(100) for the exothermic quantity of the crystallization peak on the lowest temperature side in a second DSC curve obtained by a process of cooling the toner from 100° C. to 20° C. at 100° C./min, the ratio [?H(100)/?H(0.5)] is at least 2.0 and not more than 6.0.
    Type: Grant
    Filed: September 6, 2016
    Date of Patent: December 12, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Yusuke Hasegawa, Tomohisa Sano, Yoshitaka Suzumura, Kozue Uratani, Yuujirou Nagashima
  • Patent number: 9841691
    Abstract: A method of manufacturing an electrostatic latent image developing toner made of a binding resin made of an amorphous resin and a crystalline resin, and toner particles containing a releasing agent and a coloring agent, the method includes: adding a monomer for forming the amorphous resin, in an aqueous medium, under presence of the fine particles containing the crystalline resin, and performing polymerization to obtain coated resin fine particles that are fine particles containing the crystalline resin, the fine particles being coated with the amorphous resin; and flocculating and fusing at least fine particles containing the amorphous resin, the coated resin fine particles, and fine particles containing the coloring agent, in an aqueous medium, under presence of a flocculating agent, to obtain the toner particles, wherein a surfactant having concentration of one to five times critical micellar concentration is added to the aqueous medium in the polymerization.
    Type: Grant
    Filed: August 27, 2015
    Date of Patent: December 12, 2017
    Assignee: KONICA MINOLTA, INC.
    Inventors: Mikio Kouyama, Hiroyuki Fukuda, Shiro Hirano, Asao Matsushima
  • Patent number: 9835964
    Abstract: The present invention provides a toner that exhibits an excellent colorant dispersibility and hence maintains the formation of a high-quality image, that is capable of low-temperature fixing, and that has a satisfactory heat-resistant storability and a satisfactory durability, in which the toner comprising a toner particle that contains a colorant and a binder resin containing a styrene-acrylic resin and a crystalline resin, wherein a compatibility parameter (V) between the styrene-acrylic resin and the crystalline resin satisfies 0.40?V?1.10.
    Type: Grant
    Filed: November 26, 2014
    Date of Patent: December 5, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Yu Yoshida, Masatake Tanaka, Yoshihiro Nakagawa, Naoya Isono, Tsutomu Shimano, Shintaro Noji
  • Patent number: 9829818
    Abstract: Provided is a toner that uses a crystalline resin, and demonstrates favorable dispersibility of the crystalline resin in the toner, demonstrates superior low-temperature fixability, and is able to inhibit fogging. The toner has a toner particle comprising a resin A, which has a long-chain alkyl group having an average number of carbon atoms of 27 to 50, and a crystalline resin, wherein the SP value (cal/cm3)1/2 of the crystalline resin is 9.00 to 12.00, and in a GC/MS analysis of components that volatize when the toner is heated for 10 minutes at 200° C., the amount of volatile components of saturated hydrocarbons having 30 to 37 carbon atoms is 90 ppm to 260 ppm of toluene equivalent, based on mass.
    Type: Grant
    Filed: September 14, 2015
    Date of Patent: November 28, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Daisuke Yoshiba, Katsuhisa Yamazaki, Koji Nishikawa, Shotaro Nomura, Hiroki Akiyama, Masami Fujimoto
  • Patent number: 9823595
    Abstract: Provided is a toner including toner particle, the toner particle having a core-shell structure having: a core containing a core resin, a colorant, and a wax; and a shell layer containing a resin “A” on a surface of the core, in which: the resin “A” contains a segment having an organopolysiloxane structure; the toner particle has an amount of Si derived from the organopolysiloxane structure of 6.0 or more and 10.0 or less, the amount of Si being measured by X-ray photoelectron spectroscopy; the resin “A” is a polymer of a monomer composition containing a monomer “a” having two or more polymerizable unsaturated groups in one molecule thereof; and the monomer “a” satisfies the following formula (1). (Xa?1.0)×Ya?3.
    Type: Grant
    Filed: June 8, 2016
    Date of Patent: November 21, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Noritaka Toyoizumi, Yusuke Kosaki, Tetsuya Kinumatsu, Kenji Aoki, Shuntaro Watanabe, Takaaki Kaya, Atsushi Tani, Takashige Kasuya
  • Patent number: 9811010
    Abstract: An electrophotographic photosensitive member includes a conductive base and a single-layer-type photosensitive layer on the conductive base. The photosensitive layer contains a binder resin, a charge generation material, a hole transport material, a fluorine-atom-containing electron transport material, and fluorine-atom-containing resin particles. An amount of the charge generation material in the photosensitive layer is 0.5% by weight or more and less than 2.0% by weight. The charge generation material has a distribution that satisfies Formula (1): 30?a/b in a thickness direction of the photosensitive layer where a and b are as defined in the specification, and b may be 0. The fluorine-atom-containing electron transport material has a distribution that satisfies Formula (2): 30?c/d in the thickness direction of the photosensitive layer where c and d are as defined in the specification, and d may be 0.
    Type: Grant
    Filed: February 5, 2016
    Date of Patent: November 7, 2017
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Yasuhiro Niida, Kazuyuki Tada, Jiro Korenaga, Yukimi Kawabata
  • Patent number: 9811011
    Abstract: Provided are an electrophotographic photosensitive member comprising: a support, an undercoat layer formed on the support, and a photosensitive layer formed on the undercoat layer, on which the undercoat layer contains one of a compound represented by the formula (1) and a polymer of a composition containing the compound represented by the formula (1).
    Type: Grant
    Filed: June 16, 2016
    Date of Patent: November 7, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Masashi Nishi, Kunihiko Sekido, Michiyo Sekiya, Kei Tagami, Akihito Saitoh
  • Patent number: 9811017
    Abstract: A low melt toner includes a core having a core polystyrene-butyl acrylate resin, a crystalline polyester resin, a pigment present in an amount from about 7% to about 20% by weight of the low melt toner, and a paraffin wax; a ratio of the polystyrene-butyl acrylate resin to crystalline polyester resin is in a range from about 5:1 to about 7:1; and a shell disposed over the core including a shell polystyrene-butyl acrylate resin.
    Type: Grant
    Filed: February 26, 2016
    Date of Patent: November 7, 2017
    Assignee: XEROX CORPORATION
    Inventors: Christopher M. Wolfe, Padam K. Angra, Jacob W. Myers, II
  • Patent number: 9804513
    Abstract: The present disclosure provides processes for producing toners by emulsion aggregation where the resulting toner particles have high pigment loadings and desired circularity. The methods include adding a metal, in embodiments a metal salt, at the beginning of coalescence, which surprisingly speeds the coalescence process and produces toner particles having a desired size and circularity for use in electrophotographic imaging systems.
    Type: Grant
    Filed: July 10, 2014
    Date of Patent: October 31, 2017
    Assignee: Xerox Corporation
    Inventors: Daryl Vanbesien, Yixin Gong, Karen A Moffat, Richard P N Veregin, Cuong Vong, Jordan H Wosnick, Suxia Yang
  • Patent number: 9804515
    Abstract: A toner of the present invention includes at least a colorant and a resin, has crystallinity CX or 20 or greater, and has a dynamic viscoelasticity characteristic in which a logarithmic value Log G?(50) of storage elastic modulus (Pa) at 50° C. is from 6.5 to 8.0 and a logarithmic value Log G?(65) of storage elastic modulus (Pa) at 65° C. is from 4.5 to 6.0, when the dynamic viscoelasticity characteristic is measured by temperature sweep from 40° C., at a frequency of 1 Hz, at a strain amount control of 0.1%, and at a temperature elevating rate of 2° C./min.
    Type: Grant
    Filed: August 30, 2013
    Date of Patent: October 31, 2017
    Assignee: Ricoh Company, Ltd.
    Inventors: Hideki Sugiura, Shinya Nakayama, Toyoshi Sawada
  • Patent number: 9791793
    Abstract: A triphenylamine derivative is represented by general formula (1). In the general formula (1): R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 each represent, independently of one another, a hydrogen atom, an optionally substituted alkyl group having a carbon number of at least 1 and no greater than 6, an optionally substituted alkoxy group having a carbon number of at least 1 and no greater than 6, an optionally substituted alkenyl group having a carbon number of at least 2 and no greater than 6, or an optionally substituted aryl group having a carbon number of at least 6 and no greater than 14; m represents an integer of at least 1 and no greater than 3; and n represents an integer of at least 0 and no greater than 2.
    Type: Grant
    Filed: July 21, 2016
    Date of Patent: October 17, 2017
    Assignee: KYOCERA Document Solutions Inc.
    Inventor: Hideki Okada
  • Patent number: 9791794
    Abstract: A toner includes a base particle comprising a crystalline polyester resin; and an external additive which is a group of silica particles having a number-average particle diameter of from 0.01 ?m to 0.11 ?m on the surface of the toner. A number ratio of the silica particles having a circularity not less than 0.8 is 20% or more in the total number of the silica particles.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: October 17, 2017
    Assignee: Ricoh Company, Ltd.
    Inventors: Junichi Watanabe, Kenji Yoneda, Kohsuke Satoh, Tsuneyasu Nagatomo, Keiji Makabe, Daichi Hisakuni
  • Patent number: 9785069
    Abstract: An image forming apparatus includes a developing unit that contains an electrostatic charge image developer and develops an electrostatic charge image formed on the surface of an image holding member as a toner image by using the developer, wherein the developer contains a carrier and an electrostatic charge image developing toner that includes a toner particle and an external additive, the toner particles have an average circularity of from 0.98 to 1.00 and a number-particle diameter distribution index (lower GSD) on a small diameter side of 1.22 or more and contain at least a vinyl resin, and the external additive contains silica particles having a compression aggregation degree of 60% to 95% and a particle compression ratio of 0.20 to 0.40.
    Type: Grant
    Filed: July 27, 2016
    Date of Patent: October 10, 2017
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Yoshifumi Iida, Hiroyoshi Okuno, Satoshi Inoue, Tomohito Nakajima, Yuka Zenitani, Yoshifumi Eri, Takeshi Iwanaga, Sakae Takeuchi, Shunsuke Nozaki, Yasuo Kadokura, Yasuhisa Morooka
  • Patent number: 9785072
    Abstract: An electrophotographic toner which is excellent in grindability, fixing property and durability by being obtained via a step of melt-kneading a mixture containing an amorphous bioplastic having a weight-average molecular weight (Mw) of 55000 to 120000, a terpene phenol resin, and a styrene acrylic resin having a weight-average molecular weight (Mw) of 85500 to 118000 so as to obtain a kneaded mixture, and a step of grinding the kneaded mixture after hardening.
    Type: Grant
    Filed: March 20, 2015
    Date of Patent: October 10, 2017
    Assignee: CASIO COMPUTER CO., LTD.
    Inventors: Kenji Kihira, Hideki Ikeda, Yuichiro Iegaki, Yuta Kan, Hideki Hasegawa
  • Patent number: 9785073
    Abstract: A developer having low-temperature fixability and storage stability, and capable of prolonging the service life is provided. A toner includes a coloring agent, an amorphous polyester, a crystal line polyester, ester wax containing multiple ester compounds, each having a carbon number selected from 32 to 54, and hydrophobic silica having an average primary particle diameter of 8 to 35 nm. When the ion intensity ratio of each ester compound having a different carbon number is expressed as percentage, the content (a) of the ester compound having a carbon number of (Cn) showing the maximum intensity ratio is from 20 to 55% by weight of the entire ester wax, the sum (g) of the content (e) of the ester compound having a carbon number of (Cn+2) and the content (f) of the ester compound having a carbon number of (Cn+4) satisfies the following formula: 0.065?g/a?0.200.
    Type: Grant
    Filed: April 8, 2015
    Date of Patent: October 10, 2017
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Koichi Kuroyama, Tsutomu Katsumata
  • Patent number: 9785075
    Abstract: Provided is a toner containing a binder resin. The binder resin contains a crystalline resin. The toner has a maximum endothermic peak temperature (P1) of from 50° C. to 80° C. and a total endothermic amount (Q) of from 35 J/g to 90 J/g at a first temperature elevation of differential scanning calorimetry. A ratio (Qp/Q) of a total endothermic amount (Qp) of the toner in a temperature range of from 20° C. to the maximum endothermic peak temperature (P1) to the total endothermic amount (Q) of the toner is from 0.65 to 0.83.
    Type: Grant
    Filed: October 11, 2013
    Date of Patent: October 10, 2017
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinya Nakayama, Atsushi Yamamoto, Minoru Masuda, Susumu Chiba, Toyoshi Sawada, Hiroshi Yamashita
  • Patent number: 9785068
    Abstract: The toner has a toner particle that contains a binder resin and a wax, wherein the wax is present in domain form in the interior of the toner particle; the proportion of toner particles for which the position of the wax domains are controlled, is in a prescribed range; using d for a major axis length of the domain having the largest major axis length and using D for a number-average particle diameter of the toner, the d and D satisfy a prescribed relationship; and the ratio between the major axis length and the minor axis length of the domain having the largest major axis length is in a prescribed range.
    Type: Grant
    Filed: August 24, 2016
    Date of Patent: October 10, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Noriyoshi Umeda, Takeshi Kaburagi, Naotaka Ikeda, Hirofumi Kyuushima, Shohei Shibahara, Yoshiaki Wada
  • Patent number: 9778584
    Abstract: According to one example of the present application, there is provided a toner for developing an electrostatic charge image, containing: a toner particle containing a binder resin; a particle adhering to a surface of the toner particle; and an elastomer particle containing one or more kinds of oil, wherein a volume particle size distribution index GSDT (D50T/D16T) on a small diameter side of the toner particle and a volume particle size distribution index GSDE (D50E/D16E) on a small diameter side of the elastomer particle satisfy Formula (1): GSDE/GSDT?1.
    Type: Grant
    Filed: August 18, 2015
    Date of Patent: October 3, 2017
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Emi Matsushita, Fusako Kiyono, Shintaro Anno, Hiroki Omori
  • Patent number: 9772574
    Abstract: A toner includes toner particles. The toner particles each include a toner core, silica particles located on a surface of the toner core, and a shell layer disposed over the surface of the toner core on which the silica particles are located. For at least 80% by number of the toner particles, along at least 80% of a circumferential length of a cross-section of the toner particle when the cross-section is analyzed by EELS, the shell layer has a thickness of at least 5 nm and satisfies a condition that a ratio of an intensity INc relative to an intensity INs is at least 0.0 and no greater than 0.2. The intensity INs indicates intensity of an N—K shell absorption-edge originating from nitrogen atoms in the shell layer. The intensity INc indicates intensity of an N—K shell absorption-edge originating from nitrogen atoms in the toner core.
    Type: Grant
    Filed: December 16, 2014
    Date of Patent: September 26, 2017
    Assignee: KYOCERA Document Solutions Inc.
    Inventors: Ryota Kobayashi, Masami Tsujihiro
  • Patent number: 9766563
    Abstract: The toner according to the present invention is used for electrostatic latent image development, and has toner particles containing a binder resin, a colorant and a release agent. The binder resin is composed of a non-crystalline resin and a crystalline resin. The toner satisfies the relationship represented by specific expressions specified by the endothermic property of the crystalline resin, the endothermic property of the toner and the content ratio of the binder resin in the toner particles.
    Type: Grant
    Filed: July 10, 2015
    Date of Patent: September 19, 2017
    Assignee: KONICA MINOLTA, INC.
    Inventors: Mikio Kouyama, Hiroyuki Fukuda, Shiro Hirano, Asao Matsushima