Abstract: There is provided a curable composition for forming an anti-reflective film. The composition includes: (a) hollow silica nanoparticles; (b) a siloxane binder having reactive groups; (c) at least one additional material having reactive groups; (d) an initiator; and (e) solvent. The siloxane binder is present in an amount that is at least 50% by weight of the total weight of (siloxane binder+additional materials having reactive groups). The weight ratio of hollow silica nanoparticles to the total of (siloxane binder+additional materials having reactive groups) is no greater than 1.75 to 1.
Abstract: The invention relates to a hydrogel based on vinyl caprolactam, with or without additional monomers, and at least two crosslinkers. The invention also relates to a method for obtaining said material and to the use thereof to culture cells/engineer cell monolayers, as well as supports for cell culture and transplant.
Type:
Grant
Filed:
October 6, 2020
Date of Patent:
February 7, 2023
Inventors:
Alberto Gallardo Ruiz, Juan Rodríguez Hernández, Helmut Reinecke, Carlos Elvira Pujalte, Carolina García Sánchez, Enríque Martínez Campos
Abstract: A radiation curable composition including at least one radiation hardenable component, a photo-initiator, and a filler material having a population of particulates in an amount greater than or equal to 50% by weight of the printable composition. The population of particulates exhibits a median diameter (D50) of greater than or equal to 0.3 micrometer on a volume-average basis as determined using the Particle Size Test Method, and the radiation curable composition exhibits a viscosity of less than or equal to 150 Pa s when measured using the Viscosity Test Method. A method, apparatus, and systems for producing composite articles by selectively exposing a portion of the radiation curable composition to a source of actinic radiation to at least partially cure the exposed portion of the radiation curable composition, thereby forming a hardened layer, preferably by an additive manufacturing process such as stereophotolithography, are also described. The composite articles may include composite dental restorations.
Type:
Grant
Filed:
August 22, 2018
Date of Patent:
January 17, 2023
Assignee:
3M Innovative Properties Company
Inventors:
Zeba Parkar, James D. Hansen, Tianyu Wu, Carsten Franke, Timothy D. Dunbar, Gregory A. Kobussen, Ahmed S. Abuelyaman, Bradley D. Craig
Abstract: A polymer composition is disclosed that comprises a polymer matrix containing at least one thermotropic liquid crystalline polymer and at least one hollow inorganic filler having a dielectric constant of about 3.0 or less at a frequency of 100 MHz wherein the weight ratio of the at least one thermotropic liquid crystalline polymer to the at least one hollow inorganic filler is from about 0.1 to about 10 and wherein the polymer composition exhibits a dielectric constant of about 4 or less and a dissipation factor of about 0.02 or less, as determined at a frequency of 10 GHz.
Abstract: A photocurable composition for three-dimensional stereolithography which has a lower viscosity and from which a cured product having a high refractive index is obtained, and a three-dimensional object formed by using the composition. The composition is a photocurable composition for three-dimensional stereolithography containing a fluorene monomer, a carbazole monomer, a diluent monomer, and a photopolymerization initiator, the carbazole monomer being contained in an amount of less than 30 wt % with respect to the total amount of the fluorene monomer and the carbazole monomer, and the diluent monomer being contained in an amount of at least 20 wt % with respect to total solids.
Type:
Grant
Filed:
July 28, 2017
Date of Patent:
January 17, 2023
Assignees:
NIKON CORPORATION, ESSILOR INTERNATIONAL
Abstract: Disclosed is an oligomer or polymer obtained by reacting at least one monomeric, oligomeric or polymeric isocyanate having two or more isocyanate groups with 2-hydroxy-3-butenoic acid and/or at least one alkyl ester of 2-hydroxy-3-butenoic acid. A composition comprising a said oligomer or polymer is also disclosed.
Type:
Grant
Filed:
August 30, 2018
Date of Patent:
January 10, 2023
Assignee:
PERSTORP AB
Inventors:
Stefan Lundmark, Pia Wennerberg, David James
Abstract: A curable composition comprises at least 10 wt % expanding monomers based on a total weight of the curable composition, at least 25 wt % acrylate monomers based on the total weight of the curable composition, a photoinitiator, and a photosensitizer. The acrylate monomers have a molecular weight of 500 or less. The curable composition has a viscosity of 10 cP or less. A total amount of the expanding monomers and the acrylate monomers are at least 90 wt % based on the total weight of the curable composition.
Abstract: An additive article stabilizing method includes prior to polymerization, adding a radiation-activated stabilizing composition to a liquid resin, forming the article from the liquid resin, layer by layer, using radiation such that the stabilizing composition does not stabilize the liquid resin but the formed article, and neutralizing free radicals generated during a degradation process initiated by exposure of the article to additional radiation post-cure.
Type:
Grant
Filed:
January 15, 2018
Date of Patent:
January 3, 2023
Assignee:
Ford Global Technologies, LLC
Inventors:
Emily Ann Ryan, Mark Edward Nichols, Ellen Cheng-Chi Lee, Christopher Michael Seubert, Deborah Frances Mielewski, Nicholas Ryan Gunther, Matthew Linden Bedell
Abstract: The disclosure provides a method for producing low molecular weight polytetrafluoroethylene containing less C6-C14 perfluorocarboxylic acids or salts thereof. The method for producing low molecular weight polytetrafluoroethylene includes: (1) irradiating high molecular weight polytetrafluoroethylene to provide low molecular weight polytetrafluoroethylene having a melt viscosity of 1.0×102 to 7.0×105 Pa·s at 380° C.; and (2) irradiating the low molecular weight polytetrafluoroethylene to a dose that does not decompose the low molecular weight polytetrafluoroethylene.
Abstract: A radiation curable polyurethane resin includes an ionic group, a polyalkylene oxide in a side chain thereof, and a (meth)acrylate or (meth)acrylamide having a hydroxyl functional group. The polyurethane resin is obtainable by reacting a polyester polyol, a polyether diol, a polyol containing an ionic group, a (meth)acrylate or (meth)acrylamide having a hydroxyl functional group, and a polyisocyanate. The polyester polyol is obtained by reacting a polycarboxylic acid and a polyol. The radiation curable polyurethane resin can be used as binder in an aqueous ink jet ink.
Type:
Grant
Filed:
November 29, 2018
Date of Patent:
January 3, 2023
Assignee:
AGFA NV
Inventors:
Hubertus Van Aert, Ellen Bertels, Johan Loccufier, Sara Matheussen
Abstract: Disclosed methods include formulating azobenzene-based polymer networks to induce a modulus change in a highly crosslinked polymer, in vivo, with no external heat requirement and using a benign light as the source of stimuli. A modulus change can be achieved via a coating on the substrate and within the bulk of the substrate via photoexposure. The azobenzene-based polymer network can be formed as a coating or in the bulk of a material from either a glassy composition comprising methyl methacrylate (MMA), poly (methyl methacrylate) (PMMA), and triethylene glycol dimethacrylate (TEGDMA) or a soft material comprising of long-chain difunctional acrylates. The disclosed technology also includes methods of biofilm disruption and removal from the surface of a substrate, and includes methods of inhibiting biofilm growth and cell attachment to a substrate.
Type:
Grant
Filed:
August 21, 2018
Date of Patent:
January 3, 2023
Assignee:
THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODY CORPORATE
Inventors:
Devatha Nair, Robert Mcleod, Sean Shaheen, Gannon Kehe, Michael Schurr, Ram Nagaraj
Abstract: The present invention relates to photosensitive compositions containing polynorbornene (PNB) polymers and certain additives that are useful for forming microelectronic and/or optoelectronic devices and assemblies thereof, and more specifically to compositions encompassing PNBs and certain multifunctional crosslinking agents, and two or more phenolic compounds which are resistant to thermo-oxidative chain degradation and exhibit improved mechanical properties.
Type:
Grant
Filed:
October 17, 2019
Date of Patent:
December 27, 2022
Assignee:
PROMERUS, LLC
Inventors:
Brian Knapp, Cheryl Burns, Carolyn Scherger
Abstract: The present application relates to a composition, which comprises: (a) a photopolymerizable substance; (b) a thiol; (c) a photoinitiator; (d) a thermosensitive polymer; and (e) water, and can be used as a bio-ink for preparing a bio-hydrogel for direct-writing 3D printing. The present invention further relates to a method for preparing the composition, and a direct-writing 3D printing method using the composition.
Abstract: Adhesive compositions that can be applied to substrates using inkjet printheads and cured to a hardened, tack-free state and readily rendered tacky on application of heat and pressure to accurately transfer foil to the substrates including one or more free-radical curing monomers, an oligomer/resin composition component including one or more oligomers and one or more inert thermoplastic resins that are soluble in the monomers, and, where required, one or more free radical photoinitiators.
Type:
Grant
Filed:
January 19, 2021
Date of Patent:
December 6, 2022
Assignee:
INX International Ink Co.
Inventors:
Jonathan Graunke, Xiang Liu, Rick Westrom
Abstract: A method for producing a polytetrafluoroethylene powder, which includes applying an ultrasonic wave to a polytetrafluoroethylene aqueous dispersion containing polytetrafluoroethylene particles to coagulate the polytetrafluoroethylene particles.
Abstract: A photosensitive resin composition is provided. The photosensitive resin composition is applied in a technical field of flexible display devices. The photosensitive resin composition comprises 5 to 50 parts by weight of an acrylate crosslink monomer, 0.2 to 0.6 parts by weight of an initiator, 5 to 8 parts by weight of a liquid pigment solid substance, 5 to 8 parts by weight of a resin, and 20 to 70 parts by weight of a solvent. The initiator is a radical initiator having a decomposition temperature less than 40° C. The acrylate crosslink monomer comprises a copolymerization two of aromatic group-containing and triol-containing acrylate polymerizable monomers for lowering a temperature of a following color filter preparing process. A method of preparing the photosensitive resin composition and a display device comprising the photosensitive resin composition are also provided.
Type:
Grant
Filed:
November 22, 2018
Date of Patent:
December 6, 2022
Assignee:
WUHAN CHINA STAR OPTOELECTRONICS SEMICONDUCTOR DISPLAY TECHNOLOGY CO., LTD.
Abstract: Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.
Type:
Grant
Filed:
April 21, 2020
Date of Patent:
December 6, 2022
Assignee:
Carbon, Inc.
Inventors:
Andrew Gordon Wright, Kai Chen, Bob E. Feller
Abstract: The present invention provides a curable compound including a pigment, a compound A, a photopolymerization initiator, a curable compound other than the compound A, and a resin, in which a content of the compound A in a total solid content of the curable composition is 1 to 15 mass %. The compound A is a compound having each of a coloring agent partial structure, an acid group or a basic group, and a curable group. The present invention further provides a method for producing the curable composition, a film formed of the curable composition, a color filter, a method for manufacturing a color filter, a solid-state imaging element, and an image display device.
Abstract: The present invention discloses a photo-crosslinked rubber composition and application thereof. The rubber composition comprises a rubber matrix and an initiator. Based on 100 parts by weight of the rubber matrix, the rubber matrix comprises a branched polyethylene with a content represented as A, in which 0<A?100, and an ethylene-propylene rubber with a content represented as B, in which 0?B<100; and the initiator accounts for 0.1-10 parts, and the initiator includes at least one of a cationic photoinitiator and a free radical photoinitiator. In the rubber composition, the ethylene-propylene rubber is partially or completely replaced by the branched polyethylene. The rubber composition can be used for rubber product crosslinked by ultraviolet light, including wire, cable, film, glove, condom, and medical catheter, which achieves excellent elasticity, electrical insulation property, aging resistance and ozone resistance, and also has good mechanical strength.
Abstract: The invention relates to a method for preparing a vinyl ether polymer by photo-initiated polymerization, which comprises the step of: under a protective atmosphere, performing photo-initiated polymerization on a vinyl ether monomer in the presence of an organic halogenated hydrocarbon and manganese carbonyl under irradiation of light having a wavelength of 365-550 nm at ?25° C. to 25° C., to obtain a vinyl ether polymer after the reaction is completed. In the method, a vinyl ether monomer is subjected to cationic polymerization in the presence of manganese carbonyl and an organic halogenated hydrocarbon under visible light, to prepare a vinyl ether polymer with controlled molecular weight and narrow molecular weight distribution.