Abstract: Systems and methods for processing one or more hydrocarbons are provided. In one or more embodiments, the method can include thermally converting a hydrocarbon comprising methane to produce a first product comprising acetylene. The method can also include hydrogenating the first product to produce a second product comprising ethylene. The method can further include catalytically reacting the second product with one or more butene products to produce a third product comprising propylene.
Abstract: A configuration includes two exhaust gas treatment devices disposed in succession in an exhaust gas line. A first exhaust gas treatment device has a first subregion connected through at least one support body to a second subregion of a second exhaust gas treatment device. The support body has opposite ends connected by connections points to respective subregions. At least the second subregion is formed by metallic components that contact one another to form contact surfaces and at most 20% of the area of the contact surfaces have brazed or solder connections and/or diffusion connections.
Type:
Grant
Filed:
May 28, 2013
Date of Patent:
March 11, 2014
Assignee:
EMITEC Gesellschaft fuer Emissionstechnologie mbH
Abstract: A process for preparing isobutene including cleaving a mixture obtained from an MTBE-containing feedstock and/or an MTBE-containing stream, affording a stream of reaction products consisting of isobutene, methanol, MTBE and by-products, the latter consisting of a1) high boilers having a boiling range above 55° C. at a pressure of 0.1 MPa; a2) medium boilers having a boiling range of 12 to 55° C. at a pressure of 0.1 MPa; and a3) low boilers having a boiling range below 12° C. at a pressure of 0.1 MPa; distillatively separating into a stream which contains the isobutene product and low boilers, and a stream which contains MTBE, methanol, medium boilers and high boilers; distillatively separating to obtain an MTBE-containing stream and a methanol-containing high boiler stream; recycling an MTBE-containing stream in which the medium boilers being removed completely or partially before recycling.
Type:
Grant
Filed:
May 19, 2009
Date of Patent:
January 21, 2014
Assignee:
Evonik Oxeno GmbH
Inventors:
Markus Winterberg, Dirk Roettger, Rainer Bukohl, Holger Wiederhold, Walter Luh
Abstract: The present invention provides a method to produce olefins by the decarboxylation of organic carboxylic acids in the presence of an organopalladium catalyst.
Type:
Grant
Filed:
March 16, 2011
Date of Patent:
January 14, 2014
Assignee:
Iowa State University Research Foundation, Inc.
Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
Type:
Grant
Filed:
March 9, 2012
Date of Patent:
December 10, 2013
Assignee:
UOP LLC
Inventors:
David A. Wegerer, Kurt M. Vanden Bussche, Mark D. Moser
Abstract: A process to prepare propylene showing desirably increased selectivity comprises contacting, at an elevated temperature, ethanol and a rhenium oxide-modified ZSM-5 zeolite catalyst, under conditions suitable to form propylene. The rhenium oxide-modified ZSM-5 zeolite catalyst may be prepared by impregnating, in an aqueous or organic medium, a ZSM-5 zeolite with a rhenium source, under conditions suitable to form a catalyst precursor, and calcining the catalyst precursor under conditions suitable to form a rhenium oxide-modified ZSM-5 zeolite catalyst.
Type:
Grant
Filed:
March 7, 2011
Date of Patent:
December 3, 2013
Assignee:
Dow Global Technologies LLC
Inventors:
Yu Liu, Andrzej M. Malek, Albert E. Schweizer, Jr.
Abstract: Processes for upgrading condensate in a first hydrocarbon stream to provide distillate material may involve ionic liquid catalyzed olefin oligomerization of olefins in the first hydrocarbon stream to provide a first distillate enriched stream, dechlorination of the first distillate enriched stream, hydroprocessing at least one of a second and a third hydrocarbon stream to provide a second distillate enriched stream, and separation of a distillate product from the first and second distillate enriched streams.
Abstract: A process is provided for the production of hydrocarbons from synthesis gas wherein the synthesis gas is fed to a reactor in which a catalyst acts on the feed at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 5 bar. The feed includes a compound containing one or both nitrogen and phosphorus added to the reactor with the synthesis gas. The compound containing nitrogen typically constitutes at least 1 vol % and preferably of the order of 4 to 20 vol % or more of the feed. The carbonaceous gas may be carbon monoxide with a ratio of hydrogen to carbon monoxide in the synthesis gas of from 0.5:1 to 5:1. The catalyst is preferably a supported cobalt catalyst and may be modified with a promoter. The process produces an enhanced proportion of olefins, in the hydrocarbons produced.
Type:
Grant
Filed:
April 15, 2009
Date of Patent:
October 15, 2013
Assignee:
University of Cape Town
Inventors:
Michael Christian Maximillian Claeys, Eric Wilhelmus Josephus Van Steen, Frank Roessner, Andreas Karl Rausch
Abstract: There is provided a method for production of a conjugated diene from a monoolefin having four or more carbon atoms by a fluidized bed reaction. The method for production of a conjugated diolefin includes bringing a catalyst in which an oxide is supported on a carrier into contact with a monoolefin having four or more carbon atoms in a fluidized bed reactor in which the catalyst and oxygen are present, wherein the method satisfies the following (1) to (3): (1) the catalyst contains Mo, Bi, and Fe; (2) a reaction temperature is in the range of 300 to 420° C.; and (3) an oxygen concentration in a reactor outlet gas is in the range of 0.05 to 3.0% by volume.
Abstract: A process for the industrial isolation of propene from a gas stream comprising at least propene and propane, which involves contacting of the gas stream with an adsorbent having a porous metal organic framework having at least one at least bidentate organic compound coordinated to at least one metal ion, with the adsorbent becoming laden with propane and the gas stream therefore having an increased proportion of propene, wherein the W least bidentate organic compound is an imidazolate which is unsubstituted or has one or more substituents selected independently from of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, O-phenyl and O—C1-6-alkyl.
Type:
Grant
Filed:
July 17, 2009
Date of Patent:
September 10, 2013
Assignee:
BASF SE
Inventors:
Markus Schubert, Ingo Richter, Ulrich Mueller, Frank Poplow, William Dolan, Christoph Kiener